CA1254317C - - Google Patents

Info

Publication number
CA1254317C
CA1254317C CA 465743 CA465743A CA1254317C CA 1254317 C CA1254317 C CA 1254317C CA 465743 CA465743 CA 465743 CA 465743 A CA465743 A CA 465743A CA 1254317 C CA1254317 C CA 1254317C
Authority
CA
Canada
Prior art keywords
charge
conjugated diene
charges
metal initiator
monoalkali metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA 465743
Other languages
English (en)
Other versions
CA1237840A (en
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Priority to CA000561683A priority Critical patent/CA1254317A/en
Publication of CA1237840A publication Critical patent/CA1237840A/en
Application granted granted Critical
Publication of CA1254317C publication Critical patent/CA1254317C/xx
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerization Catalysts (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Preparing Plates And Mask In Photomechanical Process (AREA)
  • Illuminated Signs And Luminous Advertising (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Polyesters Or Polycarbonates (AREA)
CA000465743A 1984-02-29 1984-10-18 CRACK RESISTANT TRANSPARENT RESIN COPOLYMERS Expired CA1237840A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA000561683A CA1254317A (en) 1984-02-29 1988-03-16 Craze-resistant transparent resinous copolymers

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/584,569 US4584346A (en) 1984-02-29 1984-02-29 Craze-resistant transparent resinous polymodal block copolymers
US584,569 1984-02-29

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CA000561683A Division CA1254317A (en) 1984-02-29 1988-03-16 Craze-resistant transparent resinous copolymers

Publications (2)

Publication Number Publication Date
CA1237840A CA1237840A (en) 1988-06-07
CA1254317C true CA1254317C (it) 1989-05-16

Family

ID=24337887

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000465743A Expired CA1237840A (en) 1984-02-29 1984-10-18 CRACK RESISTANT TRANSPARENT RESIN COPOLYMERS

Country Status (9)

Country Link
US (1) US4584346A (it)
EP (1) EP0153727B1 (it)
JP (1) JPS60206814A (it)
CN (2) CN1004874B (it)
AT (1) ATE89019T1 (it)
CA (1) CA1237840A (it)
DE (1) DE3587313T2 (it)
ES (1) ES540737A0 (it)
MX (1) MX173496B (it)

Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4704435A (en) * 1986-03-24 1987-11-03 Phillips Petroleum Company Craze-resistant polymodal linear block copolymers with resinous terminal blocks
US4704434A (en) * 1986-03-24 1987-11-03 Phillips Petroleum Company Craze-resistant polymodal linear block copolymers with terminal tapered blocks
DE3738748A1 (de) * 1987-11-14 1989-05-24 Basf Ag Verfahren zur diskontinuierlichen herstellung von unsymmetrisch aufgebauten, sternfoermig verzweigten blockcopolymerisaten und ihre verwendung
US4956408A (en) * 1988-06-13 1990-09-11 Phillips Petroleum Company Complex acrylates as stabilizer for conjugated diene/monovinyl aromatic copolymers
DE3910259A1 (de) * 1989-03-30 1990-10-04 Basf Ag Antiblockend ausgeruestete thermoplastische formmasse, verfahren zu ihrer herstellung und ihre verwendung
CA2028410C (en) * 1990-01-02 1996-09-17 William J. Trepka Tapered block styrene/butadiene copolymers
US5319033A (en) * 1990-01-02 1994-06-07 Phillips Petroleum Company Tapered block monovinyl aromatic/conjugated diene copolymer
US5270396A (en) * 1990-07-06 1993-12-14 Phillips Petroleum Company Sequential coupling in formation of resinous block copolymers
US5418102A (en) * 1990-11-29 1995-05-23 Canon Kabushiki Kaisha Developer for developing electrostatic image, image forming method, toner imager fixing method and image forming apparatus
US5256736A (en) * 1991-05-08 1993-10-26 Phillips Petroleum Company Tapered block copolymers of conjugated dienes and monovinylarenes
US5290875A (en) * 1992-11-30 1994-03-01 Phillips Petroleum Company Conjugated diene/monovinylarene block copolymers with multiple tapered blocks
US5296547A (en) * 1993-01-28 1994-03-22 Minnesota Mining And Manufacturing Company Block copolymer having mixed molecular weight endblocks
CA2117708C (en) * 1993-09-30 2002-10-22 William J. Trepka Block copolymers of monovinylarenes and conjugated dienes and preparation thereof
US5436298A (en) * 1993-09-30 1995-07-25 Phillips Petroleum Company Block copolymers of monovinylarenes and conjugated dienes and preparation thereof
FR2714384B1 (fr) * 1993-12-29 1996-02-02 Atochem Elf Sa Copolymère bloc étoile d'un monomère vinylaromatique et d'un diène conjugué, son procédé d'obtention, et les compositions comprenant ledit copolymère et du polystyrène cristal.
US5422389A (en) * 1994-02-04 1995-06-06 Phillips Petroleum Company Method for stabilizing monovinylarene/conjugated diene copolymers and a method for preparing a stabilizing mixture
US6153695A (en) 1994-02-14 2000-11-28 Fina Research, S.A. Process for the preparation of block copolymers
US5438103A (en) * 1994-03-23 1995-08-01 Phillips Petroleum Company Block copolymers of monovinylaromatic and conjugated diene monomers
DE4420769A1 (de) * 1994-06-15 1995-12-21 Basf Ag Mit alpha-Tocopherol stabilisierte Styrol/Butadien-Blockcopolymere
US6162874A (en) 1994-11-07 2000-12-19 Bridgestone/Firestone, Inc. Block copolymers interpolymerized with in situ polystyrene and process for preparation thereof
US6835778B2 (en) * 1995-08-29 2004-12-28 Chevron Phillips Chemical Company Lp Conjugated diene/monovinylarene block copolymers blends
US5777030A (en) * 1996-09-27 1998-07-07 Phillips Petroleum Company Blends of a styrenic polymer and monovinylaren/conjugated diene block copolymers
US6127487A (en) * 1998-10-14 2000-10-03 Phillips Petroleum Company Process to produce coupled block copolymers and said copolymers
US6136921A (en) * 1998-12-07 2000-10-24 Taiwan Synthetic Rubber Corperation Coupled polymers and process for preparing the same
ES2168887B1 (es) * 1998-12-18 2003-11-01 Taiwan Synthetic Rubber Corp Polimeros acoplados y proceso para su preparacion.
US6225415B1 (en) * 1999-09-20 2001-05-01 University Of North Carolina At Charlotte Process to selectively place functional groups within polymer chain
KR100471716B1 (ko) 2002-08-03 2005-03-10 금호석유화학 주식회사 연속식 음이온 중합에 의한 내충격 비닐 방향족 고분자의제조방법
DE10240578A1 (de) * 2002-08-29 2004-03-11 Basf Ag Stabilisierte Blockcopolymere aus Styrolmonomer und Dienmonomer
WO2004041887A1 (es) * 2002-11-08 2004-05-21 Dynasol Elastomeros, S.A. De C.V. Preparacion de materiales termoplasticos resistentes al impacto a partir de copolimeros estireno/butadieno con bloques de estireno polidispersos
ATE392450T1 (de) * 2003-08-14 2008-05-15 Basf Se Mischung von polyester und blockcopolymeren aus vinylaromaten und konjugierten dienen
US20050090587A1 (en) * 2003-10-28 2005-04-28 Dunn John E. Ultraviolet light stability of monovinylarene-conjugated diene copolymer compositions
US7037980B2 (en) * 2003-11-10 2006-05-02 Chevron Phillips Chemical Company, Lp Monovinylarene/conjugated diene copolymers having lower glass transition temperatures
US20050166551A1 (en) * 2004-02-02 2005-08-04 Keane J. A. Multilayer high clarity shrink film comprising monovinylarene-conjugated diene copolymer
WO2006052623A2 (en) * 2004-11-08 2006-05-18 Nova Chemicals Inc. Polymer blends of a monovinylarene conjugated diene block copolymer and a monovinylarene acrylate copolymer
US20070269670A1 (en) * 2006-05-17 2007-11-22 Ronald Wilmer Multilayered structures and their use as optical storage media
US20080081879A1 (en) * 2006-09-29 2008-04-03 Kim Balfour Crosslinked block copolymer composition and method
US20080081874A1 (en) * 2006-09-29 2008-04-03 Kim Balfour Poly(arylene ether) composition, method, and article
US8415429B2 (en) 2006-12-11 2013-04-09 Chervron Phillips Chemical Company LP Styrene butadiene block copolymers for film applications
CN101831133B (zh) * 2009-03-13 2012-05-30 中国石油天然气股份有限公司 一种透明嵌段共聚组合物及其制备方法
US20100272975A1 (en) * 2009-04-23 2010-10-28 Chevron Phillips Chemical Company Lp System and method for the production and use of lamination films
US10023676B2 (en) * 2016-02-24 2018-07-17 Ineos Styrolution Group Gmbh Styrene-butadiene block copolymers with an internal butadiene block for tubing applications
CN111989366B (zh) 2018-02-16 2023-08-29 英力士苯领集团股份公司 高耐热性abs模塑组合物
WO2019201784A1 (en) 2018-04-16 2019-10-24 Ineos Styrolution Group Gmbh Ultra-high flow acrylonitrile butadiene styrene copolymer compositions
ES2909771T3 (es) 2018-04-16 2022-05-10 Ineos Styrolution Group Gmbh Composiciones de copolímero de estireno-acrilonitrilo de flujo ultra alto
CN114573921A (zh) * 2022-03-25 2022-06-03 浙江大晋新材料科技有限公司 一种超高冲ps生产原料、制备高冲ps的方法以及应用

Family Cites Families (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US953011A (en) * 1907-05-28 1910-03-22 Oneida Steel Pulley Company Sheet-metal pulley.
US967004A (en) * 1907-06-17 1910-08-09 Hatchik Ehikian Knee-cushion.
US3639517A (en) * 1969-09-22 1972-02-01 Phillips Petroleum Co Resinous branched block copolymers
ZA707312B (en) * 1969-11-26 1971-08-25 Firestone Rubber And Tire Co Butadiene/styrene copolymer with high proportion of pendant vinyl groups
JPS5629276B2 (it) * 1972-06-29 1981-07-07
US4054616A (en) * 1973-09-29 1977-10-18 Sumitomo Chemical Company, Limited Process for producing transparent block copolymer resins
US4087484A (en) * 1973-12-13 1978-05-02 Sumitomo Chemical Company, Limited Process for producing transparent block copolymer resin
US4089913A (en) * 1974-01-10 1978-05-16 Sumitomo Chemical Company, Limited Process for producing transparent block copolymer resin
US4122134A (en) * 1974-02-13 1978-10-24 Sumitomo Chemical Company, Limited Method for producing transparent block copolymer resin
US3937760A (en) * 1974-04-29 1976-02-10 The Firestone Tire & Rubber Company Process for producing multiblock copolymer and products produced thereby
US4208356A (en) * 1974-09-17 1980-06-17 Asahi Kasei Kogyo Kabushiki Kaisha Process for producing mixture of block copolymers
US3992483A (en) * 1975-09-25 1976-11-16 Phillips Petroleum Company Promoters in the polymerization of monovinyl-aromatic compounds with primary lithium initiators
UST953011I4 (en) 1975-11-07 1976-12-07 The Firestone Tire & Rubber Company Transparent impact polystyrene plastics of multiple block copolymers
DE2550226C2 (de) * 1975-11-08 1984-12-13 Basf Ag, 6700 Ludwigshafen Verzweigte Blockcopolymerisate und Verfahren zu ihrer Herstellung
US4167545A (en) * 1975-11-08 1979-09-11 Basf Aktiengesellschaft Branched block copolymers and their manufacture
US4080407A (en) * 1975-11-10 1978-03-21 Phillips Petroleum Company Resinous linear copolymers having blocks with a heterogeneity index of 2.3 to 4.5
UST967004I4 (en) 1975-11-28 1978-02-07 The Firestone Tire & Rubber Company Transparent impact polystyrene plastics of di-block copolymers
JPS5952171B2 (ja) * 1976-03-19 1984-12-18 旭化成株式会社 共重合体混合物の製造方法
US4091053A (en) * 1976-06-24 1978-05-23 Phillips Petroleum Company Coupled resinous diene copolymer with good integral hinge flex life and high hardness
US4267284A (en) * 1977-01-07 1981-05-12 Phillips Petroleum Company Tough, transparent articles from styrene polymers blended with certain block-random copolymers
US4291139A (en) * 1977-03-09 1981-09-22 The Firestone Tire & Rubber Company Process for preparation of block copolymers
US4153647A (en) * 1977-06-15 1979-05-08 Glukhovskoi Vladimir S Process for producing-impact polystyrene
US4180530A (en) * 1979-02-05 1979-12-25 Arco Polymers, Inc. Clear impact resistant thermoplastic star-block copolymers
US4248983A (en) * 1979-02-05 1981-02-03 Arco Polymers, Inc. Clear impact resistant thermoplastic star-block copolymers
US4248981A (en) * 1979-04-30 1981-02-03 Arco Polymers, Inc. Clear impact resistant thermoplastic star-block copolymers
US4248980A (en) * 1979-04-30 1981-02-03 Arco Polymers, Inc. Clear impact resistant thermoplastic star-block copolymers
US4248982A (en) * 1979-04-30 1981-02-03 Arco Polymers, Inc. Clear impact resistant thermoplastic star-block copolymers
US4248984A (en) * 1979-05-11 1981-02-03 Arco Polymers, Inc. Clear impact resistant thermoplastic star-block copolymers
US4221884A (en) * 1979-05-14 1980-09-09 Arco Polymers, Inc. Clear impact resistant thermoplastic star-block copolymers
DE2940861A1 (de) * 1979-10-09 1981-04-23 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von mischungen linearer dreiblockcopolymerisate sowie formteile aus diesen
US4346198A (en) * 1980-07-14 1982-08-24 Atlantic Richfield Company Clear impact resistant thermoplastic star-block copolymers
DE3032832A1 (de) * 1980-08-30 1982-04-22 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von verzweigten blockcopolymerisaten, verwendung derselben und formteile aus diesen
JPS57118722A (en) * 1981-01-11 1982-07-23 Iseki Agricult Mach Rush reaper
US4386125A (en) * 1981-02-20 1983-05-31 Asahi Kasei Kogyo Kabushiki Kaisha Film, sheet or tube of a block copolymer or a composition containing the same
US4405754A (en) * 1982-01-13 1983-09-20 Phillips Petroleum Company Haze-free, clear, impact-resistant resinous polymers
US4403074A (en) * 1982-01-13 1983-09-06 Phillips Petroleum Company Clear haze-free impact-resistant resinous polymers

Also Published As

Publication number Publication date
MX204417A (es) 1993-09-01
ES8603520A1 (es) 1985-12-16
JPH0430964B2 (it) 1992-05-25
EP0153727A2 (en) 1985-09-04
MX173496B (es) 1994-03-09
EP0153727A3 (en) 1986-11-20
EP0153727B1 (en) 1993-05-05
JPS60206814A (ja) 1985-10-18
ATE89019T1 (de) 1993-05-15
DE3587313T2 (de) 1993-08-12
CN1028371C (zh) 1995-05-10
CN1040208A (zh) 1990-03-07
CA1237840A (en) 1988-06-07
ES540737A0 (es) 1985-12-16
CN1004874B (zh) 1989-07-26
US4584346A (en) 1986-04-22
CN85100418A (zh) 1986-09-24
DE3587313D1 (de) 1993-06-09

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Legal Events

Date Code Title Description
MKEX Expiry
MKEX Expiry

Effective date: 20050607