CA1129878A - Copper (ii) alkanolamine complexes useful as algacides and herbicides - Google Patents
Copper (ii) alkanolamine complexes useful as algacides and herbicidesInfo
- Publication number
- CA1129878A CA1129878A CA209,196A CA209196A CA1129878A CA 1129878 A CA1129878 A CA 1129878A CA 209196 A CA209196 A CA 209196A CA 1129878 A CA1129878 A CA 1129878A
- Authority
- CA
- Canada
- Prior art keywords
- copper
- complex
- water
- trialkanolamine
- concentrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 title abstract description 17
- 239000004009 herbicide Substances 0.000 title description 3
- JJLJMEJHUUYSSY-UHFFFAOYSA-L copper(II) hydroxide Inorganic materials [OH-].[OH-].[Cu+2] JJLJMEJHUUYSSY-UHFFFAOYSA-L 0.000 claims abstract description 52
- 241000195493 Cryptophyta Species 0.000 claims abstract description 11
- 239000010949 copper Substances 0.000 claims description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 43
- 229910052802 copper Inorganic materials 0.000 claims description 40
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 37
- 238000000034 method Methods 0.000 claims description 18
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical group OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 14
- 239000012141 concentrate Substances 0.000 claims description 13
- 229960004418 trolamine Drugs 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 10
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 7
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- AEJIMXVJZFYIHN-UHFFFAOYSA-N copper;dihydrate Chemical compound O.O.[Cu] AEJIMXVJZFYIHN-UHFFFAOYSA-N 0.000 abstract description 17
- 239000007864 aqueous solution Substances 0.000 abstract description 6
- 241000196324 Embryophyta Species 0.000 abstract description 5
- 150000001875 compounds Chemical class 0.000 abstract description 5
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 36
- 238000001914 filtration Methods 0.000 description 12
- 235000013350 formula milk Nutrition 0.000 description 7
- 239000011541 reaction mixture Substances 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- 230000000536 complexating effect Effects 0.000 description 6
- -1 copper (II) compound Chemical class 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 230000005484 gravity Effects 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000003643 water by type Substances 0.000 description 4
- 241000498251 Hydrilla Species 0.000 description 3
- 230000000875 corresponding effect Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 241000736839 Chara Species 0.000 description 2
- 239000005750 Copper hydroxide Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003619 algicide Substances 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 150000001879 copper Chemical class 0.000 description 2
- 229910001956 copper hydroxide Inorganic materials 0.000 description 2
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
- PTVDYARBVCBHSL-UHFFFAOYSA-N copper;hydrate Chemical compound O.[Cu] PTVDYARBVCBHSL-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- LITQZINTSYBKIU-UHFFFAOYSA-F tetracopper;hexahydroxide;sulfate Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Cu+2].[Cu+2].[Cu+2].[Cu+2].[O-]S([O-])(=O)=O LITQZINTSYBKIU-UHFFFAOYSA-F 0.000 description 2
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 description 1
- 240000000073 Achillea millefolium Species 0.000 description 1
- 235000007754 Achillea millefolium Nutrition 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 241000192542 Anabaena Species 0.000 description 1
- MVVPIAAVGAWJNQ-DOFZRALJSA-N Arachidonoyl dopamine Chemical compound CCCCC\C=C/C\C=C/C\C=C/C\C=C/CCCC(=O)NCCC1=CC=C(O)C(O)=C1 MVVPIAAVGAWJNQ-DOFZRALJSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 241000544618 Chara vulgaris Species 0.000 description 1
- 241000518994 Conta Species 0.000 description 1
- 239000005752 Copper oxychloride Substances 0.000 description 1
- 229910021592 Copper(II) chloride Inorganic materials 0.000 description 1
- 241000196173 Hydrodictyon Species 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 241000721654 Lepomis macrochirus Species 0.000 description 1
- 241001134698 Lyngbya Species 0.000 description 1
- 241000192701 Microcystis Species 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- 241000546131 Oedogonium Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241000199919 Phaeophyceae Species 0.000 description 1
- 241000342009 Pithophora Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 241000183024 Populus tremula Species 0.000 description 1
- 241000206572 Rhodophyta Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 241000196294 Spirogyra Species 0.000 description 1
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 1
- XAMVGJCPVGBYGO-UHFFFAOYSA-L [OH-].[OH-].[Cu+2].OCCN(CCO)CCO Chemical compound [OH-].[OH-].[Cu+2].OCCN(CCO)CCO XAMVGJCPVGBYGO-UHFFFAOYSA-L 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 230000002353 algacidal effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000004103 aminoalkyl group Chemical group 0.000 description 1
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- HKMOPYJWSFRURD-UHFFFAOYSA-N chloro hypochlorite;copper Chemical compound [Cu].ClOCl HKMOPYJWSFRURD-UHFFFAOYSA-N 0.000 description 1
- 230000009918 complex formation Effects 0.000 description 1
- 230000000332 continued effect Effects 0.000 description 1
- 229940116318 copper carbonate Drugs 0.000 description 1
- 229910000009 copper(II) carbonate Inorganic materials 0.000 description 1
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 1
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- SKQUUKNCBWILCD-UHFFFAOYSA-J dicopper;chloride;trihydroxide Chemical compound [OH-].[OH-].[OH-].[Cl-].[Cu+2].[Cu+2] SKQUUKNCBWILCD-UHFFFAOYSA-J 0.000 description 1
- 229940043237 diethanolamine Drugs 0.000 description 1
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 1
- 229940043276 diisopropanolamine Drugs 0.000 description 1
- MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 description 1
- 239000012972 dimethylethanolamine Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- UXIJQZSBOOKEKZ-UHFFFAOYSA-N oxocopper hydrate Chemical compound O.[Cu]=O UXIJQZSBOOKEKZ-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000036647 reaction Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/005—Compounds containing elements of Groups 1 or 11 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
- C02F1/505—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment by oligodynamic treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US39713673A | 1973-09-13 | 1973-09-13 | |
| US397,136 | 1973-09-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1129878A true CA1129878A (en) | 1982-08-17 |
Family
ID=23569974
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA209,196A Expired CA1129878A (en) | 1973-09-13 | 1974-09-13 | Copper (ii) alkanolamine complexes useful as algacides and herbicides |
Country Status (17)
| Country | Link |
|---|---|
| JP (1) | JPS5076228A (da) |
| AT (1) | AT353050B (da) |
| BE (1) | BE819908A (da) |
| BR (1) | BR7407620D0 (da) |
| CA (1) | CA1129878A (da) |
| CH (2) | CH599754A5 (da) |
| DD (1) | DD115024A5 (da) |
| DE (1) | DE2443890A1 (da) |
| DK (1) | DK484174A (da) |
| ES (1) | ES430034A1 (da) |
| FR (1) | FR2243643B1 (da) |
| GB (1) | GB1479052A (da) |
| IL (1) | IL45656A (da) |
| IT (1) | IT1053780B (da) |
| MX (1) | MX3396E (da) |
| NL (1) | NL7412162A (da) |
| ZA (1) | ZA745835B (da) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4324578A (en) * | 1977-09-15 | 1982-04-13 | Applied Biochemists, Inc. | Method of preparing a copper complex for use as an algaecide |
| US7273944B2 (en) * | 2003-11-19 | 2007-09-25 | Arch Chemicals, Inc. | Methods for producing copper ethanolamine solutions |
-
1974
- 1974-09-06 CH CH1101277A patent/CH599754A5/xx not_active IP Right Cessation
- 1974-09-06 CH CH1215574A patent/CH604528A5/xx not_active IP Right Cessation
- 1974-09-12 IT IT27230/74A patent/IT1053780B/it active
- 1974-09-13 MX MX004586U patent/MX3396E/es unknown
- 1974-09-13 JP JP49106594A patent/JPS5076228A/ja active Pending
- 1974-09-13 DD DD181088A patent/DD115024A5/xx unknown
- 1974-09-13 BR BR7620/74A patent/BR7407620D0/pt unknown
- 1974-09-13 DK DK484174A patent/DK484174A/da unknown
- 1974-09-13 CA CA209,196A patent/CA1129878A/en not_active Expired
- 1974-09-13 AT AT741674A patent/AT353050B/de not_active IP Right Cessation
- 1974-09-13 ZA ZA00745835A patent/ZA745835B/xx unknown
- 1974-09-13 IL IL45656A patent/IL45656A/xx unknown
- 1974-09-13 BE BE148517A patent/BE819908A/xx unknown
- 1974-09-13 DE DE19742443890 patent/DE2443890A1/de active Pending
- 1974-09-13 ES ES430034A patent/ES430034A1/es not_active Expired
- 1974-09-13 GB GB39995/74A patent/GB1479052A/en not_active Expired
- 1974-09-13 NL NL7412162A patent/NL7412162A/xx unknown
- 1974-09-13 FR FR747431080A patent/FR2243643B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| ATA741674A (de) | 1979-03-15 |
| NL7412162A (nl) | 1975-03-17 |
| AU7331774A (en) | 1976-03-18 |
| IL45656A0 (en) | 1974-11-29 |
| CH599754A5 (da) | 1978-05-31 |
| DK484174A (da) | 1975-05-12 |
| GB1479052A (en) | 1977-07-06 |
| CH604528A5 (da) | 1978-09-15 |
| BR7407620D0 (pt) | 1975-07-08 |
| AT353050B (de) | 1979-10-25 |
| DE2443890A1 (de) | 1975-04-03 |
| IL45656A (en) | 1978-07-31 |
| JPS5076228A (da) | 1975-06-21 |
| FR2243643B1 (da) | 1979-02-09 |
| DD115024A5 (da) | 1975-09-12 |
| ES430034A1 (es) | 1977-05-16 |
| FR2243643A1 (da) | 1975-04-11 |
| MX3396E (es) | 1980-10-28 |
| BE819908A (fr) | 1975-03-13 |
| IT1053780B (it) | 1981-10-10 |
| ZA745835B (en) | 1976-04-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |