CA1147909A - Method for delignifying and/or bleaching cellulose pulp - Google Patents
Method for delignifying and/or bleaching cellulose pulpInfo
- Publication number
- CA1147909A CA1147909A CA000390852A CA390852A CA1147909A CA 1147909 A CA1147909 A CA 1147909A CA 000390852 A CA000390852 A CA 000390852A CA 390852 A CA390852 A CA 390852A CA 1147909 A CA1147909 A CA 1147909A
- Authority
- CA
- Canada
- Prior art keywords
- chlorine
- pulp
- bleaching
- liquid
- cellulose pulp
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004061 bleaching Methods 0.000 title claims abstract description 133
- 229920002678 cellulose Polymers 0.000 title claims abstract description 89
- 239000001913 cellulose Substances 0.000 title claims abstract description 89
- 238000000034 method Methods 0.000 title claims abstract description 43
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims abstract description 173
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 133
- 239000000460 chlorine Substances 0.000 claims abstract description 133
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 130
- 235000019398 chlorine dioxide Nutrition 0.000 claims abstract description 87
- 239000004155 Chlorine dioxide Substances 0.000 claims abstract description 86
- 239000007788 liquid Substances 0.000 claims abstract description 74
- 230000003247 decreasing effect Effects 0.000 claims description 3
- 238000011282 treatment Methods 0.000 description 42
- 239000003513 alkali Substances 0.000 description 28
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 28
- 239000000725 suspension Substances 0.000 description 26
- 239000000126 substance Substances 0.000 description 22
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
- 239000000243 solution Substances 0.000 description 17
- 238000005660 chlorination reaction Methods 0.000 description 16
- 238000000605 extraction Methods 0.000 description 15
- 229920005610 lignin Polymers 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 10
- 238000003825 pressing Methods 0.000 description 9
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 7
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 7
- 230000014759 maintenance of location Effects 0.000 description 7
- 238000005406 washing Methods 0.000 description 7
- 238000002156 mixing Methods 0.000 description 6
- 239000002699 waste material Substances 0.000 description 6
- 239000007900 aqueous suspension Substances 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 230000001965 increasing effect Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 235000018185 Betula X alpestris Nutrition 0.000 description 3
- 235000018212 Betula X uliginosa Nutrition 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 229910001902 chlorine oxide Inorganic materials 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 244000228957 Ferula foetida Species 0.000 description 2
- 229920001131 Pulp (paper) Polymers 0.000 description 2
- YUHVVTLNLCJEOB-UHFFFAOYSA-N [Cl].O=Cl=O Chemical compound [Cl].O=Cl=O YUHVVTLNLCJEOB-UHFFFAOYSA-N 0.000 description 2
- WBLXMRIMSGHSAC-UHFFFAOYSA-N [Cl].[Cl] Chemical compound [Cl].[Cl] WBLXMRIMSGHSAC-UHFFFAOYSA-N 0.000 description 2
- 238000009874 alkali refining Methods 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 235000014633 carbohydrates Nutrition 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 239000012978 lignocellulosic material Substances 0.000 description 2
- 238000004537 pulping Methods 0.000 description 2
- 238000010977 unit operation Methods 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 241000609240 Ambelania acida Species 0.000 description 1
- 241000861718 Chloris <Aves> Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 229920002488 Hemicellulose Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241001397173 Kali <angiosperm> Species 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 241001648341 Orites Species 0.000 description 1
- 241000218657 Picea Species 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000010905 bagasse Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- MAYPHUUCLRDEAZ-UHFFFAOYSA-N chlorine peroxide Inorganic materials ClOOCl MAYPHUUCLRDEAZ-UHFFFAOYSA-N 0.000 description 1
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 229940000425 combination drug Drugs 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- FDADMSDCHGXBHS-UHFFFAOYSA-N copper;ethene Chemical group [Cu].C=C FDADMSDCHGXBHS-UHFFFAOYSA-N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- -1 for example Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000004045 organic chlorine compounds Chemical class 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 238000004076 pulp bleaching Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/1026—Other features in bleaching processes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/12—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S162/00—Paper making and fiber liberation
- Y10S162/08—Chlorine-containing liquid regeneration
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE8008337-1 | 1980-11-27 | ||
| SE8008337A SE442881B (sv) | 1980-11-27 | 1980-11-27 | Forfarande for delignifiering/blekning av cellulosamassa med klordioxid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1147909A true CA1147909A (en) | 1983-06-14 |
Family
ID=20342345
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000390852A Expired CA1147909A (en) | 1980-11-27 | 1981-11-25 | Method for delignifying and/or bleaching cellulose pulp |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4537656A (en, 2012) |
| JP (1) | JPS57121691A (en, 2012) |
| CA (1) | CA1147909A (en, 2012) |
| FI (1) | FI73020C (en, 2012) |
| NO (1) | NO156906C (en, 2012) |
| SE (1) | SE442881B (en, 2012) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4662993A (en) * | 1983-08-15 | 1987-05-05 | Westvaco Corporation | Bleach system for dissolving chlorine gas into a bleach filtrate |
| JPH01151991A (ja) * | 1987-12-07 | 1989-06-14 | Oji Paper Co Ltd | 悪臭ドレーンの脱臭方法 |
| JP2528727Y2 (ja) * | 1990-12-18 | 1997-03-12 | 未来工業株式会社 | 管、ケーブル等の支持装置 |
| JP2812056B2 (ja) * | 1992-03-30 | 1998-10-15 | 王子製紙株式会社 | リグノセルロース物質の漂白方法 |
| US6315863B1 (en) * | 1998-06-18 | 2001-11-13 | Weyerhaeuser Company | Chlorine dioxide pulp bleaching process having reduced barium scaling by recycling post-chlorination waste filtrate |
| US20070133346A1 (en) * | 2005-12-14 | 2007-06-14 | Tommy Jacobson | Mixing of chemicals into a thin stock pipe |
| WO2007137127A2 (en) * | 2006-05-19 | 2007-11-29 | The Research Foundation Of State University Of New York | Methods for carbonate pretreatment and pulping of cellulosic material |
| US8303767B2 (en) * | 2008-03-18 | 2012-11-06 | The Research Foundation Of State University Of New York | Methods of pretreating comminuted cellulosic material with carbonate-containing solutions |
-
1980
- 1980-11-27 SE SE8008337A patent/SE442881B/sv not_active IP Right Cessation
-
1981
- 1981-11-23 FI FI813733A patent/FI73020C/fi not_active IP Right Cessation
- 1981-11-25 CA CA000390852A patent/CA1147909A/en not_active Expired
- 1981-11-26 NO NO814025A patent/NO156906C/no unknown
- 1981-11-26 JP JP56190473A patent/JPS57121691A/ja active Granted
-
1983
- 1983-12-01 US US06/557,385 patent/US4537656A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| NO814025L (no) | 1982-05-28 |
| SE442881B (sv) | 1986-02-03 |
| NO156906B (no) | 1987-09-07 |
| NO156906C (no) | 1987-12-16 |
| SE8008337L (sv) | 1982-05-28 |
| US4537656A (en) | 1985-08-27 |
| FI813733L (fi) | 1982-05-28 |
| JPS6262200B2 (en, 2012) | 1987-12-25 |
| JPS57121691A (en) | 1982-07-29 |
| FI73020B (fi) | 1987-04-30 |
| FI73020C (fi) | 1987-08-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |