CA2044865C - Woody board - Google Patents

Woody board Download PDF

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Publication number
CA2044865C
CA2044865C CA002044865A CA2044865A CA2044865C CA 2044865 C CA2044865 C CA 2044865C CA 002044865 A CA002044865 A CA 002044865A CA 2044865 A CA2044865 A CA 2044865A CA 2044865 C CA2044865 C CA 2044865C
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Canada
Prior art keywords
woody
board
substrate
thickness
molded
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CA002044865A
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French (fr)
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CA2044865A1 (en
Inventor
Yusho Nakamoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Juken Sangyo Co Ltd
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Juken Sangyo Co Ltd
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Publication of CA2044865A1 publication Critical patent/CA2044865A1/en
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Publication of CA2044865C publication Critical patent/CA2044865C/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/06Making particle boards or fibreboards, with preformed covering layers, the particles or fibres being compressed with the layers to a board in one single pressing operation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/02Manufacture of substantially flat articles, e.g. boards, from particles or fibres from particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27DWORKING VENEER OR PLYWOOD
    • B27D1/00Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)
  • Veneer Processing And Manufacture Of Plywood (AREA)
  • Laminated Bodies (AREA)

Abstract

ABSTRACT OF THE DISCLOSURE

Disclosed is a woody board, in which a molded layer of a woody material of a wood powder or woody fibers is provided on one surface or both surfaces of a woody substrate of a molded sheet of a coniferous tree plywood or coniferous tree LVL, and a method of preparing said woody board. The woody board is prepared by molding a woody material mix comprising an adhesive and a woody material of a wood powder or woody fibers on at least one surface of a woody substrate. The woody board has a flat and smooth surface and has a high mechanical strength and a high screw-drawing resistance.

Description

WOODY BOARD

BACKGRO~ND OF THE INVENTION

Fiel~_e~_~h~ ention The present invention relates to a woody board, which has sufficient ~echanical strength as a woody material and which has a smooth surface.

Description of Prior Art Various simplex boards prepared by separately shaping a wood powder, woody fibers or wood chips, optionally along with a binder, under pressure have heretofore been known, but a composite board composed of a plurality of such simplex boards is unknown.
A wood powder and woody fibers are well known in this technical field.
Briefly, the former is one obtained by ~inely pulverizing wood like sawdust; and the latter are obtained by disintegrating wood into fibers.
Wood chips in this case are also known, which are obtalned by shaving or cutting a wood ba.r from the top end thereof, with the bar being rotated in the same way that a pencil is shaven, into chips each having a si~e oE
about 1.5 mm or less as the thickness, about 30 mm or less as the width and about 100 mm or less as the length. Examples of molded boards made oE such woody material will be mentioned. Example of simplex boards made of a wood powder, are particle boards; examples of simplex boards made of woody fibers are hard boards, middle density fiber boards (MDF) and insulation boards; and examples of simplex boards made of wood chips, are strand boards and oriented strand boards ~OSB).
These boards have both merits and demerits, and they often cause some inconvenience in actual use thereof.
In manufacturing stairs, service counters, doors and the like, when substrates which have a sufficient thickness and a sufficient mechanical strength and wh;ch have a smooth surface capable of being covered with a PAT 176~8-1 4~6~
decorative sheet with screws are needed, but the above-mentioned simplex boards could not be used as such substrates. Of these boards, a hard board may be mentioned to have a relatively high mechanical strength and a relatively satisfactory surface smoothness. However, it is impossible to obtain a hard board having sufficient thickness. Additionally, since a hard board is prepared by a wet method, it has a large specific gravity and is therefore defectively extremely heavy. Further, screws do not hold well in hard board as the board has a low screw-drawing resistance value.
It may be considered to laminate an MDF having a sufficient surface smoothness onto the both surfaces of a strand board or OSB, but adhesion between them would be poor and unstable since the strand board and OSB have a poor surface smoothness. Fven if they could be laminated, the resulting laminated product will have the problem that the laminating cost is high since double lamination is necessary. In addition, as an MDF has low mechanical strength, it is diEficult to prepare a too thin MDF. As a result, where the both surfaces of a strand board or OSB are laminated with such a thick MDF by double lamination, the resulting laminate would thereby have a lowered mechanical strength, disadvantageously.
In addition to the above-mentioned boards, where a plywood or L~L
(laminated veneer lumber) is made from a coniferous tree material, there occurs a problem that the woody product could hardly have a smooth surface.
This is because when a coniferous tree material is formed into veneers, in general, the surfaces often have knots and cracks. There are few coniferous trees which have no drawbacks, like lauan and other trees from the South Sea Islands. Though there would be some knot-free good tree materials to be derived from coniferous trees, the amount is small and the cost thereof ls high. Additionally, even defectless coniferous tree materials often giva shaped articles having uneven surfaces because of the pressure as applied thereto for shaping under pressure, since the hardness of them is not constant but various depending upon the winter-grown part being hard and the summer-grown part being soft.
Undar the situation, in order to overcome the problems, there have been proposed a patching method of cutting out the knots in the surface veneer followed by embedding wood patches in the cut out parts and a method of laminating a woody material having a smooth surface, such as an MDF
PAT 1768~-1 (middle density fiber board) to the both surEaces of a substrate woody material. However, the former pa-tching method causes a disadvantageous drawbac~ that the outward appearance of the patched surface is bad due to the existence of embedding traces. Even though an additional thin decorative paper or decorative veneer is laminated as a secondary lamination so as to cover the patched surface, such an unfavorable outward appearance of the patched surface would still appear through the surface of the covered decorative paper or veneer.
On the other hand, the latter method also has a troublesome problem that the mechanical strength of the resulting laminate board is low, because of the following reasons. In general, an MDF could not be thinner than 3 mm, as too thin MDF sheets would curve owing to insufficient strength. Therefore, even when the thinnest MDF sheet having a thickness of 3 mm is laminated to the both surfaces of a substrate woody material by the method, the resulting plywood is to have a total thickness of the both laminated MDF's of being 6 mm, so that the mechanical strength of the plywood is lowered relative to the thickness. In this connection, if an MD~ sheet is laminated onto only one surface of a subs-trate, the resulting plywood laminate is also disadvantageous as it is often warped.
S~MMARY OF THE INVENTION

The present invention provi.des a woody board, which has good phys:Lcal properties with respect to the mechanical strength, the surfnce smoottmess and the screw-drawing resistance value and which is prepared at a low manufacture cost.
The present invention also provides a method of preparing a woody board having a good surface smoothness and a sufficient mechanical strength.
The present invention also provides a method of preparing a woody material of a coniferous tree material, which has a woody substrate of a coniferous tree woody material and which has a smooth surface with neither warp nor reduction of the mechanical strength.
Specifically, there i5 provided in accordance with the present invention a woody board, which is characterized in that said woody board 4~5 uses a coniferous tree material of a coniferous tree plywood or coniferous tree LVL as a woody substrate and is formed with molded layer of woody material such as wood powder or woody fibers on one surface or both surfaces of the woody substrate. In preparing such a woody board oE the present invention, it is desired, if possible, tha-t the woody substrate and the molded layer of a woody material are pressed simultaneously under heat and pressure.

DETAILED DESCRIPTION OF THE INVENTION
As one embodiment, the present invention provides a method of preparing a woody board in which a woody substrate of coniferous tree LVL, coniferous tree plywood or the like is sandwiched between molded layers of a woody material such as a wood powder or woody fibers to form a woody board, and the method is carried out by first forming a woody material layer of a wood powder or woody fibers, as previously blended with an adhesive by spraying, then putting an LVL, plywood or the like thereon, and thereafter further :Eorming said woody material layer thereon, whereupon al].
the piled-up layers are integrated by hot-pressing under pressure and heat.
In this case, the coniferous tree plywood or LVL may be either in the form of a previously shaped one or in the form of a combination of plural veneers as merely piled up prior to being shaped into a plywood.
The raw material of a board to be used in the present invention, which comprises a woody material of a wood powder or woody fibers and an adhesive, may be one tv be speciEica:Lly prepared for repairing or may also be any general raw material for ordinary particle boards or fiber boards.
Therefore, as a woody material for use in the present invention, a wood powder as well as fine wood chips to be prepared by finely pulverizing a wood material and small wood flakes to be obtained by cutting or shaving a wood material, and also shaped bodies to be formed by shaping such a wood powder, wood chips or wood flakes under pressure, and fibrous materials of them may be employed. The particle size of the wood powder as well as the size of the wood flakes may well be selected and determined in accordance with the intended surface smoothness of the final product of a woody board.
Recently, a special attention has been paid to a middle density fiber 2~ 8~5 board (MDF), which is said to have a property similar t~ a plywood. As the material of such a board is composed of fine woody fibers, the final product to be obtained by using it may thereby have a better surface smoothness. Therefore, it is recommended to employ the raw material.
The hot-pressing method of forming the woody board of the present invention may be either a hot plate-pressing method or a hot roll-pressing method. As a heating means in the method, a hot plate or a hot roll may be applied to the materials to be laminated and molded under pressure, or hot steam may also be applied thereto under pressure. If desired, the materials to be laminated and molded may previously be heated by blowing hot steam thereon or by heating them in an oven, and the thus preheated materials may be pressed and integrated to obtain the intended woody board.
As the adhesive to be applied to the respective molding materials and laminates of the present invention, a hot-gluing adhesive is used since the molding materials and laminates are pressed under heat to give an integrated woody board. Any conventional adhesives well known in this technical field, such as phenolic resins and melamine resins, can be used for the purpose. Where thermosetting and water-proofing resins such as melamine resins are selectively used, the water-proofness of the molded board layers is advantageously improved.
The thickness of the molded layer of a woody mate.rial may well be increased or decreased in accordance with the object of the woody board to be prepared. For instance, where the ob;ect of the board is to have merely a smooth surface, the layer of the molded layer may be thin to have a thickness of from 1 to 2 mm after shaped. On the other hand, where the surface of the woody material is to be further cut and machined, the thickness may bs approximately from 5 to 10 mm.
It is preferred that the molded layer of a woody material is put on the both surf~ces of the substrate both in the same thickness, in view of the balance to be formed. In accordance with the present invention, however, since the thickness of the molded layer of a woody material may well be similar to that of the substrate, it is possible to prepare a one side-molded woody board with no warp and it is also possible to prepare a both sides-molded woody board where each molded layer on each surface has a different thickness.

The woody material for the molded layer may be elther in the form of an already cold-pressed sheet or an adhesive applied but no-t cold-pressed sheet. In the latter case, the woody material is in the form of a compound of a wood powder or woody fibers as already blended with an adhesive. If desired, the woody material for molded layer may also be in the Eorm of a sheet to be obtained by pre-hot-pressing the woody material along with an adhesive. In that case, a two-staee polymerizing resin may advantageously be used as an adhesive. Precisely, the respective woody material layers may be preshaped by the first hot pressing and thereafter they are integrated by the ne~t hot-pressing.
Where a plywood or LVL ls used as the woody substrate in preparing the woody board of the present invention, a coniferous tree plywood or a coniferous tree LVL is preferred in view of the obiect of the present invention. An adhesive may be coated to such a coniferous tree molded to give a molded coniferous tree plywood or LVL. The resulting coniferous tree plywood or LVL layer can be used as a molded substrate. The woody substrate may also be in the form of a sheet as prepared by hot-pressing the corresponding plywood or LVL piled strips, or in the form of cold-pressed piled strips prior to hot-pressing, or itl the form of an adhesive-applied but not cold-pressed layer of veneers or laminates. Anyhow, all the woody substrate materials may be hot-pressed with putting other raw board materials thereon to give the woody board of the present invention.
Where a board only is formed of an MDF, the mechanical strength of the resulting MDF board is lowered so that the fle~ibility of the board is large, as mentioned above. Therefore, a satisfactory board, e.g., large-sized board, could not be formed of such an MDF. In addition, since an MDF
board is often wavy or warped, the thickness thereoE is generally up to 3 mm. Because of these reasons, a thin and strong woody material could not be obtained by molding of MDF layers. In accordance with the present invention, however, where a woody substrate is a coniferous tree LVL, a woody material layer is formed on one or both surfaces of the woody substrate so that the board layer may well have a thickness oE 3 mm or less in order to obtain the intended woody board. As a result, the woody board to be obtained by the present invention may have a smooth surface and a high mechanical strength.

In addition, in accordance with the present invention, an extremely thin woody material molded layer May be formed on the surface(s) of the woody laminate substrate. Therefore, even though the coat is formed on only one surface of the substrate to form a one surface-molded board, the resulting one surface-molded ~oard is advantageously free from warping.
The present invention will be explained in more detail by way of the following examples, which, however, are not intended to restrict the scope of the present invention. Unless otherwise specifically indicated, "%" is % by weight in these examples.
E~AMPLE 1 A melamine resin adhesive was applied to five sheets of Douglas fir rotary veneer each having a thickness of 2.5 mm in the direction perpendicular to the fibrous direction of each sheet by a known method of forming a conventional plywood, and the thus adhesive coated sheets were cold-pressed to form a woody substrate. The veneers constituting the surfaces of the substrate had 25 knots each having a diameter of approximately 35 mm in an area of 1850 mm x 980 mm.
On the other hand, as woody material, wood of Douglas fir rotary veneer was finely pulverized, and ths resulting wood powder was blended with 12~ of a melamine resin adhesive by spraying to prepare an MDF
material. This was put in an iron plate in a thickness of 15 mm, and the previously cold-pressed plywood was layered thereover. Further, the wood powder was layered over the plywood in a thickness of 15 mm.
The thus piled-up woody layers were inserted into a hot pressing machine along with the iron plate, where they are hot-pressed at a temperature oE 130C and a pressure of 12 kg/m2 for 10 minutes.
Accordingly, a flat and smooth 14.5 mm thick woody board having a board layer of one mm thickness on both surfaces thereof was prepared.
A decorative veneer of Douglas fir having a thickness of 0.6 mm was stuck to one surface of the woody board to give a decorative plywood having an extremely flat and smoothly finished surface.

~ 35 EX~MPLE 2 In accordance wîth the same process as in Example 1, except that the woody material layer was put on only one surface of the cold-pressed plywood substrate, a woody board having one smooth and flat surface was obtained by hot-pressing.
The woody board thus obtained warped with the smooth surface being convex in such a condition that the arrow height was 1.5 mm along the length of 1850 mm. However, warping of such a degree has heretofore been said to cause no problem in practical use of the board, and the board withstood the product standard test.

In accordance with the same process as in Example 1, except that the thickness of the rotary veneer of Douglas fir, which was 2.5 mm in Example 1, was varied to 1.7 mm, a laminate substrate was prepared. Both surfaces of the substrate were coated with an MDF having a thickness of 3 mm, in place of the woody material as used in Example 1. The thus piled-up woody layers were then hot-pressed in the same way as in Example 1 to obtained a woody material having the same thickness as that obtained in Example 1.
The thus prepared woody material had a low and insufficient mechanical strength relative to the thickness thereof and therefore it was not suitable to prac-tical use. The mechanical strength values of the product are shown in Table 1 below.

The same process as in Comparative Example 1 was repeated, except -that an MDF was coated on only one surface by hot-pressing. Though the woody material product obtained had a smooth surface, it warped with the MDF
coated surface being convex in such a condition that the arrow height was 13 mm in the direction of the length of being 1850 mm.
The warp was too large so that the product was not useful.

The same process as in Example 1 was repeated, except that the thickness of the rotary veneer of Douglas fir rotary veneer, which was 2.5 mm in Example 1, was varied to 2.9 mm and that the woody material was not used, but a coniferous tree plywood was only used. Accordingly, a decorative plywood havi.ng almost the same thickness as that of the product oE Example 1 was prepared.
The decorative plywood thus prepared had many knots and cracks, and the outward appearance thereof did not stand the test.
The physical data of the products obtained in the above-mentioned examples and comparative examples are shown in Table 1 below.

s Table 1 Bending Bending Young's Strength Modulus Arrow Height Outward (kg/m2) (x 103 kg/m2) oE Warp (mm) Appearance Example 1 555 5.15 0 0 Example 2 542 5.25 1.5 0 15 Comparative Example 1 342 3.11 0 0 Comparative Example 2 524 5.29 13 0 Comparative Example 3 683 10.04 0 Note: Arrow height of warp Indicates the hei~ht of the warp at the center along the length of 1850 mm.

As is understood ~rom the results and data obtained in the above-mentioned examples and comparative examples, substantially warp-free woody boards and decorated boards ~lich have smooth and flat outward surfaces and which have sufficient mechanica]. strength are obtained by the method of the prasent invention, and the industrial advantage of the present invention is noticeable.
~ hile the invention has been described in detail and with reference to specific embodiments thereof, it will be apparent to one skilled in the art that various changes and modifications can be made therein without departing from the spirit and scope thereof.

Claims (10)

1. A woody board comprising an integrally molded layer of woody fibers provided on one surface or both surfaces of a woody substrate of plywood;
wherein said woody substrate consists of several sheets of tree veneer laminated to form said substrate; and in which said molded layer of woody fibers is one that has been pressed and molded onto said substrate;
wherein:
said substrate consists of five layers of a coniferous wood;
the substrate has a thickness of 12.5 mm; and the molded layer is in the form of a middle density fiber board having a thickness of 3 mm or less.
2. The woody board as claimed in Claim 1, wherein the thickness of the molded layer of woody fibers is 1 to 2 mm.
3. The woody board as claimed in Claim 1 and wherein said molded layer is provided on both surfaces of the woody substrate and pressed so as to integrally form a middle density fiber board having a thickness of 1 mm; and wherein each molded layer is laminated with a decorative veneer.
4. The woody board as claimed in Claim 1, wherein the woody substrate is a coniferous tree plywood or a coniferous laminated veneer lumber comprising five coniferous tree strips pressed together in a direction perpendicular to the fibrous direction of each strip.
5. The woody board as claimed in Claim 1, wherein the thickness of the veneer is 2.5 mm.
6. The woody board as claimed in Claim 1, wherein said molded layer of woody fibers is on one surface only of said woody substrate and the resulting woody board has an arrow height of warp of 1.5 mm at the center of a length of 1850 mm of said woody board.
7. A method of preparing a woody board in which a woody material mix obtained by blending an adhesive and woody fibers is molded on at least one surface of a woody substrate of a coniferous tree plywood;
the woody substrate being made from five sheets of a coniferous tree veneer that are laminated to form a substrate having a thickness of 12.5 mm;
and wherein the or each layer of woody material mix is pressed and molded onto said substrate to create a middle density fiber board having a thickness of 3 mm or less.
8. The method according to Claim 7 wherein the woody material mix is applied to the woody substrate by a hot-pressing method.
9. The method of Claim 8 wherein the hot-pressing method is a hot plate-pressing method.
10. The method of Claim 8 wherein the hot-pressing method is a hot roll-pressing method.
CA002044865A 1990-06-19 1991-06-18 Woody board Expired - Lifetime CA2044865C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JPHEI2-160399 1990-06-19
JP2160399A JP3038488B2 (en) 1990-06-19 1990-06-19 Method of manufacturing coniferous wood

Publications (2)

Publication Number Publication Date
CA2044865A1 CA2044865A1 (en) 1991-12-20
CA2044865C true CA2044865C (en) 2000-03-14

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CA002044865A Expired - Lifetime CA2044865C (en) 1990-06-19 1991-06-18 Woody board

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EP (1) EP0462586B1 (en)
JP (1) JP3038488B2 (en)
KR (1) KR0183985B1 (en)
AU (1) AU653529B2 (en)
CA (1) CA2044865C (en)
DE (1) DE69131547T2 (en)
NZ (1) NZ238616A (en)

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US5855832A (en) * 1996-06-27 1999-01-05 Clausi; Robert N. Method of molding powdered plant fiber into high density materials
FI972955A (en) * 1997-07-11 1999-01-12 Roctex Oy Ab The fiber mat
US6309492B1 (en) * 1998-09-16 2001-10-30 Marc A. Seidner Polymer fill coating for laminate or composite wood products and method of making same
KR100446710B1 (en) * 2002-07-04 2004-09-07 김태홍 Pannel for construction and producing method thereof
DE202006012116U1 (en) * 2006-08-08 2007-12-27 Vöhringer GmbH Wood panel
RU2007124945A (en) * 2007-07-02 2009-01-10 Михаил Мукарасович Ахмеджанов (RU) METHOD FOR PRODUCING WOODBOARDS
JP5736582B2 (en) * 2010-10-07 2015-06-17 地方独立行政法人北海道立総合研究機構 Method for preventing breakthrough and its woody material
JP2014083810A (en) * 2012-10-25 2014-05-12 Nichiha Corp Woody decorative bed plate composite base material
JP6782524B2 (en) * 2014-04-02 2020-11-11 ニチハ株式会社 Wood board and decorative plywood
FI129218B (en) 2016-11-22 2021-09-30 Metsaeliitto Osuuskunta Coated multi-ply wood panel and method of producing a core board
JP6985657B2 (en) * 2017-03-13 2021-12-22 地方独立行政法人北海道立総合研究機構 Manufacturing method of wood composite board
JP7149817B2 (en) * 2018-11-19 2022-10-07 ニチハ株式会社 Method for manufacturing wooden board and decorative plywood

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FR1444912A (en) * 1965-05-28 1966-07-08 Composite panel and improved process for its manufacture
DE1653323A1 (en) * 1966-05-06 1971-02-04 Triangel Spanplattenwerke Der Process for the production of a multilayer board from wood materials
BE788503A (en) * 1972-09-07 1973-01-02 Santens Paul E G EL MADE IN ACCORDANCE WITH THIS METHOD. PROCESS FOR THE MANUFACTURE OF A PANEL AND PANE
NZ200674A (en) * 1981-05-26 1985-09-13 Earl Herbert Robbins A composite wood panel that is veneered and has an intermediate veneer
FR2568510B1 (en) * 1984-08-01 1986-09-05 Garcia Jean MANUFACTURE OF PANELS OF AGGLOMERATE PARTICLES AND OR FIBERS, COMPRISING A WOODEN CORE, OR ANY OTHER MATERIAL. SLICED WOOD OR SAW
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SE461775B (en) * 1986-04-24 1990-03-26 Swedoor Ab PROCEDURE FOR MANUFACTURE OF DEEP SHAPED DISC
SE458839B (en) * 1988-03-16 1989-05-16 Inst Traeteknisk Forskning PROCEDURES FOR THE PREPARATION OF CHEESE DISCOVERED MACHINES DETAILED ACCORDING TO THE PROCEDURE

Also Published As

Publication number Publication date
AU653529B2 (en) 1994-10-06
CA2044865A1 (en) 1991-12-20
EP0462586A3 (en) 1993-01-13
AU7914991A (en) 1992-01-02
NZ238616A (en) 1994-07-26
DE69131547T2 (en) 2000-01-13
EP0462586B1 (en) 1999-08-25
KR920000447A (en) 1992-01-29
EP0462586A2 (en) 1991-12-27
KR0183985B1 (en) 1999-04-01
JP3038488B2 (en) 2000-05-08
DE69131547D1 (en) 1999-09-30
JPH0452102A (en) 1992-02-20

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