CA1159203A - Process for bleaching cellulose pulp by activation with no.sub.2 and oxygen and alkali-extraction at elevated temperature with cellulose degradation - Google Patents
Process for bleaching cellulose pulp by activation with no.sub.2 and oxygen and alkali-extraction at elevated temperature with cellulose degradationInfo
- Publication number
- CA1159203A CA1159203A CA000392232A CA392232A CA1159203A CA 1159203 A CA1159203 A CA 1159203A CA 000392232 A CA000392232 A CA 000392232A CA 392232 A CA392232 A CA 392232A CA 1159203 A CA1159203 A CA 1159203A
- Authority
- CA
- Canada
- Prior art keywords
- pulp
- process according
- activation
- range
- stage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims abstract description 58
- 229920002678 cellulose Polymers 0.000 title claims abstract description 51
- 239000001913 cellulose Substances 0.000 title claims abstract description 51
- 230000004913 activation Effects 0.000 title claims abstract description 43
- 230000015556 catabolic process Effects 0.000 title claims abstract description 8
- 238000006731 degradation reaction Methods 0.000 title claims abstract description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims description 16
- 229910052760 oxygen Inorganic materials 0.000 title claims description 16
- 239000001301 oxygen Substances 0.000 title claims description 16
- 238000004061 bleaching Methods 0.000 title abstract description 29
- 238000000605 extraction Methods 0.000 title description 4
- 238000011282 treatment Methods 0.000 claims abstract description 47
- 239000003513 alkali Substances 0.000 claims abstract description 40
- 230000003213 activating effect Effects 0.000 claims abstract description 31
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229910001882 dioxygen Inorganic materials 0.000 claims abstract description 25
- 239000007789 gas Substances 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- JCXJVPUVTGWSNB-UHFFFAOYSA-N Nitrogen dioxide Chemical compound O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 claims description 65
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 claims description 59
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 58
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 39
- 238000006243 chemical reaction Methods 0.000 claims description 25
- 239000007788 liquid Substances 0.000 claims description 7
- 238000011065 in-situ storage Methods 0.000 claims description 2
- 239000012978 lignocellulosic material Substances 0.000 claims description 2
- 238000004537 pulping Methods 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 37
- 238000001994 activation Methods 0.000 description 31
- 229910052757 nitrogen Inorganic materials 0.000 description 18
- 229920005610 lignin Polymers 0.000 description 13
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 11
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 11
- 239000000460 chlorine Substances 0.000 description 11
- 235000011121 sodium hydroxide Nutrition 0.000 description 11
- 229910052801 chlorine Inorganic materials 0.000 description 10
- 229920002488 Hemicellulose Polymers 0.000 description 8
- 229940083608 sodium hydroxide Drugs 0.000 description 8
- 229910021653 sulphate ion Inorganic materials 0.000 description 8
- 239000002699 waste material Substances 0.000 description 8
- 238000005406 washing Methods 0.000 description 7
- WFPZPJSADLPSON-UHFFFAOYSA-N dinitrogen tetraoxide Chemical compound [O-][N+](=O)[N+]([O-])=O WFPZPJSADLPSON-UHFFFAOYSA-N 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 241001397173 Kali <angiosperm> Species 0.000 description 5
- 239000000543 intermediate Substances 0.000 description 5
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 4
- 230000002349 favourable effect Effects 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 4
- 101150080656 DIO2 gene Proteins 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 3
- 235000011613 Pinus brutia Nutrition 0.000 description 3
- 241000018646 Pinus brutia Species 0.000 description 3
- 229920001131 Pulp (paper) Polymers 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- 239000007844 bleaching agent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011122 softwood Substances 0.000 description 3
- 239000004155 Chlorine dioxide Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 230000018199 S phase Effects 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 235000014633 carbohydrates Nutrition 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 235000019398 chlorine dioxide Nutrition 0.000 description 2
- 238000010411 cooking Methods 0.000 description 2
- 230000000875 corresponding effect Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000029087 digestion Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000011121 hardwood Substances 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- 229940099990 ogen Drugs 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 230000008016 vaporization Effects 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 241000218657 Picea Species 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- -1 a~aline materials Chemical compound 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000007084 catalytic combustion reaction Methods 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 229910001902 chlorine oxide Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003471 mutagenic agent Substances 0.000 description 1
- 231100000707 mutagenic chemical Toxicity 0.000 description 1
- VOVZXURTCKPRDQ-CQSZACIVSA-N n-[4-[chloro(difluoro)methoxy]phenyl]-6-[(3r)-3-hydroxypyrrolidin-1-yl]-5-(1h-pyrazol-5-yl)pyridine-3-carboxamide Chemical compound C1[C@H](O)CCN1C1=NC=C(C(=O)NC=2C=CC(OC(F)(F)Cl)=CC=2)C=C1C1=CC=NN1 VOVZXURTCKPRDQ-CQSZACIVSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 238000003918 potentiometric titration Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000003265 pulping liquor Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/1005—Pretreatment of the pulp, e.g. degassing the pulp
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
- Investigating Or Analysing Biological Materials (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE80-08874-3 | 1980-12-17 | ||
| SE8008874A SE445122B (sv) | 1980-12-17 | 1980-12-17 | Forfarande for delignifiering av cellulosamassa i nervaro av kvevedioxid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1159203A true CA1159203A (en) | 1983-12-27 |
Family
ID=20342493
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000392232A Expired CA1159203A (en) | 1980-12-17 | 1981-12-14 | Process for bleaching cellulose pulp by activation with no.sub.2 and oxygen and alkali-extraction at elevated temperature with cellulose degradation |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS57121689A (enrdf_load_stackoverflow) |
| AU (1) | AU548046B2 (enrdf_load_stackoverflow) |
| CA (1) | CA1159203A (enrdf_load_stackoverflow) |
| FI (1) | FI73017C (enrdf_load_stackoverflow) |
| FR (1) | FR2496138A1 (enrdf_load_stackoverflow) |
| NO (1) | NO158953C (enrdf_load_stackoverflow) |
| NZ (1) | NZ198925A (enrdf_load_stackoverflow) |
| SE (1) | SE445122B (enrdf_load_stackoverflow) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE434283B (sv) * | 1982-12-01 | 1984-07-16 | Mo Och Domsjoe Ab | Forfarande for delignifiering av cellulosamassa med kveveoxider och syrgas |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1070909A (en) * | 1976-05-04 | 1980-02-05 | Canadian Industries Limited | Nitrogen dioxide-oxygen delignification |
-
1980
- 1980-12-17 SE SE8008874A patent/SE445122B/sv not_active IP Right Cessation
-
1981
- 1981-11-10 NZ NZ198925A patent/NZ198925A/en unknown
- 1981-11-23 AU AU77738/81A patent/AU548046B2/en not_active Ceased
- 1981-12-09 FI FI813954A patent/FI73017C/fi not_active IP Right Cessation
- 1981-12-14 CA CA000392232A patent/CA1159203A/en not_active Expired
- 1981-12-14 JP JP56202386A patent/JPS57121689A/ja active Granted
- 1981-12-16 NO NO814309A patent/NO158953C/no unknown
- 1981-12-16 FR FR8123482A patent/FR2496138A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| FR2496138A1 (fr) | 1982-06-18 |
| SE445122B (sv) | 1986-06-02 |
| AU548046B2 (en) | 1985-11-21 |
| NO158953B (no) | 1988-08-08 |
| FI813954L (fi) | 1982-06-18 |
| NO814309L (no) | 1982-06-18 |
| AU7773881A (en) | 1982-06-24 |
| FI73017C (fi) | 1987-08-10 |
| FR2496138B1 (enrdf_load_stackoverflow) | 1983-12-02 |
| JPS57121689A (en) | 1982-07-29 |
| SE8008874L (sv) | 1982-06-18 |
| NO158953C (no) | 1988-11-16 |
| FI73017B (fi) | 1987-04-30 |
| NZ198925A (en) | 1984-09-28 |
| JPS6350466B2 (enrdf_load_stackoverflow) | 1988-10-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |