CA1209726A - Zirconium alloy barrier having improved corrosion resistance - Google Patents
Zirconium alloy barrier having improved corrosion resistanceInfo
- Publication number
- CA1209726A CA1209726A CA000427055A CA427055A CA1209726A CA 1209726 A CA1209726 A CA 1209726A CA 000427055 A CA000427055 A CA 000427055A CA 427055 A CA427055 A CA 427055A CA 1209726 A CA1209726 A CA 1209726A
- Authority
- CA
- Canada
- Prior art keywords
- zirconium
- chromium
- iron
- weight
- zirconium alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910001093 Zr alloy Inorganic materials 0.000 title claims abstract description 116
- 238000005260 corrosion Methods 0.000 title abstract description 17
- 230000007797 corrosion Effects 0.000 title abstract description 17
- 230000004888 barrier function Effects 0.000 title abstract description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 156
- 238000005253 cladding Methods 0.000 claims abstract description 128
- 229910052742 iron Inorganic materials 0.000 claims abstract description 78
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 76
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 76
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 76
- 239000011651 chromium Substances 0.000 claims abstract description 76
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 74
- 239000003758 nuclear fuel Substances 0.000 claims abstract description 71
- 239000002131 composite material Substances 0.000 claims abstract description 59
- 239000000758 substrate Substances 0.000 claims abstract description 46
- 239000000463 material Substances 0.000 claims abstract description 37
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229910052802 copper Inorganic materials 0.000 claims abstract description 31
- 239000010949 copper Substances 0.000 claims abstract description 31
- 229910052751 metal Inorganic materials 0.000 claims abstract description 31
- 239000002184 metal Substances 0.000 claims abstract description 31
- 229910045601 alloy Inorganic materials 0.000 claims description 21
- 239000000956 alloy Substances 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 7
- 230000006872 improvement Effects 0.000 claims description 4
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 claims 2
- 229910052778 Plutonium Inorganic materials 0.000 claims 2
- 229910052776 Thorium Inorganic materials 0.000 claims 2
- 229910052770 Uranium Inorganic materials 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- OYEHPCDNVJXUIW-UHFFFAOYSA-N plutonium atom Chemical compound [Pu] OYEHPCDNVJXUIW-UHFFFAOYSA-N 0.000 claims 2
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 claims 2
- 230000004992 fission Effects 0.000 abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 12
- 239000012535 impurity Substances 0.000 abstract description 6
- 230000003647 oxidation Effects 0.000 abstract description 6
- 238000007254 oxidation reaction Methods 0.000 abstract description 6
- 238000005336 cracking Methods 0.000 abstract description 5
- 239000000446 fuel Substances 0.000 description 41
- 239000002826 coolant Substances 0.000 description 13
- 239000007789 gas Substances 0.000 description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 239000010935 stainless steel Substances 0.000 description 9
- 229910001220 stainless steel Inorganic materials 0.000 description 8
- 239000008188 pellet Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 6
- 238000009792 diffusion process Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000007792 addition Methods 0.000 description 5
- 239000010410 layer Substances 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- FCTBKIHDJGHPPO-UHFFFAOYSA-N uranium dioxide Inorganic materials O=[U]=O FCTBKIHDJGHPPO-UHFFFAOYSA-N 0.000 description 5
- 238000013459 approach Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 230000003993 interaction Effects 0.000 description 4
- 229910001338 liquidmetal Inorganic materials 0.000 description 4
- 239000010955 niobium Substances 0.000 description 4
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 4
- OOAWCECZEHPMBX-UHFFFAOYSA-N oxygen(2-);uranium(4+) Chemical compound [O-2].[O-2].[U+4] OOAWCECZEHPMBX-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 229910052758 niobium Inorganic materials 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000002285 radioactive effect Effects 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BHMLFPOTZYRDKA-IRXDYDNUSA-N (2s)-2-[(s)-(2-iodophenoxy)-phenylmethyl]morpholine Chemical compound IC1=CC=CC=C1O[C@@H](C=1C=CC=CC=1)[C@H]1OCCNC1 BHMLFPOTZYRDKA-IRXDYDNUSA-N 0.000 description 1
- 229910018125 Al-Si Inorganic materials 0.000 description 1
- 229910018520 Al—Si Inorganic materials 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 241001611408 Nebo Species 0.000 description 1
- 229910001128 Sn alloy Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- XNFDWBSCUUZWCI-UHFFFAOYSA-N [Zr].[Sn] Chemical compound [Zr].[Sn] XNFDWBSCUUZWCI-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000004845 hydriding Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000009659 non-destructive testing Methods 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 150000003061 plutonium compounds Chemical class 0.000 description 1
- UTDLAEPMVCFGRJ-UHFFFAOYSA-N plutonium dihydrate Chemical compound O.O.[Pu] UTDLAEPMVCFGRJ-UHFFFAOYSA-N 0.000 description 1
- FLDALJIYKQCYHH-UHFFFAOYSA-N plutonium(IV) oxide Inorganic materials [O-2].[O-2].[Pu+4] FLDALJIYKQCYHH-UHFFFAOYSA-N 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000036647 reaction Effects 0.000 description 1
- 239000003870 refractory metal Substances 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910001256 stainless steel alloy Inorganic materials 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 150000003586 thorium compounds Chemical class 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 150000003671 uranium compounds Chemical class 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21C—NUCLEAR REACTORS
- G21C3/00—Reactor fuel elements and their assemblies; Selection of substances for use as reactor fuel elements
- G21C3/02—Fuel elements
- G21C3/04—Constructional details
- G21C3/16—Details of the construction within the casing
- G21C3/20—Details of the construction within the casing with coating on fuel or on inside of casing; with non-active interlayer between casing and active material with multiple casings or multiple active layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
- B32B15/013—Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E30/00—Energy generation of nuclear origin
- Y02E30/30—Nuclear fission reactors
Landscapes
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Plasma & Fusion (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Monitoring And Testing Of Nuclear Reactors (AREA)
- Laminated Bodies (AREA)
- Details Of Rigid Or Semi-Rigid Containers (AREA)
- Physical Vapour Deposition (AREA)
- Powder Metallurgy (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US37405282A | 1982-05-03 | 1982-05-03 | |
US374,052 | 1982-05-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1209726A true CA1209726A (en) | 1986-08-12 |
Family
ID=23475064
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA000427055A Expired CA1209726A (en) | 1982-05-03 | 1983-04-29 | Zirconium alloy barrier having improved corrosion resistance |
Country Status (10)
Country | Link |
---|---|
JP (1) | JPS58199836A (sv) |
KR (1) | KR910003286B1 (sv) |
BE (1) | BE895526A (sv) |
CA (1) | CA1209726A (sv) |
DE (1) | DE3248235A1 (sv) |
ES (1) | ES8506926A1 (sv) |
FR (1) | FR2526213B1 (sv) |
GB (1) | GB2119559B (sv) |
IT (1) | IT1153911B (sv) |
SE (1) | SE459101B (sv) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3571096D1 (en) * | 1984-03-09 | 1989-07-20 | Nippon Nuclear Fuel Dev Co | Cladding tube for nuclear fuel and nuclear fuel element having this cladding tube |
US4675153A (en) * | 1984-03-14 | 1987-06-23 | Westinghouse Electric Corp. | Zirconium alloy fuel cladding resistant to PCI crack propagation |
US4664881A (en) * | 1984-03-14 | 1987-05-12 | Westinghouse Electric Corp. | Zirconium base fuel cladding resistant to PCI crack propagation |
JPS61217793A (ja) * | 1985-03-08 | 1986-09-27 | ウエスチングハウス・エレクトリック・コ−ポレ−ション | 原子炉燃料被覆管 |
US4775508A (en) * | 1985-03-08 | 1988-10-04 | Westinghouse Electric Corp. | Zirconium alloy fuel cladding resistant to PCI crack propagation |
CN86101123A (zh) * | 1985-03-08 | 1987-01-21 | 西屋电气公司 | 水堆燃料包壳管 |
JPS6224182A (ja) * | 1985-03-08 | 1987-02-02 | ウエスチングハウス・エレクトリック・コ−ポレ−ション | 原子炉燃料被覆管 |
US4933136A (en) * | 1985-03-08 | 1990-06-12 | Westinghouse Electric Corp. | Water reactor fuel cladding |
US4894203A (en) * | 1988-02-05 | 1990-01-16 | General Electric Company | Nuclear fuel element having oxidation resistant cladding |
US6243433B1 (en) | 1999-05-14 | 2001-06-05 | General Electic Co. | Cladding for use in nuclear reactors having improved resistance to stress corrosion cracking and corrosion |
US20100040189A1 (en) * | 2006-10-16 | 2010-02-18 | Commissariat A L'energie Atomique | Erbium-containing zirconium alloy, methods for preparing and shaping the same, and structural component containing said alloy. |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE571786A (sv) * | 1957-10-16 | |||
US3925151A (en) * | 1974-02-11 | 1975-12-09 | Gen Electric | Nuclear fuel element |
GB1507487A (en) * | 1974-06-24 | 1978-04-12 | Gen Electric | Nuclear fuel element |
US4029545A (en) * | 1974-11-11 | 1977-06-14 | General Electric Company | Nuclear fuel elements having a composite cladding |
FR2404898B2 (fr) * | 1974-11-11 | 1986-05-02 | Gen Electric | Gaine composite pour element de combustible nucleaire |
US4045288A (en) * | 1974-11-11 | 1977-08-30 | General Electric Company | Nuclear fuel element |
GB1525717A (en) * | 1974-11-11 | 1978-09-20 | Gen Electric | Nuclear fuel elements |
GB1569078A (en) * | 1977-09-30 | 1980-06-11 | Gen Electric | Nuclear fuel element |
CA1139023A (en) * | 1979-06-04 | 1983-01-04 | John H. Davies | Thermal-mechanical treatment of composite nuclear fuel element cladding |
-
1982
- 1982-12-21 IT IT24877/82A patent/IT1153911B/it active
- 1982-12-22 GB GB08236441A patent/GB2119559B/en not_active Expired
- 1982-12-28 DE DE19823248235 patent/DE3248235A1/de not_active Ceased
- 1982-12-28 FR FR8221912A patent/FR2526213B1/fr not_active Expired
- 1982-12-28 JP JP57227826A patent/JPS58199836A/ja active Pending
- 1982-12-29 ES ES518638A patent/ES8506926A1/es not_active Expired
- 1982-12-30 BE BE0/209838A patent/BE895526A/fr not_active IP Right Cessation
- 1982-12-31 KR KR8205904A patent/KR910003286B1/ko active
-
1983
- 1983-01-03 SE SE8300016A patent/SE459101B/sv not_active IP Right Cessation
- 1983-04-29 CA CA000427055A patent/CA1209726A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
KR840003119A (ko) | 1984-08-13 |
ES518638A0 (es) | 1985-07-16 |
IT1153911B (it) | 1987-01-21 |
SE459101B (sv) | 1989-06-05 |
JPS58199836A (ja) | 1983-11-21 |
IT8224877A0 (it) | 1982-12-21 |
FR2526213B1 (fr) | 1986-10-31 |
ES8506926A1 (es) | 1985-07-16 |
GB2119559A (en) | 1983-11-16 |
DE3248235A1 (de) | 1983-11-03 |
BE895526A (fr) | 1983-06-30 |
SE8300016L (sv) | 1983-11-04 |
KR910003286B1 (ko) | 1991-05-25 |
GB2119559B (en) | 1986-02-26 |
SE8300016D0 (sv) | 1983-01-03 |
IT8224877A1 (it) | 1984-06-21 |
FR2526213A1 (fr) | 1983-11-04 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MKEX | Expiry |