CA2230019C - Procede de reactivation d'un agent de sorption permettant sa reutilisation - Google Patents

Procede de reactivation d'un agent de sorption permettant sa reutilisation Download PDF

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Publication number
CA2230019C
CA2230019C CA002230019A CA2230019A CA2230019C CA 2230019 C CA2230019 C CA 2230019C CA 002230019 A CA002230019 A CA 002230019A CA 2230019 A CA2230019 A CA 2230019A CA 2230019 C CA2230019 C CA 2230019C
Authority
CA
Canada
Prior art keywords
cao
ash particulates
particulates containing
combustor
fossil fuel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA002230019A
Other languages
English (en)
Other versions
CA2230019A1 (fr
Inventor
John H. Chiu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Alstom SA
Original Assignee
ABB Research Ltd Sweden
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ABB Research Ltd Sweden filed Critical ABB Research Ltd Sweden
Publication of CA2230019A1 publication Critical patent/CA2230019A1/fr
Application granted granted Critical
Publication of CA2230019C publication Critical patent/CA2230019C/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L7/00—Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
    • F23L7/002—Supplying water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77—Liquid phase processes
    • B01D53/79—Injecting reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/50—Sulfur oxides
    • B01D53/508—Sulfur oxides by treating the gases with solids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/96—Regeneration, reactivation or recycling of reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3433—Regenerating or reactivating of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
    • B01J20/3458—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase
    • B01J20/3466—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase with steam
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00—Fluidised bed combustion apparatus
    • F23C10/02—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed
    • F23C10/04—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed the particles being circulated to a section, e.g. a heat-exchange section or a return duct, at least partially shielded from the combustion zone, before being reintroduced into the combustion zone
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00—Fluidised bed combustion apparatus
    • F23C10/02—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed
    • F23C10/04—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed the particles being circulated to a section, e.g. a heat-exchange section or a return duct, at least partially shielded from the combustion zone, before being reintroduced into the combustion zone
    • F23C10/08—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed the particles being circulated to a section, e.g. a heat-exchange section or a return duct, at least partially shielded from the combustion zone, before being reintroduced into the combustion zone characterised by the arrangement of separation apparatus, e.g. cyclones, for separating particles from the flue gases
    • F23C10/10—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed the particles being circulated to a section, e.g. a heat-exchange section or a return duct, at least partially shielded from the combustion zone, before being reintroduced into the combustion zone characterised by the arrangement of separation apparatus, e.g. cyclones, for separating particles from the flue gases the separation apparatus being located outside the combustion chamber
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C2206/00—Fluidised bed combustion
    • F23C2206/10—Circulating fluidised bed
    • F23C2206/103—Cooling recirculating particles
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00—Preventing emissions
    • F23J2215/20—Sulfur; Compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Fluidized-Bed Combustion And Resonant Combustion (AREA)
  • Processing Of Solid Wastes (AREA)
  • Treating Waste Gases (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

La présente invention concerne un procédé de réactivation, aux fins de réutilisation, d'un agent de sorption contenant du CaO n'ayant pas réagi, incorporé dans de la cendre usée produite par la combustion, dans une chambre de combustion (14), d'un combustible fossile en présence d'un agent de sorption contenant du Ca. L'agent de sorption contenant le CaO qui n'a pas réagi est soumis à l'action de vapeur ayant une température prédéterminée et une pression partielle prédéterminée, qui conviennent pour exécuter la conversion du CaO n'ayant pas réagi en Ca(OH)¿2?. Il se produit alors une rupture de l'agent de sorption, si bien que le Ca(OH)¿2? devient accessible. Ensuite, l'agent de sorption, qui contient à présent du Ca(OH)¿2?, est réinjecté dans la chambre de combustion (14) brûlant un combustible fossile, à une température, à l'intérieur de cette chambre (14), qui convient pour effectuer la reconversion du Ca(OH)¿2? en CaO.
CA002230019A 1995-08-21 1996-07-29 Procede de reactivation d'un agent de sorption permettant sa reutilisation Expired - Fee Related CA2230019C (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US51748695A 1995-08-21 1995-08-21
US08/517,486 1995-08-21
PCT/IB1996/000930 WO1997006889A1 (fr) 1995-08-21 1996-07-29 Procede de reactivation d'un agent de sorption permettant sa reutilisation

Publications (2)

Publication Number Publication Date
CA2230019A1 CA2230019A1 (fr) 1997-02-27
CA2230019C true CA2230019C (fr) 2002-01-22

Family

ID=24060013

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002230019A Expired - Fee Related CA2230019C (fr) 1995-08-21 1996-07-29 Procede de reactivation d'un agent de sorption permettant sa reutilisation

Country Status (10)

Country Link
KR (1) KR100312360B1 (fr)
CN (1) CN1104946C (fr)
CA (1) CA2230019C (fr)
CZ (1) CZ51098A3 (fr)
FI (1) FI980394A (fr)
IN (1) IN188644B (fr)
PL (1) PL325057A1 (fr)
SE (1) SE9800396D0 (fr)
TW (1) TW397706B (fr)
WO (1) WO1997006889A1 (fr)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6290921B1 (en) * 1999-11-03 2001-09-18 Foster Wheeler Enegeria Oy Method and apparatus for binding pollutants in flue gas
ES2365199T3 (es) * 2003-11-14 2011-09-26 Her Majesty The Queen In Right Of Canada As Represented By The Minister Of Natural Resources Pre-tratamiento de absorbentes basados en cal usando hidratación.
KR100699519B1 (ko) * 2005-11-15 2007-03-23 한국에너지기술연구원 폐기물과 알피에프 연소 전용 순환유동층 보일러
CN102307646B (zh) * 2008-11-19 2014-08-27 俄亥俄州立大学研究基金会 使用高可再生的吸附剂进行co2捕获的碳酸化煅烧反应方法
US9074767B2 (en) * 2010-02-11 2015-07-07 Alstom Technology Ltd Rotary bottom ash regeneration system
US9657937B2 (en) * 2010-08-23 2017-05-23 Saudi Arabian Oil Company Steam generation system having multiple combustion chambers and dry flue gas cleaning
FI123704B (fi) 2011-02-04 2013-09-30 Foster Wheeler Energia Oy Menetelmä happipolttokiertoleijupetikattilan käyttämiseksi
SE538327C2 (sv) * 2012-08-31 2016-05-17 Marketing I Konsulting Per Anders Brattemo Förfarande för att rena avgaser
CN103446875B (zh) * 2013-07-29 2016-03-30 浙江大学 循环流化床燃烧系统的脱硫剂强化脱硫的方法及其系统
EP2884163B1 (fr) * 2013-12-16 2017-04-05 Doosan Lentjes GmbH Dispositif à lit fluidisé avec un échangeur de chaleur à lit fluidisé
JP2017120151A (ja) * 2015-12-28 2017-07-06 川崎重工業株式会社 燃焼設備
TWI849370B (zh) * 2021-12-23 2024-07-21 興展技術開發股份有限公司 用來降低氟化鈣汙泥中硫含量的方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4312280A (en) * 1980-03-13 1982-01-26 The United States Of America As Represented By The United States Department Of Energy Method of increasing the sulfation capacity of alkaline earth sorbents
SE457014B (sv) * 1987-03-25 1988-11-21 Abb Stal Ab Saett att foerbaettra utnyttjningen av svavelabsorbent vid foerbraenning i en fluidiserad baedd och en kraftanlaeggning med foerbraenning i fluidiserad baedd
US5345883A (en) * 1992-12-31 1994-09-13 Combustion Engineering, Inc. Reactivation of sorbent in a fluid bed boiler

Also Published As

Publication number Publication date
FI980394A (fi) 1998-04-20
KR19990044099A (ko) 1999-06-25
SE9800396L (sv) 1998-02-11
IN188644B (fr) 2002-10-26
CZ51098A3 (cs) 1998-07-15
KR100312360B1 (ko) 2002-02-28
CA2230019A1 (fr) 1997-02-27
PL325057A1 (en) 1998-07-06
WO1997006889A1 (fr) 1997-02-27
CN1199353A (zh) 1998-11-18
TW397706B (en) 2000-07-11
FI980394A0 (fi) 1998-02-20
CN1104946C (zh) 2003-04-09
SE9800396D0 (sv) 1998-02-11

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