CA2042857A1 - Curable bismaleide systems - Google Patents

Curable bismaleide systems

Info

Publication number
CA2042857A1
CA2042857A1 CA002042857A CA2042857A CA2042857A1 CA 2042857 A1 CA2042857 A1 CA 2042857A1 CA 002042857 A CA002042857 A CA 002042857A CA 2042857 A CA2042857 A CA 2042857A CA 2042857 A1 CA2042857 A1 CA 2042857A1
Authority
CA
Canada
Prior art keywords
bismaleide
products
curable
systems
alkenylphenol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002042857A
Other languages
French (fr)
Other versions
CA2042857C (en
Inventor
Rudolf Brunner
Friedrich Stockinger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huntsman Advanced Materials Switzerland GmbH
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of CA2042857A1 publication Critical patent/CA2042857A1/en
Application granted granted Critical
Publication of CA2042857C publication Critical patent/CA2042857C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/12—Unsaturated polyimide precursors
    • C08G73/126—Unsaturated polyimide precursors the unsaturated precursors being wholly aromatic
    • C08G73/127—Unsaturated polyimide precursors the unsaturated precursors being wholly aromatic containing oxygen in the form of ether bonds in the main chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/36—Amides or imides
    • C08F222/40—Imides, e.g. cyclic imides
    • C08F222/404—Imides, e.g. cyclic imides substituted imides comprising oxygen other than the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/12—Unsaturated polyimide precursors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/12—Unsaturated polyimide precursors
    • C08G73/124—Unsaturated polyimide precursors the unsaturated precursors containing oxygen in the form of ether bonds in the main chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/12—Unsaturated polyimide precursors
    • C08G73/125—Unsaturated polyimide precursors the unsaturated precursors containing atoms other than carbon, hydrogen, oxygen or nitrogen in the main chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/12—Unsaturated polyimide precursors
    • C08G73/126—Unsaturated polyimide precursors the unsaturated precursors being wholly aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Resins (AREA)
  • Polyethers (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

There are disclosed novel compositions comprising a) at least one bismaleide, b) at least one mono- or polynuclear alkenylphenol, one alkenylphenol ether or a mixture thereof, wherein the alkenyl group contains at least three 3 carbon atoms, c) a copolyether resin.

The compositions of the invention can be cured to products having improved toughness and high glass transition temperatures. These products are suitable for making high-performance moulded articles which can be subjected to high temperatures, for example fibre-reinforced composites, structural adhesives, laminating or electrical insulating resins.
CA002042857A 1990-05-21 1991-05-17 Curable bismaleide systems Expired - Fee Related CA2042857C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH171490 1990-05-21
CH1714/90-7 1990-05-21

Publications (2)

Publication Number Publication Date
CA2042857A1 true CA2042857A1 (en) 1991-11-22
CA2042857C CA2042857C (en) 2002-09-10

Family

ID=4216884

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002042857A Expired - Fee Related CA2042857C (en) 1990-05-21 1991-05-17 Curable bismaleide systems

Country Status (5)

Country Link
EP (1) EP0458744B1 (en)
JP (1) JPH04227931A (en)
CA (1) CA2042857C (en)
DE (1) DE59105833D1 (en)
ES (1) ES2074251T3 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5827907A (en) * 1993-08-30 1998-10-27 Ibm Corporation Homo-, co- or multicomponent thermoplastic polymer dispersed in a thermoset resin

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH615935A5 (en) * 1975-06-19 1980-02-29 Ciba Geigy Ag
US4288583A (en) * 1978-12-29 1981-09-08 Ciba-Geigy Corporation Curable mixtures based on maleimides and 1-propenyl-substituted phenols
US4883855A (en) * 1988-02-01 1989-11-28 Ciba-Geigy Corporation Ethylenically unsaturated polyether sulfone or polyether ketone copolymer
US4883845A (en) * 1988-02-01 1989-11-28 Ciba-Geigy Corporation Curable composition of polyether sulfone or polyether ketone copolymer and unsaturated imide
EP0385937A1 (en) * 1989-02-28 1990-09-05 Ciba-Geigy Ag Curable blends based on aromatic bismaleinimides
JPH03160036A (en) * 1989-11-17 1991-07-10 Toray Ind Inc Thermoset resin composition for prepreg
JPH03162406A (en) * 1989-11-21 1991-07-12 Mitsubishi Rayon Co Ltd Resin composition for composite material
EP0438378A1 (en) * 1990-01-18 1991-07-24 Ciba-Geigy Ag Substituted diallylphenol derivatives as reactive diluents for bismaleimides

Also Published As

Publication number Publication date
JPH04227931A (en) 1992-08-18
EP0458744A3 (en) 1993-04-28
EP0458744A2 (en) 1991-11-27
EP0458744B1 (en) 1995-06-28
DE59105833D1 (en) 1995-08-03
ES2074251T3 (en) 1995-09-01
CA2042857C (en) 2002-09-10

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Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed