CA2277023A1 - Gas generants comprising transition metal nitrite complexes - Google Patents
Gas generants comprising transition metal nitrite complexes Download PDFInfo
- Publication number
- CA2277023A1 CA2277023A1 CA002277023A CA2277023A CA2277023A1 CA 2277023 A1 CA2277023 A1 CA 2277023A1 CA 002277023 A CA002277023 A CA 002277023A CA 2277023 A CA2277023 A CA 2277023A CA 2277023 A1 CA2277023 A1 CA 2277023A1
- Authority
- CA
- Canada
- Prior art keywords
- composition
- metal
- nitrate
- ammonium
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- -1 transition metal nitrite complexes Chemical class 0.000 title claims description 29
- 229910052723 transition metal Inorganic materials 0.000 title claims description 21
- 239000000203 mixture Substances 0.000 claims abstract description 150
- 239000007789 gas Substances 0.000 claims abstract description 92
- 229910052751 metal Inorganic materials 0.000 claims abstract description 70
- 239000002184 metal Substances 0.000 claims abstract description 70
- 229910052755 nonmetal Inorganic materials 0.000 claims abstract description 46
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims abstract description 37
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 34
- 150000001875 compounds Chemical class 0.000 claims abstract description 25
- 238000000034 method Methods 0.000 claims abstract description 21
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 19
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 19
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 17
- 239000003446 ligand Substances 0.000 claims abstract description 14
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 12
- JCXJVPUVTGWSNB-UHFFFAOYSA-N Nitrogen dioxide Chemical compound O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 claims abstract description 11
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims abstract description 9
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims abstract description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 56
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 42
- 239000007795 chemical reaction product Substances 0.000 claims description 39
- 239000000446 fuel Substances 0.000 claims description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 34
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 33
- 229910052708 sodium Inorganic materials 0.000 claims description 33
- 239000011734 sodium Substances 0.000 claims description 33
- 239000007800 oxidant agent Substances 0.000 claims description 27
- 229910001868 water Inorganic materials 0.000 claims description 27
- 238000002485 combustion reaction Methods 0.000 claims description 26
- 150000004696 coordination complex Chemical class 0.000 claims description 25
- 239000002244 precipitate Substances 0.000 claims description 25
- 229910052783 alkali metal Inorganic materials 0.000 claims description 24
- 150000001340 alkali metals Chemical class 0.000 claims description 22
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 21
- NDEMNVPZDAFUKN-UHFFFAOYSA-N guanidine;nitric acid Chemical compound NC(N)=N.O[N+]([O-])=O.O[N+]([O-])=O NDEMNVPZDAFUKN-UHFFFAOYSA-N 0.000 claims description 20
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 19
- KPTSBKIDIWXFLF-UHFFFAOYSA-N 1,1,2-triaminoguanidine Chemical compound NN=C(N)N(N)N KPTSBKIDIWXFLF-UHFFFAOYSA-N 0.000 claims description 18
- ULRPISSMEBPJLN-UHFFFAOYSA-N 2h-tetrazol-5-amine Chemical compound NC1=NN=NN1 ULRPISSMEBPJLN-UHFFFAOYSA-N 0.000 claims description 16
- HAMNKKUPIHEESI-UHFFFAOYSA-N aminoguanidine Chemical compound NNC(N)=N HAMNKKUPIHEESI-UHFFFAOYSA-N 0.000 claims description 16
- 239000012153 distilled water Substances 0.000 claims description 16
- KJUGUADJHNHALS-UHFFFAOYSA-N 1H-tetrazole Substances C=1N=NNN=1 KJUGUADJHNHALS-UHFFFAOYSA-N 0.000 claims description 14
- BAKYASSDAXQKKY-UHFFFAOYSA-N 4-Hydroxy-3-methylbenzaldehyde Chemical compound CC1=CC(C=O)=CC=C1O BAKYASSDAXQKKY-UHFFFAOYSA-N 0.000 claims description 14
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 13
- BYHQZKJXCMXMFX-UHFFFAOYSA-N [Na].NN Chemical group [Na].NN BYHQZKJXCMXMFX-UHFFFAOYSA-N 0.000 claims description 12
- 150000003536 tetrazoles Chemical class 0.000 claims description 12
- 229910002651 NO3 Inorganic materials 0.000 claims description 11
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 11
- 150000002357 guanidines Chemical class 0.000 claims description 11
- 150000003624 transition metals Chemical class 0.000 claims description 11
- 150000003852 triazoles Chemical class 0.000 claims description 11
- FQQQSNAVVZSYMB-UHFFFAOYSA-N 1,1-diaminoguanidine Chemical compound NN(N)C(N)=N FQQQSNAVVZSYMB-UHFFFAOYSA-N 0.000 claims description 10
- 229910021529 ammonia Inorganic materials 0.000 claims description 10
- 150000001768 cations Chemical class 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 10
- 150000003839 salts Chemical class 0.000 claims description 10
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 10
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims description 9
- IDCPFAYURAQKDZ-UHFFFAOYSA-N 1-nitroguanidine Chemical compound NC(=N)N[N+]([O-])=O IDCPFAYURAQKDZ-UHFFFAOYSA-N 0.000 claims description 9
- 150000001540 azides Chemical class 0.000 claims description 9
- JAWGVVJVYSANRY-UHFFFAOYSA-N cobalt(3+) Chemical compound [Co+3] JAWGVVJVYSANRY-UHFFFAOYSA-N 0.000 claims description 9
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000003513 alkali Substances 0.000 claims description 8
- 239000002893 slag Substances 0.000 claims description 8
- 150000003918 triazines Chemical class 0.000 claims description 8
- 150000002429 hydrazines Chemical class 0.000 claims description 7
- 239000003607 modifier Substances 0.000 claims description 7
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 7
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 7
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 6
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims description 6
- 125000000129 anionic group Chemical group 0.000 claims description 6
- QSQUFRGBXGXOHF-UHFFFAOYSA-N cobalt(iii) nitrate Chemical compound [Co].O[N+]([O-])=O.O[N+]([O-])=O.O[N+]([O-])=O QSQUFRGBXGXOHF-UHFFFAOYSA-N 0.000 claims description 6
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims description 6
- 150000002823 nitrates Chemical class 0.000 claims description 6
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 6
- 229910000314 transition metal oxide Inorganic materials 0.000 claims description 6
- AOYBLZGEIIBUTE-UHFFFAOYSA-N 1,2,5-oxadiazol-3-amine Chemical class NC=1C=NON=1 AOYBLZGEIIBUTE-UHFFFAOYSA-N 0.000 claims description 5
- MTAYYBKXNAEQOK-UHFFFAOYSA-N 5-(2h-tetrazol-5-yl)-2h-tetrazole Chemical compound N1N=NC(C2=NNN=N2)=N1 MTAYYBKXNAEQOK-UHFFFAOYSA-N 0.000 claims description 5
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims description 5
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
- 238000009835 boiling Methods 0.000 claims description 5
- 239000003054 catalyst Substances 0.000 claims description 5
- 125000004122 cyclic group Chemical group 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 239000011521 glass Substances 0.000 claims description 5
- 150000004820 halides Chemical class 0.000 claims description 5
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 5
- 150000002826 nitrites Chemical class 0.000 claims description 5
- 229910052700 potassium Inorganic materials 0.000 claims description 5
- 239000011591 potassium Substances 0.000 claims description 5
- UDATXMIGEVPXTR-UHFFFAOYSA-N 1,2,4-triazolidine-3,5-dione Chemical compound O=C1NNC(=O)N1 UDATXMIGEVPXTR-UHFFFAOYSA-N 0.000 claims description 4
- YXYNPIWENOTEHZ-UHFFFAOYSA-N 2-nitramidoguanidine Chemical compound NC(=N)NN[N+]([O-])=O YXYNPIWENOTEHZ-UHFFFAOYSA-N 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical class [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
- QMKBSUASRATAHH-UHFFFAOYSA-N N.N.N1=NN=NC1=C1N=NN=N1 Chemical class N.N.N1=NN=NC1=C1N=NN=N1 QMKBSUASRATAHH-UHFFFAOYSA-N 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- 125000000852 azido group Chemical group *N=[N+]=[N-] 0.000 claims description 4
- 150000003851 azoles Chemical class 0.000 claims description 4
- 125000002091 cationic group Chemical group 0.000 claims description 4
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 claims description 4
- 239000002826 coolant Substances 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 239000011777 magnesium Substances 0.000 claims description 4
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 4
- 229910052982 molybdenum disulfide Inorganic materials 0.000 claims description 4
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 claims description 4
- 150000003891 oxalate salts Chemical class 0.000 claims description 4
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 claims description 4
- 230000000737 periodic effect Effects 0.000 claims description 4
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims description 4
- 239000004317 sodium nitrate Substances 0.000 claims description 4
- 235000010344 sodium nitrate Nutrition 0.000 claims description 4
- DHEQXMRUPNDRPG-UHFFFAOYSA-N strontium nitrate Chemical compound [Sr+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DHEQXMRUPNDRPG-UHFFFAOYSA-N 0.000 claims description 4
- 150000004763 sulfides Chemical class 0.000 claims description 4
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 4
- CZGWDPMDAIPURF-UHFFFAOYSA-N (4,6-dihydrazinyl-1,3,5-triazin-2-yl)hydrazine Chemical compound NNC1=NC(NN)=NC(NN)=N1 CZGWDPMDAIPURF-UHFFFAOYSA-N 0.000 claims description 3
- JHJVSUCUNFXIHN-UHFFFAOYSA-N 1,2,5-oxadiazole-3,4-diamine Chemical compound NC1=NON=C1N JHJVSUCUNFXIHN-UHFFFAOYSA-N 0.000 claims description 3
- IPZQGRLGQRWVRV-UHFFFAOYSA-N 2-(2h-tetrazol-5-yl)guanidine Chemical compound NC(N)=NC=1N=NNN=1 IPZQGRLGQRWVRV-UHFFFAOYSA-N 0.000 claims description 3
- ZILVNHNSYBNLSZ-UHFFFAOYSA-N 2-(diaminomethylideneamino)guanidine Chemical compound NC(N)=NNC(N)=N ZILVNHNSYBNLSZ-UHFFFAOYSA-N 0.000 claims description 3
- DQSBZDLZCZUJCJ-UHFFFAOYSA-N 2h-triazole-4,5-diamine Chemical compound NC=1N=NNC=1N DQSBZDLZCZUJCJ-UHFFFAOYSA-N 0.000 claims description 3
- QJTIRVUEVSKJTK-UHFFFAOYSA-N 5-nitro-1,2-dihydro-1,2,4-triazol-3-one Chemical compound [O-][N+](=O)C1=NC(=O)NN1 QJTIRVUEVSKJTK-UHFFFAOYSA-N 0.000 claims description 3
- KLSJWNVTNUYHDU-UHFFFAOYSA-N Amitrole Chemical compound NC1=NC=NN1 KLSJWNVTNUYHDU-UHFFFAOYSA-N 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 3
- 239000005751 Copper oxide Substances 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 3
- SZGMMTRAJFHIIR-UHFFFAOYSA-N [N+](=O)([O-])[O-].[Zn+2].NN.[N+](=O)([O-])[O-] Chemical compound [N+](=O)([O-])[O-].[Zn+2].NN.[N+](=O)([O-])[O-] SZGMMTRAJFHIIR-UHFFFAOYSA-N 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- VZVHUBYZGAUXLX-UHFFFAOYSA-N azane;azanide;cobalt(3+) Chemical compound N.N.N.[NH2-].[NH2-].[NH2-].[Co+3] VZVHUBYZGAUXLX-UHFFFAOYSA-N 0.000 claims description 3
- 229910052796 boron Inorganic materials 0.000 claims description 3
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical class OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 3
- 229910000431 copper oxide Inorganic materials 0.000 claims description 3
- SFDJOSRHYKHMOK-UHFFFAOYSA-N nitramide Chemical class N[N+]([O-])=O SFDJOSRHYKHMOK-UHFFFAOYSA-N 0.000 claims description 3
- UZGLIIJVICEWHF-UHFFFAOYSA-N octogen Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)CN([N+]([O-])=O)C1 UZGLIIJVICEWHF-UHFFFAOYSA-N 0.000 claims description 3
- 239000008188 pellet Substances 0.000 claims description 3
- 150000002978 peroxides Chemical class 0.000 claims description 3
- 239000004323 potassium nitrate Substances 0.000 claims description 3
- 235000010333 potassium nitrate Nutrition 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 229910052712 strontium Inorganic materials 0.000 claims description 3
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 239000001993 wax Substances 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- JGZAFSFVZSXXCJ-ONEGZZNKSA-N (E)-bis(2H-tetrazol-5-yl)diazene Chemical compound N(=N\C1=NN=NN1)/C1=NN=NN1 JGZAFSFVZSXXCJ-ONEGZZNKSA-N 0.000 claims description 2
- BVGPZRCQJJMXBI-UHFFFAOYSA-N 1,2-diaminoguanidine;nitric acid Chemical compound O[N+]([O-])=O.NN\C(N)=N/N BVGPZRCQJJMXBI-UHFFFAOYSA-N 0.000 claims description 2
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 claims description 2
- RFUUOGMETNERHK-UHFFFAOYSA-N 1-amino-1,2,4-triazolidine-3,5-dione Chemical compound NN1NC(=O)NC1=O RFUUOGMETNERHK-UHFFFAOYSA-N 0.000 claims description 2
- XCYQVKRPRUBCEH-UHFFFAOYSA-N 2-nitroguanidine;perchloric acid Chemical class OCl(=O)(=O)=O.NC(N)=N[N+]([O-])=O XCYQVKRPRUBCEH-UHFFFAOYSA-N 0.000 claims description 2
- GDDNTTHUKVNJRA-UHFFFAOYSA-N 3-bromo-3,3-difluoroprop-1-ene Chemical compound FC(F)(Br)C=C GDDNTTHUKVNJRA-UHFFFAOYSA-N 0.000 claims description 2
- YXFWFUSVDJIVIV-UHFFFAOYSA-N 4-nitro-2h-triazole Chemical compound [O-][N+](=O)C=1C=NNN=1 YXFWFUSVDJIVIV-UHFFFAOYSA-N 0.000 claims description 2
- ZGZLYKUHYXFIIO-UHFFFAOYSA-N 5-nitro-2h-tetrazole Chemical compound [O-][N+](=O)C=1N=NNN=1 ZGZLYKUHYXFIIO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052582 BN Inorganic materials 0.000 claims description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 2
- YIKSCQDJHCMVMK-UHFFFAOYSA-N Oxamide Chemical compound NC(=O)C(N)=O YIKSCQDJHCMVMK-UHFFFAOYSA-N 0.000 claims description 2
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 2
- AKQIEWGBBBQCDJ-UHFFFAOYSA-L [Mg++].NN.NN.[O-][Cl](=O)(=O)=O.[O-][Cl](=O)(=O)=O Chemical compound [Mg++].NN.NN.[O-][Cl](=O)(=O)=O.[O-][Cl](=O)(=O)=O AKQIEWGBBBQCDJ-UHFFFAOYSA-L 0.000 claims description 2
- WQRKPBDHBAYGEM-UHFFFAOYSA-N [Zn++].NN.NN.NN.[O-][N+]([O-])=O.[O-][N+]([O-])=O Chemical compound [Zn++].NN.NN.NN.[O-][N+]([O-])=O.[O-][N+]([O-])=O WQRKPBDHBAYGEM-UHFFFAOYSA-N 0.000 claims description 2
- 150000004645 aluminates Chemical class 0.000 claims description 2
- BRUFJXUJQKYQHA-UHFFFAOYSA-O ammonium dinitramide Chemical compound [NH4+].[O-][N+](=O)[N-][N+]([O-])=O BRUFJXUJQKYQHA-UHFFFAOYSA-O 0.000 claims description 2
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 2
- 229910052570 clay Inorganic materials 0.000 claims description 2
- GARCJIQFHZTIFC-UHFFFAOYSA-N diaminomethylideneazanium;2,4,6-trinitrophenolate Chemical compound NC(N)=N.OC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O GARCJIQFHZTIFC-UHFFFAOYSA-N 0.000 claims description 2
- SWRGUMCEJHQWEE-UHFFFAOYSA-N ethanedihydrazide Chemical compound NNC(=O)C(=O)NN SWRGUMCEJHQWEE-UHFFFAOYSA-N 0.000 claims description 2
- 229920002313 fluoropolymer Polymers 0.000 claims description 2
- 239000004811 fluoropolymer Substances 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 claims description 2
- KBJCHZXIAAWHMB-UHFFFAOYSA-N guanidine;perchloric acid Chemical compound NC(N)=N.OCl(=O)(=O)=O KBJCHZXIAAWHMB-UHFFFAOYSA-N 0.000 claims description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 2
- VFHUOQLSEMBILN-UHFFFAOYSA-L hydrazine platinum(2+) dinitrite Chemical compound N(=O)[O-].[Pt+2].NN.NN.N(=O)[O-] VFHUOQLSEMBILN-UHFFFAOYSA-L 0.000 claims description 2
- 150000002443 hydroxylamines Chemical class 0.000 claims description 2
- 239000004571 lime Substances 0.000 claims description 2
- QYAVNUDBHUKUCY-UHFFFAOYSA-N magnesium hydrazine dinitrate Chemical compound [Mg++].NN.NN.[O-][N+]([O-])=O.[O-][N+]([O-])=O QYAVNUDBHUKUCY-UHFFFAOYSA-N 0.000 claims description 2
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- 239000010935 stainless steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- PDEROVFZLWBVSG-UHFFFAOYSA-N strontium;diazide Chemical compound [Sr+2].[N-]=[N+]=[N-].[N-]=[N+]=[N-] PDEROVFZLWBVSG-UHFFFAOYSA-N 0.000 description 1
- 229960005453 strychnine Drugs 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 231100000925 very toxic Toxicity 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B35/00—Compositions containing a metal azide
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06D—MEANS FOR GENERATING SMOKE OR MIST; GAS-ATTACK COMPOSITIONS; GENERATION OF GAS FOR BLASTING OR PROPULSION (CHEMICAL PART)
- C06D5/00—Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets
- C06D5/06—Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets by reaction of two or more solids
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B25/00—Compositions containing a nitrated organic compound
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Air Bags (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/797,398 US6077371A (en) | 1997-02-10 | 1997-02-10 | Gas generants comprising transition metal nitrite complexes |
| US797,398 | 1997-02-10 | ||
| PCT/US1998/001750 WO1998036938A2 (en) | 1997-02-10 | 1998-01-29 | Gas generants comprising transition metal nitrite complexes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2277023A1 true CA2277023A1 (en) | 1998-08-27 |
Family
ID=25170727
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002277023A Abandoned CA2277023A1 (en) | 1997-02-10 | 1998-01-29 | Gas generants comprising transition metal nitrite complexes |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6077371A (enExample) |
| EP (1) | EP0964843B1 (enExample) |
| JP (1) | JP2002508732A (enExample) |
| KR (1) | KR20000070680A (enExample) |
| CA (1) | CA2277023A1 (enExample) |
| DE (1) | DE69832155T2 (enExample) |
| WO (1) | WO1998036938A2 (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6306232B1 (en) * | 1996-07-29 | 2001-10-23 | Automotive Systems Laboratory, Inc. | Thermally stable nonazide automotive airbag propellants |
| WO1999054270A1 (en) * | 1998-04-20 | 1999-10-28 | Daicel Chemical Industries, Ltd. | METHOD OF REDUCING NO¿x? |
| US6132538A (en) * | 1998-07-30 | 2000-10-17 | Autoliv Development Ab | High gas yield generant compositions |
| US6287400B1 (en) | 1999-03-01 | 2001-09-11 | Automotive Systems Laboratory, Inc. | Gas generant composition |
| US6277221B1 (en) * | 1999-04-13 | 2001-08-21 | Atlantic Research Corporation | Propellant compositions with salts and complexes of lanthanide and rare earth elements |
| US6361630B2 (en) * | 1999-08-17 | 2002-03-26 | Trw Inc. | Cool burning gas generating composition |
| US6673173B1 (en) | 2000-02-02 | 2004-01-06 | Autoliv Asp. Inc. | Gas generation with reduced NOx formation |
| JP4500399B2 (ja) * | 2000-02-04 | 2010-07-14 | ダイセル化学工業株式会社 | トリアジン誘導体を含むガス発生剤組成物 |
| US6358339B1 (en) * | 2000-04-28 | 2002-03-19 | The Regents Of The University Of California | Use of 3,3'-diamino-4,4'-azoxyfurazan and 3,3'-diamino-4,4'-azofurazan as insensitive high explosive materials |
| EP1278662B1 (en) | 2000-05-02 | 2008-03-12 | Automotive Systems Laboratory Inc. | Inflator |
| US6513834B1 (en) * | 2000-08-29 | 2003-02-04 | Trw Inc. | Monopropellant smokeless gas generant materials |
| JP2002302010A (ja) * | 2001-04-04 | 2002-10-15 | Daicel Chem Ind Ltd | ハイブリッドインフレータの窒素酸化物の低減法 |
| US6712918B2 (en) | 2001-11-30 | 2004-03-30 | Autoliv Asp, Inc. | Burn rate enhancement via a transition metal complex of diammonium bitetrazole |
| WO2004024503A2 (en) * | 2002-09-13 | 2004-03-25 | Automotive Systems Laboratory, Inc. | Inflator |
| US20040094250A1 (en) * | 2002-11-14 | 2004-05-20 | Estes-Cox Corporation | Composite propellant compositions |
| WO2004067477A2 (en) * | 2003-01-21 | 2004-08-12 | Autoliv Asp, Inc. | Gas generants |
| US20040144455A1 (en) * | 2003-01-21 | 2004-07-29 | Mendenhall Ivan V. | Pyrotechnic compositions for gas generant applications |
| US20060289096A1 (en) * | 2003-07-25 | 2006-12-28 | Mendenhall Ivan V | Extrudable gas generant |
| WO2005019421A2 (en) * | 2003-08-11 | 2005-03-03 | University Of Utah Research Foundation | Crosslinking within coordination complexes |
| US7527290B2 (en) | 2003-10-21 | 2009-05-05 | Automotive Systems Laboratory, Inc. | Pressurized gas release mechanism |
| US7192055B2 (en) * | 2003-11-13 | 2007-03-20 | Automotive Systems Laboratory, Inc. | Pyrotechnic linear inflator |
| US7243946B2 (en) * | 2003-11-18 | 2007-07-17 | Automotive Systems Laboratory, Inc. | Peroxide linear inflator |
| US7080854B2 (en) | 2004-01-13 | 2006-07-25 | Automotive Systems Laboratory, Inc. | Pyrotechnic linear inflator |
| US20050200103A1 (en) * | 2004-02-27 | 2005-09-15 | Burns Sean P. | Pyrotechnic linear inflator with structural enhancement |
| US20050257866A1 (en) * | 2004-03-29 | 2005-11-24 | Williams Graylon K | Gas generant and manufacturing method thereof |
| JP4500576B2 (ja) * | 2004-04-01 | 2010-07-14 | ダイセル化学工業株式会社 | ガス発生剤組成物 |
| US7789018B2 (en) * | 2004-04-02 | 2010-09-07 | Automotive Systems Laboratory, Inc. | Gas generator assembly |
| US7293798B2 (en) * | 2004-04-05 | 2007-11-13 | Automotive Systems Laboratory, Inc. | Pyrotechnic linear inflator |
| US7588265B2 (en) * | 2004-04-12 | 2009-09-15 | Automotive Systems Laboratory, Inc. | Pressurized gas release mechanism |
| KR100612417B1 (ko) * | 2004-07-21 | 2006-08-16 | 삼성전자주식회사 | 펄스-기반 고속 저전력 게이티드 플롭플롭 회로 |
| US8622419B2 (en) * | 2004-07-27 | 2014-01-07 | Automotive Systems Laboratory, Inc. | Vehicle component with integral inflator |
| DE112006000259T5 (de) * | 2005-01-20 | 2007-12-13 | Automotive Systems Laboratory, Inc., Armada | Flexibler Gaserzeuger |
| US20060220362A1 (en) * | 2005-03-31 | 2006-10-05 | Hordos Deborah L | Gas generator |
| US9046327B2 (en) | 2005-03-31 | 2015-06-02 | Tk Holdings Inc. | Gas generator |
| JP2006328034A (ja) * | 2005-05-30 | 2006-12-07 | Nippon Zeon Co Ltd | 遷移金属錯体、環状オレフィン重合用触媒、および環状オレフィン重合体の製造方法 |
| JP2009500276A (ja) * | 2005-06-30 | 2009-01-08 | オートモーティブ システムズ ラボラトリィ、 インク． | 自己発火組成物 |
| US20070044675A1 (en) * | 2005-08-31 | 2007-03-01 | Burns Sean P | Autoignition compositions |
| JP2009512613A (ja) * | 2005-09-29 | 2009-03-26 | オートモーティブ システムズ ラボラトリィ、 インク． | ガス生成物質 |
| US20070084532A1 (en) * | 2005-09-30 | 2007-04-19 | Burns Sean P | Gas generant |
| US20070169863A1 (en) * | 2006-01-19 | 2007-07-26 | Hordos Deborah L | Autoignition main gas generant |
| US20100326575A1 (en) * | 2006-01-27 | 2010-12-30 | Miller Cory G | Synthesis of 2-nitroimino-5-nitrohexahydro-1,3,5-triazine |
| US7959749B2 (en) * | 2006-01-31 | 2011-06-14 | Tk Holdings, Inc. | Gas generating composition |
| US20080271825A1 (en) * | 2006-09-29 | 2008-11-06 | Halpin Jeffrey W | Gas generant |
| US9556078B1 (en) | 2008-04-07 | 2017-01-31 | Tk Holdings Inc. | Gas generator |
| US8097103B2 (en) * | 2009-06-18 | 2012-01-17 | Autoliv Asp, Inc. | Copper complexes with oxalyldihydrazide moieties |
| DE102010050862A1 (de) * | 2010-11-09 | 2012-05-10 | Diehl Bgt Defence Gmbh & Co. Kg | Sprengstoff umfassend eine Tetrazolverbindung |
| CZ305190B6 (cs) * | 2011-07-04 | 2015-06-03 | Univerzita Pardubice | Použití komplexních sloučenin biguanidu jako paliva do pyrotechnické slože a pyrotechnická slož pro bezpečnostní systémy pasivní ochrany |
| US8980023B2 (en) * | 2011-07-27 | 2015-03-17 | Autoliv Asp, Inc. | Gas generation via elemental carbon-based compositions |
| US9073512B1 (en) | 2012-07-23 | 2015-07-07 | Tk Holdings Inc. | Gas generating system with gas generant cushion |
| WO2014082038A1 (en) * | 2012-11-26 | 2014-05-30 | Kansas State University Research Foundation | Thermochemical ammonia and hydrocarbons |
| IL235415A0 (en) | 2014-10-30 | 2015-01-29 | Univ Ramot | Energetic substances and mixtures containing them |
| WO2016097826A1 (en) * | 2014-12-19 | 2016-06-23 | Tubitak | O -chlorobenzylidene malononitrile (cs) based self-combustible pyrotechnic compositions which have low ignition temperatures |
| US10358393B2 (en) * | 2016-05-23 | 2019-07-23 | Joyson Safety Systems Acquisition Llc | Gas generating compositions and methods of making and using thereof |
| CN106278771B (zh) * | 2016-08-12 | 2017-09-19 | 中山大学 | 一类化合物在作为含能材料方面的用途 |
| US12122729B2 (en) | 2016-08-12 | 2024-10-22 | Xi'an Crysten Materials Technology Corporation Limited | Perovskite-type compounds of formula ABX3 |
| CN109180536A (zh) * | 2018-10-09 | 2019-01-11 | 南通天泽化工有限公司 | 一种硝基脒基肼的制备方法 |
| CN119039545A (zh) * | 2024-08-01 | 2024-11-29 | 北京化工大学 | 具有从水中提取金的胍基离子型多孔有机聚合物的制备与应用 |
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| US2222175A (en) * | 1939-03-04 | 1940-11-19 | Du Pont | Nonsetting ammonium nitrate explosive composition and process |
| US2220891A (en) * | 1939-08-09 | 1940-11-12 | Du Pont | Ammonium nitrate explosive composition |
| US2220892A (en) * | 1939-08-09 | 1940-11-12 | Du Pont | Method of preparing ammonium nitrate explosives |
| GB544582A (en) * | 1940-08-16 | 1942-04-20 | Du Pont | Improvements in or relating to ammonium nitrate explosives |
| US3463684A (en) * | 1966-12-19 | 1969-08-26 | Heinz Dehn | Crystalline explosive composed of an alkyl sulfoxide solvating a hydrate-forming salt and method of making |
| US3673015A (en) * | 1969-05-23 | 1972-06-27 | Us Army | Explosive pyrotechnic complexes of ferrocene and inorganic nitrates |
| US4336085A (en) * | 1975-09-04 | 1982-06-22 | Walker Franklin E | Explosive composition with group VIII metal nitroso halide getter |
| US4863534A (en) * | 1987-12-23 | 1989-09-05 | The Lubrizol Corporation | Explosive compositions using a combination of emulsifying salts |
| GB2293820B (en) * | 1988-12-20 | 1996-07-03 | Aerojet General Co | Liquid oxidizer compositions and their use in energetic formulations |
| US5266132A (en) * | 1991-10-08 | 1993-11-30 | The United States Of America As Represented By The United States Department Of Energy | Energetic composites |
| US5160386A (en) * | 1991-11-04 | 1992-11-03 | Morton International, Inc. | Gas generant formulations containing poly(nitrito) metal complexes as oxidants and method |
| US5460669A (en) * | 1993-06-28 | 1995-10-24 | Thiokol Corporation | 3-nitramino-4-nitrofurazan and salts thereof |
| US5682014A (en) * | 1993-08-02 | 1997-10-28 | Thiokol Corporation | Bitetrazoleamine gas generant compositions |
| US5472647A (en) * | 1993-08-02 | 1995-12-05 | Thiokol Corporation | Method for preparing anhydrous tetrazole gas generant compositions |
| US5544687A (en) * | 1993-12-10 | 1996-08-13 | Morton International, Inc. | Gas generant compositions using dicyanamide salts as fuel |
| US5725699A (en) * | 1994-01-19 | 1998-03-10 | Thiokol Corporation | Metal complexes for use as gas generants |
| JP4109317B2 (ja) * | 1994-01-19 | 2008-07-02 | アライアント・テクシステムズ・インコーポレーテッド | ガス発生剤として用いる金属錯体 |
| US5542704A (en) * | 1994-09-20 | 1996-08-06 | Oea, Inc. | Automotive inflatable safety system propellant with complexing agent |
| US5756929A (en) * | 1996-02-14 | 1998-05-26 | Automotive Systems Laboratory Inc. | Nonazide gas generating compositions |
-
1997
- 1997-02-10 US US08/797,398 patent/US6077371A/en not_active Expired - Fee Related
-
1998
- 1998-01-29 WO PCT/US1998/001750 patent/WO1998036938A2/en not_active Ceased
- 1998-01-29 EP EP98911364A patent/EP0964843B1/en not_active Expired - Lifetime
- 1998-01-29 CA CA002277023A patent/CA2277023A1/en not_active Abandoned
- 1998-01-29 JP JP53664398A patent/JP2002508732A/ja not_active Ceased
- 1998-01-29 DE DE69832155T patent/DE69832155T2/de not_active Expired - Fee Related
- 1998-01-29 KR KR1019997006929A patent/KR20000070680A/ko not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| WO1998036938A2 (en) | 1998-08-27 |
| DE69832155D1 (de) | 2005-12-08 |
| EP0964843A4 (en) | 2001-02-28 |
| EP0964843A2 (en) | 1999-12-22 |
| JP2002508732A (ja) | 2002-03-19 |
| DE69832155T2 (de) | 2006-07-27 |
| WO1998036938A3 (en) | 1999-03-25 |
| US6077371A (en) | 2000-06-20 |
| KR20000070680A (ko) | 2000-11-25 |
| EP0964843B1 (en) | 2005-11-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |