CA1151350A - Preparation of resilient foams based on a melamine/formaldehyde condensate - Google Patents
Preparation of resilient foams based on a melamine/formaldehyde condensateInfo
- Publication number
- CA1151350A CA1151350A CA000347095A CA347095A CA1151350A CA 1151350 A CA1151350 A CA 1151350A CA 000347095 A CA000347095 A CA 000347095A CA 347095 A CA347095 A CA 347095A CA 1151350 A CA1151350 A CA 1151350A
- Authority
- CA
- Canada
- Prior art keywords
- foam
- precondensate
- melamine
- foaming
- din
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000006260 foam Substances 0.000 title claims abstract description 76
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 238000005187 foaming Methods 0.000 claims abstract description 46
- 238000000034 method Methods 0.000 claims abstract description 44
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 36
- 239000004604 Blowing Agent Substances 0.000 claims abstract description 35
- 230000008569 process Effects 0.000 claims abstract description 33
- 239000006185 dispersion Substances 0.000 claims abstract description 25
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- 239000007864 aqueous solution Substances 0.000 claims abstract description 17
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 17
- 239000000203 mixture Substances 0.000 claims description 25
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 239000000654 additive Substances 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 9
- 238000009835 boiling Methods 0.000 claims description 7
- 238000007906 compression Methods 0.000 claims description 5
- 230000006835 compression Effects 0.000 claims description 5
- 239000004640 Melamine resin Substances 0.000 description 26
- 238000001723 curing Methods 0.000 description 26
- 229920005989 resin Polymers 0.000 description 19
- 239000011347 resin Substances 0.000 description 19
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 16
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 14
- 239000000463 material Substances 0.000 description 10
- 239000000243 solution Substances 0.000 description 8
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 7
- 235000019253 formic acid Nutrition 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 7
- 235000019256 formaldehyde Nutrition 0.000 description 6
- 229960004279 formaldehyde Drugs 0.000 description 6
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 6
- 229940091868 melamine Drugs 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 5
- 238000009413 insulation Methods 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical class C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 229920001807 Urea-formaldehyde Polymers 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 150000008052 alkyl sulfonates Chemical class 0.000 description 3
- 229920003180 amino resin Polymers 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- -1 oleic acid triethanolamine ester Chemical class 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 2
- 229940029284 trichlorofluoromethane Drugs 0.000 description 2
- 150000004072 triols Chemical class 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- GKQHIYSTBXDYNQ-UHFFFAOYSA-M 1-dodecylpyridin-1-ium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+]1=CC=CC=C1 GKQHIYSTBXDYNQ-UHFFFAOYSA-M 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000011111 cardboard Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 150000001767 cationic compounds Chemical class 0.000 description 1
- VXIVSQZSERGHQP-UHFFFAOYSA-N chloroacetamide Chemical compound NC(=O)CCl VXIVSQZSERGHQP-UHFFFAOYSA-N 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 150000003977 halocarboxylic acids Chemical class 0.000 description 1
- 150000005826 halohydrocarbons Chemical class 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 150000008040 ionic compounds Chemical class 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 238000011417 postcuring Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/141—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2361/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08J2361/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C08J2361/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
Landscapes
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Molding Of Porous Articles (AREA)
- Biological Depolymerization Polymers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP2915467.4 | 1979-04-17 | ||
| DE19792915467 DE2915467A1 (de) | 1979-04-17 | 1979-04-17 | Verfahren zur herstellung von elastischen schaumstoffen auf basis eines melamin/ formaldehyd-kondensationsprodukts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1151350A true CA1151350A (en) | 1983-08-02 |
Family
ID=6068510
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000347095A Expired CA1151350A (en) | 1979-04-17 | 1980-03-06 | Preparation of resilient foams based on a melamine/formaldehyde condensate |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP0017671B1 (enExample) |
| JP (1) | JPS55142628A (enExample) |
| AT (1) | ATE2224T1 (enExample) |
| AU (1) | AU531639B2 (enExample) |
| BR (1) | BR8002360A (enExample) |
| CA (1) | CA1151350A (enExample) |
| DE (2) | DE2915467A1 (enExample) |
| DK (1) | DK158045C (enExample) |
| ES (1) | ES490632A0 (enExample) |
| FI (1) | FI67874C (enExample) |
| NO (1) | NO151291C (enExample) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6284077B1 (en) | 1997-08-29 | 2001-09-04 | Dap Products Inc. | Stable, foamed caulk and sealant compounds and methods of use thereof |
| US6291536B1 (en) | 1998-02-07 | 2001-09-18 | Dap Products Inc. | Foamed caulk and sealant compounds |
| US6333365B1 (en) | 1996-09-19 | 2001-12-25 | Dap Products Inc. | Stable, foamed caulk and sealant compounds and methods of use thereof |
| US8937106B2 (en) | 2010-12-07 | 2015-01-20 | Basf Se | Melamine resin foams with nanoporous fillers |
| US9056961B2 (en) | 2009-11-20 | 2015-06-16 | Basf Se | Melamine-resin foams comprising hollow microbeads |
| US9353232B2 (en) | 2011-05-16 | 2016-05-31 | Basf Se | Melamine-formaldehyde foams comprising hollow microspheres |
| US9663625B2 (en) | 2012-09-04 | 2017-05-30 | Basf Se | Method for producing melamine/formaldehyde foams |
| US11254795B2 (en) | 2016-11-23 | 2022-02-22 | Basf Se | Production of melamine-formaldehyde foams |
Families Citing this family (44)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2950289A1 (de) * | 1979-12-14 | 1981-06-19 | Basf Ag, 6700 Ludwigshafen | Elastischer schaumstoff auf basis eines harnstoff/formaldehyd-kondensationsproduktes |
| DE3037683A1 (de) * | 1980-10-04 | 1982-05-19 | Basf Ag, 6700 Ludwigshafen | Elastische duroplast-schaumstoffe |
| EP0068673A1 (en) * | 1981-06-13 | 1983-01-05 | BP Chemicals Limited | Phenolic foam of increased resilience and process for making it |
| DE3534739C2 (de) * | 1985-09-28 | 1994-02-03 | Basf Ag | Verfahren zur Herstellung von Schaumstoffen auf Basis von Melaminharzen |
| DE3534738A1 (de) * | 1985-09-28 | 1987-04-09 | Basf Ag | Verfahren zur herstellung von elastischen melamin-schaumstoffen |
| DE3816858A1 (de) * | 1988-05-18 | 1989-11-30 | Basf Ag | Verbundschaumstoff und verfahren zu seiner herstellung |
| JPH05502410A (ja) * | 1989-10-03 | 1993-04-28 | イーストマン コダック カンパニー | インク印字ヘツドを組み込まれたインク貯蔵容器を備えるインク印字装置用印字モジユール |
| US5849805A (en) * | 1995-01-10 | 1998-12-15 | The Procter & Gamble Company | Process for making foams useful as absorbent members for catamenial pads |
| US5650222A (en) * | 1995-01-10 | 1997-07-22 | The Procter & Gamble Company | Absorbent foam materials for aqueous fluids made from high internal phase emulsions having very high water-to-oil ratios |
| EG21087A (en) * | 1995-01-10 | 2000-10-31 | Procter & Gamble | Foams made from high internal phase emulsions useful as absorbent members from catamenial pads |
| US5563179A (en) * | 1995-01-10 | 1996-10-08 | The Proctor & Gamble Company | Absorbent foams made from high internal phase emulsions useful for acquiring and distributing aqueous fluids |
| US5633291A (en) * | 1995-06-07 | 1997-05-27 | The Procter & Gamble Company | Use of foam materials derived from high internal phase emulsions for insulation |
| US5550167A (en) * | 1995-08-30 | 1996-08-27 | The Procter & Gamble Company | Absorbent foams made from high internal phase emulsions useful for acquiring aqueous fluids |
| US5817704A (en) * | 1996-03-08 | 1998-10-06 | The Procter & Gamble Company | Heterogeneous foam materials |
| JPH1187978A (ja) * | 1997-09-09 | 1999-03-30 | Nitto Boseki Co Ltd | 不燃性電波吸収体 |
| US6160028A (en) * | 1998-07-17 | 2000-12-12 | The Procter & Gamble Company | Flame retardant microporous polymeric foams |
| US6245697B1 (en) | 1998-11-12 | 2001-06-12 | The Procter & Gamble Company | Flexible mat for absorbing liquids comprising polymeric foam materials |
| DE10047717A1 (de) * | 2000-09-27 | 2002-04-18 | Basf Ag | Hydrophile, offenzellige, elastische Schaumstoffe auf Basis von Melamin/Formaldehyd-Harzen, ihre Herstellung und ihre Verwendung in Hygieneartikeln |
| DE10047719A1 (de) * | 2000-09-27 | 2002-04-11 | Basf Ag | Hydrophile, offenzellige, elastische Schaumstoffe auf Basis von Melamin/Formaldehyd-Harzen, ihre Herstellung und ihre Verwendung in Hygieneartikeln |
| ES2272569T3 (es) | 2000-12-15 | 2007-05-01 | Ami Agrolinz Melamine International Gmbh | Particulas inorganicas modificadas por un p0olimero. |
| AT410211B (de) | 2000-12-15 | 2003-03-25 | Agrolinz Melamin Gmbh | Halbzeuge und formstoffe aus aminoplasten |
| ES2292832T3 (es) | 2001-11-19 | 2008-03-16 | Ami Agrolinz Melamine International Gmbh | Productos, especialmente masas de moldeo de polimeros que contienen segmentos de triazina, procedimiento para su fabricacion y usos. |
| JP3783039B2 (ja) | 2002-04-24 | 2006-06-07 | 国立大学法人広島大学 | 天然歯用のブラシ |
| DE10335957A1 (de) * | 2003-08-04 | 2005-02-24 | Basf Ag | Formteile aus Melamin/Formaldehyd-Schaumstoffen mit geringer Formaldehyd-Emission |
| US7331087B2 (en) | 2003-12-22 | 2008-02-19 | Kimberly-Clark Worldwide, Inc. | Activatable fastening system and web having elevated regions and functional material members |
| CN100434471C (zh) * | 2005-07-27 | 2008-11-19 | 北京绿寰宇化工有限公司 | 一种纳米材料改性增韧蜜胺泡沫塑料及其生产方法 |
| DE102006001862A1 (de) | 2006-01-13 | 2007-07-19 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Treibmittelfreier Aminoharzschaum, Verfahren zu dessen Herstellung und dessen Verwendung |
| JP5679664B2 (ja) * | 2007-03-12 | 2015-03-04 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 抗菌性を有するメラミン−ホルムアルデヒドフォーム |
| SI2197927T1 (en) | 2007-10-12 | 2018-01-31 | Borealis Agrolinz Melamine Gmbh | Aromatic resin, which can be thermoplastic, durable finely-fibrous nonwovens, as well as the process and device for their production |
| DE102011009397A1 (de) | 2011-01-25 | 2012-07-26 | Basf Se | Verbundschaumstoff zur Schalldämmung |
| EP2702906B1 (en) | 2011-04-27 | 2016-03-02 | Inoac Corporation | Mat and method for manufacturing the same |
| EP2709507B1 (en) | 2011-05-16 | 2016-08-10 | The Procter and Gamble Company | Cleaning implement based on melamine-formaldehyde foam comprising hollow microspheres |
| CN103547617B (zh) | 2011-05-16 | 2015-04-22 | 巴斯夫欧洲公司 | 包含中空微球的三聚氰胺-甲醛泡沫 |
| JP2015527413A (ja) | 2012-05-31 | 2015-09-17 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 結合剤 |
| DE102016212418B4 (de) | 2016-07-07 | 2019-06-06 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zur Herstellung eines Biopolymer-Partikel enthaltenden Aminoharzschaumstoffs, Aminoharzschaumstoff sowie dessen Verwendung |
| US11224328B2 (en) | 2016-11-23 | 2022-01-18 | The Procter & Gamble Company | Cleaning implement comprising a modified open-cell foam |
| US11259680B2 (en) | 2016-11-23 | 2022-03-01 | The Procter & Gamble Company | Cleaning implement comprising a modified open-cell foam |
| CN106674890A (zh) * | 2016-12-05 | 2017-05-17 | 钦州市钦南区生产力促进中心 | 一种高分子泡沫材料及其制备方法 |
| CA3074089A1 (en) | 2017-09-13 | 2019-03-21 | Basf Se | Auxetic polyurethane and melamine foams by triaxial compression |
| US11045844B2 (en) | 2017-09-22 | 2021-06-29 | The Procter & Gamble Company | Cleaning article comprising multiple sheets and methods thereof |
| US20200015651A1 (en) | 2018-07-13 | 2020-01-16 | The Procter & Gamble Company | Cleaning article comprising multiple sheets and methods thereof |
| WO2020221800A1 (en) | 2019-05-02 | 2020-11-05 | Basf Se | Melamine formaldehyde foam with reduced formaldehyde emission |
| WO2021216288A1 (en) | 2020-04-10 | 2021-10-28 | The Procter & Gamble Company | Cleaning implement with a rheological solid composition |
| WO2024094552A1 (en) | 2022-11-03 | 2024-05-10 | Basf Se | Melamine resin foams by oxidation reaction |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE870027C (de) * | 1944-07-28 | 1953-03-09 | Ciba Geigy | Verfahren zur Herstellung von Schaumisoliermassen |
| US3063953A (en) * | 1960-08-22 | 1962-11-13 | Scott Paper Co | Process of improving the physical characteristics of an amine-formaldehyde foam by compression and product produced thereform |
| DE2348476A1 (de) * | 1973-10-22 | 1975-04-03 | Coordenacao Dos Programas De P | Hartschaeume aus kunstharzsystemen und verschiedenen fuellmitteln sowie verfahren zu deren herstellung |
-
1979
- 1979-04-17 DE DE19792915467 patent/DE2915467A1/de not_active Withdrawn
- 1979-12-17 AT AT79105216T patent/ATE2224T1/de not_active IP Right Cessation
- 1979-12-17 DE DE7979105216T patent/DE2964510D1/de not_active Expired
- 1979-12-17 EP EP79105216A patent/EP0017671B1/de not_active Expired
-
1980
- 1980-03-06 CA CA000347095A patent/CA1151350A/en not_active Expired
- 1980-03-21 FI FI800888A patent/FI67874C/fi not_active IP Right Cessation
- 1980-04-14 JP JP4815980A patent/JPS55142628A/ja active Granted
- 1980-04-16 BR BR8002360A patent/BR8002360A/pt not_active IP Right Cessation
- 1980-04-16 DK DK160780A patent/DK158045C/da not_active IP Right Cessation
- 1980-04-16 NO NO801102A patent/NO151291C/no unknown
- 1980-04-16 ES ES490632A patent/ES490632A0/es active Granted
- 1980-04-16 AU AU57512/80A patent/AU531639B2/en not_active Ceased
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6333365B1 (en) | 1996-09-19 | 2001-12-25 | Dap Products Inc. | Stable, foamed caulk and sealant compounds and methods of use thereof |
| US6395794B2 (en) | 1996-09-19 | 2002-05-28 | Dap Products Inc. | Stable, foamed caulk and sealant compounds and methods of use thereof |
| US6284077B1 (en) | 1997-08-29 | 2001-09-04 | Dap Products Inc. | Stable, foamed caulk and sealant compounds and methods of use thereof |
| US6291536B1 (en) | 1998-02-07 | 2001-09-18 | Dap Products Inc. | Foamed caulk and sealant compounds |
| US6414044B2 (en) | 1998-02-07 | 2002-07-02 | Dap Products Inc. | Foamed caulk and sealant compounds |
| US9056961B2 (en) | 2009-11-20 | 2015-06-16 | Basf Se | Melamine-resin foams comprising hollow microbeads |
| US8937106B2 (en) | 2010-12-07 | 2015-01-20 | Basf Se | Melamine resin foams with nanoporous fillers |
| US9353232B2 (en) | 2011-05-16 | 2016-05-31 | Basf Se | Melamine-formaldehyde foams comprising hollow microspheres |
| US9663625B2 (en) | 2012-09-04 | 2017-05-30 | Basf Se | Method for producing melamine/formaldehyde foams |
| US11254795B2 (en) | 2016-11-23 | 2022-02-22 | Basf Se | Production of melamine-formaldehyde foams |
Also Published As
| Publication number | Publication date |
|---|---|
| DK158045B (da) | 1990-03-19 |
| ES8101098A1 (es) | 1980-12-01 |
| NO151291B (no) | 1984-12-03 |
| DK160780A (da) | 1980-10-18 |
| BR8002360A (pt) | 1980-12-02 |
| AU531639B2 (en) | 1983-09-01 |
| DK158045C (da) | 1990-08-13 |
| EP0017671B1 (de) | 1983-01-12 |
| ATE2224T1 (de) | 1983-01-15 |
| AU5751280A (en) | 1980-10-23 |
| NO151291C (no) | 1985-03-13 |
| JPS638976B2 (enExample) | 1988-02-25 |
| EP0017671A1 (de) | 1980-10-29 |
| FI67874C (fi) | 1985-06-10 |
| JPS55142628A (en) | 1980-11-07 |
| ES490632A0 (es) | 1980-12-01 |
| NO801102L (no) | 1980-10-20 |
| DE2915467A1 (de) | 1980-10-30 |
| DE2964510D1 (en) | 1983-02-17 |
| FI800888A7 (fi) | 1980-10-18 |
| FI67874B (fi) | 1985-02-28 |
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