JP6968989B2 - 複数のシートを圧縮する洗浄物品、及びその方法 - Google Patents
複数のシートを圧縮する洗浄物品、及びその方法 Download PDFInfo
- Publication number
- JP6968989B2 JP6968989B2 JP2020515893A JP2020515893A JP6968989B2 JP 6968989 B2 JP6968989 B2 JP 6968989B2 JP 2020515893 A JP2020515893 A JP 2020515893A JP 2020515893 A JP2020515893 A JP 2020515893A JP 6968989 B2 JP6968989 B2 JP 6968989B2
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- Prior art keywords
- melamine
- formaldehyde foam
- cleaning article
- cleaning
- formaldehyde
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000004140 cleaning Methods 0.000 title claims description 93
- 238000000034 method Methods 0.000 title claims description 39
- 239000006260 foam Substances 0.000 claims description 121
- 229920000877 Melamine resin Polymers 0.000 claims description 102
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 claims description 79
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 36
- 239000000463 material Substances 0.000 claims description 34
- 239000000203 mixture Substances 0.000 claims description 28
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 22
- 239000002253 acid Substances 0.000 claims description 21
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- 239000002904 solvent Substances 0.000 claims description 13
- 150000003839 salts Chemical class 0.000 claims description 10
- 239000004094 surface-active agent Substances 0.000 claims description 8
- 239000007844 bleaching agent Substances 0.000 claims description 7
- 230000003068 static effect Effects 0.000 claims description 7
- 238000005520 cutting process Methods 0.000 claims description 4
- 239000003599 detergent Substances 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 2
- 239000004599 antimicrobial Substances 0.000 claims 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims 1
- -1 linorium Polymers 0.000 description 41
- 238000012360 testing method Methods 0.000 description 24
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 19
- 229920000642 polymer Polymers 0.000 description 19
- 239000004088 foaming agent Substances 0.000 description 15
- 150000007513 acids Chemical class 0.000 description 13
- 230000009286 beneficial effect Effects 0.000 description 13
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
- 125000000217 alkyl group Chemical group 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 230000008569 process Effects 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- 239000003139 biocide Substances 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 239000000975 dye Substances 0.000 description 8
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 8
- 239000000377 silicon dioxide Substances 0.000 description 7
- 241000195493 Cryptophyta Species 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 239000002270 dispersing agent Substances 0.000 description 6
- 239000003995 emulsifying agent Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 5
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- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 4
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 4
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical group OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
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- 125000001931 aliphatic group Chemical group 0.000 description 4
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- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
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- 239000000126 substance Substances 0.000 description 4
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- 239000010457 zeolite Substances 0.000 description 4
- VNDYJBBGRKZCSX-UHFFFAOYSA-L zinc bromide Chemical compound Br[Zn]Br VNDYJBBGRKZCSX-UHFFFAOYSA-L 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical compound OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 235000015165 citric acid Nutrition 0.000 description 3
- 238000006073 displacement reaction Methods 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 239000000417 fungicide Substances 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
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- 229920000098 polyolefin Polymers 0.000 description 3
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- 229910052700 potassium Inorganic materials 0.000 description 3
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- 239000000341 volatile oil Substances 0.000 description 3
- 150000005207 1,3-dihydroxybenzenes Chemical class 0.000 description 2
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- AUKRYONWZHRJRE-UHFFFAOYSA-N 9-anthrol Chemical compound C1=CC=C2C(O)=C(C=CC=C3)C3=CC2=C1 AUKRYONWZHRJRE-UHFFFAOYSA-N 0.000 description 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- QDHHCQZDFGDHMP-UHFFFAOYSA-N Chloramine Chemical compound ClN QDHHCQZDFGDHMP-UHFFFAOYSA-N 0.000 description 2
- GHXZTYHSJHQHIJ-UHFFFAOYSA-N Chlorhexidine Chemical compound C=1C=C(Cl)C=CC=1NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)NC1=CC=C(Cl)C=C1 GHXZTYHSJHQHIJ-UHFFFAOYSA-N 0.000 description 2
- 229920001634 Copolyester Polymers 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
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- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
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- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
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- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
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- 125000000129 anionic group Chemical group 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
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- 239000001506 calcium phosphate Substances 0.000 description 2
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- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
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- CUVLMZNMSPJDON-UHFFFAOYSA-N 1-(1-butoxypropan-2-yloxy)propan-2-ol Chemical compound CCCCOCC(C)OCC(C)O CUVLMZNMSPJDON-UHFFFAOYSA-N 0.000 description 1
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- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 150000003232 pyrogallols Chemical class 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229940071089 sarcosinate Drugs 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- LMEWRZSPCQHBOB-UHFFFAOYSA-M silver;2-hydroxypropanoate Chemical compound [Ag+].CC(O)C([O-])=O LMEWRZSPCQHBOB-UHFFFAOYSA-M 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 229960000776 sodium tetradecyl sulfate Drugs 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- UPUIQOIQVMNQAP-UHFFFAOYSA-M sodium;tetradecyl sulfate Chemical compound [Na+].CCCCCCCCCCCCCCOS([O-])(=O)=O UPUIQOIQVMNQAP-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- KUCOHFSKRZZVRO-UHFFFAOYSA-N terephthalaldehyde Chemical compound O=CC1=CC=C(C=O)C=C1 KUCOHFSKRZZVRO-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- ASTWEMOBIXQPPV-UHFFFAOYSA-K trisodium;phosphate;dodecahydrate Chemical class O.O.O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[Na+].[O-]P([O-])([O-])=O ASTWEMOBIXQPPV-UHFFFAOYSA-K 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 229960000314 zinc acetate Drugs 0.000 description 1
- GTQFPPIXGLYKCZ-UHFFFAOYSA-L zinc chlorate Chemical compound [Zn+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O GTQFPPIXGLYKCZ-UHFFFAOYSA-L 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 229960001939 zinc chloride Drugs 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
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- B08B1/143—
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/049—Cleaning or scouring pads; Wipes
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
- A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
- A47L13/16—Cloths; Pads; Sponges
- A47L13/17—Cloths; Pads; Sponges containing cleaning agents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/32—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed at least two layers being foamed and next to each other
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C08G12/30—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with substituted triazines
- C08G12/32—Melamines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2266/00—Composition of foam
- B32B2266/02—Organic
- B32B2266/0214—Materials belonging to B32B27/00
- B32B2266/0285—Condensation resins of aldehydes, e.g. with phenols, ureas, melamines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/72—Density
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2432/00—Cleaning articles, e.g. mops, wipes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
Description
本明細書の洗浄物品10は、メラミン−ホルムアルデヒド発泡体に基づいており、複数のシート20を含む。メラミン−ホルムアルデヒド発泡体のシートは、熱圧縮される。「熱圧縮された」とは、メラミン−ホルムアルデヒド発泡体20が、本明細書で更に詳細に記載されるように、同時に実施され得る加熱工程及び圧縮工程の2つの操作を受けていることを意味する。
a)典型的には1:1.3〜1:5、好ましくは1:2.5〜1:3.5の範囲のモル比を有するメラミン−ホルムアルデヒド予備縮合物と、少なくとも1つの直鎖状ポリマーと、硬化剤と、分散剤と、発泡剤と、を含む混合物を発泡させ、架橋させるために加熱する工程、及び
b)プロセス工程a)で得られた発泡体を乾燥させる工程であって、
これらのプロセス工程、及びまた工程a)で有用なメラミン−ホルムアルデヒド予備縮合体、硬化剤、分散剤、及び発泡剤が、当業者に原則として既知であり、文献に記載されている工程。
非常に好ましい実施形態では、上述のように、本明細書の洗浄物品10は、(少なくとも)1つの追加層30を含み得る。第2の層30は、発泡体、フィルム、合成不織布、セルロース系シート、持続可能なシート、及びこれらの組み合わせを含み得る。複数の層は、同じ材料及び/又は異なる材料を含む、これらの材料及びその積層体のうちの1つ以上を含み得る。
本明細書の洗浄物品は、当該技術分野において既知の任意の場所に配置された有益剤を含有し得る。一実施形態では、活性剤はメラミン−ホルムアルデヒド発泡体層20のシートに含浸される。別の実施形態では、有益剤は第2の層30に埋め込まれる。更に別の実施形態では、有益剤は、上述したように、メラミン−ホルムアルデヒド発泡体層20のシートを第2の層30に付着させる。しかしながら、また更なる実施形態では、有益剤は、当該技術分野において既知のように、メラミン−ホルムアルデヒド発泡体層20、第2の層30、又は付着手段のシートのいずれか又は全てに配置され得ることが理解されるであろう。好適な有益剤は、界面活性剤、漂白剤、ライムスケール還元剤、殺生物剤、溶媒、ポリマー、固体、着色剤、及びこれらの混合物の中から選択される。一実施形態では、有益剤は、約5よりも大きい、あるいは約8〜約14よりも大きい、あるいは約12よりも大きいHLBを有し得る。別の実施形態では、有益剤は、約5重量%〜約20重量%又は約10重量%〜約15重量%の有益剤の量で遊離形態で存在し得る。遊離形態の有益剤とは、洗浄物品からの放出が意図的に制御、遅延、又は持続されない、その未希釈形態で、洗浄物品に供給されることを意味する。いくつかの好ましい実施形態では、有益剤(複数可)は、洗浄物品からの放出が意図的に制御、遅延、又は持続されるように、当該技術分野において既知の形態で洗浄物品に供給される。
本明細書の洗浄物品は、包装手段を用いて製造物品内で組み合わされ得る。
別の実施形態では、本発明は、本明細書に上述した洗浄物品を用いて硬質表面を洗浄する方法を包含する。
図6に示されるように、試料の改良円形曲げを、測定した力がセルの限界の10%〜90%以内となるロードセルを使用した定速の延伸引張試験機(好適な計器は、MTS Systems Corp.(Eden Prairie,MN)から入手可能な、Testworks 4.0 Softwareを使用したMTS Allianceである)で測定する。全ての試験は、23℃±3℃及び50%±2%の相対湿度に制御された部屋にて行われる。
TS7及びTS750値は、Emtec TSAソフトウェア(バージョン3.19又はこれに相当するもの)を実行するコンピュータに接続されたEMTEC Tissue Softness Analyzer(「Emtec TSA」)(Emtec Electronic GmbH、Leipzig,Germany)を使用して測定される。Emtecによれば、TS7値は、実際の材料の柔らかさと相関し、TS750値は、材料のフェルト平滑度/粗さと相関している。Emtec TSAは、規定の較正された回転速度(製造業者によって設定される)及び100mNの接触力で試験試料上で回転する垂直ブレードを備えたロータを有している。垂直ブレードと試験片との接触によって振動が発生し、この振動が器具内のマイクによって記録される音を発生させる。次に、記録された音声ファイルは、Emtec TSAソフトウェアによって分析される。試料調製、器具操作、及び試験手順は、機器製造者の仕様書に従って行う。
試験試料は、最終製品から正方形又は円形の試料を切り出すことによって調製される。試験試料は、試料をTSA機器内に適切に固定することができるように、約90mm以上及び約120mm以下の長さ及び幅(又は円形の場合は直径)にこれらの寸法のいずれにおいても切断される。試験試料は、試験領域内に穿孔、しわ、又は折り目がないように選択される。試験のために、8つの実質的に同様の複製試料を調製する。TSA試験を実施する前に、全ての試料をTAPPIの標準温度及び相対湿度条件(23℃±2℃及び50%±2%)で少なくとも1時間平衡化する。TSA試験もTAPPI条件下で行う。
Emtec参照2X(nn.n)試料に対する1点較正法を用いて、製造業者の指示に従って機器を較正する。これらの参照試料が入手可能ではない場合、製造業者によって提供される適当な参照試料を使用する。結果がEmtec参照2X(nn.n)試料に対する1点較正法を用いた場合に得られるものと同等となるように、製造業者の推奨及び指示に従って機器を較正する。
Claims (14)
- 複数のメラミン−ホルムアルデヒド発泡体シートの積層体を含む洗浄物品であって、前記複数のメラミン−ホルムアルデヒド発泡体シートの積層体が、12kg/m3を上回る密度を有し、前記複数のメラミン−ホルムアルデヒド発泡体シートが、厚さ方向に互いに接着され、各メラミン−ホルムアルデヒド発泡体シートが、約0.5〜約4mmの厚さであり、2枚のメラミン−ホルムアルデヒド発泡体シート間の静的摩擦係数(COF)が、6よりも大きく、前記複数のメラミン−ホルムアルデヒド発泡体シートの積層体が、メラミン−ホルムアルデヒド発泡体の少なくとも一部分がメラミン−ホルムアルデヒド発泡体の少なくとも一縁部に沿って切断されずに残るように、メラミン−ホルムアルデヒド発泡体を前記複数のメラミン−ホルムアルデヒド発泡体シートに切断することによって調製される、洗浄物品。
- 前記複数のメラミン−ホルムアルデヒド発泡体シートの積層体が、約18〜約36kg/m3の範囲の密度を有する、請求項1に記載の洗浄物品。
- 前記2枚のメラミン−ホルムアルデヒド発泡体シート間の静的摩擦係数(COF)が、8よりも大きい、請求項1に記載の洗浄物品。
- 前記2枚のメラミン−ホルムアルデヒド発泡体シート間の静的摩擦係数(COF)が、10よりも大きい、請求項1に記載の洗浄物品。
- 前記積層体が、少なくとも5枚のメラミン−ホルムアルデヒド発泡体シートを含む、請求項1に記載の洗浄物品。
- 前記積層体が、少なくとも10枚のメラミン−ホルムアルデヒド発泡体シートを含む、請求項1に記載の洗浄物品。
- 前記複数のメラミン−ホルムアルデヒド発泡体シートの積層体が、1.2よりも大きいTS750比を有する、請求項1に記載の洗浄物品。
- 前記複数のメラミン−ホルムアルデヒド発泡体シートの積層体が、洗剤組成物、界面活性剤、染料、インク、顔料、芳香、酸、塩基、油、塩、漂白剤、抗微生物剤、芳香剤、溶媒、殺生物剤、疎水化剤、触覚に影響を及ぼす薬剤、汚れ放出挙動に影響を及ぼす薬剤、ホルムアルデヒド捕捉剤、及び無機物などの研磨剤、からなる群から選択される有益剤を含む、請求項1に記載の洗浄物品。
- 裏材層を更に含む、請求項1に記載の洗浄物品。
- 硬質表面を洗浄する方法であって、請求項1に記載の洗浄物品を硬質表面と接触させることを含む、方法。
- 前記複数のメラミン−ホルムアルデヒド発泡体シートの積層体が、18kg/m3を上回る密度を有し、各メラミン−ホルムアルデヒド発泡体シートが、約0.5〜約4mmの厚さであり、剛性が、750を下回る、請求項1に記載の洗浄物品。
- 前記複数のメラミン−ホルムアルデヒド発泡体シートの積層体が、18kg/m3を上回る密度を有し、各メラミン−ホルムアルデヒド発泡体シートが、約0.5〜約4mmの厚さ、約18%の増分応力、及び100のエネルギーを有する、請求項1に記載の洗浄物品。
- 硬質表面を洗浄する方法であって、
a)請求項1に記載の洗浄物品を提供することと、
b)前記洗浄物品からシートを除去することと、
c)前記シートを前記硬質表面と接触させることと、を含む、方法。 - 前記2枚のメラミン−ホルムアルデヒド発泡体シート間の静的摩擦係数(COF)が、6よりも大きい、請求項13に記載の硬質表面を洗浄する方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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PCT/US2018/052098 WO2019060647A1 (en) | 2017-09-22 | 2018-09-21 | CLEANING ARTICLE COMPRISING MULTIPLE SHEETS AND ASSOCIATED METHODS |
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EP (1) | EP3684901B1 (ja) |
JP (1) | JP6968989B2 (ja) |
CA (1) | CA3074273C (ja) |
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CN112961299A (zh) * | 2021-02-06 | 2021-06-15 | 台州学院 | 一种共价-有机骨架材料及其制备方法 |
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- 2018-09-21 EP EP18786495.4A patent/EP3684901B1/en active Active
- 2018-09-21 JP JP2020515893A patent/JP6968989B2/ja active Active
- 2018-09-21 WO PCT/US2018/052098 patent/WO2019060647A1/en unknown
- 2018-09-21 US US16/137,556 patent/US11045844B2/en active Active
- 2018-09-21 CA CA3074273A patent/CA3074273C/en active Active
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WO2019060647A1 (en) | 2019-03-28 |
EP3684901A1 (en) | 2020-07-29 |
EP3684901B1 (en) | 2023-11-08 |
US11045844B2 (en) | 2021-06-29 |
US20190091732A1 (en) | 2019-03-28 |
JP2020534405A (ja) | 2020-11-26 |
CA3074273A1 (en) | 2019-03-28 |
CA3074273C (en) | 2022-10-18 |
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