CA1285508C - Dry bleach and stable enzyme granular composition - Google Patents
Dry bleach and stable enzyme granular compositionInfo
- Publication number
- CA1285508C CA1285508C CA000512635A CA512635A CA1285508C CA 1285508 C CA1285508 C CA 1285508C CA 000512635 A CA000512635 A CA 000512635A CA 512635 A CA512635 A CA 512635A CA 1285508 C CA1285508 C CA 1285508C
- Authority
- CA
- Canada
- Prior art keywords
- enzyme
- granulate
- granular composition
- weight
- alkaline buffer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 102000004190 Enzymes Human genes 0.000 title claims abstract description 128
- 108090000790 Enzymes Proteins 0.000 title claims abstract description 128
- 239000000203 mixture Substances 0.000 title claims abstract description 57
- 239000007844 bleaching agent Substances 0.000 title claims abstract description 42
- 239000008187 granular material Substances 0.000 claims abstract description 119
- 239000000337 buffer salt Substances 0.000 claims abstract description 54
- 150000004965 peroxy acids Chemical class 0.000 claims abstract description 27
- 150000003839 salts Chemical class 0.000 claims abstract description 21
- 230000009849 deactivation Effects 0.000 claims abstract description 3
- 229940088598 enzyme Drugs 0.000 claims description 124
- 239000000463 material Substances 0.000 claims description 35
- 238000000576 coating method Methods 0.000 claims description 32
- 239000011248 coating agent Substances 0.000 claims description 28
- 239000000126 substance Substances 0.000 claims description 24
- 239000003963 antioxidant agent Substances 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 230000003078 antioxidant effect Effects 0.000 claims description 16
- 239000011230 binding agent Substances 0.000 claims description 16
- 239000011253 protective coating Substances 0.000 claims description 15
- 239000003979 granulating agent Substances 0.000 claims description 14
- 239000001913 cellulose Substances 0.000 claims description 12
- 229920002678 cellulose Polymers 0.000 claims description 12
- 235000010980 cellulose Nutrition 0.000 claims description 12
- 239000000945 filler Substances 0.000 claims description 11
- 108091005804 Peptidases Proteins 0.000 claims description 8
- 102000035195 Peptidases Human genes 0.000 claims description 7
- 108010065511 Amylases Proteins 0.000 claims description 6
- 102000013142 Amylases Human genes 0.000 claims description 6
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 6
- 239000001110 calcium chloride Substances 0.000 claims description 6
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 6
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- 150000002191 fatty alcohols Chemical class 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 6
- 230000008018 melting Effects 0.000 claims description 6
- 239000011736 potassium bicarbonate Substances 0.000 claims description 6
- 235000015497 potassium bicarbonate Nutrition 0.000 claims description 6
- 229910000028 potassium bicarbonate Inorganic materials 0.000 claims description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 6
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 claims description 6
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 6
- 235000019418 amylase Nutrition 0.000 claims description 5
- 230000000694 effects Effects 0.000 claims description 5
- 238000003860 storage Methods 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 4
- 239000008240 homogeneous mixture Substances 0.000 claims description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- 229920001353 Dextrin Polymers 0.000 claims description 3
- 239000004365 Protease Substances 0.000 claims description 3
- 229940025131 amylases Drugs 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 3
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 3
- 235000011181 potassium carbonates Nutrition 0.000 claims description 3
- 235000010265 sodium sulphite Nutrition 0.000 claims description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
- 235000021314 Palmitic acid Nutrition 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims description 2
- 239000000428 dust Substances 0.000 claims description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- 235000017550 sodium carbonate Nutrition 0.000 claims description 2
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims description 2
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 claims description 2
- 235000019345 sodium thiosulphate Nutrition 0.000 claims description 2
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 claims description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims 1
- 239000002202 Polyethylene glycol Substances 0.000 claims 1
- 229920000388 Polyphosphate Polymers 0.000 claims 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims 1
- 229910001424 calcium ion Inorganic materials 0.000 claims 1
- FYGDTMLNYKFZSV-MRCIVHHJSA-N dextrin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)OC1O[C@@H]1[C@@H](CO)OC(O[C@@H]2[C@H](O[C@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-MRCIVHHJSA-N 0.000 claims 1
- 229910017053 inorganic salt Inorganic materials 0.000 claims 1
- 150000002943 palmitic acids Chemical class 0.000 claims 1
- 239000001205 polyphosphate Substances 0.000 claims 1
- 235000011176 polyphosphates Nutrition 0.000 claims 1
- 239000003760 tallow Substances 0.000 claims 1
- 239000003599 detergent Substances 0.000 abstract description 15
- 239000000654 additive Substances 0.000 abstract description 5
- 239000004615 ingredient Substances 0.000 abstract description 5
- 230000000996 additive effect Effects 0.000 abstract description 3
- 239000004094 surface-active agent Substances 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 13
- 239000000843 powder Substances 0.000 description 12
- 239000000835 fiber Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 7
- 238000005469 granulation Methods 0.000 description 6
- 230000003179 granulation Effects 0.000 description 6
- -1 so~teners Substances 0.000 description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 229960005069 calcium Drugs 0.000 description 5
- 229910052791 calcium Inorganic materials 0.000 description 5
- 235000001465 calcium Nutrition 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 4
- 229920003043 Cellulose fiber Polymers 0.000 description 4
- 235000011148 calcium chloride Nutrition 0.000 description 4
- 229960002713 calcium chloride Drugs 0.000 description 4
- 239000002304 perfume Substances 0.000 description 4
- 230000002797 proteolythic effect Effects 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 230000003625 amylolytic effect Effects 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 235000019833 protease Nutrition 0.000 description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- 235000019832 sodium triphosphate Nutrition 0.000 description 3
- 239000004382 Amylase Substances 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- JHUXOSATQXGREM-UHFFFAOYSA-N dodecanediperoxoic acid Chemical compound OOC(=O)CCCCCCCCCCC(=O)OO JHUXOSATQXGREM-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 description 2
- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 230000000813 microbial effect Effects 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 229920000305 Nylon 6,10 Polymers 0.000 description 1
- 229920002535 Polyethylene Glycol 1500 Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 108010056079 Subtilisins Proteins 0.000 description 1
- 102000005158 Subtilisins Human genes 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 108700040099 Xylose isomerases Proteins 0.000 description 1
- YHGREDQDBYVEOS-UHFFFAOYSA-N [acetyloxy-[2-(diacetyloxyamino)ethyl]amino] acetate Chemical class CC(=O)ON(OC(C)=O)CCN(OC(C)=O)OC(C)=O YHGREDQDBYVEOS-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 229920006184 cellulose methylcellulose Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000013365 dairy product Nutrition 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000010981 drying operation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 229910003480 inorganic solid Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 108010003855 mesentericopeptidase Proteins 0.000 description 1
- 108010020132 microbial serine proteinases Proteins 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 235000019419 proteases Nutrition 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229940032158 sodium silicate Drugs 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- VUYXVWGKCKTUMF-UHFFFAOYSA-N tetratriacontaethylene glycol monomethyl ether Chemical compound COCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO VUYXVWGKCKTUMF-UHFFFAOYSA-N 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38672—Granulated or coated enzymes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3945—Organic per-compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US75056985A | 1985-06-28 | 1985-06-28 | |
| US750,569 | 1985-06-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1285508C true CA1285508C (en) | 1991-07-02 |
Family
ID=25018383
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000512635A Expired - Lifetime CA1285508C (en) | 1985-06-28 | 1986-06-27 | Dry bleach and stable enzyme granular composition |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0206418B1 (de) |
| JP (1) | JPS6279296A (de) |
| AU (1) | AU585031B2 (de) |
| CA (1) | CA1285508C (de) |
| DE (1) | DE3682443D1 (de) |
| GR (1) | GR861664B (de) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5093021A (en) * | 1985-08-21 | 1992-03-03 | The Clorox Company | Encapsulated enzyme in dry bleach composition |
| ES2001074A6 (es) * | 1985-08-21 | 1988-04-16 | Clorox Co | Perfeccionamientos en la fabricacion de productos blanqueantes secos basados en diperacidos. |
| US4863626A (en) * | 1985-08-21 | 1989-09-05 | The Clorox Company | Encapsulated enzyme in dry bleach composition |
| US5254287A (en) * | 1985-08-21 | 1993-10-19 | The Clorox Company | Encapsulated enzyme in dry bleach composition |
| US5167854A (en) * | 1985-08-21 | 1992-12-01 | The Clorox Company | Encapsulated enzyme in dry bleach composition |
| EP0212976B2 (de) * | 1985-08-21 | 1995-03-15 | The Clorox Company | Stabiles Persäurebleichmittel |
| US4832864A (en) * | 1987-09-15 | 1989-05-23 | Ecolab Inc. | Compositions and methods that introduce variations in color density into cellulosic fabrics, particularly indigo dyed denim |
| EP0396341A3 (de) * | 1989-05-01 | 1992-01-22 | The Procter & Gamble Company | Agglomeriertes Persäurebleichmittelgranulat und Verfahren zu dessen Herstellung |
| TR25837A (tr) * | 1990-05-31 | 1993-09-01 | Procter & Gamble | KüLCELENDIRILMIS PEROKSIASIT AGARTICI GRANüLü VE BUNU YAPMAYA MAHSUS YÖNTEM. |
| GB9025673D0 (en) * | 1990-11-26 | 1991-01-09 | Unilever Plc | Detergent powders and process for preparing them |
| CZ101595A3 (en) * | 1992-10-23 | 1996-04-17 | Procter & Gamble | Granular detergents with protease and bleaching activity |
| AU677342B2 (en) * | 1993-05-18 | 1997-04-17 | Genencor International, Inc. | Process for dust-free enzyme manufacture |
| DE4322229A1 (de) * | 1993-07-05 | 1995-01-12 | Cognis Bio Umwelt | Umhüllte Enzymzubereitung für Wasch- und Reinigungsmittel |
| ES2164685T3 (es) * | 1994-03-24 | 2002-03-01 | Procter & Gamble | Materiales granulados enzimaticos. |
| DE4422609A1 (de) * | 1994-06-28 | 1996-01-04 | Cognis Bio Umwelt | Mehrenzymgranulat |
| ATE198765T1 (de) * | 1994-11-18 | 2001-02-15 | Genencor Int | Umhüllte enzymgranulate |
| EP0723006A3 (de) * | 1995-01-23 | 1998-07-01 | The Procter & Gamble Company | Reinigungsverfahren und -produkte, die eine aufeinander abgestimmte, stufenweise Freisetzung eines Bleichmittels, gefolgt von Enzymen, bewirken |
| FR2741355B1 (fr) * | 1995-11-17 | 1998-12-31 | Anios Lab Sarl | Composition pour le traitement d'objets que l'on souhaite nettoyer et/ou desinfecter |
| US5858952A (en) * | 1995-12-22 | 1999-01-12 | Kao Corporation | Enzyme-containing granulated product method of preparation and compositions containing the granulated product |
| DE19644591A1 (de) * | 1996-10-26 | 1998-04-30 | Henkel Ecolab Gmbh & Co Ohg | Verfahren zur Herstellung enzym- und bleichmittelhaltiger Wasch- und Reinigungsmittel |
| DE19651446A1 (de) * | 1996-12-11 | 1998-06-18 | Henkel Kgaa | Umhüllte Enzymzubereitung mit verbesserter Löslichkeit |
| CA2313238C (en) * | 1997-12-20 | 2009-05-12 | Genencor International, Inc. | Granule with hydrated barrier material |
| EP1517981A2 (de) * | 2002-07-01 | 2005-03-30 | Novozymes A/S | Stabilisierung von granulat |
| US7425528B2 (en) | 2002-07-01 | 2008-09-16 | Novozymes A/S | Stabilization of granules |
| US7682403B2 (en) | 2004-01-09 | 2010-03-23 | Ecolab Inc. | Method for treating laundry |
| EP2674475A1 (de) | 2012-06-11 | 2013-12-18 | The Procter & Gamble Company | Wasch- und Reinigungsmittel |
| US20170260482A1 (en) * | 2016-03-08 | 2017-09-14 | The Procter & Gamble Company | Particles including enzyme |
| JP6959370B2 (ja) | 2017-06-22 | 2021-11-02 | エコラボ ユーエスエー インコーポレイティド | ペルオキシギ酸および酸素触媒を使用する漂白 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL7000742A (en) * | 1970-01-19 | 1971-07-21 | Granular enzyme prepn | |
| GB1590432A (en) * | 1976-07-07 | 1981-06-03 | Novo Industri As | Process for the production of an enzyme granulate and the enzyme granuate thus produced |
| US4421664A (en) * | 1982-06-18 | 1983-12-20 | Economics Laboratory, Inc. | Compatible enzyme and oxidant bleaches containing cleaning composition |
| ZA841401B (en) * | 1983-03-15 | 1985-10-30 | Colgate Palmolive Co | Bleaching and laundering composition free of water-soluble silicates |
| GB8312185D0 (en) * | 1983-05-04 | 1983-06-08 | Unilever Plc | Bleaching and cleaning composition |
| GB8321923D0 (en) * | 1983-08-15 | 1983-09-14 | Unilever Plc | Machine-dishwashing compositions |
-
1986
- 1986-06-18 EP EP19860201055 patent/EP0206418B1/de not_active Expired
- 1986-06-18 DE DE8686201055T patent/DE3682443D1/de not_active Expired - Lifetime
- 1986-06-26 GR GR861664A patent/GR861664B/el unknown
- 1986-06-27 JP JP61151359A patent/JPS6279296A/ja active Pending
- 1986-06-27 AU AU59322/86A patent/AU585031B2/en not_active Ceased
- 1986-06-27 CA CA000512635A patent/CA1285508C/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| GR861664B (en) | 1986-10-09 |
| DE3682443D1 (de) | 1991-12-19 |
| JPS6279296A (ja) | 1987-04-11 |
| EP0206418B1 (de) | 1991-11-13 |
| AU5932286A (en) | 1987-01-08 |
| EP0206418A3 (en) | 1988-11-17 |
| EP0206418A2 (de) | 1986-12-30 |
| AU585031B2 (en) | 1989-06-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1285508C (en) | Dry bleach and stable enzyme granular composition | |
| US4707287A (en) | Dry bleach stable enzyme composition | |
| US4767557A (en) | Dry bleach and stable enzyme granular composition | |
| EP0404806B1 (de) | Stabilisierte teilchenzusammensetzung | |
| US3723327A (en) | Granular proteolytic enzyme composition | |
| US3858854A (en) | Enzymatic detergent | |
| EP0780466B2 (de) | Enzym enthaltendes Granulat, Herstellungsmethode und das Granulat enthaltende Zusammensetzungen | |
| JPH03149298A (ja) | 乾燥漂白組成物におけるカプセル化した酵素 | |
| US5318714A (en) | Stabilized particulate composition | |
| US3650967A (en) | Enzymatic granules | |
| EP1124945B1 (de) | Matrixgranulat | |
| FI66426B (fi) | Partikelartad blekningsblandning innehaollande tetra-acetyletylen-diamin | |
| US3661786A (en) | Detergent compositions containing stabilized alpha-amylase | |
| US3781228A (en) | Laundry product containing enzyme | |
| US5783547A (en) | Enzyme granulates | |
| US3823090A (en) | Production of powdered detergent | |
| US6204236B1 (en) | Enzyme granulates comprising an enzyme and an organic disulfide core | |
| NO131892B (de) | ||
| JP2909888B2 (ja) | 酵素含有造粒物、その製造法及びこれを含有する洗浄剤及び漂白剤組成物 | |
| JPH09224667A (ja) | 酵素含有造粒物、その製造法及びこれを含有する組成物 | |
| JPH0267399A (ja) | 漂白洗剤組成物 | |
| US3634267A (en) | Enzyme additives | |
| MXPA98010048A (en) | New granulated enzyme materials comprising an enzyme and a nucleus of organic disulfide | |
| MXPA98000179A (en) | Granulated compositions of e-ftalimidoperoxihexano acid |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKLA | Lapsed |