CA1170429A - Process and apparatus for producing hydrogen - Google Patents
Process and apparatus for producing hydrogenInfo
- Publication number
- CA1170429A CA1170429A CA000340246A CA340246A CA1170429A CA 1170429 A CA1170429 A CA 1170429A CA 000340246 A CA000340246 A CA 000340246A CA 340246 A CA340246 A CA 340246A CA 1170429 A CA1170429 A CA 1170429A
- Authority
- CA
- Canada
- Prior art keywords
- heat
- reaction
- heating
- hydrocarbons
- producing hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims abstract description 26
- 230000008569 process Effects 0.000 title claims abstract description 24
- 239000001257 hydrogen Substances 0.000 title claims abstract description 9
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims abstract description 24
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 15
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 15
- 238000010438 heat treatment Methods 0.000 claims abstract description 12
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000005485 electric heating Methods 0.000 claims abstract description 5
- 239000007858 starting material Substances 0.000 claims abstract description 5
- 239000007789 gas Substances 0.000 claims description 13
- 238000011084 recovery Methods 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 3
- 238000002485 combustion reaction Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000003638 chemical reducing agent Substances 0.000 claims description 2
- 239000007809 chemical reaction catalyst Substances 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 14
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 3
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 3
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000001149 thermolysis Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
- B01J8/067—Heating or cooling the reactor
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00389—Controlling the temperature using electric heating or cooling elements
- B01J2208/00398—Controlling the temperature using electric heating or cooling elements inside the reactor bed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00477—Controlling the temperature by thermal insulation means
- B01J2208/00495—Controlling the temperature by thermal insulation means using insulating materials or refractories
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/0053—Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
- C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/085—Methods of heating the process for making hydrogen or synthesis gas by electric heating
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0866—Methods of heating the process for making hydrogen or synthesis gas by combination of different heating methods
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1193578A CH645318A5 (de) | 1978-11-21 | 1978-11-21 | Verfahren und vorrichtung zur herstellung von wasserstoff. |
| CH11935/78-4 | 1978-11-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1170429A true CA1170429A (en) | 1984-07-10 |
Family
ID=4378298
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000340246A Expired CA1170429A (en) | 1978-11-21 | 1979-11-20 | Process and apparatus for producing hydrogen |
Country Status (8)
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4863707A (en) * | 1982-09-30 | 1989-09-05 | Engelhard Corporation | Method of ammonia production |
| EP0124226B1 (en) * | 1983-03-25 | 1989-10-18 | Imperial Chemical Industries Plc | Steam reforming |
| GB8308343D0 (en) * | 1983-03-25 | 1983-05-05 | Ici Plc | Steam reforming |
| US4822521A (en) * | 1983-06-09 | 1989-04-18 | Uop | Integrated process and apparatus for the primary and secondary catalytic steam reforming of hydrocarbons |
| US4919844A (en) * | 1984-08-16 | 1990-04-24 | Air Products And Chemicals, Inc. | Enhanced heat transfer reformer and method |
| US4670359A (en) * | 1985-06-10 | 1987-06-02 | Engelhard Corporation | Fuel cell integrated with steam reformer |
| IT1211957B (it) * | 1987-12-07 | 1989-11-08 | Kinetics Technology | Procedimento,apparato e relativo metodo di funzionamento per la generazione di vapore ed il recupero dicalore in impianti di produzione di idrogeno e gas di sintesi |
| JPH07315801A (ja) * | 1994-05-23 | 1995-12-05 | Ngk Insulators Ltd | 高純度水素製造システム、高純度水素の製造方法及び燃料電池システム |
| DE19621036C2 (de) * | 1996-05-24 | 2000-07-06 | Westfalen Ag | Vorrichtung zur Erzeugung von Endogas |
| US7066973B1 (en) | 1996-08-26 | 2006-06-27 | Nuvera Fuel Cells | Integrated reformer and shift reactor |
| JPH11130405A (ja) * | 1997-10-28 | 1999-05-18 | Ngk Insulators Ltd | 改質反応装置、触媒装置、それらに用いる発熱・触媒体、及び改質反応装置の運転方法 |
| US6986797B1 (en) | 1999-05-03 | 2006-01-17 | Nuvera Fuel Cells Inc. | Auxiliary reactor for a hydrocarbon reforming system |
| US6641625B1 (en) | 1999-05-03 | 2003-11-04 | Nuvera Fuel Cells, Inc. | Integrated hydrocarbon reforming system and controls |
| US7160342B2 (en) | 2001-02-13 | 2007-01-09 | Delphi Technologies, Inc. | Fuel reformer system |
| FR2831154B1 (fr) * | 2001-10-18 | 2004-02-06 | Physiques Ecp Et Chimiques | Assistance electrique au reformage d'une matiere hydrocarbonee |
| US7507384B2 (en) | 2002-06-13 | 2009-03-24 | Nuvera Fuel Cells, Inc. | Preferential oxidation reactor temperature regulation |
| US8821832B2 (en) * | 2003-06-27 | 2014-09-02 | UltraCell, L.L.C. | Fuel processor for use with portable fuel cells |
| US7168544B2 (en) * | 2003-10-02 | 2007-01-30 | Sulzer Euroflamm Us Inc. | Friction facing material for use in a friction environment |
| US7306781B2 (en) * | 2004-07-09 | 2007-12-11 | Catacel Corp. | Hydrogen generator |
| US8864855B2 (en) | 2008-10-01 | 2014-10-21 | Societe Bic | Portable hydrogen generator |
| DE102008050817A1 (de) * | 2008-10-08 | 2010-04-15 | Karl-Heinz Tetzlaff | Abgasfreie allotherme Dampfreformierung |
| DE102015004121A1 (de) * | 2015-03-31 | 2016-10-06 | Linde Aktiengesellschaft | Ofen mit elektrisch sowie mittels Brennstoff beheizbaren Reaktorrohren zur Dampfreformierung eines kohlenwasserstoffhaltigen Einsatzes |
| WO2020150244A1 (en) * | 2019-01-15 | 2020-07-23 | Sabic Global Technologies, B.V. | Use of renewable energy in olefin synthesis |
| EP3895795B1 (en) * | 2020-04-18 | 2024-04-17 | Gianluca Pauletto | A reactor with an electrically heated structured ceramic catalyst |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE350555A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | ||||
| US2235401A (en) * | 1939-04-29 | 1941-03-18 | Westinghouse Electric & Mfg Co | Gas generator for heat treating atmospheres |
| US2942958A (en) * | 1953-07-03 | 1960-06-28 | Kellogg M W Co | Process for the conversion of a normally gaseous hydrocarbon to carbon monoxide and hydrogen |
| US2799640A (en) * | 1953-12-31 | 1957-07-16 | Texas Co | Spark discharge activated chemical reactions |
| US2894826A (en) * | 1957-12-09 | 1959-07-14 | Commercial Solvents Corp | Apparatus for reforming hydrocarbons |
| GB866085A (en) | 1958-04-28 | 1961-04-26 | Charmilles Sa Ateliers | Improvements in or relating to a process and plant for the decomposition of gas oilsinto hydrogen and carbon dioxide by water vapour |
| DE1468159A1 (de) * | 1964-08-05 | 1969-05-08 | Knapsack Ag | Verfahren und Vorrichtung zur Spaltung von Kohlenwasserstoffen mit Hilfe des elektrischen Lichtbogens |
| US3397962A (en) * | 1965-02-16 | 1968-08-20 | Arthur M. Squires | Process for hydrogen or ammonia synthesis gas |
| US3578416A (en) * | 1968-12-19 | 1971-05-11 | Bill J Pope | High temperature reactor |
| US3685977A (en) * | 1969-04-16 | 1972-08-22 | Texas Instruments Inc | Partial oxidation of hydrocarbons |
| US3751228A (en) * | 1970-12-16 | 1973-08-07 | V Semenov | Apparatus for reforming hydrocarbons under pressure |
| JPS571482B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1973-09-26 | 1982-01-11 | ||
| DE2809126C2 (de) | 1978-03-03 | 1986-07-17 | GHT Gesellschaft für Hochtemperaturreaktor-Technik mbH, 5060 Bergisch Gladbach | Spaltofen |
-
1978
- 1978-11-21 CH CH1193578A patent/CH645318A5/de not_active IP Right Cessation
-
1979
- 1979-08-20 DE DE7979900925T patent/DE2967133D1/de not_active Expired
- 1979-08-20 WO PCT/CH1979/000112 patent/WO1980001065A1/de unknown
- 1979-08-20 AT AT79900925T patent/ATE8605T1/de not_active IP Right Cessation
- 1979-08-20 JP JP50125479A patent/JPS55500986A/ja active Pending
- 1979-08-20 US US06/200,491 patent/US4391794A/en not_active Expired - Lifetime
- 1979-11-20 CA CA000340246A patent/CA1170429A/en not_active Expired
-
1980
- 1980-06-03 EP EP79900925A patent/EP0020358B1/de not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| WO1980001065A1 (en) | 1980-05-29 |
| DE2967133D1 (en) | 1984-08-30 |
| CH645318A5 (de) | 1984-09-28 |
| EP0020358B1 (de) | 1984-07-25 |
| US4391794A (en) | 1983-07-05 |
| EP0020358A1 (de) | 1981-01-07 |
| ATE8605T1 (de) | 1984-08-15 |
| JPS55500986A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1980-11-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |