CA2280221A1 - Process for the production of vinyl acetate - Google Patents

Process for the production of vinyl acetate Download PDF

Info

Publication number
CA2280221A1
CA2280221A1 CA002280221A CA2280221A CA2280221A1 CA 2280221 A1 CA2280221 A1 CA 2280221A1 CA 002280221 A CA002280221 A CA 002280221A CA 2280221 A CA2280221 A CA 2280221A CA 2280221 A1 CA2280221 A1 CA 2280221A1
Authority
CA
Canada
Prior art keywords
promoter
added
catalyst
weight
acetic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002280221A
Other languages
English (en)
French (fr)
Inventor
Bruce Leo Williams
George Frederick Salem
Simon James Kitchen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chemicals Ltd
Original Assignee
BP Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Chemicals Ltd filed Critical BP Chemicals Ltd
Publication of CA2280221A1 publication Critical patent/CA2280221A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/12—Acetic acid esters
    • C07C69/14—Acetic acid esters of monohydroxylic compounds
    • C07C69/145—Acetic acid esters of monohydroxylic compounds of unsaturated alcohols
    • C07C69/15—Vinyl acetate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8926—Copper and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/60—Platinum group metals with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/892—Nickel and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CA002280221A 1998-08-11 1999-08-10 Process for the production of vinyl acetate Abandoned CA2280221A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9817365.1 1998-08-11
GBGB9817365.1A GB9817365D0 (en) 1998-08-11 1998-08-11 Process for the production of vinyl acetate

Publications (1)

Publication Number Publication Date
CA2280221A1 true CA2280221A1 (en) 2000-02-11

Family

ID=10836991

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002280221A Abandoned CA2280221A1 (en) 1998-08-11 1999-08-10 Process for the production of vinyl acetate

Country Status (14)

Country Link
US (1) US6350901B1 (cg-RX-API-DMAC10.html)
EP (1) EP0985655B1 (cg-RX-API-DMAC10.html)
JP (1) JP2000063324A (cg-RX-API-DMAC10.html)
KR (1) KR100620298B1 (cg-RX-API-DMAC10.html)
CN (1) CN1216849C (cg-RX-API-DMAC10.html)
BR (1) BR9916139A (cg-RX-API-DMAC10.html)
CA (1) CA2280221A1 (cg-RX-API-DMAC10.html)
DE (1) DE69919285T2 (cg-RX-API-DMAC10.html)
ES (1) ES2226292T3 (cg-RX-API-DMAC10.html)
GB (1) GB9817365D0 (cg-RX-API-DMAC10.html)
MX (1) MXPA99007415A (cg-RX-API-DMAC10.html)
SA (1) SA99200625B1 (cg-RX-API-DMAC10.html)
SG (1) SG85663A1 (cg-RX-API-DMAC10.html)
TW (1) TW552253B (cg-RX-API-DMAC10.html)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0014584D0 (en) * 2000-06-14 2000-08-09 Bp Chem Int Ltd Apparatus and process
GB0014583D0 (en) 2000-06-14 2000-08-09 Bp Chem Int Ltd Process
US6420308B1 (en) * 2000-07-07 2002-07-16 Saudi Basic Industries Corp Highly selective shell impregnated catalyst of improved space time yield for production of vinyl acetate
US6794332B2 (en) * 2000-07-07 2004-09-21 Saudi Basic Industries Corporation Highly selective shell impregnated catalyst of improved space time yield for production of vinyl acetate
US6534438B1 (en) * 2000-07-26 2003-03-18 Bp Chemicals Limited Catalyst composition
EP1288188A1 (en) * 2001-08-28 2003-03-05 Avantium International B.V. Supported catalyst composition, processes for the preparation thereof and use of the supported catalyst composition
TWI304359B (en) * 2001-12-04 2008-12-21 Bp Chem Int Ltd Oxidation process in fluidised bed reactor
US7718811B2 (en) 2002-11-26 2010-05-18 Ineos Europe Limited Oxidation process in fluidised bed reactor
TW201240725A (en) * 2003-12-19 2012-10-16 Celanese Int Corp Layered support material for catalysts
ZA200704864B (en) * 2004-12-20 2008-08-27 Celanese Int Corp Modified support materials for catalysts
US8227369B2 (en) 2005-05-25 2012-07-24 Celanese International Corp. Layered composition and processes for preparing and using the composition
CN114425454B (zh) * 2020-10-14 2024-02-02 中国石油化工股份有限公司 醋酸乙烯催化剂及醋酸乙烯合成方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB979552A (en) * 1961-05-12 1965-01-06 Printing Packaging & Allied Tr Improvements in or relating to photosensitive printing plates
SU383274A3 (cg-RX-API-DMAC10.html) 1968-09-24 1973-05-25
DE1793474C3 (de) 1968-09-24 1974-05-22 Knapsack Ag, 5033 Huerth-Knapsack Verfahren zur Herstellung von Vinylacetat
EP0672453B1 (en) 1994-02-22 2005-11-02 The Standard Oil Company Process for the preparation of fluid bed vinyl acetate catalyst
US5665667A (en) * 1994-06-02 1997-09-09 The Standard Oil Company Process for the preparation of vinyl acetate catalyst
DE69511464T2 (de) 1994-06-02 1999-12-16 The Standard Oil Co., Cleveland Fliessbett-Verfahren zur Acetoxylierung von Äthylen zur Herstellung von Vinylacetat
GB9622911D0 (en) 1996-11-04 1997-01-08 Bp Chem Int Ltd Process
GB9625599D0 (en) * 1996-12-10 1997-01-29 Bp Chem Int Ltd Process
US5859287A (en) * 1997-10-30 1999-01-12 Celanese International Corporation Process for preparing vinyl acetate utilizing a catalyst comprising palladium, gold, and any of certain third metals

Also Published As

Publication number Publication date
BR9916139A (pt) 2001-07-24
EP0985655A1 (en) 2000-03-15
SA99200625B1 (ar) 2006-09-25
DE69919285D1 (de) 2004-09-16
EP0985655B1 (en) 2004-08-11
CN1248572A (zh) 2000-03-29
CN1216849C (zh) 2005-08-31
JP2000063324A (ja) 2000-02-29
ES2226292T3 (es) 2005-03-16
DE69919285T2 (de) 2005-09-08
SG85663A1 (en) 2002-01-15
KR100620298B1 (ko) 2006-09-06
TW552253B (en) 2003-09-11
KR20000017199A (ko) 2000-03-25
US6350901B1 (en) 2002-02-26
GB9817365D0 (en) 1998-10-07
MXPA99007415A (es) 2004-12-03

Similar Documents

Publication Publication Date Title
JP3868514B2 (ja) 酢酸ビニルの製造におけるエチレンのアセトキシル化のための流動層法
EP0985657B1 (en) Improved process for the production of vinyl acetate
EP0985655B1 (en) Process for the production of vinyl acetate
EP0985656B1 (en) Process for the production of vinyl acetate
US7145033B2 (en) Oxidation process in fluidized bed reactor
US5550281A (en) Fluid bed process for the acetoxylation of ethylene in the production of vinyl acetate
US7718811B2 (en) Oxidation process in fluidised bed reactor
US20020016495A1 (en) Process for the production of vinyl acetate
US7166742B2 (en) Fluid bed process for the acetoxylation of ethylene in the production of vinyl acetate
CN100577627C (zh) 羧酸烯基酯的制备方法
MXPA99008565A (es) Proceso mejorado para la produccion de acetato devinilo.

Legal Events

Date Code Title Description
FZDE Discontinued