CA1171576A - Stabilized ethylene/tetrafluoroethylene copolymers - Google Patents
Stabilized ethylene/tetrafluoroethylene copolymersInfo
- Publication number
- CA1171576A CA1171576A CA000399787A CA399787A CA1171576A CA 1171576 A CA1171576 A CA 1171576A CA 000399787 A CA000399787 A CA 000399787A CA 399787 A CA399787 A CA 399787A CA 1171576 A CA1171576 A CA 1171576A
- Authority
- CA
- Canada
- Prior art keywords
- cuprous
- composition
- ethylene
- tetrafluoroethylene
- units
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001577 copolymer Polymers 0.000 title claims abstract description 27
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 239000005977 Ethylene Substances 0.000 title claims abstract description 15
- 229910021595 Copper(I) iodide Inorganic materials 0.000 claims abstract description 47
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 claims abstract description 31
- 229910021591 Copper(I) chloride Inorganic materials 0.000 claims abstract description 30
- 229940045803 cuprous chloride Drugs 0.000 claims abstract description 14
- LSXDOTMGLUJQCM-UHFFFAOYSA-M copper(i) iodide Chemical compound I[Cu] LSXDOTMGLUJQCM-UHFFFAOYSA-M 0.000 claims abstract description 12
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000010949 copper Substances 0.000 claims description 37
- 239000000203 mixture Substances 0.000 claims description 27
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 17
- 229910052802 copper Inorganic materials 0.000 claims description 16
- -1 ethylene, tetrafluoroethylene Chemical group 0.000 claims description 5
- GVEUEBXMTMZVSD-UHFFFAOYSA-N 3,3,4,4,5,5,6,6,6-nonafluorohex-1-ene Chemical group FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C=C GVEUEBXMTMZVSD-UHFFFAOYSA-N 0.000 claims description 4
- VBZWSGALLODQNC-UHFFFAOYSA-N hexafluoroacetone Chemical group FC(F)(F)C(=O)C(F)(F)F VBZWSGALLODQNC-UHFFFAOYSA-N 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims 8
- 229910001502 inorganic halide Inorganic materials 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- 230000015556 catabolic process Effects 0.000 abstract description 9
- 238000006731 degradation reaction Methods 0.000 abstract description 9
- 229920000573 polyethylene Polymers 0.000 abstract 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 32
- 239000000654 additive Substances 0.000 description 16
- 239000000843 powder Substances 0.000 description 16
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 13
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 description 13
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 230000032683 aging Effects 0.000 description 8
- QTMDXZNDVAMKGV-UHFFFAOYSA-L copper(ii) bromide Chemical compound [Cu+2].[Br-].[Br-] QTMDXZNDVAMKGV-UHFFFAOYSA-L 0.000 description 8
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 description 6
- 238000005187 foaming Methods 0.000 description 6
- 150000004820 halides Chemical class 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 230000004580 weight loss Effects 0.000 description 6
- 229910021589 Copper(I) bromide Inorganic materials 0.000 description 5
- 230000000996 additive effect Effects 0.000 description 5
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229910021590 Copper(II) bromide Inorganic materials 0.000 description 4
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 229960004643 cupric oxide Drugs 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 230000019612 pigmentation Effects 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 2
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 230000003389 potentiating effect Effects 0.000 description 2
- 238000001175 rotational moulding Methods 0.000 description 2
- 238000004383 yellowing Methods 0.000 description 2
- RRZIJNVZMJUGTK-UHFFFAOYSA-N 1,1,2-trifluoro-2-(1,2,2-trifluoroethenoxy)ethene Chemical class FC(F)=C(F)OC(F)=C(F)F RRZIJNVZMJUGTK-UHFFFAOYSA-N 0.000 description 1
- DNJRKFKAFWSXSE-UHFFFAOYSA-N 1-chloro-2-ethenoxyethane Chemical compound ClCCOC=C DNJRKFKAFWSXSE-UHFFFAOYSA-N 0.000 description 1
- 239000005749 Copper compound Substances 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 229910017610 Cu(NO3) Inorganic materials 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 238000006388 chemical passivation reaction Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 229940108928 copper Drugs 0.000 description 1
- 150000001880 copper compounds Chemical class 0.000 description 1
- 229960003280 cupric chloride Drugs 0.000 description 1
- 229940112669 cuprous oxide Drugs 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 229960003750 ethyl chloride Drugs 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US25710781A | 1981-04-24 | 1981-04-24 | |
| US257,107 | 1981-04-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1171576A true CA1171576A (en) | 1984-07-24 |
Family
ID=22974922
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000399787A Expired CA1171576A (en) | 1981-04-24 | 1982-03-30 | Stabilized ethylene/tetrafluoroethylene copolymers |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS57182342A (enrdf_load_stackoverflow) |
| BR (1) | BR8202193A (enrdf_load_stackoverflow) |
| CA (1) | CA1171576A (enrdf_load_stackoverflow) |
| DE (1) | DE3215127A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2504538B1 (enrdf_load_stackoverflow) |
| GB (1) | GB2097406B (enrdf_load_stackoverflow) |
| IT (1) | IT1151740B (enrdf_load_stackoverflow) |
| NL (1) | NL8201697A (enrdf_load_stackoverflow) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5039445A (en) * | 1990-10-03 | 1991-08-13 | E. I. Du Pont De Nemours And Company | Ternary azeotropic compositions of N-perfluorobutylethylene and cis-1,2-dichloroethylene with methanol or ethanol or isopropanol |
| US5037572A (en) * | 1990-10-03 | 1991-08-06 | E. I. Du Pont De Nemours And Company | Ternary azeotropic compositions of n-perfluorobutylethylene and trans-1,2-dichloroethylene with methanol or ethanol or isopropanol |
| US5037573A (en) * | 1990-10-03 | 1991-08-06 | E. I. Du Pont De Nemours And Company | Binary azeotropic compositions of 1,1-dichloro-1-fluoroethane and n-perfluorobutylethylene |
| CN101547945B (zh) * | 2006-12-08 | 2011-07-06 | 旭硝子株式会社 | 乙烯/四氟乙烯类共聚物及其制造方法 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5225850A (en) * | 1975-08-25 | 1977-02-26 | Asahi Glass Co Ltd | Ethylene-tetrafluoroethylene copolymer composition with improved heat stability |
-
1982
- 1982-03-30 CA CA000399787A patent/CA1171576A/en not_active Expired
- 1982-04-16 BR BR8202193A patent/BR8202193A/pt not_active IP Right Cessation
- 1982-04-21 JP JP57065546A patent/JPS57182342A/ja active Granted
- 1982-04-22 GB GB8211683A patent/GB2097406B/en not_active Expired
- 1982-04-23 NL NL8201697A patent/NL8201697A/nl not_active Application Discontinuation
- 1982-04-23 FR FR8207034A patent/FR2504538B1/fr not_active Expired
- 1982-04-23 DE DE19823215127 patent/DE3215127A1/de active Granted
- 1982-04-23 IT IT20920/82A patent/IT1151740B/it active
Also Published As
| Publication number | Publication date |
|---|---|
| IT8220920A0 (it) | 1982-04-23 |
| FR2504538A1 (fr) | 1982-10-29 |
| JPS632291B2 (enrdf_load_stackoverflow) | 1988-01-18 |
| IT1151740B (it) | 1986-12-24 |
| BR8202193A (pt) | 1983-03-29 |
| FR2504538B1 (fr) | 1986-04-04 |
| NL8201697A (nl) | 1982-11-16 |
| JPS57182342A (en) | 1982-11-10 |
| DE3215127C2 (enrdf_load_stackoverflow) | 1990-08-30 |
| DE3215127A1 (de) | 1982-11-11 |
| GB2097406A (en) | 1982-11-03 |
| GB2097406B (en) | 1984-10-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEC | Expiry (correction) | ||
| MKEX | Expiry |