CA1144306A - Cured rubber skim stock compositions having improved metal adhesion and metal adhesion retention - Google Patents
Cured rubber skim stock compositions having improved metal adhesion and metal adhesion retentionInfo
- Publication number
- CA1144306A CA1144306A CA000358619A CA358619A CA1144306A CA 1144306 A CA1144306 A CA 1144306A CA 000358619 A CA000358619 A CA 000358619A CA 358619 A CA358619 A CA 358619A CA 1144306 A CA1144306 A CA 1144306A
- Authority
- CA
- Canada
- Prior art keywords
- rubber
- parts
- stock
- skim stock
- cobalt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 102
- 239000000203 mixture Substances 0.000 title claims abstract description 29
- 239000002184 metal Substances 0.000 title claims abstract description 26
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 26
- 230000014759 maintenance of location Effects 0.000 title claims abstract description 9
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 36
- 239000010959 steel Substances 0.000 claims abstract description 36
- 229920005989 resin Polymers 0.000 claims abstract description 29
- 239000011347 resin Substances 0.000 claims abstract description 29
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 16
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 16
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 16
- 239000010941 cobalt Substances 0.000 claims abstract description 16
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 16
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000306 component Substances 0.000 claims description 16
- SAXCKUIOAKKRAS-UHFFFAOYSA-N cobalt;hydrate Chemical group O.[Co] SAXCKUIOAKKRAS-UHFFFAOYSA-N 0.000 claims description 13
- 150000001868 cobalt Chemical class 0.000 claims description 9
- 230000003014 reinforcing effect Effects 0.000 claims description 5
- 150000002815 nickel Chemical class 0.000 claims description 4
- 239000004636 vulcanized rubber Substances 0.000 claims description 4
- 238000012360 testing method Methods 0.000 abstract description 30
- 230000002787 reinforcement Effects 0.000 abstract description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 229910052759 nickel Inorganic materials 0.000 abstract description 4
- 230000006872 improvement Effects 0.000 abstract description 3
- 229910017053 inorganic salt Inorganic materials 0.000 abstract description 3
- 238000009472 formulation Methods 0.000 abstract description 2
- 239000004615 ingredient Substances 0.000 description 10
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 8
- 229910001369 Brass Inorganic materials 0.000 description 6
- 239000010951 brass Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 229910052725 zinc Inorganic materials 0.000 description 6
- 239000011701 zinc Substances 0.000 description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 230000032683 aging Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- -1 ferrous metals Chemical class 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 238000003490 calendering Methods 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 150000001869 cobalt compounds Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- MHKLKWCYGIBEQF-UHFFFAOYSA-N 4-(1,3-benzothiazol-2-ylsulfanyl)morpholine Chemical compound C1COCCN1SC1=NC2=CC=CC=C2S1 MHKLKWCYGIBEQF-UHFFFAOYSA-N 0.000 description 2
- 206010059837 Adhesion Diseases 0.000 description 2
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 2
- 235000011613 Pinus brutia Nutrition 0.000 description 2
- 241000018646 Pinus brutia Species 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000002318 adhesion promoter Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 229910000428 cobalt oxide Inorganic materials 0.000 description 2
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 description 2
- YEXPOXQUZXUXJW-UHFFFAOYSA-N lead(II) oxide Inorganic materials [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 2
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000010734 process oil Substances 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- NZDXSXLYLMHYJA-UHFFFAOYSA-M 4-[(1,3-dimethylimidazol-1-ium-2-yl)diazenyl]-n,n-dimethylaniline;chloride Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1N=NC1=[N+](C)C=CN1C NZDXSXLYLMHYJA-UHFFFAOYSA-M 0.000 description 1
- DOFLWDGGNKBGSL-UHFFFAOYSA-N 6-dodecyl-2,2,4-trimethyl-1h-quinoline Chemical compound N1C(C)(C)C=C(C)C2=CC(CCCCCCCCCCCC)=CC=C21 DOFLWDGGNKBGSL-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920001967 Metal rubber Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920000473 Phlobaphene Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 230000021736 acetylation Effects 0.000 description 1
- 238000006640 acetylation reaction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 239000004840 adhesive resin Substances 0.000 description 1
- 229920006223 adhesive resin Polymers 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- DECIPOUIJURFOJ-UHFFFAOYSA-N ethoxyquin Chemical compound N1C(C)(C)C=C(C)C2=CC(OCC)=CC=C21 DECIPOUIJURFOJ-UHFFFAOYSA-N 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- GRVDJDISBSALJP-UHFFFAOYSA-N methyloxidanyl Chemical group [O]C GRVDJDISBSALJP-UHFFFAOYSA-N 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- SPIFDSWFDKNERT-UHFFFAOYSA-N nickel;hydrate Chemical compound O.[Ni] SPIFDSWFDKNERT-UHFFFAOYSA-N 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 125000004971 nitroalkyl group Chemical group 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 238000010058 rubber compounding Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/10—Reinforcing macromolecular compounds with loose or coherent fibrous material characterised by the additives used in the polymer mixture
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/10—Metal compounds
- C08K3/11—Compounds containing metals of Groups 4 to 10 or of Groups 14 to 16 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2321/00—Characterised by the use of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L93/00—Compositions of natural resins; Compositions of derivatives thereof
- C08L93/04—Rosin
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Engineering & Computer Science (AREA)
- Tires In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Reinforced Plastic Materials (AREA)
- Ropes Or Cables (AREA)
- Laminated Bodies (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
- Tyre Moulding (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Moulding By Coating Moulds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/068,824 US4258770A (en) | 1979-08-22 | 1979-08-22 | Cured rubber skim stock compositions having improved metal adhesion and metal adhesion retention |
| US068,824 | 1979-08-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1144306A true CA1144306A (en) | 1983-04-12 |
Family
ID=22084937
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000358619A Expired CA1144306A (en) | 1979-08-22 | 1980-08-20 | Cured rubber skim stock compositions having improved metal adhesion and metal adhesion retention |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4258770A (Direct) |
| EP (1) | EP0031398B1 (Direct) |
| JP (2) | JPS5632530A (Direct) |
| CA (1) | CA1144306A (Direct) |
| DE (1) | DE3066972D1 (Direct) |
| ES (1) | ES494382A0 (Direct) |
| NO (1) | NO158025C (Direct) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1598388A (en) * | 1978-05-26 | 1981-09-16 | Bekaert Sa Nv | Steel wire reinforcing elements |
| MX158710A (es) * | 1980-09-19 | 1989-03-03 | Goodyear Tire & Rubber | Mejoras en refuerzo de filamento de alambre revestido con una composicion de caucho |
| US4324710A (en) * | 1980-10-02 | 1982-04-13 | The Firestone Tire & Rubber Company | Naturally occurring thermoplastic resins as a substitute for various petroleum-derived materials in rubber stocks |
| DE3043227A1 (de) * | 1980-11-15 | 1982-10-21 | Hoechst Ag, 6000 Frankfurt | Kautschukmischungen und daraus hergestellte vulkanisate |
| US4340515A (en) * | 1981-06-16 | 1982-07-20 | Akzo Nv | Solid rubber adhesion promoter and a method for improving the adhesion of rubber to metal reinforcing elements embedded therein |
| JPS6028858B2 (ja) * | 1981-11-24 | 1985-07-06 | 横浜ゴム株式会社 | ゴム組成物 |
| US4719266A (en) * | 1983-03-21 | 1988-01-12 | The Goodyear Tire & Rubber Company | Vulcanization formulations with cobalt compounds |
| US4435477A (en) * | 1983-07-25 | 1984-03-06 | The Firestone Tire & Rubber Company | Rubber compositions and articles thereof having improved metal adhesion and metal adhesion retention |
| US4478993A (en) * | 1984-01-06 | 1984-10-23 | The Goodyear Tire & Rubber Company | Rubber containing decarboxylated rosins |
| US4551391A (en) * | 1984-01-20 | 1985-11-05 | The Firestone Tire & Rubber Company | Rubber compositions and articles thereof having improved metal adhesion and metal adhesion retention |
| US4594381A (en) * | 1985-06-05 | 1986-06-10 | The Firestone Tire & Rubber Company | Method for improved metal adhesion and metal adhesion retention |
| JPS61285234A (ja) * | 1985-06-13 | 1986-12-16 | Bridgestone Corp | ゴム組成物 |
| IT1246740B (it) * | 1990-12-27 | 1994-11-26 | Pirelli Cavi Spa | Articolo comprendente almeno un filo metallico annegato in un materiale elastomerico vulcanizzato. |
| JPH0519541U (ja) * | 1991-08-29 | 1993-03-12 | 日産自動車株式会社 | 内燃機関の本体構造 |
| IT1273334B (it) * | 1994-02-24 | 1997-07-08 | Pirelli | Filo metallico trattato superficialmente per renderlo adatto all'impiego in elementi compositi in materiale elastomerico e procedimento per la sua realizzazione |
| DE69608387T2 (de) * | 1995-09-29 | 2001-01-04 | Bridgestone Corp., Tokio/Tokyo | Haftende Kautschukzusammensetzung für Stahlkord |
| JP2002067617A (ja) * | 2000-08-29 | 2002-03-08 | Sumitomo Rubber Ind Ltd | 空気入りタイヤ |
| WO2006102518A1 (en) * | 2005-03-24 | 2006-09-28 | Bridgestone Corporation | Compounding silica-reinforced rubber with low volatile organic compound (voc) emission |
| JP5358191B2 (ja) * | 2006-12-22 | 2013-12-04 | バンドー化学株式会社 | 伝動ベルト用ゴム組成物及び伝動ベルト |
| US7915368B2 (en) * | 2007-05-23 | 2011-03-29 | Bridgestone Corporation | Method for making alkoxy-modified silsesquioxanes |
| US8501895B2 (en) * | 2007-05-23 | 2013-08-06 | Bridgestone Corporation | Method for making alkoxy-modified silsesquioxanes and amino alkoxy-modified silsesquioxanes |
| US8962746B2 (en) * | 2007-12-27 | 2015-02-24 | Bridgestone Corporation | Methods of making blocked-mercapto alkoxy-modified silsesquioxane compounds |
| US8513371B2 (en) * | 2007-12-31 | 2013-08-20 | Bridgestone Corporation | Amino alkoxy-modified silsesquioxanes and method of preparation |
| US8794282B2 (en) | 2007-12-31 | 2014-08-05 | Bridgestone Corporation | Amino alkoxy-modified silsesquioxane adhesives for improved metal adhesion and metal adhesion retention to cured rubber |
| US8642691B2 (en) | 2009-12-28 | 2014-02-04 | Bridgestone Corporation | Amino alkoxy-modified silsesquioxane adhesives for improved metal adhesion and metal adhesion retention to cured rubber |
| WO2015116943A2 (en) | 2014-01-31 | 2015-08-06 | Monolith Materials, Inc. | Plasma torch design |
| US11401440B2 (en) | 2014-12-31 | 2022-08-02 | Bridgestone Corporation | Amino alkoxy-modified silsesquioxane adhesives for adhering steel alloy to rubber |
| MX2017009981A (es) | 2015-02-03 | 2018-01-25 | Monolith Mat Inc | Sistema generador de negro de humo. |
| CA3032246C (en) | 2015-07-29 | 2023-12-12 | Monolith Materials, Inc. | Dc plasma torch electrical power design method and apparatus |
| EP3331821A4 (en) | 2015-08-07 | 2018-12-26 | Monolith Materials, Inc. | Method of making carbon black |
| CA3033947C (en) | 2015-09-09 | 2024-05-28 | Monolith Materials, Inc. | Circular few layer graphene |
| US10472502B2 (en) | 2015-12-31 | 2019-11-12 | Kraton Polymers U.S. Llc | Resin-extended rubber composition and tire rubber compositions prepared therewith |
| US12377684B2 (en) * | 2019-11-13 | 2025-08-05 | Bridgestone Americas Tire Operations, Llc | Non-pneumatic tire having multilayer spokes |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2240805A (en) * | 1936-10-20 | 1941-05-06 | Goodrich Co B F | Composite article and method of making same |
| US2491477A (en) * | 1943-12-07 | 1949-12-20 | Minnesota Mining & Mfg | Adhesive cement having a butadiene-acrylonitrile copolymer base |
| US2643273A (en) * | 1950-03-18 | 1953-06-23 | Nat Standard Co | Method of securing rubber adhesion to metal and composition therefor |
| US2912355A (en) * | 1955-06-20 | 1959-11-10 | Goodrich Co B F | Composition, article and method |
| US3897583A (en) * | 1973-11-08 | 1975-07-29 | Uniroyal Sa | Adhesion of metal to rubber |
| US3936536A (en) * | 1974-02-13 | 1976-02-03 | The Firestone Tire & Rubber Company | Method of making rubber-coated wire |
| JPS5110885A (en) * | 1974-07-04 | 1976-01-28 | Bridgestone Tire Co Ltd | Gomusoseibutsuto kinzokuzairyotokaranarufukugotai oyobi sonoseizohoho |
| US4068041A (en) * | 1975-09-18 | 1978-01-10 | The B. F. Goodrich Company | Method for rubberizing steel cords |
| US4076668A (en) * | 1976-02-27 | 1978-02-28 | The Yokohama Rubber Co., Ltd. | Rubber composition |
| JPS52127952A (en) * | 1976-04-20 | 1977-10-27 | Nippon Zeon Co Ltd | Rubber compositions for use in bonding to zinc |
-
1979
- 1979-08-22 US US06/068,824 patent/US4258770A/en not_active Expired - Lifetime
-
1980
- 1980-07-29 DE DE8080104473T patent/DE3066972D1/de not_active Expired
- 1980-07-29 EP EP80104473A patent/EP0031398B1/en not_active Expired
- 1980-08-20 CA CA000358619A patent/CA1144306A/en not_active Expired
- 1980-08-20 ES ES494382A patent/ES494382A0/es active Granted
- 1980-08-20 NO NO802476A patent/NO158025C/no unknown
- 1980-08-20 JP JP11355980A patent/JPS5632530A/ja active Granted
-
1985
- 1985-03-13 JP JP60048449A patent/JPS60229804A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| ES8105755A1 (es) | 1981-07-01 |
| EP0031398B1 (en) | 1984-03-14 |
| JPS6360061B2 (Direct) | 1988-11-22 |
| DE3066972D1 (en) | 1984-04-19 |
| NO802476L (no) | 1981-02-23 |
| JPS60229804A (ja) | 1985-11-15 |
| EP0031398A3 (en) | 1981-07-15 |
| US4258770A (en) | 1981-03-31 |
| EP0031398A2 (en) | 1981-07-08 |
| NO158025B (no) | 1988-03-21 |
| JPH0219853B2 (Direct) | 1990-05-07 |
| JPS5632530A (en) | 1981-04-02 |
| NO158025C (no) | 1988-06-29 |
| ES494382A0 (es) | 1981-07-01 |
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