CA1190533A - Catalysts for alkoxylation reactions - Google Patents

Catalysts for alkoxylation reactions

Info

Publication number
CA1190533A
CA1190533A CA000430155A CA430155A CA1190533A CA 1190533 A CA1190533 A CA 1190533A CA 000430155 A CA000430155 A CA 000430155A CA 430155 A CA430155 A CA 430155A CA 1190533 A CA1190533 A CA 1190533A
Authority
CA
Canada
Prior art keywords
acid
para
group
groups
methyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA000430155A
Other languages
English (en)
French (fr)
Inventor
Kang Yang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ConocoPhillips Co
Original Assignee
Conoco Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Conoco Inc filed Critical Conoco Inc
Application granted granted Critical
Publication of CA1190533A publication Critical patent/CA1190533A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/02—Preparation of ethers from oxiranes
    • C07C41/03—Preparation of ethers from oxiranes by reaction of oxirane rings with hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/70—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form
    • C07C45/71—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form being hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/367—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by introduction of functional groups containing oxygen only in singly bound form
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/269—Mixed catalyst systems, i.e. containing more than one reactive component or catalysts formed in-situ
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/48—Ring-opening reactions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA000430155A 1982-09-23 1983-06-10 Catalysts for alkoxylation reactions Expired CA1190533A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/422,324 US4456697A (en) 1982-09-23 1982-09-23 Catalysts for alkoxylation reactions
US422,324 1982-09-23

Publications (1)

Publication Number Publication Date
CA1190533A true CA1190533A (en) 1985-07-16

Family

ID=23674379

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000430155A Expired CA1190533A (en) 1982-09-23 1983-06-10 Catalysts for alkoxylation reactions

Country Status (7)

Country Link
US (1) US4456697A (Direct)
EP (1) EP0104309B1 (Direct)
JP (1) JPS5955351A (Direct)
CA (1) CA1190533A (Direct)
DE (2) DE3372856D1 (Direct)
NO (1) NO831589L (Direct)
PH (1) PH19843A (Direct)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4490561A (en) * 1983-10-13 1984-12-25 Conoco Inc. Method for alkoxylating fluorinated alcohols
DE3574370D1 (en) * 1984-10-29 1989-12-28 Shell Int Research Alkoxylation process using bimetallic oxo catalyst
EP0180267B1 (en) * 1984-10-29 1989-11-23 Shell Internationale Researchmaatschappij B.V. Alkoxylation process using bimetallic oxo catalyst
US4721816A (en) * 1985-12-23 1988-01-26 Shell Oil Company Preparation of nonionic surfactants
US4775653A (en) * 1987-04-28 1988-10-04 Vista Chemical Company Alkoxylation process using calcium based catalysts
US4835321A (en) * 1987-04-28 1989-05-30 Vista Chemical Company Alkoxylaton process using calcium based catalysts
DE3814849A1 (de) * 1988-05-02 1989-11-16 Henkel Kgaa Verwendung von estern der titan- und/oder zirkonsaeure als katalysatoren fuer die ethoxylierung bzw. propoxylierung
US5120697A (en) * 1988-09-30 1992-06-09 Union Carbide Chemicals & Plastics Technology Corporation Alkoxylation using modified calcium-containing catalysts
US5112789A (en) * 1988-09-30 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Alkoxylation catalysis
US5118650A (en) * 1988-09-30 1992-06-02 Union Carbide Chemicals & Plastics Technology Corporation Alkoxylation using modified group iiib metal-containing bimetallic or polymetallic catalysts
US5112788A (en) * 1988-09-30 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Alkoxylation using modified group iia metal-containing bimetallic or polymetallic catalysts
US4946984A (en) * 1988-09-30 1990-08-07 Union Carbide Chemicals And Plastics Company Inc. Alkoxylation using a calcium sulfate catalyst
US5114900A (en) * 1988-09-30 1992-05-19 Union Carbide Chemicals & Plastics Technology Corporation Alkoxylation using modified calcium-containing bimetallic or polymetallic catalysts
US5210325A (en) * 1990-04-23 1993-05-11 Shell Oil Company Alkoxylation process catalyzed by supported rare earth elements
US5102849A (en) * 1990-04-23 1992-04-07 Shell Oil Company Supported rare earth and phosphorus catalyst
US5118870A (en) * 1990-04-23 1992-06-02 Shell Oil Company Alkoxylation process catalyzed by rare earth and phosphorus-containing xerogels
US5208199A (en) * 1990-04-23 1993-05-04 Shell Oil Company Catalyst of rare earth and phosphorus-containing xerogels for alkoxylation process
US5104987A (en) * 1990-09-20 1992-04-14 Union Carbide Chemicals & Plastics Technology Corporation Alkoxylation of active hydrogen-containing compounds
US5191104A (en) * 1990-09-20 1993-03-02 Union Carbide Chemicals & Plastics Technology Corporation Alkoxylation of carboxylated compounds
US6235300B1 (en) 1999-01-19 2001-05-22 Amway Corporation Plant protecting adjuvant containing topped or peaked alcohol alkoxylates and conventional alcohol alkoxylates
US6593500B2 (en) 2001-01-19 2003-07-15 Rhodia, Inc. Process for alkoxylation with a boron-containing catalyst
EP1448653A1 (en) * 2001-11-19 2004-08-25 Shell Internationale Researchmaatschappij B.V. Process for the polymerisation of epoxy resins
JP2008514619A (ja) * 2004-09-23 2008-05-08 アクゾ・ノベル・エヌ・ベー ピーク型分布を有するアルコキシル化アルキルアミン／アルキルエーテルアミン
US20060069220A1 (en) * 2004-09-28 2006-03-30 Meurs Jan Hermen H Process for preparing an alkoxylated alcohol or phenol
JP2009531329A (ja) * 2006-03-23 2009-09-03 アクゾ・ノベル・エヌ・ベー ピーク型分布を有するアルコキシル化アルキルアミン／アルキルエーテルアミン
US8946486B2 (en) * 2007-12-03 2015-02-03 Tyco Fire & Security Gmbh Method of forming alkoxylated fluoroalcohols
EP2403892B1 (en) * 2009-03-04 2014-06-18 Dow Global Technologies LLC Thermosettable composition containing a glycidylether based on trimethylolpropane octadecaethoxilate
CA2912431C (en) * 2013-07-31 2018-07-31 Halliburton Energy Services, Inc. Alkoxylated humus material compositions and methods of making same
JP6122221B2 (ja) 2013-11-22 2017-04-26 ダウ グローバル テクノロジーズ エルエルシー エポキシドモノマーの重合のための亜鉛触媒／添加剤システム

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3056818A (en) * 1955-10-13 1962-10-02 Goodrich Co B F Titanium and zirconium esterification catalysts
US3244646A (en) * 1962-01-04 1966-04-05 Socony Mobil Oil Co Inc Polymerization of epoxides using as catalyst a metal alkoxide-phosphorous acid reaction product
US3395185A (en) * 1964-11-18 1968-07-30 Wyandotte Chemicals Corp Low molecular weight stereoregular polyoxyalkylene glycols
US3449318A (en) * 1966-11-21 1969-06-10 Staley Mfg Co A E Hydroxyalkylation of (a) polyhydric alcohols using hydrogen fluoride catalyst and (b) dextrose
FR1542470A (fr) * 1966-12-02 1968-10-18 Inst Francais Du Petrole Nouveaux catalyseurs de polymérisation d'oxydes d'alcoylènes
US3687910A (en) * 1970-03-20 1972-08-29 Du Pont Transition metal oxide catalysts
CH654221A5 (de) * 1979-09-18 1986-02-14 Minnesota Mining & Mfg 2-komponenten-katalysator-system und verfahren zur herstellung von mit hydroxyl endenden aethern.

Also Published As

Publication number Publication date
NO831589L (no) 1984-03-26
EP0104309A2 (en) 1984-04-04
US4456697A (en) 1984-06-26
EP0104309B1 (en) 1987-08-05
PH19843A (en) 1986-07-22
DE104309T1 (de) 1984-09-13
JPH0435224B2 (Direct) 1992-06-10
DE3372856D1 (en) 1987-09-10
JPS5955351A (ja) 1984-03-30
EP0104309A3 (en) 1984-06-20

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