CA2099508C - Compact detergent compositions with high activity cellulase - Google Patents
Compact detergent compositions with high activity cellulaseInfo
- Publication number
- CA2099508C CA2099508C CA 2099508 CA2099508A CA2099508C CA 2099508 C CA2099508 C CA 2099508C CA 2099508 CA2099508 CA 2099508 CA 2099508 A CA2099508 A CA 2099508A CA 2099508 C CA2099508 C CA 2099508C
- Authority
- CA
- Canada
- Prior art keywords
- detergent composition
- cellulase
- endoglucanase
- ser
- ala
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 108010059892 Cellulase Proteins 0.000 title claims abstract description 171
- 239000000203 mixture Substances 0.000 title claims abstract description 136
- 239000003599 detergent Substances 0.000 title claims abstract description 103
- 229940106157 cellulase Drugs 0.000 title claims abstract description 90
- 230000000694 effects Effects 0.000 title description 36
- 238000000034 method Methods 0.000 claims abstract description 57
- 150000003839 salts Chemical class 0.000 claims abstract description 26
- 239000011256 inorganic filler Substances 0.000 claims abstract description 15
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 15
- -1 alkaline-earth metal salts Chemical class 0.000 claims description 34
- 239000004744 fabric Substances 0.000 claims description 29
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 23
- 238000005406 washing Methods 0.000 claims description 23
- 102000004190 Enzymes Human genes 0.000 claims description 21
- 108090000790 Enzymes Proteins 0.000 claims description 21
- 239000004094 surface-active agent Substances 0.000 claims description 20
- 108091028043 Nucleic acid sequence Proteins 0.000 claims description 18
- 210000004027 cell Anatomy 0.000 claims description 18
- 229940088598 enzyme Drugs 0.000 claims description 18
- 108020004414 DNA Proteins 0.000 claims description 15
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 14
- 239000013598 vector Substances 0.000 claims description 13
- 239000002243 precursor Substances 0.000 claims description 11
- 241001480714 Humicola insolens Species 0.000 claims description 10
- 125000003275 alpha amino acid group Chemical group 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 9
- 108020004511 Recombinant DNA Proteins 0.000 claims description 7
- 241000894007 species Species 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical class [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 6
- 241000228212 Aspergillus Species 0.000 claims description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 4
- 150000001860 citric acid derivatives Chemical class 0.000 claims description 4
- 239000001963 growth medium Substances 0.000 claims description 4
- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 claims description 3
- 241000588724 Escherichia coli Species 0.000 claims description 3
- 241000223218 Fusarium Species 0.000 claims description 3
- 241000223198 Humicola Species 0.000 claims description 3
- 241000894006 Bacteria Species 0.000 claims description 2
- 241000187747 Streptomyces Species 0.000 claims description 2
- 241000223259 Trichoderma Species 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims description 2
- 150000002500 ions Chemical class 0.000 claims description 2
- 210000005253 yeast cell Anatomy 0.000 claims description 2
- 241000193830 Bacillus <bacterium> Species 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical class [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- 241000233866 Fungi Species 0.000 claims 1
- 241000235648 Pichia Species 0.000 claims 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims 1
- 125000002467 phosphate group Chemical class [H]OP(=O)(O[H])O[*] 0.000 claims 1
- 239000000463 material Substances 0.000 description 35
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 33
- 239000001768 carboxy methyl cellulose Substances 0.000 description 30
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 30
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 30
- 229940105329 carboxymethylcellulose Drugs 0.000 description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
- 229910001868 water Inorganic materials 0.000 description 24
- 108090000623 proteins and genes Proteins 0.000 description 20
- 102000004169 proteins and genes Human genes 0.000 description 19
- 230000002285 radioactive effect Effects 0.000 description 18
- 239000000243 solution Substances 0.000 description 17
- 238000012360 testing method Methods 0.000 description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 16
- 238000002360 preparation method Methods 0.000 description 14
- 229920001577 copolymer Polymers 0.000 description 13
- 229920001296 polysiloxane Polymers 0.000 description 13
- 108010084185 Cellulases Proteins 0.000 description 12
- 102000005575 Cellulases Human genes 0.000 description 12
- 239000012085 test solution Substances 0.000 description 12
- 238000005342 ion exchange Methods 0.000 description 11
- 238000012216 screening Methods 0.000 description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 229910021536 Zeolite Inorganic materials 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 10
- 239000010457 zeolite Substances 0.000 description 10
- 239000004615 ingredient Substances 0.000 description 9
- 239000000377 silicon dioxide Substances 0.000 description 8
- 108010071097 threonyl-lysyl-proline Proteins 0.000 description 8
- 229920000742 Cotton Polymers 0.000 description 7
- 239000007844 bleaching agent Substances 0.000 description 7
- 239000004927 clay Substances 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
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- 229920005646 polycarboxylate Polymers 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 239000000758 substrate Substances 0.000 description 7
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- WFAUDCSNCWJJAA-KXNHARMFSA-N Thr-Lys-Pro Chemical compound C[C@@H](O)[C@H](N)C(=O)N[C@@H](CCCCN)C(=O)N1CCC[C@@H]1C(O)=O WFAUDCSNCWJJAA-KXNHARMFSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- XKUKSGPZAADMRA-UHFFFAOYSA-N glycyl-glycyl-glycine Natural products NCC(=O)NCC(=O)NCC(O)=O XKUKSGPZAADMRA-UHFFFAOYSA-N 0.000 description 6
- 230000002209 hydrophobic effect Effects 0.000 description 6
- 108010020755 prolyl-glycyl-glycine Proteins 0.000 description 6
- 108010053725 prolylvaline Proteins 0.000 description 6
- 239000000523 sample Substances 0.000 description 6
- 159000000000 sodium salts Chemical class 0.000 description 6
- 244000060011 Cocos nucifera Species 0.000 description 5
- 235000013162 Cocos nucifera Nutrition 0.000 description 5
- SVWQEIRZHHNBIO-WHFBIAKZSA-N Ser-Gly-Cys Chemical compound [H]N[C@@H](CO)C(=O)NCC(=O)N[C@@H](CS)C(O)=O SVWQEIRZHHNBIO-WHFBIAKZSA-N 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 244000005700 microbiome Species 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 239000002689 soil Substances 0.000 description 5
- 229910021653 sulphate ion Inorganic materials 0.000 description 5
- FUHFYEKSGWOWGZ-XHNCKOQMSA-N Asn-Gln-Pro Chemical compound C1C[C@@H](N(C1)C(=O)[C@H](CCC(=O)N)NC(=O)[C@H](CC(=O)N)N)C(=O)O FUHFYEKSGWOWGZ-XHNCKOQMSA-N 0.000 description 4
- AAIUGNSRQDGCDC-ZLUOBGJFSA-N Asp-Cys-Cys Chemical compound C([C@@H](C(=O)N[C@@H](CS)C(=O)N[C@@H](CS)C(=O)O)N)C(=O)O AAIUGNSRQDGCDC-ZLUOBGJFSA-N 0.000 description 4
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical group [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 4
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- AHZNUGRZHMZGFL-GUBZILKMSA-N Met-Arg-Ser Chemical compound CSCC[C@H](N)C(=O)N[C@H](C(=O)N[C@@H](CO)C(O)=O)CCCNC(N)=N AHZNUGRZHMZGFL-GUBZILKMSA-N 0.000 description 4
- 108091005804 Peptidases Proteins 0.000 description 4
- MKGIILKDUGDRRO-FXQIFTODSA-N Pro-Ser-Ser Chemical compound OC[C@@H](C(O)=O)NC(=O)[C@H](CO)NC(=O)[C@@H]1CCCN1 MKGIILKDUGDRRO-FXQIFTODSA-N 0.000 description 4
- 239000004365 Protease Substances 0.000 description 4
- XTZNCVSCVHTPAI-UHFFFAOYSA-N Salmeterol xinafoate Chemical compound C1=CC=CC2=C(O)C(C(=O)O)=CC=C21.C1=C(O)C(CO)=CC(C(O)CNCCCCCCOCCCCC=2C=CC=CC=2)=C1 XTZNCVSCVHTPAI-UHFFFAOYSA-N 0.000 description 4
- SNXUIBACCONSOH-BWBBJGPYSA-N Ser-Thr-Ser Chemical compound OC[C@H](N)C(=O)N[C@@H]([C@H](O)C)C(=O)N[C@@H](CO)C(O)=O SNXUIBACCONSOH-BWBBJGPYSA-N 0.000 description 4
- 239000004902 Softening Agent Substances 0.000 description 4
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 4
- 239000012190 activator Substances 0.000 description 4
- 108010077245 asparaginyl-proline Proteins 0.000 description 4
- 150000007942 carboxylates Chemical class 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- 239000002299 complementary DNA Substances 0.000 description 4
- 230000001276 controlling effect Effects 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 239000008103 glucose Substances 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 239000002773 nucleotide Substances 0.000 description 4
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- 239000007921 spray Substances 0.000 description 4
- 238000010561 standard procedure Methods 0.000 description 4
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- 108010017949 tyrosyl-glycyl-glycine Proteins 0.000 description 4
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- BIVYLQMZPHDUIH-WHFBIAKZSA-N Asp-Gly-Cys Chemical compound C([C@@H](C(=O)NCC(=O)N[C@@H](CS)C(=O)O)N)C(=O)O BIVYLQMZPHDUIH-WHFBIAKZSA-N 0.000 description 3
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- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 3
- OLPPXYMMIARYAL-QMMMGPOBSA-N Gly-Gly-Val Chemical compound CC(C)[C@@H](C(O)=O)NC(=O)CNC(=O)CN OLPPXYMMIARYAL-QMMMGPOBSA-N 0.000 description 3
- WMGHDYWNHNLGBV-ONGXEEELSA-N Gly-Phe-Ala Chemical compound OC(=O)[C@H](C)NC(=O)[C@@H](NC(=O)CN)CC1=CC=CC=C1 WMGHDYWNHNLGBV-ONGXEEELSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
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- 239000010452 phosphate Substances 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
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- 229920000573 polyethylene Polymers 0.000 description 1
- 238000003752 polymerase chain reaction Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
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- 239000000843 powder Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- NJKRDXUWFBJCDI-UHFFFAOYSA-N propane-1,1,2,3-tetracarboxylic acid Chemical class OC(=O)CC(C(O)=O)C(C(O)=O)C(O)=O NJKRDXUWFBJCDI-UHFFFAOYSA-N 0.000 description 1
- NJEVMKZODGWUQT-UHFFFAOYSA-N propane-1,1,3,3-tetracarboxylic acid Chemical class OC(=O)C(C(O)=O)CC(C(O)=O)C(O)=O NJEVMKZODGWUQT-UHFFFAOYSA-N 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
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- 238000004007 reversed phase HPLC Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 1
- 235000019254 sodium formate Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 108010061238 threonyl-glycine Proteins 0.000 description 1
- 210000001541 thymus gland Anatomy 0.000 description 1
- 230000002103 transcriptional effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 150000003641 trioses Chemical class 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 108010079202 tyrosyl-alanyl-cysteine Proteins 0.000 description 1
- 108010020532 tyrosyl-proline Proteins 0.000 description 1
- 108010003137 tyrosyltyrosine Proteins 0.000 description 1
- 108010073969 valyllysine Proteins 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Enzymes And Modification Thereof (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP91870006.3A EP0495344A1 (en) | 1991-01-16 | Compact detergent compositions | |
EP91870006.3 | 1991-01-16 | ||
EP91202879.2 | 1991-11-06 | ||
EP91202879A EP0495257B1 (en) | 1991-01-16 | 1991-11-06 | Compact detergent compositions with high activity cellulase |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2099508A1 CA2099508A1 (en) | 1992-07-17 |
CA2099508C true CA2099508C (en) | 1999-03-23 |
Family
ID=26129458
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA 2099508 Expired - Fee Related CA2099508C (en) | 1991-01-16 | 1992-01-15 | Compact detergent compositions with high activity cellulase |
Country Status (13)
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ATE222286T1 (de) * | 1994-06-17 | 2002-08-15 | Genencor Int | Reinigungsverfahren mit pflanzenzellwände abbauendes hemicellulase enzym enthaltender zusammensetzung und deren verwendung in reinigungsverfahren |
CN1079432C (zh) * | 1994-12-28 | 2002-02-20 | 陕西科学院酶工程研究所 | 酶洗纺织品专用酶制剂的制备方法 |
GB201406268D0 (en) * | 2014-04-08 | 2014-05-21 | Pq Silicas Uk Ltd | Particulate zeolite composition |
-
1992
- 1992-01-14 MA MA22671A patent/MA22386A1/fr unknown
- 1992-01-14 PH PH43772A patent/PH30778A/en unknown
- 1992-01-14 EG EG2092A patent/EG20196A/xx active
- 1992-01-15 JP JP4506431A patent/JPH06505049A/ja not_active Ceased
- 1992-01-15 CA CA 2099508 patent/CA2099508C/en not_active Expired - Fee Related
- 1992-01-15 IE IE920115A patent/IE920115A1/en unknown
- 1992-01-15 AU AU15420/92A patent/AU662736B2/en not_active Ceased
- 1992-01-15 MX MX9200171A patent/MX9200171A/es not_active IP Right Cessation
- 1992-01-15 NZ NZ24130892A patent/NZ241308A/en unknown
- 1992-01-16 IN IN33DE1992 patent/IN185871B/en unknown
- 1992-01-16 CN CN 92100955 patent/CN1034084C/zh not_active Expired - Fee Related
- 1992-01-16 MY MYPI92000070A patent/MY108934A/en unknown
- 1992-01-16 PT PT10002792A patent/PT100027B/pt not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
PT100027B (pt) | 1999-06-30 |
AU662736B2 (en) | 1995-09-14 |
MY108934A (en) | 1996-11-30 |
CN1034084C (zh) | 1997-02-19 |
CN1064309A (zh) | 1992-09-09 |
EG20196A (en) | 1997-10-30 |
MX9200171A (es) | 1993-05-01 |
IN185871B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 2001-05-12 |
JPH06505049A (ja) | 1994-06-09 |
AU1542092A (en) | 1992-08-27 |
CA2099508A1 (en) | 1992-07-17 |
PT100027A (pt) | 1993-05-31 |
MA22386A1 (fr) | 1992-10-01 |
NZ241308A (en) | 1994-07-26 |
PH30778A (en) | 1997-10-17 |
IE920115A1 (en) | 1992-07-29 |
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Legal Events
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MKLA | Lapsed |