CA1125731A - Process for the catalytic incineration of hydrogen sulphide-containing waste gases and a catalyst composition therefor - Google Patents
Process for the catalytic incineration of hydrogen sulphide-containing waste gases and a catalyst composition thereforInfo
- Publication number
- CA1125731A CA1125731A CA294,517A CA294517A CA1125731A CA 1125731 A CA1125731 A CA 1125731A CA 294517 A CA294517 A CA 294517A CA 1125731 A CA1125731 A CA 1125731A
- Authority
- CA
- Canada
- Prior art keywords
- weight
- catalyst
- copper
- bismuth
- hydrogen sulphide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 51
- 238000000034 method Methods 0.000 title claims abstract description 40
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title claims description 46
- 239000002912 waste gas Substances 0.000 title claims description 10
- 239000000203 mixture Substances 0.000 title claims description 9
- 230000003197 catalytic effect Effects 0.000 title description 7
- 239000010949 copper Substances 0.000 claims abstract description 34
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 29
- 229910052802 copper Inorganic materials 0.000 claims abstract description 29
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 19
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract description 19
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 4
- 239000007789 gas Substances 0.000 claims description 29
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 20
- 239000001301 oxygen Substances 0.000 claims description 20
- 229910052760 oxygen Inorganic materials 0.000 claims description 20
- 239000012876 carrier material Substances 0.000 claims description 5
- 229960003903 oxygen Drugs 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 6
- 239000005864 Sulphur Substances 0.000 abstract description 5
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- 238000006243 chemical reaction Methods 0.000 description 20
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 10
- 239000002245 particle Substances 0.000 description 10
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 239000000969 carrier Substances 0.000 description 5
- 239000000306 component Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 239000000243 solution Substances 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000011149 active material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 101100379067 Caenorhabditis elegans anc-1 gene Proteins 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001341 alkaline earth metal compounds Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229940000425 combination drug Drugs 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 150000002738 metalloids Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- -1 niekel Chemical class 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 235000010269 sulphur dioxide Nutrition 0.000 description 1
- 239000004291 sulphur dioxide Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/843—Arsenic, antimony or bismuth
- B01J23/8437—Bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Biomedical Technology (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Incineration Of Waste (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US75753177A | 1977-01-07 | 1977-01-07 | |
| US757,531 | 1977-01-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1125731A true CA1125731A (en) | 1982-06-15 |
Family
ID=25048172
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA294,517A Expired CA1125731A (en) | 1977-01-07 | 1978-01-06 | Process for the catalytic incineration of hydrogen sulphide-containing waste gases and a catalyst composition therefor |
Country Status (13)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4576814A (en) * | 1979-04-04 | 1986-03-18 | Union Oil Company Of California | Catalyst and process for oxidizing hydrogen sulfide |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3280104D1 (de) * | 1982-02-02 | 1990-03-15 | Union Oil Co | Katalysator und verfahren zum oxydieren von schwefelwasserstoff. |
| FR2631854A1 (fr) * | 1988-05-26 | 1989-12-01 | Norsolor Sa | Procede de purification catalytique d'un effluent aqueux |
| WO1998004338A1 (en) * | 1996-07-26 | 1998-02-05 | Shell Internationale Research Maatschappij B.V. | Catalyst composition, its preparation, and its use in catalytic incineration |
| JP2000515806A (ja) * | 1996-07-26 | 2000-11-28 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 接触灰化法及び前記方法に有用な触媒組成物 |
| WO2002032810A1 (en) | 2000-10-18 | 2002-04-25 | Jgc Corporation | Method and apparatus for removing sulfur compound in gas containing hydrogen sulfide, mercaptan, carbon dioxide and aromatic hydrocarbon |
| IT1403545B1 (it) * | 2011-02-02 | 2013-10-31 | Eonsudenergia Srl | Catalizzatore per la termolisi di rifiuti |
| EP3799854A1 (en) | 2019-10-01 | 2021-04-07 | Stefan Johannes Fellner | Extract of organic humified materials |
| CN113117517B (zh) * | 2019-12-31 | 2022-10-11 | 中国石油化工股份有限公司 | 一种高浓度含硫有机废气的处理方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1900751A (en) * | 1928-02-27 | 1933-03-07 | Ig Farbenindustrie Ag | Purification of gases |
| GB319396A (en) * | 1928-06-20 | 1929-09-20 | Ig Farbenindustrie Ag | Improvements relating to the purification of gas containing sulphuretted hydrogen |
| FR1070681A (fr) * | 1953-02-06 | 1954-08-05 | Bataafsche Petroleum | Procédé de préparation du soufre à partir de l'hydrogène sulfuré |
-
1977
- 1977-12-08 DE DE2754762A patent/DE2754762C2/de not_active Expired
- 1977-12-29 BE BE1008616A patent/BE862443A/xx not_active IP Right Cessation
-
1978
- 1978-01-05 JP JP5678A patent/JPS5377873A/ja active Granted
- 1978-01-05 GB GB368/78A patent/GB1558656A/en not_active Expired
- 1978-01-05 FR FR7800205A patent/FR2376686A1/fr active Granted
- 1978-01-05 AU AU32198/78A patent/AU510872B2/en not_active Expired
- 1978-01-05 BR BR7800064A patent/BR7800064A/pt unknown
- 1978-01-05 NL NLAANVRAGE7800126,A patent/NL190357C/xx not_active IP Right Cessation
- 1978-01-05 ZA ZA00780050A patent/ZA7850B/xx unknown
- 1978-01-05 RO RO7892830A patent/RO76367A/ro unknown
- 1978-01-05 AR AR270636A patent/AR212728A1/es active
- 1978-01-06 CA CA294,517A patent/CA1125731A/en not_active Expired
-
1981
- 1981-12-30 MY MY349/81A patent/MY8100349A/xx unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4576814A (en) * | 1979-04-04 | 1986-03-18 | Union Oil Company Of California | Catalyst and process for oxidizing hydrogen sulfide |
Also Published As
| Publication number | Publication date |
|---|---|
| AR212728A1 (es) | 1978-09-15 |
| NL190357C (nl) | 1994-02-01 |
| ZA7850B (en) | 1978-12-27 |
| NL7800126A (nl) | 1978-07-11 |
| GB1558656A (en) | 1980-01-09 |
| RO76367A (ro) | 1981-11-04 |
| MY8100349A (en) | 1981-12-31 |
| JPS6120342B2 (enrdf_load_stackoverflow) | 1986-05-21 |
| DE2754762A1 (de) | 1978-07-13 |
| AU3219878A (en) | 1979-07-12 |
| BE862443A (nl) | 1978-06-29 |
| FR2376686B1 (enrdf_load_stackoverflow) | 1982-05-07 |
| AU510872B2 (en) | 1980-07-17 |
| DE2754762C2 (de) | 1987-02-05 |
| NL190357B (nl) | 1993-09-01 |
| JPS5377873A (en) | 1978-07-10 |
| BR7800064A (pt) | 1979-01-02 |
| FR2376686A1 (fr) | 1978-08-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |