CA2015447A1 - Modification of natural zeolite and its use as an oligomerisation catalyst - Google Patents
Modification of natural zeolite and its use as an oligomerisation catalystInfo
- Publication number
- CA2015447A1 CA2015447A1 CA002015447A CA2015447A CA2015447A1 CA 2015447 A1 CA2015447 A1 CA 2015447A1 CA 002015447 A CA002015447 A CA 002015447A CA 2015447 A CA2015447 A CA 2015447A CA 2015447 A1 CA2015447 A1 CA 2015447A1
- Authority
- CA
- Canada
- Prior art keywords
- zeolite
- modified
- clinoptilolite
- propene
- natural
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 229910021536 Zeolite Inorganic materials 0.000 title claims abstract description 23
- 239000010457 zeolite Substances 0.000 title claims abstract description 23
- 230000004048 modification Effects 0.000 title claims abstract description 9
- 238000012986 modification Methods 0.000 title claims abstract description 9
- 239000003054 catalyst Substances 0.000 title description 22
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 48
- 238000000034 method Methods 0.000 claims abstract description 42
- JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229910001603 clinoptilolite Inorganic materials 0.000 claims abstract description 20
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 17
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 17
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 10
- 238000001354 calcination Methods 0.000 claims abstract description 8
- 239000002253 acid Substances 0.000 claims abstract description 5
- 239000003513 alkali Substances 0.000 claims abstract description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 5
- 239000011707 mineral Substances 0.000 claims abstract description 5
- 238000005406 washing Methods 0.000 claims abstract description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 15
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- 230000009466 transformation Effects 0.000 claims description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 3
- -1 that from Fatatsui Chemical compound 0.000 description 3
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 238000004587 chromatography analysis Methods 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 238000010306 acid treatment Methods 0.000 description 1
- 238000001994 activation Methods 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001506 fluorescence spectroscopy Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000001272 nitrous oxide Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/06—Washing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ZA89/3132 | 1989-04-27 | ||
| ZA893132A ZA893132B (en) | 1989-04-27 | 1989-04-27 | Modification of natural zeolite and its use as an oligomerisation catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2015447A1 true CA2015447A1 (en) | 1990-10-27 |
Family
ID=25579677
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002015447A Abandoned CA2015447A1 (en) | 1989-04-27 | 1990-04-25 | Modification of natural zeolite and its use as an oligomerisation catalyst |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0395373B1 (https=) |
| AT (1) | ATE85240T1 (https=) |
| AU (1) | AU620509B2 (https=) |
| BR (1) | BR9001984A (https=) |
| CA (1) | CA2015447A1 (https=) |
| DE (1) | DE69000847T2 (https=) |
| ES (1) | ES2054246T3 (https=) |
| GR (1) | GR3007240T3 (https=) |
| ZA (1) | ZA893132B (https=) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DK0452085T3 (da) * | 1990-04-10 | 1993-12-27 | Zeofuels Res Pty Ltd | Fremgangsmåde til fremstilling af methylaminer |
| US5268107A (en) * | 1990-05-09 | 1993-12-07 | Zeofuels Research (Proprietary) Limited | Modified clinoptilolite as an ion exchange material |
| IL97895A0 (en) * | 1990-05-09 | 1992-06-21 | Zeofuels Res Pty Ltd | Modified clinoptilolite and its use as an ion exchange material |
| KR19990066988A (ko) * | 1995-10-24 | 1999-08-16 | 그레이스 스티븐 에스. | 알루미노실리케이트와 실리카의 다공성을 변화시키는 방법 및이로부터 유도된 메조다공질 조성물 |
| ATE524235T1 (de) | 2005-12-15 | 2011-09-15 | Leroy Andree | Aluminosilikat-katalysatorsystem und seine verwendung |
| CN101428817B (zh) * | 2007-11-07 | 2010-12-22 | 中国石油化工股份有限公司 | 空腔式zsm-5改性沸石分子筛的制备方法 |
| CN103930206A (zh) * | 2011-10-24 | 2014-07-16 | 道达尔炼油法国 | 用于制备包含介孔的催化剂的方法、由此获得的催化剂及其在加氢转化方法中的用途 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3367884A (en) * | 1965-12-30 | 1968-02-06 | Mobil Oil Corp | Production and use of hydrocarbon conversion catalysts comprising acid treated crystalline aluminosilicates |
| FR1523979A (fr) * | 1966-05-25 | 1968-05-03 | Exxon Research Engineering Co | Zéolites |
| NZ204091A (en) * | 1982-05-18 | 1986-03-14 | Mobil Oil Corp | Manufacture of synthetic crystalling zeolite beta with a low aluminium content |
| AU6299386A (en) * | 1985-10-18 | 1987-04-30 | Mobil Oil Corp. | Hydroxyl-rich zeolites and their preparation |
| AU609874B2 (en) * | 1987-09-11 | 1991-05-09 | Zeofuels Research (Proprietary) Limited | Modified zeolite catalysts and use thereof in the preparation and transformation of hydrocarbons |
-
1989
- 1989-04-27 ZA ZA893132A patent/ZA893132B/xx unknown
-
1990
- 1990-04-24 AU AU53827/90A patent/AU620509B2/en not_active Ceased
- 1990-04-25 AT AT90304429T patent/ATE85240T1/de not_active IP Right Cessation
- 1990-04-25 ES ES90304429T patent/ES2054246T3/es not_active Expired - Lifetime
- 1990-04-25 EP EP90304429A patent/EP0395373B1/en not_active Expired - Lifetime
- 1990-04-25 CA CA002015447A patent/CA2015447A1/en not_active Abandoned
- 1990-04-25 DE DE9090304429T patent/DE69000847T2/de not_active Expired - Fee Related
- 1990-04-27 BR BR909001984A patent/BR9001984A/pt unknown
-
1993
- 1993-03-05 GR GR930400460T patent/GR3007240T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ATE85240T1 (de) | 1993-02-15 |
| DE69000847T2 (de) | 1993-05-19 |
| AU620509B2 (en) | 1992-02-20 |
| ZA893132B (en) | 1990-12-28 |
| EP0395373B1 (en) | 1993-02-03 |
| EP0395373A3 (en) | 1991-01-23 |
| EP0395373A2 (en) | 1990-10-31 |
| BR9001984A (pt) | 1991-07-30 |
| DE69000847D1 (de) | 1993-03-18 |
| GR3007240T3 (https=) | 1993-07-30 |
| ES2054246T3 (es) | 1994-08-01 |
| AU5382790A (en) | 1990-11-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |