CA2098396C - Layered oxide materials and swollen and pillared forms thereof - Google Patents
Layered oxide materials and swollen and pillared forms thereof Download PDFInfo
- Publication number
- CA2098396C CA2098396C CA002098396A CA2098396A CA2098396C CA 2098396 C CA2098396 C CA 2098396C CA 002098396 A CA002098396 A CA 002098396A CA 2098396 A CA2098396 A CA 2098396A CA 2098396 C CA2098396 C CA 2098396C
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- Prior art keywords
- ray diffraction
- diffraction pattern
- swollen
- layered
- oxide
- Prior art date
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- 239000000463 material Substances 0.000 title claims abstract description 169
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- 238000001354 calcination Methods 0.000 claims abstract description 17
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- 238000000034 method Methods 0.000 claims description 28
- -1 alkaline earth metal cations Chemical class 0.000 claims description 27
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- 229910002804 graphite Inorganic materials 0.000 description 1
- 229910052621 halloysite Inorganic materials 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 239000000138 intercalating agent Substances 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000002648 laminated material Substances 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000012229 microporous material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-O oxonium Chemical compound [OH3+] XLYOFNOQVPJJNP-UHFFFAOYSA-O 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 208000012318 pareses Diseases 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000003058 platinum compounds Chemical class 0.000 description 1
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- APSPVJKFJYTCTN-UHFFFAOYSA-N tetramethylazanium;silicate Chemical compound C[N+](C)(C)C.C[N+](C)(C)C.C[N+](C)(C)C.C[N+](C)(C)C.[O-][Si]([O-])([O-])[O-] APSPVJKFJYTCTN-UHFFFAOYSA-N 0.000 description 1
- 229940095070 tetrapropyl orthosilicate Drugs 0.000 description 1
- ZQZCOBSUOFHDEE-UHFFFAOYSA-N tetrapropyl silicate Chemical compound CCCO[Si](OCCC)(OCCC)OCCC ZQZCOBSUOFHDEE-UHFFFAOYSA-N 0.000 description 1
- LPSKDVINWQNWFE-UHFFFAOYSA-M tetrapropylazanium;hydroxide Chemical compound [OH-].CCC[N+](CCC)(CCC)CCC LPSKDVINWQNWFE-UHFFFAOYSA-M 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/16—Clays or other mineral silicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/049—Pillared clays
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/026—After-treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dispersion Chemistry (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Glass Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- X-Ray Techniques (AREA)
- Materials For Medical Uses (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US64033091A | 1991-01-11 | 1991-01-11 | |
| US64034091A | 1991-01-11 | 1991-01-11 | |
| US640,330 | 1991-01-11 | ||
| US640,340 | 1991-01-11 | ||
| US811,360 | 1991-12-20 | ||
| US07/811,360 US5250277A (en) | 1991-01-11 | 1991-12-20 | Crystalline oxide material |
| PCT/US1992/000095 WO1992011934A1 (en) | 1991-01-11 | 1992-01-10 | Layered oxide materials and swollen and pillared forms thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2098396A1 CA2098396A1 (en) | 1992-07-12 |
| CA2098396C true CA2098396C (en) | 2003-10-07 |
Family
ID=27417658
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002098396A Expired - Fee Related CA2098396C (en) | 1991-01-11 | 1992-01-10 | Layered oxide materials and swollen and pillared forms thereof |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP0566680B1 (OSRAM) |
| JP (1) | JP3360176B2 (OSRAM) |
| KR (1) | KR100204951B1 (OSRAM) |
| AT (1) | ATE165531T1 (OSRAM) |
| AU (1) | AU654329B2 (OSRAM) |
| CA (1) | CA2098396C (OSRAM) |
| DE (1) | DE69225311T2 (OSRAM) |
| DK (1) | DK0566680T3 (OSRAM) |
| ES (1) | ES2115669T3 (OSRAM) |
| TW (1) | TW224075B (OSRAM) |
| WO (1) | WO1992011934A1 (OSRAM) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5354718A (en) * | 1993-04-05 | 1994-10-11 | Mobil Oil Corporation | Catalyst and process for isoparaffin-olefin alkylation |
| ES2124154B1 (es) | 1995-11-08 | 1999-12-01 | Univ Politecnica De Valencia C | Metodo de preparaciion y propiedades cataliticas de un solido microporoso con alta superficie externa. |
| WO1999065822A1 (en) * | 1998-06-18 | 1999-12-23 | The Dow Chemical Company | New process to make mesoporous crystalline materials, and materials made by such process |
| ES2156509B1 (es) * | 1998-10-27 | 2002-02-01 | Univ Valencia Politecnica | Oxido acido con caracteristicas micro y mesoporosas: itq-36. |
| EP1242343B1 (en) * | 1999-09-20 | 2004-06-23 | Consejo Superior De Investigaciones Cientificas | Aromatics alkylation |
| FR2867200B1 (fr) * | 2004-03-05 | 2006-05-26 | Inst Francais Du Petrole | Solide cristallise uvl-1 et procede d'hydroconversion / hydrocraquage de charges hydrocarbonees |
| FR2895412B1 (fr) * | 2005-12-23 | 2008-05-23 | Saint Gobain Vetrotex | Procede de preparation de nanoparticules en feuillets et nanoparticules obtenues. |
| EP2051805B1 (en) * | 2006-07-28 | 2019-10-02 | ExxonMobil Chemical Patents Inc. | A mcm-22 family molecular sieve composition, its method of making, and use for hydrocarbon conversions |
| EP2051804B1 (en) * | 2006-07-28 | 2016-08-10 | ExxonMobil Chemical Patents Inc. | Molecular sieve composition (emm-10-p), its method of making, and use for hydrocarbon conversions |
| US7959899B2 (en) | 2006-07-28 | 2011-06-14 | Exxonmobil Chemical Patents Inc. | Molecular sieve composition (EMM-10-P), its method of making, and use for hydrocarbon conversions |
| JP5571950B2 (ja) * | 2006-07-28 | 2014-08-13 | エクソンモービル・ケミカル・パテンツ・インク | モレキュラーシーブ組成物（ｅｍｍ−１０）とその製造方法、およびこの組成物を用いた炭化水素の転換方法 |
| TWI414482B (zh) * | 2010-08-12 | 2013-11-11 | 私立中原大學 | 無機層狀材料的脫層方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4176090A (en) * | 1975-11-18 | 1979-11-27 | W. R. Grace & Co. | Pillared interlayered clay materials useful as catalysts and sorbents |
| US4248739A (en) * | 1979-09-04 | 1981-02-03 | W. R. Grace & Co. | Stabilized pillared interlayered clays |
| FR2563446A1 (fr) * | 1984-04-25 | 1985-10-31 | Raffinage Cie Francaise | Nouvelle zeolite a structure bidimensionnelle et application de ladite zeolite |
| US4859648A (en) * | 1984-12-28 | 1989-08-22 | Mobil Oil Corporation | Layered metal chalcogenides containing interspathic polymeric chalcogenides |
| US4954325A (en) * | 1986-07-29 | 1990-09-04 | Mobil Oil Corp. | Composition of synthetic porous crystalline material, its synthesis and use |
| IT1213363B (it) * | 1986-10-22 | 1989-12-20 | Eniricerche Spa | Materiale sintetico cristallino poroso contenente ossidi di silicio titanio e gallio. |
| KR920702852A (ko) * | 1990-02-06 | 1992-10-28 | 에드워드. 에이취. 바란스 | 케냐이트-타입 층상 실리케이트 물질의 합성 및 주상화 방법 |
-
1992
- 1992-01-10 CA CA002098396A patent/CA2098396C/en not_active Expired - Fee Related
- 1992-01-10 AU AU12308/92A patent/AU654329B2/en not_active Ceased
- 1992-01-10 AT AT92904552T patent/ATE165531T1/de not_active IP Right Cessation
- 1992-01-10 ES ES92904552T patent/ES2115669T3/es not_active Expired - Lifetime
- 1992-01-10 EP EP92904552A patent/EP0566680B1/en not_active Expired - Lifetime
- 1992-01-10 WO PCT/US1992/000095 patent/WO1992011934A1/en not_active Ceased
- 1992-01-10 DE DE69225311T patent/DE69225311T2/de not_active Expired - Lifetime
- 1992-01-10 KR KR1019930702064A patent/KR100204951B1/ko not_active Expired - Fee Related
- 1992-01-10 JP JP50446092A patent/JP3360176B2/ja not_active Expired - Lifetime
- 1992-01-10 DK DK92904552T patent/DK0566680T3/da active
- 1992-04-18 TW TW081103040A patent/TW224075B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| WO1992011934A1 (en) | 1992-07-23 |
| JPH06505224A (ja) | 1994-06-16 |
| DE69225311T2 (de) | 1998-08-20 |
| EP0566680B1 (en) | 1998-04-29 |
| AU654329B2 (en) | 1994-11-03 |
| KR930703068A (ko) | 1993-11-29 |
| KR100204951B1 (ko) | 1999-06-15 |
| TW224075B (OSRAM) | 1994-05-21 |
| EP0566680A1 (en) | 1993-10-27 |
| ES2115669T3 (es) | 1998-07-01 |
| AU1230892A (en) | 1992-08-17 |
| ATE165531T1 (de) | 1998-05-15 |
| EP0566680A4 (OSRAM) | 1994-04-27 |
| DK0566680T3 (da) | 1998-10-07 |
| DE69225311D1 (de) | 1998-06-04 |
| JP3360176B2 (ja) | 2002-12-24 |
| CA2098396A1 (en) | 1992-07-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |