CA1159435A - Catalyst for the synthesis of alcohol mixtures containing methanol and higher alcohols - Google Patents

Catalyst for the synthesis of alcohol mixtures containing methanol and higher alcohols

Info

Publication number
CA1159435A
CA1159435A CA000370852A CA370852A CA1159435A CA 1159435 A CA1159435 A CA 1159435A CA 000370852 A CA000370852 A CA 000370852A CA 370852 A CA370852 A CA 370852A CA 1159435 A CA1159435 A CA 1159435A
Authority
CA
Canada
Prior art keywords
oxides
catalyst
zinc
copper
salts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA000370852A
Other languages
English (en)
French (fr)
Inventor
Carl E. Hofstadt
Karl Kochloefl
Ortwin Bock
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Application granted granted Critical
Publication of CA1159435A publication Critical patent/CA1159435A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/868—Chromium copper and chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA000370852A 1980-02-14 1981-02-13 Catalyst for the synthesis of alcohol mixtures containing methanol and higher alcohols Expired CA1159435A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19803005551 DE3005551A1 (de) 1980-02-14 1980-02-14 Katalysator zur synthese von methanol und hoehere alkohole enthaltenden alkoholgemischen
DEP3005551.7 1980-02-14

Publications (1)

Publication Number Publication Date
CA1159435A true CA1159435A (en) 1983-12-27

Family

ID=6094610

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000370852A Expired CA1159435A (en) 1980-02-14 1981-02-13 Catalyst for the synthesis of alcohol mixtures containing methanol and higher alcohols

Country Status (11)

Country Link
EP (1) EP0034338B1 (enrdf_load_stackoverflow)
JP (1) JPS577256A (enrdf_load_stackoverflow)
AT (1) ATE2051T1 (enrdf_load_stackoverflow)
AU (1) AU6729981A (enrdf_load_stackoverflow)
CA (1) CA1159435A (enrdf_load_stackoverflow)
DE (2) DE3005551A1 (enrdf_load_stackoverflow)
DK (1) DK63381A (enrdf_load_stackoverflow)
ES (1) ES499117A0 (enrdf_load_stackoverflow)
FI (1) FI810460A7 (enrdf_load_stackoverflow)
NO (1) NO810102L (enrdf_load_stackoverflow)
ZA (1) ZA81981B (enrdf_load_stackoverflow)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4766155A (en) * 1984-11-26 1988-08-23 Atlantic Richfield Company Process for producing alcohols
US5068215A (en) * 1987-06-04 1991-11-26 Standard Oil Company Catalyst for upgrading low molecular weight hydrocarbons
US5703133A (en) * 1995-12-08 1997-12-30 Exxon Research And Engineering Company Isoalcohol synthesis
WO2010067079A1 (en) 2008-12-12 2010-06-17 Bp P.L.C An improved process for hydrogenating alkyl ester(s) in the presence of carbon monoxide
US9295978B2 (en) 2012-02-15 2016-03-29 Basf Corporation Catalyst and method for the direct synthesis of dimethyl ether from synthesis gas
CN106582700A (zh) * 2016-11-29 2017-04-26 中国科学院山西煤炭化学研究所 一种合成气制低碳混合醇的石墨烯负载催化剂及制法和应用

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57130547A (en) * 1981-02-06 1982-08-13 Mitsubishi Gas Chem Co Inc Catalyst for methanol synthesis
DE3377471D1 (en) * 1982-07-19 1988-09-01 Shell Int Research Modified copper, and zinc-containing catalyst and process for producing methanol using said catalyst
ZA835200B (en) * 1982-07-19 1984-03-28 Shell Res Ltd Modified copper,and zinc-containing catalyst and process for producing methanol using said catalyst
AU565013B2 (en) * 1982-11-29 1987-09-03 Research Association For Petroleum Alternatives Development Production of mixed alcohols
US4477594A (en) * 1982-12-16 1984-10-16 Chem Systems, Inc. Process for the synthesis of aliphatic alcohol-containing mixtures
US4843101A (en) * 1983-06-01 1989-06-27 Lehigh University Catalyst and method for producing methanol
US4642381A (en) * 1983-06-01 1987-02-10 Lehigh University Catalyst and method for production of methylamines
US4565803A (en) * 1983-12-16 1986-01-21 Shell Oil Company Methanol synthesis catalyst
FR2558738B1 (fr) * 1984-01-27 1987-11-13 Inst Francais Du Petrole Procede de fabrication de catalyseurs contenant du cuivre, du zinc et de l'aluminium, utilisables pour la production de methanol a partir de gaz de synthese
DE3403492A1 (de) * 1984-02-02 1985-08-08 Metallgesellschaft Ag, 6000 Frankfurt Verfahren zur herstellung einer mischung aus methanol und hoeheren alkoholen
DE3403491A1 (de) * 1984-02-02 1985-08-14 Süd-Chemie AG, 8000 München Katalysator zur synthese von methanol und hoehere alkohole enthaltenden alkoholgemischen
FR2560531B1 (fr) * 1984-03-02 1988-04-08 Inst Francais Du Petrole Procede de fabrication de catalyseurs contenant du cuivre, du zinc, de l'aluminium et au moins un metal du groupe forme par les terres rares et le zirconium et utilisation des catalyseurs obtenus pour les reactions mettant en jeu un gaz de synthese
US4562174A (en) * 1984-05-21 1985-12-31 Alberta Gas Chemicals Ltd. Catalyst for the production of alkanols
NZ212638A (en) * 1984-07-07 1988-01-08 British Petroleum Co Plc Copper/thorium catalyst and conversion of synthesis gas to methanol
US4762817A (en) * 1986-11-03 1988-08-09 Union Carbide Corporation Aldehyde hydrogenation catalyst
US4789502A (en) * 1986-11-24 1988-12-06 Shell Oil Company Carboxylic acid production
JP2535876B2 (ja) * 1987-02-27 1996-09-18 三菱瓦斯化学株式会社 混合アルコ−ル合成用流動触媒
DE3810421A1 (de) * 1988-03-26 1989-10-05 Union Rheinische Braunkohlen Verbessertes verfahren zur katalytischen herstellung eines alkoholgemischs mit erhoehtem isobutanolgehalt
DE3837308A1 (de) * 1988-11-03 1990-05-10 Basf Ag Kupferhaltiger katalysator zur tieftemperaturkonvertierung
US5008235A (en) * 1989-12-21 1991-04-16 Union Carbide Chemicals And Plastics Technology Corporation Catalysts of Cu-Al-third metal for hydrogenation
US5142067A (en) * 1989-12-21 1992-08-25 Union Carbide Chemicals & Plastics Technology Corporation Hydrogenation with Cu-Al-X catalysts
US5347021A (en) * 1990-04-16 1994-09-13 Isp Investments Inc. Process of vapor phase catalytic hydrogenation of maleic anhydride to gamma-butyrolactone in high conversion and high selectivity using an activated catalyst
DE4141199A1 (de) * 1991-12-13 1993-06-17 Sued Chemie Ag Chromfreier katalysator fuer die hydrierung von organischen verbindungen, die die carbonylfunktionen enthalten
DE4142899A1 (de) * 1991-12-23 1993-06-24 Sued Chemie Ag Verfahren zur herstellung von alkoholen durch katalytische hydrierung von carbonsaeurealkylestern
DE4301469A1 (de) * 1993-01-21 1994-07-28 Basf Ag Katalysatoren mit hochdisperser Verteilung der Aktivkomponente
JPH08299796A (ja) * 1995-05-11 1996-11-19 Mitsubishi Gas Chem Co Inc メタノール合成触媒の製造法
DE69808983T2 (de) * 1997-03-31 2003-08-07 Director General Of Agency Of Industrial Science And Technology, Tokio/Tokyo Methanolsynthese- und Reformierungskatalysator bestehend aus Kupfer, Zink und Aluminium
ES2500141T3 (es) * 2005-07-06 2014-09-30 Bp Chemicals Limited Deshidratación de alcoholes mixtos
JP2012217886A (ja) * 2011-04-05 2012-11-12 Mitsubishi Heavy Ind Ltd エタノール合成触媒及びエタノール合成システム
EP2736636B1 (en) * 2011-07-27 2020-01-08 Saudi Arabian Oil Company Method for removing sulfur compounds from gaseous hydrocarbons using catalytic compositions
US8906227B2 (en) 2012-02-02 2014-12-09 Suadi Arabian Oil Company Mild hydrodesulfurization integrating gas phase catalytic oxidation to produce fuels having an ultra-low level of organosulfur compounds
US8920635B2 (en) 2013-01-14 2014-12-30 Saudi Arabian Oil Company Targeted desulfurization process and apparatus integrating gas phase oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds
CN111499479B (zh) * 2020-04-14 2021-11-23 西安近代化学研究所 一种碳基氧化锌复合推进剂用燃速调节剂及其低温制备方法
WO2022055509A1 (en) * 2020-09-14 2022-03-17 Uop Llc Catalysts for isobutanol synthesis from syngas and ethanol or propanol

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL70072C (enrdf_load_stackoverflow) * 1950-02-18 1900-01-01
JPS4935510B1 (enrdf_load_stackoverflow) * 1962-04-24 1974-09-24
DE1767881C3 (de) * 1967-08-19 1980-06-26 Nina I. Jesipova Katalysator für die Konvertierung von Kohlenmonoxid und für die Methanolsynthese
NL7114914A (enrdf_load_stackoverflow) * 1970-11-02 1972-05-04
DE2056612C3 (de) * 1970-11-18 1979-09-13 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Methanol
CA1021354A (en) * 1972-04-20 1977-11-22 Alvin B. Stiles Methanol synthesis catalyst
JPS5315996A (en) * 1976-07-27 1978-02-14 Kowa Sangiyou Kk Method of assembling corrugated cardboard structure
JPS5426983A (en) * 1977-08-02 1979-02-28 Mitsubishi Gas Chem Co Inc Methanol synthesis catalyst
JPS5453691A (en) * 1977-10-06 1979-04-27 Mitsubishi Gas Chem Co Inc Methanol synthesis catalyst
PL208467A1 (enrdf_load_stackoverflow) * 1978-07-15 1980-02-25 Inst Ciezkiej Syntezy Orga
FR2441420A1 (fr) * 1978-11-17 1980-06-13 Catalyse Soc Prod Francais Catalyseur renfermant de l'oxyde de cuivre, de l'oxyde de zinc et une terre rare, sa preparation et son utilisation dans les reactions de conversion du monoxyde de carbone

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4766155A (en) * 1984-11-26 1988-08-23 Atlantic Richfield Company Process for producing alcohols
US5068215A (en) * 1987-06-04 1991-11-26 Standard Oil Company Catalyst for upgrading low molecular weight hydrocarbons
US5703133A (en) * 1995-12-08 1997-12-30 Exxon Research And Engineering Company Isoalcohol synthesis
WO2010067079A1 (en) 2008-12-12 2010-06-17 Bp P.L.C An improved process for hydrogenating alkyl ester(s) in the presence of carbon monoxide
US8704009B2 (en) 2008-12-12 2014-04-22 Bp P.L.C. Process for hydrogenating alkyl ester(s) in the presence of carbon monoxide
US9295978B2 (en) 2012-02-15 2016-03-29 Basf Corporation Catalyst and method for the direct synthesis of dimethyl ether from synthesis gas
CN106582700A (zh) * 2016-11-29 2017-04-26 中国科学院山西煤炭化学研究所 一种合成气制低碳混合醇的石墨烯负载催化剂及制法和应用

Also Published As

Publication number Publication date
DE3160017D1 (en) 1983-01-27
ATE2051T1 (de) 1983-01-15
FI810460L (fi) 1981-08-15
FI810460A7 (fi) 1981-08-15
JPS577256A (en) 1982-01-14
JPH0450059B2 (enrdf_load_stackoverflow) 1992-08-13
DE3005551A1 (de) 1981-08-20
EP0034338B1 (de) 1982-12-22
DK63381A (da) 1981-08-15
ZA81981B (en) 1982-03-31
ES8201038A1 (es) 1981-12-16
AU6729981A (en) 1981-08-20
EP0034338A3 (en) 1981-09-09
ES499117A0 (es) 1981-12-16
EP0034338A2 (de) 1981-08-26
NO810102L (no) 1981-08-17

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Legal Events

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