CA1333627C - Interior-finishing material for use in automobiles and a method for producing the same - Google Patents
Interior-finishing material for use in automobiles and a method for producing the sameInfo
- Publication number
- CA1333627C CA1333627C CA000607646A CA607646A CA1333627C CA 1333627 C CA1333627 C CA 1333627C CA 000607646 A CA000607646 A CA 000607646A CA 607646 A CA607646 A CA 607646A CA 1333627 C CA1333627 C CA 1333627C
- Authority
- CA
- Canada
- Prior art keywords
- interior
- finishing material
- glass
- microbeads
- substrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/02—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
- B29C44/12—Incorporating or moulding on preformed parts, e.g. inserts or reinforcements
- B29C44/1209—Incorporating or moulding on preformed parts, e.g. inserts or reinforcements by impregnating a preformed part, e.g. a porous lining
Landscapes
- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
- Laminated Bodies (AREA)
Abstract
An interior-finishing material for use in automobiles is provided. The interior-finishing material comprises a substrate made of a needled glass-fiber sheet containing a thermoplastic resin binder, the said needled glass-fiber sheet being mainly composed of glass fiber, a heat-fusible adhesive layer with air permeability disposed on said substrate, and a surface layer with air permeability disposed on said adhesive layer, wherein the substrate further contains expanded microbeads.
Description
BACKGROUND OF THE INVENTION
1. Field of the invention:
The present invention relates to an interior-finishing material for use in automobiles, such as forheadlinings, doors, or the like. More specifically, the present invention relates to an interior-finishing material that can be readily produced by the one-piece molding method, and that has excellent sound absorbing characteristics, resistance to deformation against heat, and moldability. Furthermore, the present invention relates to a method for producing an interior-finishing material for use in automobiles having the above-mentioned excellent properties.
1. Field of the invention:
The present invention relates to an interior-finishing material for use in automobiles, such as forheadlinings, doors, or the like. More specifically, the present invention relates to an interior-finishing material that can be readily produced by the one-piece molding method, and that has excellent sound absorbing characteristics, resistance to deformation against heat, and moldability. Furthermore, the present invention relates to a method for producing an interior-finishing material for use in automobiles having the above-mentioned excellent properties.
2. Description of the prior art:
Various interior-finishing materials for use in automobiles, such as headlinings, etc., have long been proposed and produced. Japanese Patent Publica-tion No. 62-20003, for instance, discloses the following method for producing an interior-finishing material. First, fibers are bound with a thermoplastic resin or a mixture of a thermoplastic resin and a thermosetting resin, resulting in a sheet. The sheet (i.e., the substrate) is preheated to about 120C and a surface material is attached thereon via a layer of a thermosetting adhesive that can be cured at a temperature of up to 120C, and the laminate is treated by cold compression molding. In this method, the substrate is heated at a relatively low temperature such as about 120C so that the surface material does not deteriorate, as it would at high temperatures.
However, the thermoplastic resin serving as a binder fails to melt thoroughly at such a low temperature.
Therefore, the bindings between the fibers are not released satisfactorily. When the heated substrate is compression-molded, stress caused by the deformation of the substrate remains. Accordingly, when the molded article is kept at a high temperature, the molded article tends to return to its original shape. In this method, an adhesive layer is provided that is curable at the relatively low temperature of up to 120C to help prevent deformation of the molded article caused by residual stress. However, the adhesive layer is very thin compared with the thickness of the substrate, resulting in insufficient prevention against the aforementioned deformation. When the thermosetting resin is incorporated into the substrate, the degree of the deformation is less than that of the substrate that contains only the thermoplastic resin. But even when the thermosetting resin is incorporated, a sufficient effect cannot be obtained. In particular, when the substrate is thick, the stress that arises in the substrate becomes large, resulting in more deformation.
Furthermore, in the method mentioned above, as the thermoplastic resin serving as a binder does not melt completely, the substrate is molded with the fibers being bound with the binder. When the substrate is press-molded, the flowability of the fibers is poor that compose the substrate is poor; that is, the fibers do not move easily. Therefore, it is difficult for the substrate to be accurately formed into the shape of a mold, and thus, greater pressure is needed for molding.
Thus, the method has a drawback in that the molding process cannot be performed with accuracy.
133~627 SUM~RY OF THE INVENTION
The interior-finishing material for use in automobiIes of this invention, which overcomes the above-discussed and numerous other disadvantages and deficiencies of the prior art, comprises a substrate made of a needled glass-fiber sheet containing a thermoplastic resin binder, a heat-fusible adhesive layer with air permeability disposed on said substrate, and a surface layer with air permeability disposed on said adhesive layer, wherein said substrate further contains expanded microbeads.
The expanded microbeads are formed by sub-jecting expandable microbeads to a heating treatment.
The method for producing an interior-finishing material for use in automobiles comprises the steps of: providing a needled glass-fiber sheet mainly composed of glass fiber; dispersing a thermoplastic resin binder and expandable microbeads into a needled glass-fiber sheet to obtain a substrate; forming a heat-fusible adhesive layer with air permeability on the surface of said substrate; heating the two-layered laminate thus obtained to expand said expandable microbeads and to melt said heat-fusible adhesive;
placing a surface material with air permeability on the surface of said adhesive layer; and subjecting the three-layered laminate thus obtained to cold compression molding.
In a preferred embodiment, the expandable microbeads are particles of thermoplastic resin con-taining an expanding agent.
In a preferred embodiment, the thermoplastic resin binder is contained in an amount of from 20 to 80 parts by weight for every 100 parts by weight of said glass-fiber sheet, and said expandable microbeads are contained in an amount of from 2 to 50 parts by weight for every 100 parts by weight of said thermoplastic resin binder.
In a preferred embodiment, the needled glass-fiber sheet further contains organic fibers.
Thus, the invention described herein makes possible the objectives of (1) providing an interior-finishing material for use in automobiles that is free from deformation when it is heated and has excellent sound absorbing characteristics; (2) providing a method for readily producing an interior-finishing material for use in automobiles that has the above-mentioned excellent properties; and (3) providing a method for producing an interior-finishing material for use in automobiles that has above-mentioned excellent prop-erties by simultaneous cold compression molding of a surface material and a substrate.
BRIEF DESCRIPTION OF THE DRAWINGS
This invention may be better understood and its numerous objects and advantages will become appar-ent to those skilled in the art by reference to the n~
accompanying drawings as follows:
Figure 1 is a cross-sectional view showing one example of the interior-finishing material for use in automobiles according to the present invention.
Figure 2 is a diagram illustrating part of the manufacturing process for the interior-finishing material of the present invention.
Figure 3 is a cross-sectional view of the laminate manufactured by the process of Fig. 2.
Figure 4 is a cross-sectional view of a heating process for the laminate.
Figure 5 is a cross-sectional view of a molding process.
Figure 6 is a perspective view of the formed interior-finishing material of the present invention.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
The glass-fiber sheet to be used for the present invention is made mainly of glass fibers and contains organic fibers when required. Examples of organic fibers include synthetic fibers such as polyester fiber, polyvinyl chloride fiber, polyethylene fiber, or the like; natural fibers such as cotton, linen, silk, or the like; and regenerated fibers such as rayon fiber or the like.
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The glass-fiber sheet is obtained, for example, by needling of a glass-fiber mat.
Alternatively, the glass-fiber sheet can be prepared as follows. First, at least one of the above-mentioned other fibers that was previously cut to suitable lengths is fibrillated and mixed with glass fibers to prepare a web. Then, the web is pressed by a roller and worked with needle punching. Needling can be effected by placing a thin nonwoven fabric on one side of the web or on both sides of the web.
The suitable glass fiber mentioned above is 5 to 15 ~m and preferably 8 to 12 ~m in diameter, and 2 to 20 cm in length. Fibers with a length of 4 to 8 cm are preferably distributed in the range of 50 to 90~ of the glass fibers constituting the substrate. The preferred glass-fiber sheet obtained is 3 to 10 mm thick and weighs 200 to 1,000 g/m2.
The above-mentioned organic fibers are preferably made of a polyester with a denier of 2 to 6 and a length of 2 to 20 cm. Polyester fibers with a length of 4 to 8 cm are preferably distributed in the range of 50 to 90~ of the polyester fibers.
Examples of the material for the thermo-plastic resin binder to be used for the present invention include acrylic resin (including acrylate resin), vinyl chloride resin, polystyrene resin, or the like. It is preferable to use at least two kinds of resins, including one resin that has a softening tem-perature of 100C or more. It is preferable to add a suitable amount of synthetic rubbers, such as SBR, NBR, :.
etc., or of natural rubber to such resins. These rubbers provide the substrate with stiffness and toughness. The above thermoplastic resin binder is usually used in the form of an emulsion by being impregnated into the aforementioned glass-fiber sheet.
The resin binder is used in the amount of 20 to 80 parts by weight as solid content per 100 parts by weight of the glass-fiber sheet. When an excess amount of the resin binder is used, the interior-finishing material that is obtained has improved stiffness, but its sound absorbing property declines and the weight of the interior-finishing material increases. When less than 20 parts by weight of the resin binder is used, the stiffness of the interior-finishing material is poor.
The expandable microbeads to be used for the present invention are particles made of a thermoplastic resin that contains an expanding agent. For example, commercial expandable polystyrene microbeads can be used in which an expanding agent such as propane, butane, pentane petroleum ether, etc. is dispersed.
Alternatively, thermal-expandable microcapsules made of vinylidene chloride copolymer or the like can be used in which a liquid expanding agent of a hydrocarbon that boils at low temperature (e.g., pentane, hexane, heptane, or the like) is contained. Useful expandable microbeads are those with a foam initiating temperature ~i.e., the temperature at which expansion occurs) higher than the temperature to be used for the drying step of the substrate that will be described later.
Generally, microbeads with having a foam initiating temperature of 100C or more are used. These expandable microbeads are, as to be described later, mixed with the above-mentioned binder, which is in the form of an emulsion to be impregnated, and dispersed into a glass-fiber sheet. Expandable microbeads with an excessively large particle diameter have poor dispersibility. The diameter of the expandable micro-beads is 200 ~m or less, preferably lOO~m or less, and more preferably 20 to 30 ~m. The expansion ratio of the expandable microbeads is preferably 40 to 80. It is desirable that the expandable microbeads are used in the amount of 2 to 50 parts by weight for every 100 parts by weight of the thermoplastic resin binder.
When a smaller amount of the expandable microbeads is used, the moldability of the substrate is poor, and the molded article thus obtained tends to be deformed at high temperatures. When an excess amount of the expandable microbeads is used, the volume of the expanded substrate layer becomes too large, resulting in insufficient stiffness. Furthermore, expandable microbeads have the drawback of being expensive.
The above-mentioned binder and expandable microbeads are usually used in the form of an emulsion with a solid content of 10 to 60 percent by weight based on the combined amount thereof.
Examples of the heat-fusible adhesive to be used for the present invention can be those of conventional heat-fusible adhesives such as amide-type adhesive, and adhesive made of ethylene-vinylacetate copolymer, polyisobutylene, or the like. The melting temperature of such adhesives is from 85 to 130C.
B
g The surface material to be used for the present invention is a sheet with air-permeability, to consider sound-absorbing properties. Furthermore, in view of the desirability of a decorative effect and pleasant feeling to the touch, a nonwoven fabric or knit fabric is usually used. Especially preferred are sheets backed with air-permeable polyurethane foam or the like to provide cushioning properties.
To prepare the interior-finishing material for use in automobiles according to the present invention, for instance, the above-mentioned glass-fiber sheet is impregnated with an emulsion containing the above thermoplastic resin and expandable microbeads. The sheet can be impregnated with the emulsion by a coating method, spraying method, or dipping method. Most preferable is the dipping method.
In this way, a substrate with a thermoplastic resin and expandable microbeads dispersed uniformly in the glass-fiber sheet can be obtained. For example, the substrate obtained by the above-mentioned dipping method is dried in a suitable way. The drying process can be a conventional drying process. For example, heating processes using hot air, infrared or far infrared rays, a gas burner, high-frequency heater, or the like can be used. Alternatively, the sheet can be dried by being brought into contact with heated rolls, a hot plate, etc. The above-mentioned drying process can be employed singly or in combination for a total of at least two processes. The drying temperature should be a temperature at which the expandable microbeads do not expand or a temperature at which the microbeads do not thoroughly expand even if they begin to expand somewhat.
Next, a heat-fusible adhesive is applied to the surface of the substrate that is obtained. For example, the adhesive is partially applied (i.e., in a striped or lattice pattern) by being sprayed on the surface of the substrate, so that the adhesive layer formed has overall air permeability. Usually, a commercially available heat-fusible adhesive in the form of a film with openings or in the form of a net is put on the substrate, heated, and pressed onto the substrate form an adhesive layer.
The heat-fusible adhesive is used preferably in the amount of 20 to 150 g and more preferably in the amount of 50 to 100 g, per 1 m2 of the substrate. The amount of the adhesive can be increased or decreased according to the kind of materials and surface conditions of the substrate and the surface material.
In the substrate, the portions of the fibers (which are mainly glass fibers) that come into contact with each other are bound partially with the thermoplastic resin, so that the substrate has a continuous structure. Therefore, the substrate is provided with both stiffness and air-permeability. The heating and the molding steps to be discussed later can be readily carried out by use of a laminate that is composed of above-mentioned substrate and the heat-fusible adhesive.
The laminate of the substrate and the heat-fusible adhesive is heated in an oven. The heating temperature is such that the above expandable micro-beads expand, the layer of the heat-fusible adhesive is thoroughly melted, and most of or all the thermoplastic resin binder is melted. Usually, the temperature is 140 to 190C. It is desirable that the heating period should be from 25 to 90 minutes. The heated laminate is then removed from the oven, and a surface material is placed on the surface of the adhesive layer while the heat-fusible adhesive remains melted and cold compression molding is done. The compression molding can be carried out satisfactorily in tens of seconds.
The heated substrate increases in thickness giving a greater volume by the expansion of the expandable microbeads, and the thermoplastic resin binder melts mostly or entirely. Accordingly, the mutual binding among the fibers is loosened or unbound, giving the fiber flowability. Furthermore, because the substrate increases in volume by expansion, the density of the substrate is lowered, resulting in further flowability of the fiber. The substrate is removed from the oven, and then the surface material is placed on the substrate, followed by cold compression-molding, so that the fiber moves easily along the shape of the mold, resulting in extremely good moldability.
The expandable microbeads that are contained in the substrate begin to expand when the laminate is heated in the oven. This expansion is not completed entirely in the oven, but proceeds until the cold compression molding process in ended and the molded article is removed from the mold. Therefore, even during the cold compression molding, the substrate expands in the direction of thickness, resulting in accurate shaping to the form of the mold. Molding, as a result, can be performed with excellent moldability because of pressure arising from the expansion of the microbeads, resulting in a molded article of an accurate thickness and shape even when the mold has a complicated shape or has minute irregular parts.
On the completion of the cold compression molding, the thermoplastic resin binder is again cooled and solidified, so that the fibers are bound to each other in a stable way so as to constitute a molded article. Accordingly, the stress that arises from deformation at the time of the press molding does not arise in this substrate. Therefore, the molded article obtained does not tend to return to its original shape when exposed to high temperatures. In other words, the molded article is excellent in heat resistance.
The expanded substrate layer of the molded article obtained increases in volume by virtue of expansion of the expandable microbeads, resulting in considerable thickness compared with an unexpandable sheet of equivalent weight. Consequently, the molded article has much stiffness.
In the present invention, only the laminate made of the substrate and the heat-fusible adhesive is heated as described above. Although the surface material is heated by contact with the melted adhesive, it is only the laminated surface that is heated, and the material is cooled immediately thereafter by cold B
133362~
compression. Thus, the heating does not cause changes in properties or shape.
The interior-finishing material prepared according to the present invention is as a whole air-permeable, excellent in sound-absorbing characteris-tics, and lightweight, and with stiffness caused by expansion of the expandable microbeads.
Because mutual binding among the fibers is lessened at the time of the compression-molding process, and as the expansion pressure allows the substrate to expand in the direction of thickness as well as to expand partially in the direction o~ the plane slightly, excellent moldability is obtained, so that molding can be performed accurately even with use of a mold of complicated shape or with minute irregular parts. The fibers are again bound to each other on completion of the molding, preventing any stress caused by the molding. Additionally, the fibers consisting mainly of glass fibers, reinforce the entire molded article. Thus, a interior-finishing material that is excellent in its resistance to deformation at high temperatures can be obtained. The interior-finishing material for use in automobiles that is prepared according to the present invention is suitable for use as headlinings or doors of automobiles.
The following description deals with one preferred embodiment of the present invention.
133~627 Example Figure 2 illustrates equipment for the manu-facture of a laminated sheet composed of a substrate and heat-fusible adhesive for the present invention.
The equipment includes rollers 221 and 223 for transporting a continuous sheet, an emulsion tank 21 for impregnating the sheet with resin emulsion 21a containing expandable microbeads, a hot-air drying unit 23, an infrared heater 24, pressure rollers 252, and a cutter 26. Sheet guide rollers 222 are disposed in the emulsion tank 21 where a glass-fiber sheet 20 is impregnated with the emulsion 21a. The emulsion pickup is adjusted by rollers 223 disposed downstream of the emulsion tank 21. Disposed upstream of the heater 24 are rollers 251 for guiding a heat-fusible adhesive film 3. The heat-fusible adhesive film 3 is laminated on the upper surface of the glass-fiber sheet 20. When heated by the infrared heater 24, the adhesive film 3 melts, and the melted adhesive film 3 and the glass-fiber sheet 20 are pressed together by means of rollers 252. The laminated sheet thus produced is cut into a desired size using the cutter 26 moving verti-cally at regular intervals.
A laminated sheet was prepared by use of the above equipment. For the glass fiber sheet 20, a sheet prepared in the following way was used. First, 90 parts by weight of glass fibers (E glass;
diameter, 9l~m; fiber length, 50-80 mm) and 10 parts by weight of polyester fibers (3 denier; fiber length, 50-80 mm) were combined to form a web. The web was then worked with needle punching using a No. 19 felt needle (needle threading density: 20 points/cm2, needle through-length: 14 mm) to prepare a sheet about 6 mm thick and weishing 550 g/m2. The emulsion 21a was prep2red in the following way. First, 100 parts by welght of polystyrene resin emulsion (ULTRASOL*, Takeda Che~ical Industries Ltd.; solid content 50%), 20 pz_ .s by weight of an ac--ylic resin emulsion (ULTRASOL*
Takeda Chemical Indust-ies Ltd.; solid content 50%), 20 parts by weight of nitrile butadiene rubber (C~OSLENE,*
Tzkeda Chemiczl Industries Ltd.) and 10 parts by weight of expandable mic~obezds (Mic~osphere* Matsumoto Yushi-Seiyaku Co., Ltd.; solid content 70%, maximum expansion ratio 70) were m xed, and by addi_lcn to the mixture of a prope- amount of a viscosity modifier and water, an emulsion of 30% solid content was obtained.
1~
The glass-fiber sheet 20 thus prepared in continuous form wzs impregnated with the emulsion 21a, and then passed between the rollers 223, the pic}~up of emulslon 21a in the glass-fiber sheet 20 being adjusted to ap?_oxim2tely 350 g/m2 in terms of solid matter.
The sheet 20 w2s then dried at approximately 100C in the hot-air drying unit 23. In this drying process, the glass fibers of the glass-fiber sheet 20 we-e partially bound with thermoplzstic resin binder. Next, the adhesive film 3 was lzminated while being pzssed between the rollers 251 onto the surface of the glass-fiber shee~ dried in ~his ~-ay and containing emulsion constituents. ~or .he adhesive film 3, a net-like polyamide type heat-fusible adhesive ( fus~ ng temperature about 120C, weight :~0 g/m2) was used. The adhesive film 3 was heated and softened by the infrared heater 24, and then pressed onto the glass-fiber sheet by means of the rollers 252. The sheet lamin2ted in * - Trade-mark this way was cut with the cutter 26 to obtain a laminate 4 composed of the glass-fiber sheet containing emulsion constituents (i.e., substrate) 2 and the adhesive film 3. Figure 3 shows a cross-sectional view of the laminate 4. The laminate 4 was about 4.0 mm thick and weighed 950 g/m2.
Next, the laminate 4 was charged into the heating furnaces 27 and 27' shown in Fig. 4, each provided with a plurality of heaters either 270 or 271', and was heated to about 170C. The press molding tools 28 and 28' shown in Fig. 5 were provided. A
surface material 5 was superimposed on the heated laminate 4 with the layer of the adhesive film 3 in the laminate 4 facing the surface material, and clamp press molding was done with the press molding tools 28 and 28'. For the surface material, a sheet backed with a urethane foam sheet was used. The urethane foam sheet had an expansion ratio of 30 and a thickness of 3.0 mm.
Press molding was performed for 30 seconds with the clamping pressure of 0.5-2.0 kg/cm2, the mold temperature of 60C, and the mold clearance of 6.0 mm.
Figure 6 shows a perspective view of an interior-finishing material 1 for use in automobiles formed by trimming after molding.
A cross-section of the interior-finishing material l formed thus is shown in Fig. 1. The interior-finishing material 1 has the substrate 2 containing expanded microbeads, the heat-fusible adhesive film 3 disposed on the substrate 2, and the surface material 5 disposed on the adhesive film 3.
The glass fiber 2a is partially bound with the binder 2b, and expanded microbeads 2c are dispersed almost uniformly within the entire substrate layer.
Table 1 shows the kinds and quantities of the glass-fiber sheet, emulsion, and heat-fusible adhesive used for the preparation of the interior-finishing material; the weight, thickness, and apparent density of the laminate 4; and the physical properties of the substrate in the formed interior-finishing material.
The flexural strength given in Table 1 was measured by the following method. A test piece was held by support members positioned 100 mm apart, pressure being applied to the middle of the test piece in the direction of its thickness, and the pressure immediately before the fracture of the test piece was recorded as the flexural strength. The moldability (i.e., mold-shape-following property) indicates the ability to follow the internal shape of the mold without leaving a gap, particularly at curved sections within the mold. The mark ~
indicates that excellent molding with a uniform thickness was obtained throughout the entire surface of the mold, including the complicated curving sections.
The mark ~ indicates that gaps were created within the mold resulting in uneven molding conditions.
Concerning the property of adhesion to the surface material, the mark ~ indicates that good adhesiveness was obtained, the urethane foam not being removable. when the urethane foam was forced to be removed, it was torn. The mark ~ indicates that apparent adhesiveness was obtained but that the urethane foam was easily removed from the surface of the substrate. The sound-absorption property (normal B
incident absorption rate) was measured by the method of JIS A1405. The higher value indicates a better absorption property.
Comparative Example The same procedure was repeated as in the Example, except that expandable microbeads were not used, that the weight of the emulsion used was changed as shown in Table 1, and that the mold clearance was set at 4.0 mm.
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TDhle Co~pDralive Unils exD~ple Exa~ple Class fiber g~ 495 495 Glass-fiber sbeel Organlc fiber 8/~lSS 55 PolYslyrene-lypo parls by e~ulsion (solid conlenl) wuislll 100 102 Acrylic-type parls by e~ulsion (solid conlenl) weigbl 20 28 Expandable oicrobeDds parls by (solid conlenl) woiglll 1O
Euulsion conlained in Enulsion subslrale (solid conlenl) g/~ 352 354 lleat-fusible adhesive g/~ 50 50 ~D
Heigllt g/~ 952 954 Oried la~inate (subslrate plus Thickness c~3.90 4.00 adhesive fil~) Apparenl densily g/c~0.244 0.238 Thickness of subslrale ~ 6.20 3.8n Apparenl densily of subslrDle g/c~ 0.153 0.251 Flexural slrength (al roow le~puraluro) kgf/SO~ 2.55 1.50 Various properlies of internal-finislling Plexural strenglh (al US C) kgf/SO~c 1.80 0.95 saterial ~oldabilitY ~ A
Adhesiveness wilh surface rlalorial ~ A
Nor~al Incidenl 1.000 Ilz % 62 43 C~
absorl~lion rDle C~:~
I,250 llz % 64 Sb C~
I bOO llz % 72 70 c~
2.000 llz % 88 83 .... . . . .. .. ~ . ~
In comparing the interior-finishing material obtained according to the present invention with that of the Comparative Example, it can be seen from Table 1 that the interior-finishing material according to the present invention is superior in the properties of flexural strength, moldability, adhesiveness to the surface material, and sound absorption.
It is understood that various other modifica-tions will be apparent to and can be readily made bythose skilled in the art without departing from the scope and spirit of this invention. Accordingly, it is not intended that the scope of the claims appended hereto be limited to the description as set forth herein, but rather that the claims be construed as en-compassing all the features of patentable novelty that reside in the present invention, including all features that would be treated as equivalents thereof by those skilled in the art to which this invention pertains.
Various interior-finishing materials for use in automobiles, such as headlinings, etc., have long been proposed and produced. Japanese Patent Publica-tion No. 62-20003, for instance, discloses the following method for producing an interior-finishing material. First, fibers are bound with a thermoplastic resin or a mixture of a thermoplastic resin and a thermosetting resin, resulting in a sheet. The sheet (i.e., the substrate) is preheated to about 120C and a surface material is attached thereon via a layer of a thermosetting adhesive that can be cured at a temperature of up to 120C, and the laminate is treated by cold compression molding. In this method, the substrate is heated at a relatively low temperature such as about 120C so that the surface material does not deteriorate, as it would at high temperatures.
However, the thermoplastic resin serving as a binder fails to melt thoroughly at such a low temperature.
Therefore, the bindings between the fibers are not released satisfactorily. When the heated substrate is compression-molded, stress caused by the deformation of the substrate remains. Accordingly, when the molded article is kept at a high temperature, the molded article tends to return to its original shape. In this method, an adhesive layer is provided that is curable at the relatively low temperature of up to 120C to help prevent deformation of the molded article caused by residual stress. However, the adhesive layer is very thin compared with the thickness of the substrate, resulting in insufficient prevention against the aforementioned deformation. When the thermosetting resin is incorporated into the substrate, the degree of the deformation is less than that of the substrate that contains only the thermoplastic resin. But even when the thermosetting resin is incorporated, a sufficient effect cannot be obtained. In particular, when the substrate is thick, the stress that arises in the substrate becomes large, resulting in more deformation.
Furthermore, in the method mentioned above, as the thermoplastic resin serving as a binder does not melt completely, the substrate is molded with the fibers being bound with the binder. When the substrate is press-molded, the flowability of the fibers is poor that compose the substrate is poor; that is, the fibers do not move easily. Therefore, it is difficult for the substrate to be accurately formed into the shape of a mold, and thus, greater pressure is needed for molding.
Thus, the method has a drawback in that the molding process cannot be performed with accuracy.
133~627 SUM~RY OF THE INVENTION
The interior-finishing material for use in automobiIes of this invention, which overcomes the above-discussed and numerous other disadvantages and deficiencies of the prior art, comprises a substrate made of a needled glass-fiber sheet containing a thermoplastic resin binder, a heat-fusible adhesive layer with air permeability disposed on said substrate, and a surface layer with air permeability disposed on said adhesive layer, wherein said substrate further contains expanded microbeads.
The expanded microbeads are formed by sub-jecting expandable microbeads to a heating treatment.
The method for producing an interior-finishing material for use in automobiles comprises the steps of: providing a needled glass-fiber sheet mainly composed of glass fiber; dispersing a thermoplastic resin binder and expandable microbeads into a needled glass-fiber sheet to obtain a substrate; forming a heat-fusible adhesive layer with air permeability on the surface of said substrate; heating the two-layered laminate thus obtained to expand said expandable microbeads and to melt said heat-fusible adhesive;
placing a surface material with air permeability on the surface of said adhesive layer; and subjecting the three-layered laminate thus obtained to cold compression molding.
In a preferred embodiment, the expandable microbeads are particles of thermoplastic resin con-taining an expanding agent.
In a preferred embodiment, the thermoplastic resin binder is contained in an amount of from 20 to 80 parts by weight for every 100 parts by weight of said glass-fiber sheet, and said expandable microbeads are contained in an amount of from 2 to 50 parts by weight for every 100 parts by weight of said thermoplastic resin binder.
In a preferred embodiment, the needled glass-fiber sheet further contains organic fibers.
Thus, the invention described herein makes possible the objectives of (1) providing an interior-finishing material for use in automobiles that is free from deformation when it is heated and has excellent sound absorbing characteristics; (2) providing a method for readily producing an interior-finishing material for use in automobiles that has the above-mentioned excellent properties; and (3) providing a method for producing an interior-finishing material for use in automobiles that has above-mentioned excellent prop-erties by simultaneous cold compression molding of a surface material and a substrate.
BRIEF DESCRIPTION OF THE DRAWINGS
This invention may be better understood and its numerous objects and advantages will become appar-ent to those skilled in the art by reference to the n~
accompanying drawings as follows:
Figure 1 is a cross-sectional view showing one example of the interior-finishing material for use in automobiles according to the present invention.
Figure 2 is a diagram illustrating part of the manufacturing process for the interior-finishing material of the present invention.
Figure 3 is a cross-sectional view of the laminate manufactured by the process of Fig. 2.
Figure 4 is a cross-sectional view of a heating process for the laminate.
Figure 5 is a cross-sectional view of a molding process.
Figure 6 is a perspective view of the formed interior-finishing material of the present invention.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
The glass-fiber sheet to be used for the present invention is made mainly of glass fibers and contains organic fibers when required. Examples of organic fibers include synthetic fibers such as polyester fiber, polyvinyl chloride fiber, polyethylene fiber, or the like; natural fibers such as cotton, linen, silk, or the like; and regenerated fibers such as rayon fiber or the like.
.~
The glass-fiber sheet is obtained, for example, by needling of a glass-fiber mat.
Alternatively, the glass-fiber sheet can be prepared as follows. First, at least one of the above-mentioned other fibers that was previously cut to suitable lengths is fibrillated and mixed with glass fibers to prepare a web. Then, the web is pressed by a roller and worked with needle punching. Needling can be effected by placing a thin nonwoven fabric on one side of the web or on both sides of the web.
The suitable glass fiber mentioned above is 5 to 15 ~m and preferably 8 to 12 ~m in diameter, and 2 to 20 cm in length. Fibers with a length of 4 to 8 cm are preferably distributed in the range of 50 to 90~ of the glass fibers constituting the substrate. The preferred glass-fiber sheet obtained is 3 to 10 mm thick and weighs 200 to 1,000 g/m2.
The above-mentioned organic fibers are preferably made of a polyester with a denier of 2 to 6 and a length of 2 to 20 cm. Polyester fibers with a length of 4 to 8 cm are preferably distributed in the range of 50 to 90~ of the polyester fibers.
Examples of the material for the thermo-plastic resin binder to be used for the present invention include acrylic resin (including acrylate resin), vinyl chloride resin, polystyrene resin, or the like. It is preferable to use at least two kinds of resins, including one resin that has a softening tem-perature of 100C or more. It is preferable to add a suitable amount of synthetic rubbers, such as SBR, NBR, :.
etc., or of natural rubber to such resins. These rubbers provide the substrate with stiffness and toughness. The above thermoplastic resin binder is usually used in the form of an emulsion by being impregnated into the aforementioned glass-fiber sheet.
The resin binder is used in the amount of 20 to 80 parts by weight as solid content per 100 parts by weight of the glass-fiber sheet. When an excess amount of the resin binder is used, the interior-finishing material that is obtained has improved stiffness, but its sound absorbing property declines and the weight of the interior-finishing material increases. When less than 20 parts by weight of the resin binder is used, the stiffness of the interior-finishing material is poor.
The expandable microbeads to be used for the present invention are particles made of a thermoplastic resin that contains an expanding agent. For example, commercial expandable polystyrene microbeads can be used in which an expanding agent such as propane, butane, pentane petroleum ether, etc. is dispersed.
Alternatively, thermal-expandable microcapsules made of vinylidene chloride copolymer or the like can be used in which a liquid expanding agent of a hydrocarbon that boils at low temperature (e.g., pentane, hexane, heptane, or the like) is contained. Useful expandable microbeads are those with a foam initiating temperature ~i.e., the temperature at which expansion occurs) higher than the temperature to be used for the drying step of the substrate that will be described later.
Generally, microbeads with having a foam initiating temperature of 100C or more are used. These expandable microbeads are, as to be described later, mixed with the above-mentioned binder, which is in the form of an emulsion to be impregnated, and dispersed into a glass-fiber sheet. Expandable microbeads with an excessively large particle diameter have poor dispersibility. The diameter of the expandable micro-beads is 200 ~m or less, preferably lOO~m or less, and more preferably 20 to 30 ~m. The expansion ratio of the expandable microbeads is preferably 40 to 80. It is desirable that the expandable microbeads are used in the amount of 2 to 50 parts by weight for every 100 parts by weight of the thermoplastic resin binder.
When a smaller amount of the expandable microbeads is used, the moldability of the substrate is poor, and the molded article thus obtained tends to be deformed at high temperatures. When an excess amount of the expandable microbeads is used, the volume of the expanded substrate layer becomes too large, resulting in insufficient stiffness. Furthermore, expandable microbeads have the drawback of being expensive.
The above-mentioned binder and expandable microbeads are usually used in the form of an emulsion with a solid content of 10 to 60 percent by weight based on the combined amount thereof.
Examples of the heat-fusible adhesive to be used for the present invention can be those of conventional heat-fusible adhesives such as amide-type adhesive, and adhesive made of ethylene-vinylacetate copolymer, polyisobutylene, or the like. The melting temperature of such adhesives is from 85 to 130C.
B
g The surface material to be used for the present invention is a sheet with air-permeability, to consider sound-absorbing properties. Furthermore, in view of the desirability of a decorative effect and pleasant feeling to the touch, a nonwoven fabric or knit fabric is usually used. Especially preferred are sheets backed with air-permeable polyurethane foam or the like to provide cushioning properties.
To prepare the interior-finishing material for use in automobiles according to the present invention, for instance, the above-mentioned glass-fiber sheet is impregnated with an emulsion containing the above thermoplastic resin and expandable microbeads. The sheet can be impregnated with the emulsion by a coating method, spraying method, or dipping method. Most preferable is the dipping method.
In this way, a substrate with a thermoplastic resin and expandable microbeads dispersed uniformly in the glass-fiber sheet can be obtained. For example, the substrate obtained by the above-mentioned dipping method is dried in a suitable way. The drying process can be a conventional drying process. For example, heating processes using hot air, infrared or far infrared rays, a gas burner, high-frequency heater, or the like can be used. Alternatively, the sheet can be dried by being brought into contact with heated rolls, a hot plate, etc. The above-mentioned drying process can be employed singly or in combination for a total of at least two processes. The drying temperature should be a temperature at which the expandable microbeads do not expand or a temperature at which the microbeads do not thoroughly expand even if they begin to expand somewhat.
Next, a heat-fusible adhesive is applied to the surface of the substrate that is obtained. For example, the adhesive is partially applied (i.e., in a striped or lattice pattern) by being sprayed on the surface of the substrate, so that the adhesive layer formed has overall air permeability. Usually, a commercially available heat-fusible adhesive in the form of a film with openings or in the form of a net is put on the substrate, heated, and pressed onto the substrate form an adhesive layer.
The heat-fusible adhesive is used preferably in the amount of 20 to 150 g and more preferably in the amount of 50 to 100 g, per 1 m2 of the substrate. The amount of the adhesive can be increased or decreased according to the kind of materials and surface conditions of the substrate and the surface material.
In the substrate, the portions of the fibers (which are mainly glass fibers) that come into contact with each other are bound partially with the thermoplastic resin, so that the substrate has a continuous structure. Therefore, the substrate is provided with both stiffness and air-permeability. The heating and the molding steps to be discussed later can be readily carried out by use of a laminate that is composed of above-mentioned substrate and the heat-fusible adhesive.
The laminate of the substrate and the heat-fusible adhesive is heated in an oven. The heating temperature is such that the above expandable micro-beads expand, the layer of the heat-fusible adhesive is thoroughly melted, and most of or all the thermoplastic resin binder is melted. Usually, the temperature is 140 to 190C. It is desirable that the heating period should be from 25 to 90 minutes. The heated laminate is then removed from the oven, and a surface material is placed on the surface of the adhesive layer while the heat-fusible adhesive remains melted and cold compression molding is done. The compression molding can be carried out satisfactorily in tens of seconds.
The heated substrate increases in thickness giving a greater volume by the expansion of the expandable microbeads, and the thermoplastic resin binder melts mostly or entirely. Accordingly, the mutual binding among the fibers is loosened or unbound, giving the fiber flowability. Furthermore, because the substrate increases in volume by expansion, the density of the substrate is lowered, resulting in further flowability of the fiber. The substrate is removed from the oven, and then the surface material is placed on the substrate, followed by cold compression-molding, so that the fiber moves easily along the shape of the mold, resulting in extremely good moldability.
The expandable microbeads that are contained in the substrate begin to expand when the laminate is heated in the oven. This expansion is not completed entirely in the oven, but proceeds until the cold compression molding process in ended and the molded article is removed from the mold. Therefore, even during the cold compression molding, the substrate expands in the direction of thickness, resulting in accurate shaping to the form of the mold. Molding, as a result, can be performed with excellent moldability because of pressure arising from the expansion of the microbeads, resulting in a molded article of an accurate thickness and shape even when the mold has a complicated shape or has minute irregular parts.
On the completion of the cold compression molding, the thermoplastic resin binder is again cooled and solidified, so that the fibers are bound to each other in a stable way so as to constitute a molded article. Accordingly, the stress that arises from deformation at the time of the press molding does not arise in this substrate. Therefore, the molded article obtained does not tend to return to its original shape when exposed to high temperatures. In other words, the molded article is excellent in heat resistance.
The expanded substrate layer of the molded article obtained increases in volume by virtue of expansion of the expandable microbeads, resulting in considerable thickness compared with an unexpandable sheet of equivalent weight. Consequently, the molded article has much stiffness.
In the present invention, only the laminate made of the substrate and the heat-fusible adhesive is heated as described above. Although the surface material is heated by contact with the melted adhesive, it is only the laminated surface that is heated, and the material is cooled immediately thereafter by cold B
133362~
compression. Thus, the heating does not cause changes in properties or shape.
The interior-finishing material prepared according to the present invention is as a whole air-permeable, excellent in sound-absorbing characteris-tics, and lightweight, and with stiffness caused by expansion of the expandable microbeads.
Because mutual binding among the fibers is lessened at the time of the compression-molding process, and as the expansion pressure allows the substrate to expand in the direction of thickness as well as to expand partially in the direction o~ the plane slightly, excellent moldability is obtained, so that molding can be performed accurately even with use of a mold of complicated shape or with minute irregular parts. The fibers are again bound to each other on completion of the molding, preventing any stress caused by the molding. Additionally, the fibers consisting mainly of glass fibers, reinforce the entire molded article. Thus, a interior-finishing material that is excellent in its resistance to deformation at high temperatures can be obtained. The interior-finishing material for use in automobiles that is prepared according to the present invention is suitable for use as headlinings or doors of automobiles.
The following description deals with one preferred embodiment of the present invention.
133~627 Example Figure 2 illustrates equipment for the manu-facture of a laminated sheet composed of a substrate and heat-fusible adhesive for the present invention.
The equipment includes rollers 221 and 223 for transporting a continuous sheet, an emulsion tank 21 for impregnating the sheet with resin emulsion 21a containing expandable microbeads, a hot-air drying unit 23, an infrared heater 24, pressure rollers 252, and a cutter 26. Sheet guide rollers 222 are disposed in the emulsion tank 21 where a glass-fiber sheet 20 is impregnated with the emulsion 21a. The emulsion pickup is adjusted by rollers 223 disposed downstream of the emulsion tank 21. Disposed upstream of the heater 24 are rollers 251 for guiding a heat-fusible adhesive film 3. The heat-fusible adhesive film 3 is laminated on the upper surface of the glass-fiber sheet 20. When heated by the infrared heater 24, the adhesive film 3 melts, and the melted adhesive film 3 and the glass-fiber sheet 20 are pressed together by means of rollers 252. The laminated sheet thus produced is cut into a desired size using the cutter 26 moving verti-cally at regular intervals.
A laminated sheet was prepared by use of the above equipment. For the glass fiber sheet 20, a sheet prepared in the following way was used. First, 90 parts by weight of glass fibers (E glass;
diameter, 9l~m; fiber length, 50-80 mm) and 10 parts by weight of polyester fibers (3 denier; fiber length, 50-80 mm) were combined to form a web. The web was then worked with needle punching using a No. 19 felt needle (needle threading density: 20 points/cm2, needle through-length: 14 mm) to prepare a sheet about 6 mm thick and weishing 550 g/m2. The emulsion 21a was prep2red in the following way. First, 100 parts by welght of polystyrene resin emulsion (ULTRASOL*, Takeda Che~ical Industries Ltd.; solid content 50%), 20 pz_ .s by weight of an ac--ylic resin emulsion (ULTRASOL*
Takeda Chemical Indust-ies Ltd.; solid content 50%), 20 parts by weight of nitrile butadiene rubber (C~OSLENE,*
Tzkeda Chemiczl Industries Ltd.) and 10 parts by weight of expandable mic~obezds (Mic~osphere* Matsumoto Yushi-Seiyaku Co., Ltd.; solid content 70%, maximum expansion ratio 70) were m xed, and by addi_lcn to the mixture of a prope- amount of a viscosity modifier and water, an emulsion of 30% solid content was obtained.
1~
The glass-fiber sheet 20 thus prepared in continuous form wzs impregnated with the emulsion 21a, and then passed between the rollers 223, the pic}~up of emulslon 21a in the glass-fiber sheet 20 being adjusted to ap?_oxim2tely 350 g/m2 in terms of solid matter.
The sheet 20 w2s then dried at approximately 100C in the hot-air drying unit 23. In this drying process, the glass fibers of the glass-fiber sheet 20 we-e partially bound with thermoplzstic resin binder. Next, the adhesive film 3 was lzminated while being pzssed between the rollers 251 onto the surface of the glass-fiber shee~ dried in ~his ~-ay and containing emulsion constituents. ~or .he adhesive film 3, a net-like polyamide type heat-fusible adhesive ( fus~ ng temperature about 120C, weight :~0 g/m2) was used. The adhesive film 3 was heated and softened by the infrared heater 24, and then pressed onto the glass-fiber sheet by means of the rollers 252. The sheet lamin2ted in * - Trade-mark this way was cut with the cutter 26 to obtain a laminate 4 composed of the glass-fiber sheet containing emulsion constituents (i.e., substrate) 2 and the adhesive film 3. Figure 3 shows a cross-sectional view of the laminate 4. The laminate 4 was about 4.0 mm thick and weighed 950 g/m2.
Next, the laminate 4 was charged into the heating furnaces 27 and 27' shown in Fig. 4, each provided with a plurality of heaters either 270 or 271', and was heated to about 170C. The press molding tools 28 and 28' shown in Fig. 5 were provided. A
surface material 5 was superimposed on the heated laminate 4 with the layer of the adhesive film 3 in the laminate 4 facing the surface material, and clamp press molding was done with the press molding tools 28 and 28'. For the surface material, a sheet backed with a urethane foam sheet was used. The urethane foam sheet had an expansion ratio of 30 and a thickness of 3.0 mm.
Press molding was performed for 30 seconds with the clamping pressure of 0.5-2.0 kg/cm2, the mold temperature of 60C, and the mold clearance of 6.0 mm.
Figure 6 shows a perspective view of an interior-finishing material 1 for use in automobiles formed by trimming after molding.
A cross-section of the interior-finishing material l formed thus is shown in Fig. 1. The interior-finishing material 1 has the substrate 2 containing expanded microbeads, the heat-fusible adhesive film 3 disposed on the substrate 2, and the surface material 5 disposed on the adhesive film 3.
The glass fiber 2a is partially bound with the binder 2b, and expanded microbeads 2c are dispersed almost uniformly within the entire substrate layer.
Table 1 shows the kinds and quantities of the glass-fiber sheet, emulsion, and heat-fusible adhesive used for the preparation of the interior-finishing material; the weight, thickness, and apparent density of the laminate 4; and the physical properties of the substrate in the formed interior-finishing material.
The flexural strength given in Table 1 was measured by the following method. A test piece was held by support members positioned 100 mm apart, pressure being applied to the middle of the test piece in the direction of its thickness, and the pressure immediately before the fracture of the test piece was recorded as the flexural strength. The moldability (i.e., mold-shape-following property) indicates the ability to follow the internal shape of the mold without leaving a gap, particularly at curved sections within the mold. The mark ~
indicates that excellent molding with a uniform thickness was obtained throughout the entire surface of the mold, including the complicated curving sections.
The mark ~ indicates that gaps were created within the mold resulting in uneven molding conditions.
Concerning the property of adhesion to the surface material, the mark ~ indicates that good adhesiveness was obtained, the urethane foam not being removable. when the urethane foam was forced to be removed, it was torn. The mark ~ indicates that apparent adhesiveness was obtained but that the urethane foam was easily removed from the surface of the substrate. The sound-absorption property (normal B
incident absorption rate) was measured by the method of JIS A1405. The higher value indicates a better absorption property.
Comparative Example The same procedure was repeated as in the Example, except that expandable microbeads were not used, that the weight of the emulsion used was changed as shown in Table 1, and that the mold clearance was set at 4.0 mm.
~y~
TDhle Co~pDralive Unils exD~ple Exa~ple Class fiber g~ 495 495 Glass-fiber sbeel Organlc fiber 8/~lSS 55 PolYslyrene-lypo parls by e~ulsion (solid conlenl) wuislll 100 102 Acrylic-type parls by e~ulsion (solid conlenl) weigbl 20 28 Expandable oicrobeDds parls by (solid conlenl) woiglll 1O
Euulsion conlained in Enulsion subslrale (solid conlenl) g/~ 352 354 lleat-fusible adhesive g/~ 50 50 ~D
Heigllt g/~ 952 954 Oried la~inate (subslrate plus Thickness c~3.90 4.00 adhesive fil~) Apparenl densily g/c~0.244 0.238 Thickness of subslrale ~ 6.20 3.8n Apparenl densily of subslrDle g/c~ 0.153 0.251 Flexural slrength (al roow le~puraluro) kgf/SO~ 2.55 1.50 Various properlies of internal-finislling Plexural strenglh (al US C) kgf/SO~c 1.80 0.95 saterial ~oldabilitY ~ A
Adhesiveness wilh surface rlalorial ~ A
Nor~al Incidenl 1.000 Ilz % 62 43 C~
absorl~lion rDle C~:~
I,250 llz % 64 Sb C~
I bOO llz % 72 70 c~
2.000 llz % 88 83 .... . . . .. .. ~ . ~
In comparing the interior-finishing material obtained according to the present invention with that of the Comparative Example, it can be seen from Table 1 that the interior-finishing material according to the present invention is superior in the properties of flexural strength, moldability, adhesiveness to the surface material, and sound absorption.
It is understood that various other modifica-tions will be apparent to and can be readily made bythose skilled in the art without departing from the scope and spirit of this invention. Accordingly, it is not intended that the scope of the claims appended hereto be limited to the description as set forth herein, but rather that the claims be construed as en-compassing all the features of patentable novelty that reside in the present invention, including all features that would be treated as equivalents thereof by those skilled in the art to which this invention pertains.
Claims (12)
1. An interior-finiching material for use in an automobile comprising:
a substrate made of a needled glass-fiber sheet containing expanded microbeads and a thermoplastic resin binder, said needled glass-fiber sheet being mainly composed of glass fiber; a heat-fusible air-permeable adhesive layer disposed on said substrate; and an air-permeable surface layer disposed on said adhesive layer;
wherein said expanded microbeads are formed by applying heat to expandable microbeads disposed in said glass-fiber sheet, wherein said expandable microbeads are particles of thermoplastic resin containing an expanding agent and the diameter of said expandable microbeads is 200µm or less;
wherein the amount of said thermoplastic resin binder is in the range of about 20 to 80 parts by weight per 100 parts by weight of said glass-fiber sheet, and the amount of said expandable microbeads is in the range of about 2 to 50 parts by weight per 100 parts by weight of said thermoplastic resin binder.
a substrate made of a needled glass-fiber sheet containing expanded microbeads and a thermoplastic resin binder, said needled glass-fiber sheet being mainly composed of glass fiber; a heat-fusible air-permeable adhesive layer disposed on said substrate; and an air-permeable surface layer disposed on said adhesive layer;
wherein said expanded microbeads are formed by applying heat to expandable microbeads disposed in said glass-fiber sheet, wherein said expandable microbeads are particles of thermoplastic resin containing an expanding agent and the diameter of said expandable microbeads is 200µm or less;
wherein the amount of said thermoplastic resin binder is in the range of about 20 to 80 parts by weight per 100 parts by weight of said glass-fiber sheet, and the amount of said expandable microbeads is in the range of about 2 to 50 parts by weight per 100 parts by weight of said thermoplastic resin binder.
2. An interior-finishing material according to claim 1, wherein the diameter of said expandable microbeads is 100 µm or less.
3. An interior-finishing material according to claim 1, wherein the diameter of said expandable microbeads is in the range of from about 20 to 30 µm.
4. An interior-finishing material according to claim 1, wherein said needled glass-fiber sheet further contains organic fibers.
5. A method for producing an interior-finishing material for use in an automobile comprising the steps of:
providing a needled glass-fiber sheet mainly composed of glass-fiber;
dispersing a thermoplastic resin binder and expandable microbeads into said needled glass-fiber sheet to obtain a substrate, wherein said expandable microbeads are particles of thermoplastic resin containing an expanding agent, and the diameter of said expandable microbeads is 200 µm or less, wherein the amount of said thermoplastic resin binder is in the range of about 20 to 80 parts by weight per 100 parts by weight of said glass-fiber sheet, and the amount of said expandable microbeads is in the range of about 2 to 50 parts by weight per 100 parts by weight of said thermoplastic resin binder;
applying a heat-fusible adhesive layer in a striped or lattice pattern by spraying on the surface of the substrate, wherein the adhesive layer has overall air permeability;
heating the two-layered laminate thus obtained to expand said expandable microbeads and to melt said heat-fusible adhesive;
placing an air-permeable surface material on the surface of said adhesive layer; and subjecting the three-layered laminate thus obtained to cold compression molding.
providing a needled glass-fiber sheet mainly composed of glass-fiber;
dispersing a thermoplastic resin binder and expandable microbeads into said needled glass-fiber sheet to obtain a substrate, wherein said expandable microbeads are particles of thermoplastic resin containing an expanding agent, and the diameter of said expandable microbeads is 200 µm or less, wherein the amount of said thermoplastic resin binder is in the range of about 20 to 80 parts by weight per 100 parts by weight of said glass-fiber sheet, and the amount of said expandable microbeads is in the range of about 2 to 50 parts by weight per 100 parts by weight of said thermoplastic resin binder;
applying a heat-fusible adhesive layer in a striped or lattice pattern by spraying on the surface of the substrate, wherein the adhesive layer has overall air permeability;
heating the two-layered laminate thus obtained to expand said expandable microbeads and to melt said heat-fusible adhesive;
placing an air-permeable surface material on the surface of said adhesive layer; and subjecting the three-layered laminate thus obtained to cold compression molding.
6. A method for producing an interior-finishing material according to claim 5, wherein the diameter of said expandable microbeads is 100 µm or less.
7. A method for producing an interior-finishing material according to claim 5, wherein the diameter of said expandable microbeads is in the range of from about 20 to 30 µm.
8. A method for producing an interior-finishing material according to claim 5, wherein said needled glass-fiber sheet further contains organic fibers.
9. A method for producing an interior-finishing material according to claim 5, wherein said expandable microbeads are made of polystyrene.
10. A method for producing an interior-finishing material according to claim 9, wherein said expanding agent is selected from the group consisting of propane, butane and pentane petroleum ether.
11. A method for producing an interior-finishing material according to claim 5, wherein said expandable microbeads are made of vinylidene chloride copolymer.
12. A method for producing an interior-finishing material according to claim 11, wherein said expanding agent is selected from the group consisting of pentane, hexane and heptane.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63196406A JPH0684055B2 (en) | 1988-08-05 | 1988-08-05 | Interior material for automobile and method for manufacturing the same |
| JP63-196406 | 1988-08-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1333627C true CA1333627C (en) | 1994-12-20 |
Family
ID=16357332
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000607646A Expired - Fee Related CA1333627C (en) | 1988-08-05 | 1989-08-04 | Interior-finishing material for use in automobiles and a method for producing the same |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JPH0684055B2 (en) |
| KR (1) | KR970011788B1 (en) |
| CA (1) | CA1333627C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114102978A (en) * | 2021-11-29 | 2022-03-01 | 天健精密模具注塑（惠州）有限公司 | Colorful shell and preparation method thereof |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05209647A (en) * | 1992-01-31 | 1993-08-20 | Fuji Kiko Co Ltd | Damper pulley |
| JP2531822Y2 (en) * | 1992-02-19 | 1997-04-09 | 池田物産株式会社 | Structural material |
| JPH06230288A (en) * | 1993-01-29 | 1994-08-19 | Topcon Corp | Stereo-microscope |
| JPH06226740A (en) * | 1993-02-03 | 1994-08-16 | Sekisui Chem Co Ltd | Production of fiber composite |
| JP3187686B2 (en) * | 1995-08-04 | 2001-07-11 | 河西工業株式会社 | Automotive interior parts |
| JP3821449B2 (en) * | 1996-10-02 | 2006-09-13 | 株式会社森傳 | Automotive interior parts and method for manufacturing the same |
| JP4264164B2 (en) * | 1998-11-04 | 2009-05-13 | 日東紡績株式会社 | Heat-expandable inorganic fiber felt |
| JP3773044B2 (en) * | 2002-01-31 | 2006-05-10 | Ｊｆｅケミカル株式会社 | Porous material |
| KR100533806B1 (en) * | 2003-07-10 | 2005-12-06 | 한국바이린주식회사 | Wallpaper for automobile and manufacturing method |
| US20050025954A1 (en) * | 2003-07-30 | 2005-02-03 | Sullivan Alfred Hardy | Cloth backing for use in a trim cover |
| JP4920909B2 (en) | 2005-06-07 | 2012-04-18 | ケープラシート株式会社 | WEB, STAMPABLE SHEET, STAMPABLE SHEET EXPANSION MOLDED PRODUCT AND METHOD FOR PRODUCING THEM |
| JP5082122B2 (en) * | 2008-01-29 | 2012-11-28 | トヨタ紡織株式会社 | Manufacturing method of fiber composite |
| JP4328822B1 (en) | 2008-03-28 | 2009-09-09 | 中川産業株式会社 | Manufacturing method of thermally expandable base material for vehicle interior and manufacturing method of base material for vehicle interior using the same |
| KR101312359B1 (en) * | 2009-06-26 | 2013-09-27 | 주식회사 나노텍리소스 | A method for reclamation of glass fiber matted thermoplastics |
| JP4590483B1 (en) | 2009-08-07 | 2010-12-01 | 中川産業株式会社 | Manufacturing method of thermally expandable base material for vehicle interior and manufacturing method of base material for vehicle interior using the same |
| FR3049894B1 (en) * | 2016-04-12 | 2018-05-18 | Treves Products, Services & Innovation | METHOD FOR MAKING AN INSONORIZING INTERIOR TRIM PANEL OF A MOTOR VEHICLE |
-
1988
- 1988-08-05 JP JP63196406A patent/JPH0684055B2/en not_active Expired - Lifetime
-
1989
- 1989-08-04 CA CA000607646A patent/CA1333627C/en not_active Expired - Fee Related
- 1989-08-04 KR KR1019890011153A patent/KR970011788B1/en not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114102978A (en) * | 2021-11-29 | 2022-03-01 | 天健精密模具注塑（惠州）有限公司 | Colorful shell and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0684055B2 (en) | 1994-10-26 |
| KR970011788B1 (en) | 1997-07-16 |
| JPH0245135A (en) | 1990-02-15 |
| KR900002908A (en) | 1990-03-23 |
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