CA2255646A1 - Process for making thermally stable metal coated polymeric monofilament or yarn - Google Patents

Process for making thermally stable metal coated polymeric monofilament or yarn

Info

Publication number
CA2255646A1
CA2255646A1 CA002255646A CA2255646A CA2255646A1 CA 2255646 A1 CA2255646 A1 CA 2255646A1 CA 002255646 A CA002255646 A CA 002255646A CA 2255646 A CA2255646 A CA 2255646A CA 2255646 A1 CA2255646 A1 CA 2255646A1
Authority
CA
Canada
Prior art keywords
yarn
thermally stable
metal coated
stable metal
coated polymeric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002255646A
Other languages
French (fr)
Other versions
CA2255646C (en
Inventor
John D. Cawston
Merwin F. Hoover
Thomas F. Burke
Thomas H. Stearns
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Micro Coax Inc
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/655,733 external-priority patent/US6045680A/en
Priority claimed from US08/656,914 external-priority patent/US5935706A/en
Application filed by Individual filed Critical Individual
Publication of CA2255646A1 publication Critical patent/CA2255646A1/en
Application granted granted Critical
Publication of CA2255646C publication Critical patent/CA2255646C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1633—Process of electroless plating
    • C23C18/1635—Composition of the substrate
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1633—Process of electroless plating
    • C23C18/1635—Composition of the substrate
    • C23C18/1639—Substrates other than metallic, e.g. inorganic or organic or non-conductive
    • C23C18/1641—Organic substrates, e.g. resin, plastic
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1633—Process of electroless plating
    • C23C18/1646—Characteristics of the product obtained
    • C23C18/165—Multilayered product
    • C23C18/1653—Two or more layers with at least one layer obtained by electroless plating and one layer obtained by electroplating
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18—Pretreatment of the material to be coated
    • C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
    • C23C18/22—Roughening, e.g. by etching
    • C23C18/24—Roughening, e.g. by etching using acid aqueous solutions
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1633—Process of electroless plating
    • C23C18/1655—Process features
    • C23C18/1658—Process features with two steps starting with metal deposition followed by addition of reducing agent
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18—Pretreatment of the material to be coated
    • C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
    • C23C18/28—Sensitising or activating
    • C23C18/30—Activating or accelerating or sensitising with palladium or other noble metal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Chemically Coating (AREA)

Abstract

Monofilaments of a yarn to be coated with electroless nickel are pretreated with an acid and a surfactant to render the monofilament surfaces water wettable and not substantially mechanically degraded. The pretreated yarns is passed through an electroless nickel coating bath under little or no tension so that the electroless nickel can coat all of the monofilament surfaces substantially uniformly. The nickel coated yam then can be coated with electrolytic metal such as copper in an electrolytic metal plating step, as desired.
CA002255646A 1996-05-30 1997-05-30 Process for making thermally stable metal coated polymeric monofilament or yarn Expired - Lifetime CA2255646C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US08/655,733 US6045680A (en) 1996-05-30 1996-05-30 Process for making thermally stable metal coated polymeric monofilament or yarn
US08/656,914 US5935706A (en) 1996-05-30 1996-05-30 Thermally stable metal coated polymeric monofilament or yarn
US08/655,733 1996-05-30
US08/656,914 1996-05-30
PCT/US1997/009116 WO1997048832A2 (en) 1996-05-30 1997-05-30 Process for making thermally stable metal coated polymeric monofilament or yarn

Publications (2)

Publication Number Publication Date
CA2255646A1 true CA2255646A1 (en) 1997-12-24
CA2255646C CA2255646C (en) 2008-04-08

Family

ID=27097017

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002255646A Expired - Lifetime CA2255646C (en) 1996-05-30 1997-05-30 Process for making thermally stable metal coated polymeric monofilament or yarn

Country Status (6)

Country Link
EP (1) EP0902854B1 (en)
JP (1) JP4060363B2 (en)
CA (1) CA2255646C (en)
DE (1) DE69709094T2 (en)
ES (1) ES2165628T3 (en)
WO (1) WO1997048832A2 (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1435407A1 (en) 2003-01-02 2004-07-07 Teijin Twaron B.V. Aramid filament yarn provided with a conductive finish
WO2006081622A1 (en) * 2005-02-03 2006-08-10 Australian Wool Innovation Limited Fibre coating composition
GB0505822D0 (en) * 2005-03-22 2005-04-27 Conductive Inkjet Tech Ltd Treatment of flexible web material
JP5327494B2 (en) * 2005-11-16 2013-10-30 日立化成株式会社 Method for producing catalyst concentrate for electroless plating and method for applying plating catalyst using the same
GB0614706D0 (en) * 2006-07-25 2006-09-06 Gore W L & Ass Uk Fabric
KR20130132754A (en) * 2010-07-23 2013-12-05 시스콤 어드밴스드 머티어리얼즈, 인코포레이티드 Electrically conductive metal-coated fibers, continuous process for preparation thereof, and use thereof
WO2012092505A1 (en) 2010-12-29 2012-07-05 Syscom Advanced Materials Metal and metallized fiber hybrid wire
WO2012111832A1 (en) 2011-02-17 2012-08-23 矢崎総業株式会社 Shield sleeve
JP6006931B2 (en) * 2011-11-24 2016-10-12 矢崎総業株式会社 Plated fiber and manufacturing method thereof
JP2014120327A (en) * 2012-12-17 2014-06-30 Yazaki Corp Conductor for electric wire
CN114687205A (en) * 2022-04-19 2022-07-01 中国科学院苏州纳米技术与纳米仿生研究所 Multi-metal compounding method of high polymer fiber material and multi-metal composite fiber

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1243493B (en) * 1961-02-04 1967-06-29 Bayer Ag Aqueous bath for chemical deposition of boron-containing metal coatings
US3515649A (en) * 1967-05-02 1970-06-02 Ivan C Hepfer Pre-plating conditioning process
GB1243481A (en) * 1969-01-22 1971-08-18 Hoechst Ag Metallisation of plastics
US4673469A (en) * 1984-06-08 1987-06-16 Mcgean-Rohco, Inc. Method of plating plastics
US4634805A (en) * 1985-05-02 1987-01-06 Material Concepts, Inc. Conductive cable or fabric
US4639380A (en) * 1985-05-06 1987-01-27 International Business Machines Corporation Process for preparing a substrate for subsequent electroless deposition of a metal
US5302415A (en) * 1992-12-08 1994-04-12 E. I. Du Pont De Nemours And Company Electroless plated aramid surfaces and a process for making such surfaces

Also Published As

Publication number Publication date
CA2255646C (en) 2008-04-08
DE69709094D1 (en) 2002-01-24
DE69709094T2 (en) 2002-07-18
EP0902854B1 (en) 2001-12-12
EP0902854A2 (en) 1999-03-24
JP2000512690A (en) 2000-09-26
WO1997048832A3 (en) 1998-02-26
ES2165628T3 (en) 2002-03-16
JP4060363B2 (en) 2008-03-12
WO1997048832A2 (en) 1997-12-24

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Effective date: 20170530