CA1132127A - Components and catalysts for the polymerization of olefins - Google Patents
Components and catalysts for the polymerization of olefinsInfo
- Publication number
- CA1132127A CA1132127A CA338,139A CA338139A CA1132127A CA 1132127 A CA1132127 A CA 1132127A CA 338139 A CA338139 A CA 338139A CA 1132127 A CA1132127 A CA 1132127A
- Authority
- CA
- Canada
- Prior art keywords
- polymerization
- alkyl
- olefins
- mmoles
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 39
- 239000003054 catalyst Substances 0.000 title claims abstract description 29
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 4
- 239000000203 mixture Substances 0.000 claims abstract description 18
- 239000004711 α-olefin Substances 0.000 claims abstract description 15
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000005977 Ethylene Substances 0.000 claims abstract description 14
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 13
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 8
- 150000005840 aryl radicals Chemical group 0.000 claims abstract description 5
- -1 aromatic alcohols Chemical class 0.000 claims description 47
- 150000001875 compounds Chemical class 0.000 claims description 43
- 238000000034 method Methods 0.000 claims description 17
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 229910010066 TiC14 Inorganic materials 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 9
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910010061 TiC13 Inorganic materials 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 125000004429 atom Chemical group 0.000 claims description 3
- 150000004820 halides Chemical class 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 229910008046 SnC14 Inorganic materials 0.000 claims description 2
- 150000001350 alkyl halides Chemical class 0.000 claims description 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 150000007522 mineralic acids Chemical class 0.000 claims description 2
- 150000002989 phenols Chemical class 0.000 claims description 2
- 150000004819 silanols Chemical class 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 1
- 150000002894 organic compounds Chemical class 0.000 claims 1
- 229920000098 polyolefin Polymers 0.000 abstract description 2
- 239000007787 solid Substances 0.000 description 66
- 230000003197 catalytic effect Effects 0.000 description 58
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 47
- 235000019441 ethanol Nutrition 0.000 description 30
- 239000004698 Polyethylene Substances 0.000 description 27
- 229920000573 polyethylene Polymers 0.000 description 27
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 21
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 21
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 21
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 16
- 239000000725 suspension Substances 0.000 description 12
- 239000000306 component Substances 0.000 description 11
- 229910001629 magnesium chloride Inorganic materials 0.000 description 10
- 238000010992 reflux Methods 0.000 description 10
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 8
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 8
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 8
- 239000000460 chlorine Substances 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 229910003910 SiCl4 Inorganic materials 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 6
- 229910010062 TiCl3 Inorganic materials 0.000 description 5
- 239000007795 chemical reaction product Substances 0.000 description 5
- 230000008034 disappearance Effects 0.000 description 5
- 238000004090 dissolution Methods 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 2
- OLLFKUHHDPMQFR-UHFFFAOYSA-N dihydroxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](O)(O)C1=CC=CC=C1 OLLFKUHHDPMQFR-UHFFFAOYSA-N 0.000 description 2
- 150000002367 halogens Chemical group 0.000 description 2
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 description 2
- QSSJZLPUHJDYKF-UHFFFAOYSA-N methyl 4-methylbenzoate Chemical compound COC(=O)C1=CC=C(C)C=C1 QSSJZLPUHJDYKF-UHFFFAOYSA-N 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 2
- LPNBBFKOUUSUDB-UHFFFAOYSA-N p-toluic acid Chemical compound CC1=CC=C(C(O)=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- BIIBYWQGRFWQKM-JVVROLKMSA-N (2S)-N-[4-(cyclopropylamino)-3,4-dioxo-1-[(3S)-2-oxopyrrolidin-3-yl]butan-2-yl]-2-[[(E)-3-(2,4-dichlorophenyl)prop-2-enoyl]amino]-4,4-dimethylpentanamide Chemical compound CC(C)(C)C[C@@H](C(NC(C[C@H](CCN1)C1=O)C(C(NC1CC1)=O)=O)=O)NC(/C=C/C(C=CC(Cl)=C1)=C1Cl)=O BIIBYWQGRFWQKM-JVVROLKMSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- CNPVJWYWYZMPDS-UHFFFAOYSA-N 2-methyldecane Chemical compound CCCCCCCCC(C)C CNPVJWYWYZMPDS-UHFFFAOYSA-N 0.000 description 1
- XPYQFIISZQCINN-QVXDJYSKSA-N 4-amino-1-[(2r,3e,4s,5r)-3-(fluoromethylidene)-4-hydroxy-5-(hydroxymethyl)oxolan-2-yl]pyrimidin-2-one;hydrate Chemical compound O.O=C1N=C(N)C=CN1[C@H]1C(=C/F)/[C@H](O)[C@@H](CO)O1 XPYQFIISZQCINN-QVXDJYSKSA-N 0.000 description 1
- 101100243951 Caenorhabditis elegans pie-1 gene Proteins 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 229910003074 TiCl4 Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 150000007860 aryl ester derivatives Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 230000002140 halogenating effect Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 1
- OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 description 1
- 229910001623 magnesium bromide Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 238000012721 stereospecific polymerization Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- AAPLIUHOKVUFCC-UHFFFAOYSA-N trimethylsilanol Chemical compound C[Si](C)(C)O AAPLIUHOKVUFCC-UHFFFAOYSA-N 0.000 description 1
- NLSXASIDNWDYMI-UHFFFAOYSA-N triphenylsilanol Chemical compound C=1C=CC=CC=1[Si](C=1C=CC=CC=1)(O)C1=CC=CC=C1 NLSXASIDNWDYMI-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
- C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT29140/78A IT1099805B (it) | 1978-10-26 | 1978-10-26 | Componenti e catalizzatori per la polimerizzazione delle olefine |
| IT29140A/78 | 1978-10-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1132127A true CA1132127A (en) | 1982-09-21 |
Family
ID=11226391
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA338,139A Expired CA1132127A (en) | 1978-10-26 | 1979-10-22 | Components and catalysts for the polymerization of olefins |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4305840A (en, 2012) |
| EP (1) | EP0010746B1 (en, 2012) |
| JP (1) | JPS5560502A (en, 2012) |
| AU (1) | AU530750B2 (en, 2012) |
| CA (1) | CA1132127A (en, 2012) |
| DE (1) | DE2966834D1 (en, 2012) |
| IT (1) | IT1099805B (en, 2012) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1144698A (en) * | 1980-01-09 | 1983-04-12 | Albert S. Matlack | 1-olefin polymerization catalyst |
| DE3015702A1 (de) * | 1980-04-24 | 1981-10-29 | Basf Ag, 6700 Ludwigshafen | Verfahren zum herstellen von homo-und copolymerisaten von (alpha) -monoolefinen mittels eines ziegler-katalysatorsystems |
| JPS5984905A (ja) * | 1982-08-27 | 1984-05-16 | フイリツプス・ペトロリユ−ム・コンパニ− | オレフイン重合用触媒およびその製法と用途 |
| JPS5975910A (ja) * | 1982-10-25 | 1984-04-28 | Mitsui Petrochem Ind Ltd | エチレン共重合体 |
| JPH062774B2 (ja) * | 1985-03-12 | 1994-01-12 | 三井東圧化学株式会社 | オレフインの重合方法 |
| DK0481749T3 (da) * | 1990-10-18 | 1999-11-29 | Union Carbide Chem Plastic | Olefinpolymerisationskatalysator |
| BE1008702A3 (fr) | 1994-09-22 | 1996-07-02 | Solvay | Procede de polymerisation d'olefines. |
| US6001939A (en) * | 1994-09-22 | 1999-12-14 | Solvay Polyolefins Europe-Belgium | Process for the polymerization of olefins |
| US6071846A (en) * | 1995-04-24 | 2000-06-06 | Tokuyama Corporation | Olefin polymerization catalyst and a polyolefin production method |
| US5817591A (en) * | 1995-06-07 | 1998-10-06 | Fina Technology, Inc. | Polyolefin catalyst from metal alkoxides or dialkyls, production and use |
| IT1277684B1 (it) * | 1995-12-21 | 1997-11-11 | Montell North America Inc | Componenti e catalizzatori per la polimerizzazione delle olefine |
| JP3943230B2 (ja) * | 1998-02-26 | 2007-07-11 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分及び触媒 |
| IN2010DN07192A (en, 2012) * | 2008-03-14 | 2015-07-24 | Saudi Basic Ind Corp | |
| EP2268681A1 (en) * | 2008-04-17 | 2011-01-05 | Saudi Basic Industries Corporation | Process for the production of ultra high molecular weight polyethylene |
| JP2011528384A (ja) * | 2008-07-18 | 2011-11-17 | サウディ ベーシック インダストリーズ コーポレイション | ポリエチレンの製造プロセス |
| EP2284199A1 (en) | 2009-08-14 | 2011-02-16 | Saudi Basic Industries Corporation | A catalyst system and a process for the production of polyethylene |
| EP2709758A2 (en) * | 2011-05-17 | 2014-03-26 | Reliance Industries Limited | Controlled morphology high activity polyolefin catalyst system |
| EP3519462A1 (en) * | 2016-09-30 | 2019-08-07 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2043508A1 (de) * | 1970-09-02 | 1972-03-16 | Farbwerke Hoechst AG, vorm. Meister Lucius & Brüning, 6000 Frankfurt | Verfahren zur Herstellung von Polyolefinen |
| US3859231A (en) * | 1972-10-13 | 1975-01-07 | Gulf Research Development Co | Simplified process for manufacture of catalyst component |
| US4071672A (en) * | 1972-11-10 | 1978-01-31 | Mitsui Petrochemical Industries Ltd. | Process for polymerizing or copolymerizing olefins |
| US4006101A (en) * | 1973-02-09 | 1977-02-01 | Nippon Oil Company Ltd. | Polymerization of olefins and catalysts therefor |
| JPS5155388A (en) * | 1974-11-09 | 1976-05-15 | Mitsubishi Petrochemical Co | Echirenjugotaino seizoho |
| JPS5812284B2 (ja) * | 1974-11-27 | 1983-03-07 | 三菱油化株式会社 | エチレンジユウゴウタイノ セイゾウホウ |
| JPS5812285B2 (ja) * | 1975-01-17 | 1983-03-07 | 三菱油化株式会社 | エチレンジユウゴウタイノセイゾウホウ |
| JPS565404B2 (en, 2012) * | 1975-02-14 | 1981-02-04 | ||
| IT1042711B (it) * | 1975-09-19 | 1980-01-30 | Montedison Spa | Compnenti di catalizzatori per la polimerizzazione di olefine |
| IT1062072B (it) * | 1976-06-03 | 1983-06-25 | Montedison Spa | Catalizzatori per la polimerizzazione di etilene |
| US4120820A (en) * | 1976-12-01 | 1978-10-17 | The Dow Chemical Company | High efficiency catalyst for polymerizing olefins |
| JPS53108184A (en) * | 1977-03-04 | 1978-09-20 | Mitsubishi Chem Ind Ltd | Preparation of polyolefin |
-
1978
- 1978-10-26 IT IT29140/78A patent/IT1099805B/it active
-
1979
- 1979-10-22 CA CA338,139A patent/CA1132127A/en not_active Expired
- 1979-10-25 AU AU52190/79A patent/AU530750B2/en not_active Ceased
- 1979-10-25 US US06/088,162 patent/US4305840A/en not_active Expired - Lifetime
- 1979-10-26 EP EP79104158A patent/EP0010746B1/en not_active Expired
- 1979-10-26 DE DE7979104158T patent/DE2966834D1/de not_active Expired
- 1979-10-26 JP JP13863879A patent/JPS5560502A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5560502A (en) | 1980-05-07 |
| IT7829140A0 (it) | 1978-10-26 |
| JPS64402B2 (en, 2012) | 1989-01-06 |
| US4305840A (en) | 1981-12-15 |
| EP0010746A1 (en) | 1980-05-14 |
| AU530750B2 (en) | 1983-07-28 |
| DE2966834D1 (en) | 1984-04-26 |
| EP0010746B1 (en) | 1984-03-21 |
| IT1099805B (it) | 1985-09-28 |
| AU5219079A (en) | 1980-05-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1132127A (en) | Components and catalysts for the polymerization of olefins | |
| EP0398698B1 (en) | Process for producing olefin polymer | |
| US4220554A (en) | Components of catalysts for polymerizing alpha-olefins and the catalysts formed from the components | |
| US6515085B1 (en) | Components and catalysts for the polymerization of olefins | |
| US4393182A (en) | Olefin polymerization process with novel supported titanium catalyst compositions | |
| CA1141092A (en) | Olefin polymerization catalyst compositions and a process for the polymerization of olefins employing such compositions | |
| DE2822809C2 (en, 2012) | ||
| CA1162526A (en) | Composition of matter and method of preparing same, catalyst, method of producing the catalyst and polymerization process employing the catalyst | |
| NO300273B1 (no) | Katalysatorbestanddeler og katalysatorer, og anvendelse av disse ved polymerisasjon av olefiner | |
| DE3751622T2 (de) | Olefinpolymerisationskatalysator. | |
| KR840001831B1 (ko) | 알파-올레핀의 중합용 할로겐화 티타늄 함유촉매제 | |
| US4061857A (en) | Process for preparing polyolefins | |
| EP0250225B1 (en) | Catalyst component for polymerization of olefin | |
| US6777508B1 (en) | Catalysts for the polymerization of olefins | |
| CA1278290C (en) | Process for producing catalyst ingredient for use in olefin polymerization | |
| EP0040711A1 (en) | Titanium halide catalyst for polymerization | |
| US4390454A (en) | Catalyst components for polymerizing olefins | |
| KR910005663B1 (ko) | 올레핀 중합용 고체 촉매성분 및 그의 제조방법 | |
| US4209602A (en) | Process for the production of polyolefins | |
| EP0262987A2 (en) | Catalysts for the preparation of elastomeric, olefin copolymers, and copolymers obtained using them | |
| US4209601A (en) | Process for the production of polyolefins | |
| EP0599355A1 (en) | Catalysts for polymerization of olefins | |
| JPH09328512A (ja) | 特定のオルガノシリコン化合物を含有するチーグラー／ナッタ触媒組成物 | |
| CA2095507C (en) | Catalyst for the polymerization of olefins | |
| EP0290150B1 (en) | Polymerisation catalyst |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |