CA2142913C - Concentrated liquid detergent composition comprising an alkyl ether sulphate and a process for making the composition - Google Patents
Concentrated liquid detergent composition comprising an alkyl ether sulphate and a process for making the compositionInfo
- Publication number
- CA2142913C CA2142913C CA002142913A CA2142913A CA2142913C CA 2142913 C CA2142913 C CA 2142913C CA 002142913 A CA002142913 A CA 002142913A CA 2142913 A CA2142913 A CA 2142913A CA 2142913 C CA2142913 C CA 2142913C
- Authority
- CA
- Canada
- Prior art keywords
- sulphate
- weight
- neutralisation
- alkyl
- earth metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 68
- 229910021653 sulphate ion Inorganic materials 0.000 title claims abstract description 47
- -1 alkyl ether sulphate Chemical class 0.000 title claims abstract description 39
- 238000000034 method Methods 0.000 title claims description 24
- 239000003599 detergent Substances 0.000 title claims description 17
- 239000007788 liquid Substances 0.000 title abstract description 10
- 238000006386 neutralization reaction Methods 0.000 claims abstract description 39
- 239000004094 surface-active agent Substances 0.000 claims abstract description 25
- 239000011777 magnesium Substances 0.000 claims abstract description 17
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 17
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000002253 acid Substances 0.000 claims abstract description 12
- 239000002243 precursor Substances 0.000 claims abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 27
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 21
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 18
- 125000000217 alkyl group Chemical group 0.000 claims description 13
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 239000002736 nonionic surfactant Substances 0.000 claims description 11
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 239000003752 hydrotrope Substances 0.000 claims description 9
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 claims description 8
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 8
- 239000000194 fatty acid Substances 0.000 claims description 8
- 229930195729 fatty acid Natural products 0.000 claims description 8
- 150000004665 fatty acids Chemical class 0.000 claims description 8
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 7
- 125000000129 anionic group Chemical group 0.000 claims description 6
- 229910052920 inorganic sulfate Inorganic materials 0.000 claims description 6
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 6
- GHPCICSQWQDZLM-UHFFFAOYSA-N 1-(4-chlorophenyl)sulfonyl-1-methyl-3-propylurea Chemical compound CCCNC(=O)N(C)S(=O)(=O)C1=CC=C(Cl)C=C1 GHPCICSQWQDZLM-UHFFFAOYSA-N 0.000 claims description 5
- 230000003472 neutralizing effect Effects 0.000 claims description 5
- 239000002002 slurry Substances 0.000 claims description 5
- 229960003237 betaine Drugs 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 claims description 4
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical compound CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 claims description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 claims description 3
- 239000000908 ammonium hydroxide Substances 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 239000008096 xylene Substances 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 229910001413 alkali metal ion Inorganic materials 0.000 claims description 2
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 125000005907 alkyl ester group Chemical group 0.000 claims 3
- 150000001805 chlorine compounds Chemical class 0.000 claims 2
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract description 7
- 150000001342 alkaline earth metals Chemical class 0.000 abstract description 7
- 238000004851 dishwashing Methods 0.000 abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract description 4
- 238000004140 cleaning Methods 0.000 abstract description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 24
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 17
- 239000000243 solution Substances 0.000 description 9
- 150000001298 alcohols Chemical class 0.000 description 8
- 239000004615 ingredient Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 6
- 239000000347 magnesium hydroxide Substances 0.000 description 6
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 6
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 5
- 235000012254 magnesium hydroxide Nutrition 0.000 description 5
- 239000012670 alkaline solution Substances 0.000 description 4
- 238000007046 ethoxylation reaction Methods 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000011552 falling film Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000013067 intermediate product Substances 0.000 description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 description 3
- 239000000395 magnesium oxide Substances 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 3
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 229930182478 glucoside Natural products 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Substances [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 235000000346 sugar Nutrition 0.000 description 2
- 150000008163 sugars Chemical class 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- 239000001117 sulphuric acid Substances 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000005011 alkyl ether group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 150000008131 glucosides Chemical group 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229910001504 inorganic chloride Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- GIPRGFRQMWSHAK-UHFFFAOYSA-M sodium;2-propan-2-ylbenzenesulfonate Chemical compound [Na+].CC(C)C1=CC=CC=C1S([O-])(=O)=O GIPRGFRQMWSHAK-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- XTHPWXDJESJLNJ-UHFFFAOYSA-N sulfurochloridic acid Chemical compound OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/04—Special methods for preparing compositions containing mixtures of detergents by chemical means, e.g. by sulfonating in the presence of other compounding ingredients followed by neutralising
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP92202559.8 | 1992-08-21 | ||
| EP92202559 | 1992-08-21 | ||
| PCT/US1993/007700 WO1994004640A1 (en) | 1992-08-21 | 1993-08-12 | Concentrated liquid detergent composition comprising an alkyl ether sulphate and a process for making the composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2142913A1 CA2142913A1 (en) | 1994-03-03 |
| CA2142913C true CA2142913C (en) | 1999-05-18 |
Family
ID=8210873
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002142913A Expired - Fee Related CA2142913C (en) | 1992-08-21 | 1993-08-12 | Concentrated liquid detergent composition comprising an alkyl ether sulphate and a process for making the composition |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP0656046A4 (zh) |
| JP (1) | JPH08500388A (zh) |
| CN (1) | CN1047615C (zh) |
| AU (1) | AU5015293A (zh) |
| BR (1) | BR9306927A (zh) |
| CA (1) | CA2142913C (zh) |
| MA (1) | MA22957A1 (zh) |
| TR (1) | TR27633A (zh) |
| TW (1) | TW246686B (zh) |
| WO (1) | WO1994004640A1 (zh) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9314410D0 (en) * | 1993-07-13 | 1993-08-25 | Jeyes Group Plc | Cleansing compositions |
| ATE273375T1 (de) * | 1996-06-28 | 2004-08-15 | Procter & Gamble | Geschirrspülmittel mit verringerter neigung zur gelierung |
| DE102005042604A1 (de) | 2005-09-07 | 2007-03-08 | Basf Ag | Neutralisationsverfahren |
| DE102005042605A1 (de) | 2005-09-07 | 2007-03-08 | Basf Ag | Neutralisationsverfahren |
| DE102005042606A1 (de) | 2005-09-07 | 2007-03-08 | Basf Ag | Neutralisationsverfahren |
| JP5465872B2 (ja) * | 2008-12-15 | 2014-04-09 | 花王株式会社 | アニオン界面活性剤組成物 |
| WO2015032083A1 (en) * | 2013-09-09 | 2015-03-12 | The Procter & Gamble Company | Process of making a liquid cleaning composition |
| EP2975107A1 (en) | 2014-07-16 | 2016-01-20 | Hayat Kimya Sanayi Anonim Sirketi | Hand dishwashing composition with improved foaming properties |
| JP6688613B2 (ja) * | 2016-01-15 | 2020-04-28 | 株式会社ニイタカ | 液体洗浄剤組成物 |
| EP4249578A1 (en) | 2022-03-07 | 2023-09-27 | The Procter & Gamble Company | Processes for making concentrated surfactant blends |
| WO2023172859A1 (en) | 2022-03-07 | 2023-09-14 | The Procter & Gamble Company | Processes for making concentrated surfactant blends |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1052223A (en) * | 1975-01-06 | 1979-04-10 | David S. Lambert | Detergent composition containing semi-polar nonionic detergent and alkaline earth metal anionic detergent |
| US4133779A (en) * | 1975-01-06 | 1979-01-09 | The Procter & Gamble Company | Detergent composition containing semi-polar nonionic detergent and alkaline earth metal anionic detergent |
| JPS5238507A (en) * | 1975-09-22 | 1977-03-25 | Kao Corp | Detergent composition |
| US4129515A (en) * | 1976-09-13 | 1978-12-12 | The Procter & Gamble Company | Heavy-duty liquid detergent and process |
| DE3168008D1 (en) * | 1980-04-24 | 1985-02-14 | Procter & Gamble | Liquid detergent compositions |
| US4316824A (en) * | 1980-06-26 | 1982-02-23 | The Procter & Gamble Company | Liquid detergent composition containing alkyl sulfate and alkyl ethoxylated sulfate |
| ATE14142T1 (de) * | 1981-04-03 | 1985-07-15 | Procter & Gamble | Fluessige detergenszusammensetzungen. |
| EP0107946B1 (en) * | 1982-10-28 | 1987-03-11 | THE PROCTER & GAMBLE COMPANY | Liquid detergent compositions |
| JPS6011593A (ja) * | 1983-06-30 | 1985-01-21 | ライオン株式会社 | 液体洗浄剤組成物 |
| IE58219B1 (en) * | 1984-11-07 | 1993-08-11 | Procter & Gamble | Liquid detergent compositions |
| US4923635A (en) * | 1987-07-06 | 1990-05-08 | Colgate-Palmolive Company | Liquid detergent composition containing alkylbenzene sulfonate, alkyl ethanol ether sulfate, alkanolamide foam booster and magnesium and triethanolammonium ions |
| US5096622A (en) * | 1988-12-05 | 1992-03-17 | Colgate-Palmolive Company | Liquid detergent composition containing alkylbenzene sulfonate, alkyl ethonal ether sulfate, alkanolamide foam booster and magnesium and triethanolammonium ions |
| ES2077250T3 (es) * | 1990-09-28 | 1995-11-16 | Procter & Gamble | Composiciones de detergentes que contienen agentes tensioactivos anionicos, polihidroxi-amidas de acidos grasos y magnesio. |
| GB9021217D0 (en) * | 1990-09-28 | 1990-11-14 | Procter & Gamble | Liquid detergent compositions |
| NZ240395A (en) * | 1990-11-21 | 1993-10-26 | Colgate Palmolive Co | Process for manufacture of concentrated liquid detergent containing magnesium alkylbenzene sulphonate and alkanolamide suds booster |
-
1993
- 1993-08-12 AU AU50152/93A patent/AU5015293A/en not_active Abandoned
- 1993-08-12 TR TR00720/93A patent/TR27633A/xx unknown
- 1993-08-12 CA CA002142913A patent/CA2142913C/en not_active Expired - Fee Related
- 1993-08-12 BR BR9306927A patent/BR9306927A/pt not_active IP Right Cessation
- 1993-08-12 WO PCT/US1993/007700 patent/WO1994004640A1/en not_active Application Discontinuation
- 1993-08-12 EP EP93920103A patent/EP0656046A4/en not_active Ceased
- 1993-08-12 JP JP6506467A patent/JPH08500388A/ja active Pending
- 1993-08-19 MA MA23264A patent/MA22957A1/fr unknown
- 1993-08-21 CN CN93118314A patent/CN1047615C/zh not_active Expired - Fee Related
- 1993-11-04 TW TW82109241A patent/TW246686B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| JPH08500388A (ja) | 1996-01-16 |
| CN1086538A (zh) | 1994-05-11 |
| AU5015293A (en) | 1994-03-15 |
| WO1994004640A1 (en) | 1994-03-03 |
| EP0656046A4 (en) | 1995-09-20 |
| EP0656046A1 (en) | 1995-06-07 |
| BR9306927A (pt) | 1999-01-12 |
| CA2142913A1 (en) | 1994-03-03 |
| MA22957A1 (fr) | 1994-04-01 |
| CN1047615C (zh) | 1999-12-22 |
| TR27633A (tr) | 1995-06-14 |
| TW246686B (zh) | 1995-05-01 |
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| Publication | Publication Date | Title |
|---|---|---|
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