CA1131221A - Stabilized amide-imide graft of ethylene copolymeric additives for lubricants - Google Patents

Stabilized amide-imide graft of ethylene copolymeric additives for lubricants

Info

Publication number
CA1131221A
CA1131221A CA343,355A CA343355A CA1131221A CA 1131221 A CA1131221 A CA 1131221A CA 343355 A CA343355 A CA 343355A CA 1131221 A CA1131221 A CA 1131221A
Authority
CA
Canada
Prior art keywords
acid
oil
grafted
anhydride
amine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA343,355A
Other languages
English (en)
French (fr)
Inventor
Salvatore J. Girgenti
John B. Gardiner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Application granted granted Critical
Publication of CA1131221A publication Critical patent/CA1131221A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
    • C10M143/02—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/236—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof
    • C10L1/2364—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof homo- or copolymers derived from unsaturated compounds containing amide and/or imide groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/027—Neutral salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/24—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions having hydrocarbon substituents containing thirty or more carbon atoms, e.g. nitrogen derivatives of substituted succinic acid
    • C10M2215/26—Amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/024—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/028—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrogen-containing hetero ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/046—Polyamines, i.e. macromoleculars obtained by condensation of more than eleven amine monomers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/046—Overbased sulfonic acid salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • C10N2070/02—Concentrating of additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Lubricants (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
CA343,355A 1979-02-14 1980-01-09 Stabilized amide-imide graft of ethylene copolymeric additives for lubricants Expired CA1131221A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/012,068 US4219432A (en) 1979-02-14 1979-02-14 Stabilized amide-imide graft of ethylene copolymeric additives for lubricants
US12,068 1979-02-14

Publications (1)

Publication Number Publication Date
CA1131221A true CA1131221A (en) 1982-09-07

Family

ID=21753224

Family Applications (1)

Application Number Title Priority Date Filing Date
CA343,355A Expired CA1131221A (en) 1979-02-14 1980-01-09 Stabilized amide-imide graft of ethylene copolymeric additives for lubricants

Country Status (5)

Country Link
US (1) US4219432A (enExample)
CA (1) CA1131221A (enExample)
DE (1) DE3004937A1 (enExample)
FR (1) FR2449122A1 (enExample)
GB (1) GB2044269B (enExample)

Families Citing this family (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4338205A (en) * 1980-08-25 1982-07-06 Exxon Research & Engineering Co. Lubricating oil with improved diesel dispersancy
US4505834A (en) * 1980-10-27 1985-03-19 Edwin Cooper, Inc. Lubricating oil compositions containing graft copolymer as viscosity index improver-dispersant
US4517104A (en) * 1981-05-06 1985-05-14 Exxon Research & Engineering Co. Ethylene copolymer viscosity index improver-dispersant additive useful in oil compositions
US4440659A (en) * 1982-02-19 1984-04-03 Ethyl Corporation Lubricating oil ashless dispersant and lubricating oils containing same
US4486573A (en) * 1982-08-09 1984-12-04 The Lubrizol Corporation Carboxylic acylating agents substituted with olefin polymers of high molecular weight mono-olefins, derivatives thereof, and fuels and lubricants containing same
US4471091A (en) * 1982-08-09 1984-09-11 The Lubrizol Corporation Combinations of carboxylic acylating agents substituted with olefin polymers of high and low molecular weight mono-olefins, derivatives thereof, and fuels and lubricants containing same
US4596663A (en) * 1982-08-09 1986-06-24 The Lubrizol Corporation Carboxylic acylating agents substituted with olefin polymers of high molecular weight mono-olefins, derivatives thereof, and fuels and lubricants containing same
US4489194A (en) * 1982-08-09 1984-12-18 The Lubrizol Corporation Carboxylic acylating agents substituted with olefin polymers of high/low molecular weight mono-olefins, derivatives thereof, and fuels and lubricants containing same
IT1155437B (it) * 1982-12-22 1987-01-28 Montedison Spa Fibre tessili di polimeri olefinici funzionalizzati e procedimento per la loro preparazione
US4810754A (en) * 1983-12-02 1989-03-07 Exxon Research & Engineering Company High temperature peroxide induced telomerization processes for grafting vinyl nitrogen containing monomers onto olefin polymers
US4640788A (en) * 1985-04-29 1987-02-03 Texaco Inc. Hydrocarbon compositions containing polyolefin graft polymers
US4735736A (en) * 1985-07-08 1988-04-05 Exxon Chemical Patents Inc. Viscosity index improver-dispersant additive
US4732942A (en) * 1986-09-02 1988-03-22 Texaco Inc. Hydrocarbon compositions containing polyolefin graft polymers
US4866135A (en) * 1986-10-07 1989-09-12 Exxon Chemical Patents Inc. Heterocyclic amine terminated, lactone modified, aminated viscosity modifiers of improved dispersancy
US4839422A (en) * 1987-12-23 1989-06-13 Exxon Chemical Patents Inc. Ternary adhesive compositions
US4933098A (en) * 1988-04-06 1990-06-12 Exxon Chemical Patents Inc. Lactone modified viscosity modifiers useful in oleaginous compositions
CA1339787C (en) * 1988-07-18 1998-03-31 David Yen-Lung Chung Multifunctional viscosity index improver
US5035821A (en) * 1988-07-18 1991-07-30 Exxon Chemical Patents Inc. End-capped multifunctional viscosity index improver
US5759967A (en) * 1988-08-01 1998-06-02 Exxon Chemical Patents Inc Ethylene α-olefin/diene interpolymer-substituted carboxylic acid dispersant additives
US5266223A (en) * 1988-08-01 1993-11-30 Exxon Chemical Patents Inc. Ethylene alpha-olefin polymer substituted mono-and dicarboxylic acid dispersant additives
US5225091A (en) * 1988-08-01 1993-07-06 Exxon Chemical Patents Inc. Ethylene alpha-olefin polymer substituted thiocarboxylic acid lubricant dispersant additives
US5350532A (en) * 1988-08-01 1994-09-27 Exxon Chemical Patents Inc. Borated ethylene alpha-olefin polymer substituted mono- and dicarboxylic acid dispersant additives
CA2034759C (en) * 1988-08-01 2003-06-03 Won R. Song Novel ethylene alpha-olefin polymer substituted mono- and dicarboxylic acid dispersant additives
US5229022A (en) * 1988-08-01 1993-07-20 Exxon Chemical Patents Inc. Ethylene alpha-olefin polymer substituted mono- and dicarboxylic acid dispersant additives (PT-920)
US5262075A (en) * 1989-05-30 1993-11-16 Exxon Chemical Patents Inc. Multifunctional viscosity index improver exhibitng improved low temperature viscometric properties
US5252238A (en) * 1989-05-30 1993-10-12 Exxon Chemical Patents Inc. Multifunctional viscosity index improver derived from amido-amine exhibiting improved low temperature viscometric properties
US5053151A (en) * 1989-05-30 1991-10-01 Exxon Chemical Patents Inc. Multifunctional viscosity index improver derived from amido-amine exhibiting improved low temperature viscometric properties
US5230834A (en) * 1989-05-30 1993-07-27 Exxon Chemical Patents Inc. Viscosity stable multifunctional viscosity index modifier additives derived from amido amines
US5167848A (en) * 1989-05-30 1992-12-01 Exxon Chemical Patents Inc. Grafted viscosity index improver
US5210146A (en) * 1989-05-30 1993-05-11 Exxon Chemical Patents Inc. Multifunctional viscosity index improver derived from polyamine containing one primary amino group and at least one secondary amino group exhibiting improved low temperature viscometric properties
EP0422857A3 (en) * 1989-10-12 1991-12-11 Exxon Chemical Patents Inc. Multifunctional viscosity index improver
US5244590A (en) * 1989-10-12 1993-09-14 Exxon Chemical Patents Inc. Viscosity index improver
US5068047A (en) * 1989-10-12 1991-11-26 Exxon Chemical Patents, Inc. Visosity index improver
US5118433A (en) * 1989-10-12 1992-06-02 Exxon Chemical Patents Inc. Multifunctional viscosity index improver derived from amido-amine and degraded ethylene copolymer exhibiting improved low temperature viscometric properties
CA2025992A1 (en) * 1989-10-12 1991-04-13 David Y. Chung Multifunctional viscosity index improver derived from polyamine containing one primary amine group and at least one tertiary amine group and degraded ethylene copolymer
US5275747A (en) * 1990-02-01 1994-01-04 Exxon Chemical Patents Inc. Derivatized ethylene alpha-olefin polymer useful as multifunctional viscosity index improver additive for oleaginous composition
US5211865A (en) * 1990-03-08 1993-05-18 Exxon Chemical Patents Inc. Multifunctional viscosity index improver-dispersant antioxidant
US5273671A (en) * 1990-03-08 1993-12-28 Exxon Chemical Patents Inc. Multifunctional viscosity index improver-dispersant antioxidant
US5167845A (en) * 1990-12-21 1992-12-01 Texaco Inc. Polymeric additives to enhance anti-wear, anti-oxidancy, and dispersancy in lubricants
US5160446A (en) * 1991-05-22 1992-11-03 Texaco Inc. Dispersant, vi improver and antioxidant additive, and lubricating oil composition containing same
IT1258249B (it) * 1992-11-06 1996-02-22 Addittivo polimerico per olii lubrificanti
CA2110463C (en) * 1992-12-17 2005-02-08 Jacob Emert Gel-free ethylene interpolymer dispersant additives useful in oleaginous compositions
IL107810A0 (en) * 1992-12-17 1994-02-27 Exxon Chemical Patents Inc Functionalized polymers and processes for the preparation thereof
CA2110649C (en) * 1992-12-17 2004-10-26 Jacob Emert Gel-free alpha-olefin dispersant additives useful in oleaginous compositions
US5643859A (en) 1992-12-17 1997-07-01 Exxon Chemical Patents Inc. Derivatives of polyamines with one primary amine and secondary of tertiary amines
US5439607A (en) * 1993-12-30 1995-08-08 Exxon Chemical Patents Inc. Multifunctional viscosity index improver-dispersant antioxidant
CA2190182C (en) * 1994-06-17 2006-08-22 Joseph V. Cusumano Lubricating oil dispersants derived from heavy polyamine
GB2307685B (en) * 1995-12-01 1999-07-07 Ethyl Petroleum Additives Ltd Seal compatible diesel dispersants
SG81254A1 (en) * 1998-12-12 2001-06-19 Ethyl Corp Highly grafted, multi-functional olefin copolymer vi modifiers
US7137289B2 (en) 2004-02-13 2006-11-21 Chevron Oronite Company, Llc High throughput screening methods for lubricating oil compositions
JP5221937B2 (ja) * 2007-11-16 2013-06-26 株式会社オートネットワーク技術研究所 酸無水物導入高分子および高分子組成物ならびに被覆電線およびワイヤーハーネス
US8927469B2 (en) 2011-08-11 2015-01-06 Afton Chemical Corporation Lubricant compositions containing a functionalized dispersant
US9624451B2 (en) 2013-03-15 2017-04-18 Castrol Limited Multiple function dispersant viscosity index improver

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Publication number Priority date Publication date Assignee Title
NL296869A (enExample) * 1962-09-04
US3687905A (en) * 1970-03-16 1972-08-29 Lubrizol Corp Reaction product of carboxylic acid with degraded ethylene-propylene interpolymer
FR2294191A1 (fr) * 1974-12-12 1976-07-09 Aquitaine Petrole Copolymeres d'olefines ou d'olefines et de dienes non conjugues avec des derives non satures d'imides cycliques
AU498559B2 (en) * 1975-06-25 1979-03-15 Exxon Research And Engineering Company Lubricating oil concentrate
US4098710A (en) * 1976-04-26 1978-07-04 Exxon Research & Engineering Co. Oil-soluble addition products of an ethylene-propylene copolymer and anionically polymerizable monomer having utility as multifunctional V.I. improver for lubricating oils
DE2702604C2 (de) * 1977-01-22 1984-08-30 Basf Ag, 6700 Ludwigshafen Polyisobutene
US4161452A (en) * 1977-01-28 1979-07-17 Rohm And Haas Company Polyolefinic copolymer additives for lubricants and fuels
US4144181A (en) * 1977-04-29 1979-03-13 Exxon Research & Engineering Co. Polymeric additives for fuels and lubricants
US4137185A (en) * 1977-07-28 1979-01-30 Exxon Research & Engineering Co. Stabilized imide graft of ethylene copolymeric additives for lubricants
US4152276A (en) * 1977-11-14 1979-05-01 Ethyl Corporation Process of making olefin copolymer lubricant additives by permanganate oxidation of olefin terpolymers
US4160739A (en) * 1977-12-05 1979-07-10 Rohm And Haas Company Polyolefinic copolymer additives for lubricants and fuels

Also Published As

Publication number Publication date
FR2449122B1 (enExample) 1984-12-28
DE3004937C2 (enExample) 1993-09-09
GB2044269A (en) 1980-10-15
GB2044269B (en) 1983-10-19
FR2449122A1 (fr) 1980-09-12
US4219432A (en) 1980-08-26
DE3004937A1 (de) 1980-08-28

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