CA1123536A - Polymer/polyols via non-aqueous dispersion stabilizers - Google Patents

Abstract

ABSTRACT OF THE DISCLOSURE
This invention relates to polymer/polyols prepared from an ethylenically unsaturated monomer or a mixture of such monomers and characterized by the utilization, in the preparation thereof, of certain preformed stabilizers tailored to the monomer system employed, a method of preparing such polymer/polyols, and to the preformed stabilizers themselves. In general, the stabilizer, com-patible with the polyol portion of the polymer/polyol, comprises a copolymer of an anchor portion consisting of an ethylenically unsaturated monomer or mixture of such monomers and a solvatable portion consisting of a propy-lene oxide polymer having a number average molecular weight of at least 800. The resulting polymer/polyols are distinguished from prior inventions by being stable, fluid, essentially free from scrap and seeds as produced and containing relatively small polymer particles. The poly-mer/polyols are useful for making polyurethane products.

Description

~ 23~6 10687 BACKGROUND OF THE INVENTION
Polymer/polyol compositions suitable for use in producing polyurethane foams, elastomers and the like are known materials.
The basic patents in this field are U.S. 3,304,273, 3,383,351 and Re. 28,715 to Stamberger. Such compositions can be produced by polymeri~ing one or more olefinically unsaturated monomers dissolved or dispersed in a polyol in the presence of a free radical catalyst. These polymer/polyol compositions have the valuable property of imparting to, for example, L0 polyurethane foams and elastomers produced therefrom, higher load-bearing properties than are provided by unmodified polyols.
In addition, U.S. 3,523,093 to Stamberger discloses a method for preparing polyurethanes by reacting a polyisocyanate with a mixture of a polyol solvent medium and a preformed normally solid film-forming polymeric material obtained by polymerization of ethylenically unsaturated monomers. The film-forming polymer may be prepared by various techniques, including polymerizing the monomers in the presence of ~0 reactive radical-containing compounds such as alcohols and mercaptans.
The polymer/polyol compositions initially introduced were primarily compositions produced from polyols and acrylonitrile and, to some extent, acrylonitrile-~ethylmethacrylate mixtures.
Such compositions were at least primarily used commercially ~"
in producing foams under conditions such that the heat generated during foaming is readily dissipated (e.g. -- the ; foams are of a relatively thin cross-section) or under conditions such that relatively little heat is generated during foaming. When the heat is not readily dissipated, the ~oams tend to scorch (discolor).

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U.S. Patent No. 4~208,314 provides an improved process for forming polymer/polyols from acrylonitrile-styrene monomer systems which includes, in general3 maintaining a low monomer concentration throughout the reaction mixture during the proces~s. The novel polymer/polyols produced can be conver~ed to low density, water-blown polyurethane foams having reduced scorch in comparison ~o all acrylonitrile, and acrylonitrile-methylmethacrylate polymer/polyols. Howeverg the stability of the polymer/polyols decreases with increasing styrene to acrylonitrile ratios. Further, the discoloration ~scorch) o the resulting foams still presents some problems 3 particularly when the polymer composition con~ains a rela-tively high acrylonitrile to styrene ratio.
Still further, U.S. Patent No. 4,104,236 discloses additional and substah~ial improvements in forming polymer/-polyols. This allows the optimization of the polymer content and the usable monomer ratios for a given polyolO
U.S. Patent No. 4,172,825 discloses ~urther improve~
ments in the formation o polymer/polyols. As discussed . therein, polymer/polyol compositions exhiblting out~ anding propertles can be made by utilizingg Ln the formation of the polymer/polyols, a specific ~ype of peroxide catalyst, namely t-alkyl peroxye~ter catalysts. By the u~iliza~ion - of thi~ specific type of catalyst, pol~mer/polyols ca~ ;
be produced on a commercial basi~ with outstandin~
proper~ies such as filterability in proces~ing ye~ which

-3-i 33j allows either the polymer or the styrene content to be increased. Also, polymer/polyols can be produced on a commercial scale with polyols havlng a molecular weight lower than have been used prior to this invention.
Despite these improvements, there is still room for further refinement. Thus, in the slabstock foam area, the problem of scorch presents a barrier to the use o~ acrylonitrile-containing polymer/polyols where the buns have a relatively large cross-section. It would be desirable to, in effect, be capable of providing acrylonitrile copolymer polymer/polyols that would be sufficiently low in acrylonitrile content to provide reliable assurance that the resulting buns would be e~en less subject to scorch. Achievement of this objective requires the utilization of relatively high levels of styrene or other comonomers, so that the acrylonitrile content is about 30 to 40 percent of the monomer system used or even lower. While such polymer/polyols can be produced with ;~ certain limitations by prior techniques, the production is not as commercially trouble-free as is desired.
More particularly, the production of polymer/polyols on a large commercial scale with the economy needed places practical limitations on the minimum ratio o~ acrylonitrile to styrene or other comonomer used in the monomer system, the minimum polyol molecular weight and the maximum polymer content when prior techniques are employed. Commercial production thus requires that the resulting polymer/polyols have relatively low viscosities so that processing in the production equipment can be economically carried out.
Further, the stability resulting mLlst be sufficient to allow operation withou~ plugging or fouling of the reactors as well as allowing for relatively long term storage.

The polymer/polyols must also be capable of being processed in the sophisticated foam equipment presently being used. Typically, the prime requirement is that the polymer/polyols possess sufficiently small particles so that filters, pumps and the like do not become plugged or fouled in relatively short periods of time.
While somewhat simplified, the commercial processability of a particular polymer/polyol comes down to its viscosity and stability against phase separation. Lower viscosities are of substantial practical and economic significance due to the ease of pumping and metering as well as ease of mixing during the formation of po~yurethanes. Stability is of prime consideration in insuring that the polymer/polyols can be processed in commercial production equipment without the necessity of additional mixing to insure homogeneity.
It has been recognized that the stability of polymer/polyols requires the presence of a minor amount of a graft or addition copolymer which is formed in situ from the polymer and polyol.
~ With regard to graft copolymer stabilizers, a number of literature references have observed large differences in grafting efficiency between the use of peroxides such as benzoyl peroxide and azobis-isobutyronitrile in certain monomer-polymer systems. In general, the conceptual thrust is that the use of peroxide catalysts should improve the ` stability inasmuch as this type of catalyst produces a relatively greater amount of the graft specie.
Others have noted no mar~ed differences in grafting efficiency. In the Journal of Cellular Plastics, March, 1966, entitled "Polymer/Polyols; A New Class of Polyurethane Intermediates" by Kuryla et al., there is reported a series ~..235;36 of precipitation experiments run to determine any marked differences in the polymer/polols produced by either benzoyl peroxide or azobis-isobutyronitrile when used as the initiators in the in situ polymerization of acrylonitrile in a propylene oxide triol having a theoretical number average molecular weight of about 3000. The data indicated no significant differences between the polymers isolated, and no marked "initiator effect" was observed.
With regard to addition copolymer stabilizers, efforts in the polymer/polyol field have been concerned with the incorporation of additional amounts of unsaturation to that inherently present in the polyoxyalkylene polyols typically used in forming polymer/polyols. U.S. patents 3,625,639 and :
3,823,201 and Great Britain 1,12~,025 all utilize this approach.
None of the above patents recognize the utility of adding a tailored, preformed stabilizer in producing polymer/polyols.
~ In general, a substantial amount of additional efort ; has been directed towards dispersion polymerization in organic liquids. This involves the polymerizàtion of a monomer dissolved in organic liquid to produce insoluble polymer dispersed in the liquid as a continuous phase in the presence of an amphipathic graft or block copolymer as the dispersant (stabilizer). According to a recent text, "Dispersion Polymerization in Organic Media", edited by K. E. G. Barrett, John Wiley & Sons; copyright 1975, the development of techniques for the preparation`of dispersions of polymers of controlled particle size in organic liquids has been largely motivated by the requirements of the surface coatings industry. The function o the dispersant or stabillæer in a sterically-stabilized colloidal dispersion is to provide a layer of ; material solvated by the dispersion medium on each particle surface. Every particle is thus surrounded by a tenuous cloud of freely-moving polymer chains which is, in effect, in solution in a continuous phase. This layer prevents the particles from coming into direct contact and also insures that, at the distance of closest approach of the two particles, the attraction between them is so small that thermal energy renders contact reversible.
The most successful type of dispersant devised for use in dispersion polymerization, according to Barrett, has been based on a block or graft copolymer which consists of two essential polymeric components -- one soluble and one insoluble in the continuous phase. The dispersant may be either preformed or formed in situ. When formed in situ, a "precursor"
is used, i.e., a soluble polymeric component that is introduced into the organic liquid serving as the polymerization medium.
The monomer system being polymerized will react with the soluble polymeric component during polymerization to form, in situ, a graft or addition copolymer dispersant. When an addition copolymer dispersant is to be produced, the source ~ of the soluble polymeric component is unsa-turated and is termed a "macromonomer". The main requirement for whàt is termed the "anchor" portion is that it be insoluble in the dispersion medium, but its effectiveness may ba greatly enhanced if it has some specific affinity for the dispersed polymer. The criterion of lnsolubility of the anchor portion also defines, in practice, the minimum size o~ the soluble portion. For a polymer to be sufficiently insoluble in the dispersion medium, the molecular weight usually has to be of the order of 1000 or greater. The soluble chain attached to such an anchor portion must be at least o~ similar molecular weight, otherwise a stable micellar solution of dispersant cannot be formed in the dispersion medium; and precipitation occurs.
The minimum molecular weight of the soluble component must 3~36 therefore be at least 500 to 1000, which is considerably greater than the minimum requirement for an effective steric barrier.
Based upon this technology, a large number of patents have been issued. The Barrett text lists some 200 issued `
United States and foreign patents. Yet, despite this con-siderable body of technology, applicants are unaware of any attempts prior to the present invention to prepare polymer/
polyols by employing preformed stabilizers. Indeed, the ; 10 prior efforts in dispersion polymerization have been directed to the use of organic liquids as d:ispersion mediums which have extremely low viscosities, e.g. - typically no more than a few centipoises at 25 C. The theoretical considerations . . .
discussed in Napper, Journal of Colloid and Interface Science, 32 pages 106-114 (1970), may wPll account for the fact that preformed stabilizers have not been used heretofore to ~`~ stabilize polymers/polyols, despite the recognition that the stability of polymer/polyols requires the presence of a graft or addition copolymer which is fortuitously formed in situ i~ conventional polymer/polyol from the polymer and polyol. Thus, the Napper article leads to the conclusion that stabilization would not be effective if the solvatable portion has a chemical compQsition identical to the polymerization : medium.
OBJECTS
It is an object of the present invention to provide a process for producing polymer/polyol compositions in which the range of commercially useful process parameters considered critical can be broadened.

A further object provides a process for producing polymer/polyol compositions which allows the production, on a commercial scale, of polymer/polyols with at least one parameter which prevented the commercial production using prior techniques.
A still further object is to provide polymer/polyol compositions which may be used to produce low density, water-blown polyurethane foams in areas such as slab foam stock which are characterized by the substantial absence of scorch or off-color.
Yet another object of this invention is to provide a versatile and economic process for producing polymer/polyol compositions.
~; A further object provides preformed stabilizers which allow the economic, commercial production of polymer/polyols.
Yet another specific object, in accordance with one aspect of this invention, lies in the provision of polymerjpolyol compositions utilizing preformed stabilizers which are capable of conversion to polyurethane foam products without ~20 any alteration of the foam formulation due to the incluslon of the stabilizer.
Still another object of this invention is to provide, in accordance with one aspect of the invention, polymer/polyols wherein the polymer particles are essentially spherical in ~` shape.
Other objects and advantages of the present invention will become apparent i.n the following description, and in the drawings in which:
FIGURE 1 is a tie-line diagram showing the anchor portion compositions of the preformed stabillzer of the 3~i present invention useful in forming polymer/polyols (line AB) when the polymer portion is formed by polymerizing from about 30/70 to about 60/40 acrylonitrile/styrene (line CD);
FIG. 2 is a tie~line diagram and illustrates the preferred .
anchor portion compositions (line EF) for forming the polymer/
polyols described in connection with FIGURE 1 (indicated by ~:~
line GH);
FIG. 3 is a tie-line diagram and shows the anchor :~
portion compositions of the preformed stabilizer of this invention useful in forming polymer/polyols (line I3) when . :
the polymer portion is formed by polymerizing from about 0/100 to about 30/70 acrylonitrile/styrene (line KL);
FIG. 4 iS a tie-line diagram illustrating the preferred `~ anchor portion compositions (line MN) for forming the polymer/
polyols described in connection with FIG. 3 (line OP), and, FIG. 5 is a tie-line diagram showing the anchor portion compositions o~ the stabilizers of this invention useful in . : :
-~ forming poly~er/polyols (line QR) when the polymer portion is formed by polymerizing from about 60/40 to about 100/0 ~20 acrylonitrile/styrene (line ST).
SUMMARY OF ~HE INVENTION
.~ In general, the present invention is predicated on the ~: ~ discovery that improved polymer/polyols can be prepared by utilizing certain preformed dispersants or stabilizers.
.; These polymer/polyols, in contrast to polymer/polyols made : by prior techniques, are characterized by stability satisfactory to allow commercial production and use of one or more of the following characteristics. (1) higher amounts of styrene or : other comonomer when acrylonitrile copolymer polymer/polyols : : ' .

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are belng prepared, (2) higher polymer contents or (3) the use of lower molecular weight polyols. The particular dispersant employed and the concentration utilized vary with respect to the monomex system used in preparing the polymer/
polyol~.
More particularly, the preformed dispersant or stabilizer used comprises a polymeric anchor portion tailored to the monomer system being utilized and a solvatable portion compatible with the polyol. In con~rast to the prior efforts in dispersion polymerization in which the primary focus is directed to designing stabilizers based upon ~he relative solubility and insolubility of the solvatable and anchor portions in the reaction medium, the present invention is based in part on the discovery that enhanced stability of polymer/polyols requires that the polymeric anchor be varied in relation to changes in the monomer system being utilized in producing the dispersed phase (i.e.-the polymer).
. The stabilizers of the present invention are characterized by extremely high viscosities in comparison to viscosities of useful polymer/polyols. Thus, the stabilizers typically :~ possess viscosities well in excess of 40,000 centipoises at 25 C. as compared to polymer/polyols which have viscosities : below ~0,000 centipoises.
The present invention is thus directed to a process : for producing fluid, stable polymer/polyol compositions which comprises polymerizing, in the presence of a free radical catalyst, ; a reaction mixture comprising:
(1) from about 10 to about 40 weight percent Q~ an :
ethylenically unsaturated monomer or a mixture of such monomers, ;
' ~L~.23S3~ 106B7 ~ 2) from 60 to abo~t 90 weight percent of a normally liquid polypropylene oxide polyol having a number average molecular weight of at least about 400 and a hydroxyl number of from about 2D to about 280, said weight percents of ~he monomer or monomer mixture and polyol being based on the total weight thereof, and ~ 3) a preformed stabilizer compatible with said polyol and present in an amount sufficient to stabilize the resulting polymer/polyol, said stabilizer being a copolymer comprising-(a~ an anchor portion consisting of a polymer ofthe monomer or mixture of monomers as defined in ~1) chemically bonded to ~ b~ a solvatable portion consisting of a propylene oxide polymer having a number average molecular weight of at least 8Q0.
~ he present invention is likewise directed to a pre~ormed copolymeric stabili~er for polymer/polyol compositions comprising:

~ .
(a) an anchor portion consisting of a polymer of an ethylenically unsaturated monomer or a mixture of such monomerc chemically bonded to ~ b) a solvatable portion consisting of a propylene oxide polymer having a number average molecular weight of at least 8G0 and being a member selected from the group consisting of:
(1) a polyoxypropylene polyol consisting essenti-ally of the reaction product of a saturated polyhydric starter and propylene oxide or propylene oxide and ethylene oxide, ~ 2~ the reaction product of a propylene oxide polymer and an organic compound capable of reaction with the propylene oxide polymer to provide a reaction product with ~ s .

Z35;~6 terminal, ethylenic unsaturation, with the proviso that said reaction product has on the average, terminal ethylenic unsaturated on only one end and (3) the reaction product of a propylene oxide polymer and an organic compound containing a group enhancing hydrogen abstraction, said stabilizer having a viscosity in excess of 40,000 centipoises at 25 C.

DETAILED DESCRIPTION
Conceptually, the monomers used in preparing the polymer/polyols can comprise any ethylenically unsaturated monomer or monomers. Suitable monomers are disclosed in the Stamberger patents, previously referred to. Representative ; useful monomers include acrylonitrile, styrene, vinyl acetate, ethyl acrylate, methyl methacrylate and acryllc acid. The selection of the monomer or monomers used will depend on considerations such as the relative cost of the monomers and the product characteristics required for the intended application.
It is preferred to utilize acrylonitrile or mixtures ~20 thereof wlth a comonomer. When monomer mixtures are employed, `
it is preferred to maintain a minimum of about 5 to 15 percent by weight acrylonitrile in the system. Styrene will generally be preferred as the comonomer, but methyl methacrylate or other monomers may be employed in place of part or all of the styrene. To provide polymer/polyols for use in applications where minimal scorch is desired, the acrylonitrile content of the monomer mixture used should be less than about 40 percent by weight, preferably less than about 30 percent.

The polymer content of the polymer/polyol can vary within wide limits, depending upon the requirements of the anticipated end use application. Conceptually, it will in general be desirable to form the polymer/polyols with as high a polymer content as will provide the desired viscosity and stability properties. In general, this will vary ~rom about 10 to about 60 percent, based upon the weight of the polymer/polyol. Lower polymer contents may, of course, be utilized; however, there is typically no incentive to use monomer amounts which will result in polymer contents lower than about 10 percent by weight because of the lower conversions and the economic penalty due to the increased throughput involved. On the other hand, it will generally be undesirable to utilize polymer contents in excess of about 4C percent by weight or so. While useful polymer/polyols with higher polymer contents certainly can be made, such polymer/polyols may possess viscosity and stability characteristics which are commercially undesirable.
The resulting polymer/polyols may, if desired~ be blended with conventional polyols or the like to reduce the polymer content to the level required for the particular end usa application. Blends in which~the resulting polymer content is as low as 4 percent of the total weight of the blend or even less are useful.
With respect to the polyol constituent, this comprises poly(oxypropylene) glycols, triols and higher func`tionality polyols. Such polyols include poly(oxypropylene-oxyethylene) polyols: however, desirably, the oxyethylene content should i ~.23S36 comprise less than about 50 percent of the total and, preferably, less than about 20 percent. The ethylene oxide can be incorporated in any fashion along the polymer chain. Stated another way, the ethylene oxide can be either incorporated in internal blocks, as terminal blocks, or may be randomly distributed along the polymer chain. As is well known in the art, the preferred polyols herein do contain varying amounts of unsaturation. The extent of unsaturation typically involved does not affect in any adverse way the formation of the polymer/polyols in accordance with the present invention.
; For the purposes of this invention, useful polyols should have a number average molecular weisht of about 400 or greater, the number average being used herein being the theoretical, hydroxyl number derived value. The true number average molecular weight may be somewhat less, depending upon the extent to which the true molecular functionality is below the starting or theoretical functionality.
The polyols employed can have hydroxyl numbers which -. , - vary over a wide range. In general, the hydroxyl numbers of ~20~ ~ the polyols employed in the invention can range from about 20 and lower, to about 280 and higher. The hydroxyl number is defined as the number of milligrams of pota sium hydroxide ~ .
required for the complete hydrolysis of the fully phthalylated derivative prepared from l gram of polyol. The hydroxyl number can also be defined by~the equation:

OH= 56.1 x-~000 x f ` m.w.
where OH = hydroxyl number of the polyol f = functionali~y, that is, average number of hydroxyl groups per molecule of polyol .

3~

m.w. = molecular weight of the polyol.
The exact polyol employed depends upon the end use of the polyurethane product to be produced. The molecular weight or the hydroxyl number is selected properly to result in flexible or semi-flexible foams or elastometers when the polymer/polyol produced from the polyol is converted to a polyurethane. The polyols preferably possess a hydroxyl number of from about 50 to about 150 for semi-flexible foams and from about 30 to about 70 for flexible foams. Such ~10 limits are not intended to be restrictive, but are merely illustrative of the large number of possible combinations of the above polyol coreactants.
Whlle not preerred, any other type of known polyol may also be used. Among the polyols which can be employed are one or more polyols from the ollowing classes of compositions, known to those skilled in the polyurethane art:
(a) Alkylene oxide adducts of non-reducing sugars and sugar derivatives;
~(b) Alkylene oxide adducts of phosphorus and poly-phosphorus acids;
(c) Alkylene oxide adducts of polyphenols;
; ~ (d) The polyols from natural oils such as castor oil, and the like;
(e) Alkylene oxide adducts of polyhydroxyalkanes other than those already described herein.
Illustrative alkylene~oxide adducts of polyhydroxyalkanes include, among others, the alkylene oxide adducts of 1, 3-dihydroxypropane~ 1,3-dihydroxybutane, 1,4-dihyrdoxybutane, 1,4-, 1,5- and 1,6-dihydroxyhexane, 1,2-, 1,3-, 1,4-, 1,6-, :

~ ~..;2 35~6 and 1,8-dihydroxyoctane, l,lO-dihydroxydecane, glycerol, 1,2,4~txihydroxybutane, 1,2,6-trihydroxyhexane, l,l,l-trimethylolethane, l,lll-trimethylolpropane, pentaerythritol, caprolactone, polycaprolactone, xylitol, arabitol, sorbitol, mannitol, and the like.
A further class of polyols which can be employed are the alkylene oxide adducts of the non-reducing sugars, wherein the alkylene oxides have ~rom 2 to 4 carbon atoms.
Among the non-reducing sugars-and sugar derivatives contemplated are sucrose, alkyl glycosides such as methyl glucoside, ethyl glucoside, and the like, glycol glycosides such as ethylene glycol glucoside, propylene glycol glucoside, glycerol glucoside, l,2,6-hexanetriol glucoside, and the like, as well as the alkylene oxide adducts of the alkyl glycosides as set forth in U.S. 3,073,788.
A still further useful class of polyol is the polyphenols, and preferably the alkylene oxide adducts thereof wherein the alkylene oxides have from 2 to 4 carbon atoms. Among the polyphenols which are contemplated are, or example, bisphenol A, bisphenol F, condensation products of phenol and formaldehyde, the novalac resins; condensation products of various phenolic compounds and acrolein; the simplest members of this class being the l,1,3-tris(hydroxyphenyl) propanes, condensation products of various phenollc compounds and glyoxal, glutaraldehyde, and other dialdehydés, the - simplest members of this class being the l,1,2,2-tetrakis (hydroxyphenol)ethanes, and the like.
The alkylene oxlde adducts of phosphorus and polyphosphorus acids are another useul class of polyols. Ethylene oxide, 1,2-epoxypropane, the epoxybutanes, 3-chloro-1,2-epoxypropane, and the like are preferred alkylene oxides. Phosphoric -17~

~..23~ 10687 acid, phosphorus acid, the polyphosphoric acids such as tripolyphosphoric acid, the polymetaphosphoric acids, and the like are desirable for use in this connection.
It should be appreciated that blends or mixtures of various useful polyols may be used if desired. With polyols other than ~he preferred type, useful monomer contents and monomer or monomers may vary somewhat. Similarly, it may be desirable or even necessary to modify the stabilizer of this inYen~ion when such other polyols are used. This can be accomplished by following the criteria discussed hereinafter in connection with the stabilizers used for ~he preferred polyols.
Regarding the catalyst employed to form the polymer/polyols, any free radical catalyst, from the conceptual standpoint, may be utilized. ~seful catalysts include the t-alkyl peroxyester ~atalysts described in the hereinbefore mentioned~
copending Van Cleve et al. appl~cation. As described therein, useful catalysts must have a satisfactory half-life within the temperature ranges used in forming the polymerfpolyol compos-itions, i.e. -- the half-life should be about 25 percent or less of the residence time in the reactor at a given temperature.
Representative examples of useful catalyst species include t-butyl pero~y-2-ethylhexanoate, t-butylperpivalate, 2,5-dimethyl-hexane-2,5-di-per-2 ethyl hexoate, t-butylperneodecanoate, t-butylperben-zoate and di-t-butylphthalate. It is, however, preferred to employ azo catalysts, with azobis-isobutyronitrile being prefer xed. In general, it is believed that the azo catalyzed polymerf polyols process better in the preparation of urethane flexible foams. Thus, the use o such catalysts will generally provide lower acidity in the resulting polymer/polyols as well ~s freedom - 18 ~

.. , . . ~

3~3~;

from the odor characteristic of products formed with peroxyester catalysts which might be objectionable to some users.
The catalyst concentration employed is not critical and can be varied within wide limits. As a representative range, the concentration can vary from about 0.1 to about 5.0 weight percent or even more, based upon the total feed to the reactor. Up to a certain point, increases in the catalyst concentration result in increased monomer conversion;
but further increases do not substantially increase conversion.
The particular catalyst concentration selected will usually be an optimum value considering all factors, including ; costs.
The polymer/polyols of the present invention are preferably produced by utili~ing the process set forth in the copending Priest application, identified herein. In accordance with that process, a low monomer to polyol ratio is maintained throughout the reaction mixture during the .. . .
process. This is achieved by employing conditions that ~20 provide rapid conversion of monomer to polymer. In practice, a low monomer to polyol ratio is maintained, in the case of semi-batch and continuous operation, by control of the temperature and mixing conditions and, in the case of semi-batch operation, also by slowly adding the monomers to the ~; polyol.
The temperature range is not critical and may vary from about 100C. to about 140 C. or perhaps greater, the preferred range being from 115 C. to 125 C. As has been noted herein, the catalyst and temperature should be selected so that the catalyst has a reasonable rate of decomposition , . : :

~.Z3536 with respect to the hold-up time in the reactor for a continuous flow reactor or the feed time for a semi-batch reactor.
The mixing conditions employed are those obtained using a back mixed reactor ~e.g. -- a stirred flask or stirred autoclave). The reactors of this type keep the reaction mixture relatively homogeneous and so prevent localized high monomer to polyol ratios such as occur in certain tubular reactors, e.g. -- in the first stages of "Marco" reactors when such reactors are operated with all the monomer added to the first stage.
The utilization of the Pxiest process is preferred since this allows the preparation of polymer/polyols with a wide range of monomer compositions, polymer contents and polyols that could not be otherwise prepared with the necessary requisite stability. E~owever, whether the utilization of the Priest process is essential depends upon whether the process parameters are such that a satisfactory polymer/polyol can be prepared without using this process.
The polymer/polyols of the present invention comprise ~20 dispersions in which the polymer particles (the same being either individual particles or agglomerates of individual particles) are relatively small in size and, in the preferred embodiment, are all essentially less than about one to three microns. ~owever, when hlgh contents of styrene are used, the particles will tend to be larger; but the resulting polymer/
polyols are highly useful, particularly where the end use application requires as little scorch as possible. In the preferred embodiment, essentially all of the product (vlz. --about 99~ or more) will pass through the filter employed in ~ 3536 10687 the filtration hinderance ~filterability) test that will be described in conjuction with the Examples. This insures that the polymer/polyol products can be successfully processed in all types of the relatively sophisticated machine systems now in use for large volume production of polyurethane products, including those employing impingement-type mixing which necessitate the use of filters that cannot tolerate any significant amount of relatively large particles. Less rigorous applications are ~atisfied when about 50 percent of the product passes through the filter. Some applications may also find useful products in which only about 20 percent or even less passes through the filter. Accordingly, the polymer/polyols Qf the present invention desirably contemplate the products in whi~h only 20 percent pass through the filter, preferably at least 50 percent and most preferably, essent~ally all.
Indeed, it should be appreciated taht l:he filtration hindrance test presents the most rigorous test of polymer/polyol stability; and, accordingly, while satisfactory filtration hindrance characteristics are certainly to be preferred, commercially stable polymerJpolyols for a variety of applications may be satisfactorily defined by their viscosity and centrifugible solids level (this test being also described in connection with the Examples). Thus, polymer/polyols are considered stable as long as the viscosity is no more th~n about 5,000 cps at 25C. and the centrifugible solids are less than about 10/ol preferably less than 5~O.
In accordance with the present invention, the preparation of the polymer/polyols is carried out in the presence of a preformed stabilizer tailored to the monomer ~..Z3~

system being employed. The stabilizer, in a functional sense, is present in an amount sufficient to insure that satisfactory stabilization will result, viz. - the desired filtration hindrance, centrifugible solids level and viscosity are provided.
According to one aspect of the present invention, the solvatable constituent of tha stabilizer is formed from a polypropylene oxide macromonomer having terminal monoethylenic unsaturation. The minimum number average molecular weight of the macromonomer should be at least about 800, prefer~bly at least about 1800 and, most preferably at least about 2600. Macromonomers with molecular weights up to 5000 or even more can be utilized if desired.
The macromonomer can be suitably prepared by condensing a polypropylene oxide material having hydroxyl functionality with any organic compound capable of providing the desired monoethylenic unsaturation. Monols, diols and triols are preferred; however, conceptually, tetrols and higher unction-ality polyols could also be employed. As is known, poly propylene oxide materials of this type can be prepared by forming adducts of propylene oxide with lower molecular weight monols, diols, triols and the like such as, for example, glycerine, dipropylene glycol, butanol and the like. The macromonomer may contain minor amounts of other materials. Thus, poly(oxypropylene-oxyethylene) materials containing up 10 to 20 weight percent oxyethylene or so may be suitably used. The condensation reaction to form the macromonomer is known and can be carried out, ~or example, in an inert solvent such as benzene at elevated temperatures in the range of 80Co to 115C.
Insofar as the constituent providing the monoethylenic terminal unsaturation is concerned, any compound which will 3~6 condense with the polypropylene oxide material may conceptually be employed. However, in practice, the compound selected should possess unsaturation of a type reactive in vinyl polymerization. For this reason, compounds containing allylic unsaturation show no advantage; in fact, the resulting stabilizers have been found to be ineffective. As representative examples, the desired unsaturation may be imparted by utilizing either acrylic acid or methacrylic acid. Use of these two compounds has not demonstrated any differences in utility of any particular significanceO Process-wise, the unsaturation can be provided by using conventional transesterification or ester interchange techniques. In addition, the unsaturation could be imparted by employing maleic anhydride or the like. A further useful embodiment can be provided by reacting toluene diisocyanate with the propylene oxide polymer to form an intermediate product which i5 thereafter reacted with hydroxyethylacrylate to form the macromonomer. The use of these latter examples provides a process advantage in that the filtration step needed when an acrylate is formed is obviated.
When diols or higher functionality polyols are employed, it is important that the reaction forming the macromonomer be carried out in a fashion designed to react away, on the average, only one of the hydroxyl groups of the polyol.
The utilization of stabilizers formed from macromonomers having on the average significantly more than one end of the chain capped with monoethylenic unsaturation have proved to be relatively ineffective in stabilizing polymer/polyols.

'' ' ' " '' "'.

~ ~35~ 10687 The dispersants or stabilizers may then be prepared by grafting the monomer or monomers used as the anchor portion to the macromonomer. As used herein, the term "grafting"
includes the species formed by free radical addition polymerization as well as the species formed via hydrogen abstraction. The reaction may be carried out in any inert solvent. Representative examples include toluene, benzene, ethylbenzene and a mixture of toluene and methylethylketone.
The solids concentration ~i.e. -- total weight of the macromonomer and monomer or monomers for the anchor portion) can vary within wide limits; and it is suitable to carry out the formation of the stabilizer with a solids concentration of from about 10 to 60 percent, based upon the total weight of the solids and solvent, preferably about lO to ~0 percent, most preferably 30 to 40 percent.
The weight ratio of the macromonomer to the monomer or , monomers used to form the anchor portion can also be varied within a wide range. However, the ratio selected will generally influence the compositional character of the dispersant formed due to the effects on the type of grafting ~; reaction which predominates. It will accordingly be generally preferred to utili2e at least about 50 percent of the macromonomer, and it is partlcularly preferred to use a solids concentration in which the macromonomer constitutes ; about 60 to 70 percent of the total with relatively high molecular weight macromonomers and about 80 percent or so with lower molecular weight macromonomers.
It is preferred to sele~t the parameters so that a homogeneous stabilizer results as opposed to one which 3 ~ 3 ~i coacervates ~vlz. --separates into layers). The advantage of having a homogeneous product to handle instead of one which has layers and must be mixed before each use is apparent.
Whether the product coacervates or not is believed to be dependent upon the extent of grafting. For a given catalyst the amount o~ the macromonomer used in relation to that of the vinyl monomer or monomers will influence this result.
The catalyst used, and the concentration, can suitably be the same as those previously discussed in connection with 10 the formation of polymer/polyols. The selection of the catalyst will also, to some extent, influence the type of grafting reaction which will predominate. For example, the use of a peroxide catalyst has been found to accentuate grafting via hydrogen abstraction.
In any instance, grafting via both hydrogen abstraction and vinyl polymerization will take place; and the resulting stabilizer will accordingly be a mixture of various compounds. ~i The exact product mixture is not of particular significance.
Indeed, the mixture will typically also include unreacted ~20macromonomer and vinyl monomer or monomers in addition to the various grafted species.
With respect to use of the stabilizers in connection with forming polymer/polyols, the resulting crude reaction stabilizer mixture may be either added directly to the polyol or separation of the solvent and/or unreacted materials may be effected. For example, the unreacted macxomonomer in ~;
` the crude product may be extracted by utilizing a solvent such as hexane. Addition of the stabiliæer in the solvent ' 3~36 in which it is formed is a highly advantageous processing technique, allowing easier dissolution into the polyol. The solvent may then be stripped out, if desired, by conventional techniques.
To provide effective stabilization, it has been found that the stabilizer should be compatible with the polyol being employed so that a homogeneous mixture is provided.
The resulting mixture, visually, may be either a clear solution or opaque depending upon the particular composition ~10 of the stabilizer. However, if solids are visually detectable in the resulting system, the use of a stabilizer will typically provide, at best, little stabilizing effect.
The crude stabilizer may be employed, without any refinement or processing other than, if desired, the stripping out of the solvent in which the stabilizer was prepared.
The amount of the crude stabilizer which may be employed should~be sufficient to achieve the desired stability. It ` has been found that a small amount- (e.g. -- about 0.2~, .
based upon the weight of the polymer/polyol) provides a dramatic~efect on at least some of the physical properties of the polymer/polyol in comparison to the pr~paration of the same polymer/polyol without the stabilizer. Typically, this effect is evident from a reduction in the viscosity as well as increased stability as indicated by a reduction of the quantity of centrifugible solids. Indeed, insofar as these properties are concerned, the addition of 0.4 weight percent of stabilizer in certain cases provides`properties equivalent to those obtained by employing 1.4 weight percent.

~:

~ -26-., ~.235~6 10687 It is, however, preferred to use an amount of stabilizer which is sufficient to provide the desired greater stability as indicated by filtration hindrance characteristics; and achieving superior filtration hindrance will generally require the addition of an amount of stabilizer in excess of that required to achieve satisfactory viscosity and centrifugible solids characteristics. Accordingly, it will generally be desirable to add from about 1 to about 5 percent or even more stabilizer, based upon the weight of the polymer/polyol.
Larger amounts could, of course, be employed but there will generally be no functional incentive to use excessive amounts.
In accordance with a still further aspect of the present invention, the acrylonitrile copolymer polymer/polyols obtained using the stabilizers of the present invention have partlcles which are spherical in shape. This is achieved by use of the stabilizers of the present invention as well as employing a monomer system in which the styrene or other comonomer is present in amounts in excess of about 40 percent ,: .
20~ by~weight.
In marked contrast to prior efforts in stabilizing polymer dispersions in ~arious organic liquids wherein the .

primary emphasis was placed on ~he relative insolubility of the anchor portion in the liquid, as has been alluded to previously, i~ has been discovered that a further factor . ~ : .
must be considered. More specificaIly, it has been found that the anchor portion of the stabilizers of the present invention must be coordinated with the type of monomer or ~ ' ~
' ~23~

monomers used to form the polymex portion of the polymer/polyol.
Conceptually, it is theorized that effective stabilization requires a careful balance between the solvatable portion and the anchor portion of the stabllizer. If the solvatable portion dominates, it is believed that the anchor portion will be, in effect~ pulled into solution thereby losing the contact with the polymer particles which is essential for optimum stability. On the other hand, iL the anchor portion dominates, it is believed that the solvatable portion will not provide the required barrier for stabilization.
In this application, the terminology "balanced stabili~er"
refers to a stabilizer having the careful balance between the solvatable and anchor portions which has been discussed herein.
Considering this aspect more fully some of the vinyl monomers useful in forming polymer/polyols are not solvents for their polymers (e.g. - acrylonitrile) whereas other useful monomers (e.g. - styrene) are solvents for their polymers. The present invention is predicated, in part, on ~20 the discovery that effective stabilization requires an anchor portion tailored in composition to the solvency, or lack thereof, of the monomer or monomers used for forming the dispersed polymer portion of the polymer/polyol.
Thus, in accordance with a preferred embodiment o~ the present invention, the anchor portion is formed from at ; least two monomers, one of which is not a solvent for its - polymer and one whlch is. Further, the respective monomer weight ratio used are preferably maintained within the range of from about 30/70 to about 80/20 (weight ratio o monomer ~28-~ Z353~ ~0687 which is not a solvent to the amount of monomer which is).
The range of useful monomer ratios to form the anchor within this range will then be at least principally dependent upon the solvency characteristics of the monomer or monomers being used to form the polymer portion.
In the ensuing discussion for sake of simplicity, the monomer ranges for the anchor portion will be set forth in terms of acrylonitrile to styrene ratios useful in forming polymer/polyols from a monomer system of acrylonitrile and/or styrene. It should, however, be appreciated that the same principles are also applicable to other monomer systems and to anchor portions formed from other monomers. When the polymer protion of the polymer/polyol is formed by polymerizing, by weight, a monomer system of from about 30/70 to about 60/40 acrylonitrile/styrene, optimum stabilization requires that the anchor portion have a composition within line AB of FIGUR~ 1, preferably within line EF of FIG. 2. An anchor portion of 30/70 acrylontrile/styrene is particularly preferred, especially for ~0/60 and 50/50 acrylonitrile/
styrene monomer systems.
As the amount of styrene in the monomer system is . . I
increased above 70 percent (i.e. - 0/100 to 30/70), the anchor portion should have a composition within line IJ of PIG.3, a composition within line MN of FIG. 4 being preferred.
For use with 20/80 and 30/70 acrylonitrile/styrene monomer systems, an anchor portion composition formed from 50/50 acrylonltrile/s~yrene is preferred. On the other hand, with increasing amounts of acrylonitrile ti.e - 60/40 to 100/0, more particularly, 60/40 to 80/20), useful anchor portions ... .

~ 353~ 10687 can be formed from a composition defined by line QR of FIG. 5.
It should be appreciated that the exemplary monomer weight ratios set forth do not present absolute limits.
Rather, these ratios provide a representative range in which effective stabilization can be achieved. Some experimentation wlthin the general concept may be needed to provide an optium stabilization effe~t for a particular monomer system. Indeed, as can be seen from the ranges previously set forth for the anchor portionsr there is some overlap. Thus, as one example, ~10 the lower limit of the high styrene range (i.e. - 30/70) polymer/polyols coincides with the upper limit of the intermediate range polymer/polyols. This coincidence causes an overlap in the sense that the useful anchor portion ratios for a 30/70 acrylonitrile/styrene polymer/polyol ;~
determined from the intermediate range is from 30/70 to 80/20 (line AB of FIGURE 1) while the determination from the ; high~styrene range polymer/polyols would indicate useful anchor portions of 30/70 to 50/50 (line IJ of FIG. 3). There ~ is a similar coincidence at the upper limit of the intermediat~e 20~ rang~e polymer/polyols~a~ can be seen by comparing FIGs. 3 and 5.
The indicated useful anchor portion ranges at these points of coinciden~ce should not be interpreted indivldually;~
rather, these ranges should be considered together. Accordingly, the overall interpretation is that, in the intermediate range where ~significant relative amounts of both acrylonitrile and styrene are present, the widest latitude for the ratio .
~ ~ ' : :~
~30-.. . . : :: : :
., : - . .: . .

3~ 6 lo 6 8 7 of the monomers used for the anchor can be employed.
However, as either the styrene or acrylonitrile in the monomer system used increases to a disproportionate level, the ratio of useful monomers for the anchor correspondingly becomes narrower.
For this reason, as the amount of styrene in the monomer system being used approaches 70%, the range of the more useful anchor portion compositions will correspond to 30/70 to 50/50. Employing anchor portions with compositions in the range of 50/50 to 8b/20 will decrease the effectiveness of the resulting stabilizers somewhat. Similarly, as the amount of acrylonitrile in the monomer system approaches 60%, the range of the more useful anchor portions will correspond to 50/50 to 80/20. Stabilization using anchor portions having 30/70 to 50/50 compositions will generally be less effective than anchors having acrylonitrile contents in excess of 50%.
The principal thrust of this preferred embodiment of this invention is thus that the anchor portion should be ~ 20 formed from at least two monomers, one of which is a solvent .~

for its polymer and one of which is not; and, further, the .~
-relative monomer weight ratlo utilized in forming the anchor port~on must be tailored to the monomer system being used in forming the polymer/polyol. This also serves to illustrate :
`~ the greater flexibility of this embodiment as compared to ' the percursor technique. As is apparent, utilizing a percursor necessitates that the anchor portion will be identical in composition to the polymer portion of the polymer/polyol being prepared. Percursors are thus only potentially useful in the range where the effective anchor fortuitously happens to match the useful composition required for the particular : .

. : : .
:

~.23536 monomer system being employed. Moreover, while the reasons are not fully understoodt a preformed stabilizer has been found to provide significantly improved stabilization in relation to stabilization achieved by a percursor technique.
It should also be appreciated that the more significant improvements in stability of the polymer/polyols in accordance with the present invention are achieved when one or more of the following parameters are present: (1) a relatively high styrene or other comonomer content (i.e. - 70% or more) in ~10 the acrylonitrile-comonomer system, (2) a relatively high monomer content (i.e. - 30~ or more) and (3) a relatively low polyol molecular weight (i.e. - less than about 2000 or so). If these general parameters are not exceeded, satisfactory stabilization will generally be inherently ~achieved without the necessity of employing any additional technique for stabilization such as the present invention.
The present invention will accordingly find its more important utility in situations where one or more of the above-identi~i~d parameters must be utili~ed to form a ~20 polymer/polyol for the particular end use application. Thus, where an application requires a relatively s~orch-free product such as in slab stock foam, this may be achieved by forming a polymer/polyol with reduced amounts o~ acrylonitrile (i.e. - less than about 40%, preferably less than 30~).
Indeed, if desired, relatively stable all-styrene polymer/polyols may be formed. Similarly, where high modulus characteristics are required, the present invention allows production 3~j of stable polymer/polyols from monomer contents of 30~ or more. Still further t stable polymer/polyols can be formed using polyols having molecular weights down to about 400 or so with relatively high monomer contents ~up to about 37%~.
The appropriate limits for the parameters capable of being used to form a stable polymer/polyol will, of course, depend on the particular stability requirements as well as the interrelationship of the parameters. Thus, when a particular acrylonitrile monomer system is being used, the maximum monomer content that may be employed decreases somewhat as the molecular weight of the polyol decreases.
As a specific example, when using a 20/80 acrylonitrile/
styrene monomer system, stable polymer/polyols can be made with 18% polymer content in a 3000, but not lower, molecular weight polyol. Similarly~ when the objective is to utilize as high a monomer content as is possible, the particular useful maximum will be de-termined by the acl-ylanitrile/styrene ; or other comonomer~ratio of the monomer system needed and the molecular weight of the polyol being u~ilized. The maximum useful polymer content will generally decrease somewhat with decreasing molecular weights of the polyol or relatively high styrene~(or other comonomer) to acrylonitrile ratlos. Satisfactorily stable polymer/polyols of about 40% polymer or so can be made with a 4Q/60 monomer system and a 3000 molecular weight polyol.
The situtation is the same when low molecular weight .
; polyols are used. Thus, whether a stable polymer/polyol can be made in a particular polyol will depend on the other two parameters desired. The present inverltion allows formation ~q.23~6 of stable polymer/polyols in polyols of 400 molecular weight at 37~ polymer content with a 50/50 monomer system.
The present invention also provides a method for producing polyurethane products by reacting: (a) a polymer/polyol composition of this invention, (b) an organic polyisocyanate, and (c) a catalyst for the reaction of (a) and (b) to produce the polyurethane product, and, when a foam is being prepared, a blowing agent and a foam stabilizer. The reaction and foaming operations can be performed ln any suitable manner, pre~erably by the one-shot technique.
The organic polyisocyanates that are useful in producing polyurethane products in accordance with this invention are ~;
organic compounds that contain at least two isocyanato groups. Such compounds are well known in the axt. Suitable organic polyisocyanates include the hydrocarbon diisocyanates, (e.g., the alkylene diisocyanates and the arylene diisocyanates) , as well as known triisocyanates. As examples of suitable polyisocyanates one can mention 1,2-diisocyanatoethane,~1,3 ; -diisocyanatopropane, 1,2-diisocyanatopropane, 1,4-diisocyana-~ tobutane, l,S-diisocyanatopentane, 1,6-diisocyanatohexane, bis(3-iso~yanatopropyl)ether, bis(3-isocyanatopropyl)sulfide, 1,7-diisocyanatoheptane, 1~5-diisocyanato-2,2-dimethylpentane, 1,6-diisocyanato-3-methoxyhexane, 1,8-diisocyanatooctane, 1,5-diisocyanato-2,2,4-trimethylpentane, l,9-diisocyanatononane,~
l,lO-diisocyanatopropyl)ether of 1,4-butylene glycol, 1,11-~ : :
diisocyanatoundecane, 1,12-dlisocyanatododecane bis(iso-cyanatohexyl)sulfide, 1,4-diisocyanatobenzene, 2,4-diisocyanato-toluene, 2,6-diisocyanato tolylene, 1,3-diisocyanato-_-xylene, 1,3-diisocyanato-m-xylene, 1,3-diisocyanato-p-xylene, , 353~

2,4-diisocyanato-1-chlorobenzene, 2,4-diisocyanato-1-nitrobenzene, and 2,5-diisocyanato-1-nitrobenzene and mixtures thereof.
The catalysts that are useful in producing polyurethanes in accordance with this invention include: (a) tertiary amines such as bis~dimethylaminoethyl)ether, trimethylamine, triethylamine, N-methylmorpholine, N-ethylmorpholine, N,N-dimethylbenzylamine, N,N-dimethylethanolamine, N,N,N',N'-; tetramethyl-1,3-butanediamine f triethanolamine, 1,4-diazabicyclo [2.2.2]octane, pyridine oxide and the like; (b) tertiary phosphines such as trialkylphosphines, dialkylbenzylphosphines, and the like; (c) strong bases such as alkali and alkaline earth metal hydroxides, alkoxides, and phenoxides; ~d) acidic metal salts of strong acids such as ferric chloride, stannic :j chloride, stannous chloride, antimony trichloride, bismuth nltrate and chloride, and the like; (e) chelates of various metals such as those which can be obtained from acetylacetone, be~zoylacetone, trifluoroacetylacetone, ethyl acetoaceta~e, salicylaldehyde, cyclopentanone-2-carboxylate, acetyl-acetoneimine, bix-acetylacetone-alkylene-diimines, salicyl-aldehydeimine, and the like, with the various metals such as Be, Mg, Zn, Cd, Pb, Ti, Zr, Sn, As, Bi, Cr, Mo, Mn, Fe, Co, Ni, or such ions as MoO2++, UO2++, and the like; (f) alcoholates and pnenolates of various metals such as Ti(OR)4, Sn(OR)4, Sn(OR)2, Al(OR)3, and the like, wherein R is alkyl or aryl, and the reaction products of alcoholates with carboxylic : acids, betadiketones, and 2-(N,N-dialkylamino)alkanols, such as the well known chelates of titanium obtained by said or equivalent procedures; (g) salts of organic acids with a , ~ 3~3~ 10687 variety of metal~ such as alkali metals, alkaline earth metals, Al, Sn, Pb, Mn, Co, Ni, and Cu, including, for example, sodium acetate, potassium laurate, calcium hexanoate, ~tannous acetate, stannous octoa~e, stannous oleate, lead octoate, metallic drie~s such as manganese and cobalt naphthenate, and the like; ~h~
organometallic derivatives of tetravalent tin, tsivalent and penta~alent As, Sb, and Bi, and metal carbonyls of iron and cobalt.
Among the organotin compounds that deserve particular mention are dialkyl~in salts of carboxylic acids, e.g. dibutyltin diace~ate, dibutyltin dilaurate, dibutyltin maleate, dilauryltin -~
diacetate, dioctyltin diacetate, dibutyltin-bis(4- methylamino-benzoate), dibutyltin~bis(6-methylamino-caproate), and the like.
Similarly there may be used a trialkyltin hydroxide, dialkyltin oxide, dialkyltin dialkoxide, or dialkyltin dichloride. Examples of these compounds include trimethyltin hydroxide, tributyltin hydroxide, trioctyltin hydroxide, dibutyltin oxide, dioctyltin oxide, dilauryltin oxide, dibutyltin-bis(isopropoxide), dibutyl-tinbis(2-dimethyl- aminopentylate), dibutyltin dichloride, ; dioctyltin dichloride, and the like.
The tertiary amines may be used as primary catalysts for accelerating ~he reactive hydrogen/isocyanate reaction or as secondary catalysts in combination with one or more of the above noted metal catalysts. Metal catalysts, or combinations of metal catalysts, may also be employed as the accelerating agants, without the use of aminesO me catalysts are employed in small , amounts, for example, from about 0.001 percent to about 5 percent, based on weight of the reaction mixture.

- - 36 - ^

~L~.Z3~;36 When the product being formed is a polyurethane foam, this may be accomplished by employing a small amount of a polyurethane blowing agent, such as water, in the reaction mixture ~for example, from about 0.5 to about 5 weight percent of water, based upon total weight of the polymer/polyol composition), or through the use of blowing agents which are vaporized by the exotherm of the reaction, or by a combination of the two methods. Illustrative polyurethane blowing agents include halogenated hydrocarbons such as trich]oromono-fluoromethane, dichlorodifluoromethane, dichloromonofluoro-methane, dichloromethane, trichloromethane, l,l-dichloro-l-fluoroethane, 1,1,2-trichloro-1,2,2-trifluoromethane, hexafluorocyclobutane, octafluorocyclobutane, and the like.
Another class of blowing agents include thermally unstable compounds which liberate gases upon heating, such as N,N'-.

dimethyl-N,N'-dinitrosoeterephthalamide, and the like. The generally preferred method of foaming for producing flexible : ~ ~
foams is the use of water or a combination of water plus a fluorocarbon blowing agent such as trichloromonofluoro-methane. The quantity of blowing agent mployed will vary with factors such as the density desired in the foamed product. The anti-scorch properties of the foams produced using polymer/ polyol compositions are most evident when at least some of the blowing agent is water and the water is used in an amount that results ln a foam having a density less than 1.75 pounds per cubic foot. Generally, the use of water in an amount of at least 3.0 percent by weight based on the total weight o~ the polymer/polyol composition results ~ ~3~i3 E;

in a foam having a density of less than 1.75 pounds per cubic foot.
It is also within the scope of the invention to employ small amounts, e.g., about OoO01 percent to 5.0 percent by weight, based on the total reaction mixture, of a foam stabilizer such as a "hydrolyzable" polysiloxane-polyoxy-alkylene block copolymer such as the block copolymers described in U.S. Patents 2,834,748 and 2,917,480. Another useful class of foam stabilizers are the "non-hydrolyzable"
polysiloxane-polyoxyalkylene block copolymers such as the block copolymers described in U.S. Patent 3,505,377; U.S.
Patent application 888,067, filed December 24, 1969 and British Patent Specification 1,220,471. The latter class of copolymers differs from the above mentioned polysiloxane-polyoxyalkylene block copolymers in that the polysiloxane moiety is bonded to the polyoxyalky].ene moiety through direct carbon-to-silicon bonds, rather than through carbon-to-oxygen-to-silicon bonds. These various polysiloxane-polyoxyalkylene block copolymers preferably contain from 5 to 50 weight percent of polysiloxane polymer with the remainder being polyoxyalkylene polymer.
Particularly useful foam formulations utilizing polymer/
polyols are well known and are being presently used commercially to form various foam products. It has been found that, when using such conventional formulations, foams made with polymer/polyols utilizing the stabilizers prepared by the technique of this invention previously described herein exhibit a tendency to collapse~ It is believed that, in .

35i36 some unknown fashion, these polymer/polyols upset the stability of the rising foam. This tendency can be overcome by, for example, either increasing the amount of catalyst used or by increasing the amount of the silicone or other surfactant employed.
The polyurethanes produced in accordance with this invention may be advantageously employed in various applications.
; For example, the present invention allows the production of polyurethane foams from polymer/polyols in which the polymer portion can be formed from a monomer system containing less than about 20 to 30 percent by weight acrylonitrile. Such foams find advantageous utility in the slab foam market where the cross-sections of the buns are relatively large and where a relatively large exotherm is encountered. In such situations, polyurethane foams produced in accordance with this invention result in whlte products with little scorch whatever being visually detectable. StiLl further, the polymer/polyols of this invention may be used to form polyurethane elastomers in which relatively low molecular weight polyols must be used to provide the requisite stiffness.
In addition, polymer/polyols stabilized in accordance with - the present lnvention may be utilized to form polyurethane products where maximum Ioad-bearing characteristics are required since the stabilization achieved allows the use of a relatively high polymer content.
In accordance with ye-t another aspect of the present invention, effective stabilizers can be prepared without the initial step of forming a macromonomer. To this end, effective stabilizers can be prepared by polymerizing in an ~ ~ ~>
~3~36 inert solvent with a free radical catalyst a polypropylene oxide material (forming the solvatable portion) with the monomer or monomers forming the anchor portion~
In this embodiment, the same considerations, in general, which are involved in forming stabilizers using the macro-monomer technique are equally applicable. Thus, the propylene oxide material may be the adduct of propylene oxide with a monol, diol, triol or the like. The minimum molecular weight of the resulting adduct should be at least about 800, preferably at least about 1800 and most preferably about ~10 2600. However, for reasons which will be apparent in the ensuing discussion, it is preferred to employ materials having relatively high molecular weights.
More specifically, in this embodiment, the stabilizer consists of graft species ob-tained only by hydrogen abstraction.
Accordingly, it is preferred to employ a free radical catalyst which enhances hydrogen abstraction, such as a peroxide catalyst. Further, relatively large solvatable portion molecular weights àre required to insure that the desired steric barrier is provided.
Inasmuch as this technique eliminates the need to form the macromonomer, stabiLi~ers produced by this technique offer real economic advantages. While it has been found that useful concentrations may require up to twice the amount of stabilizers made with the macromonomer technique to provide equivalent stability characteristics, there is still a significant economic advantage in using this alternative technique. ;
In connection with this technique, a further aspect of ~ -this invention provides modifying the polypropylene oxide ; ~ , -40- ~

i;;36 material by incorporation of a group which enhances hydrogen abstraction. While various compounds are known and may be used, a particularly useful solvatable portion comprises the - reaction product of the propylene oxide material with toluene diisocyanate. This requires that the propylene oxide material either contain, as formed~ at least one functional group reactive with the diisocyanate or be modified after preparation to introduce the requisite functional group or groups. Regardless of the type, it is preferred in this embodiment that the propylene oxide material be monofunctional, although difunctional materials are satisfactory. The use of tri- or higher functionality materials should be avoided as extensive cross-linking has been found to occur. Hydroxyl ~roups are particularly preferred as the functional group. The diisocyanate is desirably used in an amount sufficient to insure reaation of ~ the isocyana~o groups.
;~ Moreover, the utilization of this technique to prepare . ~ . :
polymer/polyols results in an unexpected advantage in :,~ :
forming polyurethane foams. Thus, in contrast to poly-urethane foams made using polymer/polyols employing stabi]izers prepared by the macromonomer technique, polyurethane foams ~ made using polymer/polyols prepared by this alternative ::'. :
technique, for some reason, exhibit less tendency to collapse.
This allows the use of the same foam formulation as would be used with a~polymer/polyol formed by known techniques. The advantages are apparent.
.

,:

.~
,: ~

.23S;~D

In accordance with yet another aspect of the present invention, no separate equipment is needed to prepare the stabilizers. Thus, in a commercial run to prepare polymer/
polyols, the equipment to be used may be initially employed to react the solvatable and anchor portions to form the required amount of stabilizer. After completion, the polymer/polyol run can be carried out in the same equipment.
The economlc advantages involved can be significant, particularly in the mode where the solvatable portion used is an unmodified polypropylene oxide material. In such a situation, it is possible to use the polyol as the solvatable portion and the same monomer or monomers to be employed to form the polymer part of the polymer/polyol as the anchor portion, thereby requiring only the solvent used to form the stabilizer as a further raw material.
Regardless of the mode of preparation used for the solvatable portion, the resulting stabilizers of this inventlon are characterized by relatively high viscosities in relation to polymer/polyols having comparable polymer , .
~i 20 contents. Thus, after removal of the solvent used to prepare the stabilizer, the stabilizer will be a solid or a liquid who~e viscosity will typically range from about `~j 60,000 up to 260,000 or more centipoises at 25 C.
~` ~ The physical character of the stabilizers, after solvent .
removal, ranges From a paste to a solld, depending upon the - . .

: : ' - '. ' ' ' , :

3S~6 type of solvatable portion utilized and the weight ratio of the monomers used to form the anchor portion. In the macromonomer mode, the stabilizers are usually solid or semi-solid regardless of the monomers used for the anchor.
With the free radical grafting mode using a polypropylene oxide material, the character of the stabilizer varies from a solid or semisolid with an anchor portion made from a 30/70 acrylonitrile/styrene monomer charge to a paste when the acrylonitrile/styrene weight ratio is increased to 50/50 or higher. While the chemical compositions of the preformed ; stabilizers of this invention may be essentially identical with the graft or addition copolymers formed in situ in conventional polymer/poiyol preparation, there are three basic differences. In the first instance, the process parameters used to prepare the preformed stabilizers can be coordinated to enhance grafting efficiency, a circumstance that may not be the situation in polymer/polyol production where the in situ formation of the graft or addition copolymer is incidental. Sec~ndly, a preformed stabilizer can be ~0 tailored to the particular monomer system being used and thus does not suffer from the serious limitation of being identical in composition to the monomer system and polyol being used in the polymer/polyol preparation. Lastly, the in situ formed graft or addition copolymer does not have practical utility apart from the particular polymer/polyol in which it is formed because it is difficult to isolate.
.~ .

3~i36 The rollowing Examples are illustrative, but not in limitation of, the present invention. These E~amples descrlbe all of the several parameters involved in preparing and using the stabilizers of the present invention, ranging from the preparation of the macromonomer used in one embodiment as the solvatable portion to screening of the parameters used to form the stabilizers to characterizing the effectiveness o~ the stabilizers in a variety of polymer/

polyol preparations. Because of the relative large number of parameters involved, a proper evaluation of the data contained requires a careful consideration of all of these parameters. The Examples should there~ore be considered together, presenting a trend showing useful parameters and stabilizers for ~arious polymer/polyol preparations. Thus, as one example, the amount of stabilizer used must be scrutinized. A level of 1% by weight provides an lndication of the effectiveness of the stabilizer; but the use of increased amounts, consistent with this invention, will ~- enhance stability. r;~
~` ~ DEFINITIQNS
As used in the Examples appearing below, the following designations, symbols, terms and abbreviations have the indicated meanings:
"Theoretical molecular weight" of a polyol denotes a - molecular weight calculated using the equation previously set forth based on the ~unctionality o~ the starter used to produce the polyol and the experimentally determined hydroxyl number of the polyol.

.

353~

"Molecular weights" of polyols are number average molecular weights.
"rpm" denotes revolutions per minute.
"mg" denotes milligrams.
"A" denotes acrylic acid.
"MMA" denotes methylmethacrylate.
"MA" denotes me~hacrylic acid.
"TBPO" denotes t-butyl per-2-ethylhexoate.
"AZO" denotes 2,2'-azobisisobutyronitrile.
"TMSN" denotes tetramethylsuccinonitrile.
"pcf" denotes pounds per cubic feet.
"Sol" denotes solution.
"S" denotes solid.
"~" denotes percent by weight.
"wt" denotes weight.
"Ratio" denotes weight ratio.
"Polypropylene oxide material I" -- a monohydroxyl polypropylene oxide produced from propylene oxide and butanol having a number average molecular weight of about 800.
"Polypropylene oxide material II" -- a monohydroxyl propylene oxide produced from propylane oxide and butanol having a number average molecular weight of about 1800.
"Polyproplene oxide material III" -- a monohydroxyl polypropylene oxide produced from propylene oxide and butanol having a number average molecular weight of about 2600.
"Polypropylene oxide material IV" -- a polypropylene oxide diol produced from propylene oxida and dipropylene glycol and having a theoretical number average molecular weight of about 4000.

~45-35;36 "Polypropylene oxide material V" -- a propylene oxide triol produced from propylene oxide and glycerine and having a theoretical number average molecular weight of about 6000.
"Polyol I" -- a polypropylene oxide triol produced from propylene oxide and glycerine and having a theoretical number average molecular weight of about 3000. ::
"Polyol II" -- a polypropylene oxide diol produced from propylene oxide and dipropylene glycol and having a theoretical number average molecular weight of about 400.
;10 "Polyol III" -- a polypropylene oxide diol produced from propylene oxide and dipropylene glycol and having a ~ `!
theoretical number average molecular weight of about 1000~ ~:
"Polyol IV" -- a polypropylene oxide triol having about ~-14% internal ethylene oxide content, a hydroxyl number of ~ about 46.6 and having a number average molecular weight of : about 3600.
"Polyol V" -- a propyoxylated/ethoxylated polyol having a hydroxyl number of about 56 mg. KOH/gm, an internal ethylene ~ oxide content of about 8%, and a number average molecular weight of about 3000.
"Urethane Catalyst" -- a solution consisting of 70% Bis t2-dimethylaminoethyl) ether and 30~ dipropylene glycol.
:~`
.` ~

'.'~

~ 10687 3S~6 "Silicone Surfactant I --a mixture of 55 wt.-% of a block copolymer having the formula:
Me3SiO(Me2SiO)72(MeSiO)5 1SiMe3 C3 6(OC2H4~24~OC3H6~27OMe where Me denotes the methyl group; and 45 wt.-% of a polyether having the formula: -C4HgO(C2H4O)l8(c3 6)13.7 "Silicone Surfactant II" --a mixture of 80 wt.-~ of the above block copolymer and 20 wt.-% of the above polyether.

, , ~.23S3~

POLYMER/POLYOL PROPERTIES
Filtration Hindrance (Filterability) This is determined by diluting a sample (470 grams) of polymer/polyol with anhydrous isopropanol (940 grams~ to remove any viscosity-imposed limitations and using a fixed quantity of material in relation to a fixed cross-sectional area of screen ( 2. 4 sq. in.) such that about 200 grams of product are passed through 150 or 700-mesh screen per one square inch of screen. The 700-mesh screen is made with a Dutch twill weave. The actual screen used had a nominal opening of 30 microns and is described in Bulletin 46267-R
of the Ronningen-Petter Company of Kalamazoo, Michigan. The dif~erence between the final and initial screen weights corresponds to the amount of polymer that did not pass through the screens. The 150-me~h screen has a square mesh with average mesh opening of 105 microns, and it is a "Standard Tyler" 150 square mesh screen. The amounts which pass through are reported in percent, a percentage of~100%
being preferred. Trace solids will generally always be pre~ent, but a value of 100~ indicates that over 99 weight percent passes through the screen.
Centrifugible Solids After stripping unreacted monomer, the polymer/polyol composition is centrifuged for about 24 hours at about 3000 revolutions per minute and 1470 radial centrifugal "g"
force. The centrifuge tube is then inverted and allowed to drain for 4 hours. The non-flowing cake remaining at the bottom of the tube is reported as wt. percent of the initial weight of the composition tested. To provide a commercially - .

~*23~6 106~7 satisfactory stable polymer/polyol, the solid should be less than about 10%, preferably less than 5~.

FO~M PROCESS PARAMETERS AND PROPERTIES

Cream Time .
The interval of time from the formation of the complete foam formulation to the appearance of a creamy color in the formulation. The creaming time is proportional to the rate of reaction of the formulation.
Rise Time ; The interval of time from the formation of the complete foam formulation to the attainment of the maximum height of the foam.
Porosity A specimen of foam 1/2 inch in thickness is compressed between two pieces of flanged plastic tubing 2 1/4 inches in diameter (ID). This assembly then becomes a component in an air flow system. Air at a control velocity enters one end of the tubing, flows through the foam specimen and exits through a restriction at the lower end of the assembly. The pressure drop across the foam due to the restriction of air ~`20 passage is measured by means of an inclined closed manometer.
One end of the manometer is connected to the upstream side of the foam and the other end to the downstream side. The flow of air on the upstream sida is adjusted to maintain a differential pressure across the specimen of 0.1 inch of water. The air porosity of the foam is reported in units of - air flow per unit area of specimen, cubic feet per minute per square foot.

--~9---.
.

~ 3536 10687 ``
Tensile Strength -ASTM D1564~69.
Tear Resistance .
ASTM D1564-69.
ILD
ASTM D1564-69.
Compression Set ASTM D1564-69.
Elongation ASTM D1564-69.
Nopco Breathability Refractometer _ Using an IDL color eye mode:L no. Dl, made by Kollmorgen Corp., Attleboro, Mass., a numerlcal rating of from 0 to 100 is made on the test specimen by comparison to a series of standards. A rating of "100" corresponds to a specimen rated as being white.
PREPARATION OF MACROMONOMERS
The polypropylene oxide material, methacrylic acid or other material used to provide the terminal unsaturation, solvent and other constituents (e.g. - acidic catalyst and the like) were placed in a 4-necked amber glass 5 liter flask equipped with a thermometer, magnetic stirrer, boiling stones and a 10-tray Old~rshaw column with decanting still headO The mixture was refluxed for from about 8 to about 12 hours at a temperature in the range of from about 80 to about 110C., , and the water from the reaction was collected. The product ~ 235~6 10687 was then neutralized at 50C. with~sodium hydroxide in water ~to form a salt). The mixture was stirred for about one hour and allowed to set for 16 hours. The water was then azeotroped from the produc-t. The dry product was mixed with a commercially available filter aid and filtered under 100 pounds of pressure at 100C. to remove the salt (e.g.-sodium p-toluene sulfonate or sodium sulfate).

PREPARATION OF DISPERSANT OR STABILIZER
Unless otherwise indicated, the procedure employed was as follows. The monomers, macromonomer or polypropylene oxide material, catalyst and solvent were placed in a 500 milliliter 4-necked flask equipped with a stixrer, dropping funnel, wa~er-cooled condenser, temperature control and nitrogen inlet and outlet. The flask was heated while stirring under a slight nitrogen purge. Additional monomer or monomers and the remainder of the catalyst charge were added over a period of about one hour. The ratio of monomer or monomers used to the macromonomer or polypropylene oxide material was in the range of, by weight, 30-50 monomer or monomers/50-70 macromonomer or polypropylene oxide material;
and the total weight of these components in the solvent was in the range of 30 to 50 percent. The mixture was heated and s~irred for an additional hour, cooled and stored in a glass jar.

POLYMERtPOLYOL PREPARATION
Unless otherwise indicated, the polymer/polyols were prepared by adding the polyol to a l-liter, 4-necked flask equipped with a stirrer (Lightnin Stirrer), dropping funnel, water-cooled condenser, nitrogen inlet and outlet. The ':
`~ -51-.23S3~
' .

flask and contents were heated to the temperature desired, and part of the free radical catalyst employed added. The monomer mixture being utilized with additional amounts of the free radical catalyst employed were then added dropwise from the dropping funnel over a period of about 45 mlnutes with continuous rapid stirring. The mixture was stirred at a high rate of speed initially, viz. - as fast as possible without excessive splashing, until about 1/2 of the monomer mixture had been added. At this time, the stirring was increased again as much as possible without causing excessive splashing. After completion of monomer addition, the reaction mixture was heated and stir~ed for about an additional hour. In some cases, a slight temperature rise was noted; and, in most cases, no attempt was made to prevent such temperature increase. The samples were then cooled, and a small amount taken or free monomer analysis by gas chromatography. Also~unless other wise indicated, the weight ratio of monomer mixture to polyol used was 2G/80.

~20 These Examples illustrate the preparation of macro-monomers using polypropylene oxide materials having molecular weights varying from about 800 to about 5000, with the terminal monoethylenic unsaturation being provided by using - either methacrylic acid or acrylic acid.
The process used was the same as has been previously set forth, and the parameters are set forth in Table I: -.

35i;36 ~ 10087 aJ
C ~ l I

o In I , ~, ~1 ~ ` ':

N ¦ ~ ~ ~ ~
~' . ~.

~ ~ ~

N
..

8 ~ 3 9 ~

. . .

353~i These Examples show the preparation of stabilizers having an acrylonitrile-styrene copolymer anchor portion and, except for Example 19, a solvatable portion formed with a terminal, monoethylenically unsaturated macromonomer, the polypropylene oxide matexial used in preparing the macro-monomer having a molecular weight in Examples 8-23 of about 2600 and in Examples 24-28 of about 800.

The stabilizers were prepared by terpolymerizing acrylonitrlle, styrene and the macromonomer at a temperature of 100C., with the exception of Examples 8-10 which were polymerized at 90C. and Example ll wherein the polymerization was carried out at %0C. The procedure for Example 19 was carried out at 100C. and was si~nilar to that described except that the solvatable portiorl was an unmodified poly-propylene oxide material, the re~3ulting graft specie being formed via hydrogen abstraction. The solvents used in preparing the stabilizers were varied as were the relatlve amounts of the solvatable and anchor portions. The resulting stabilizers were evaluated in terms o~ their homogeneity, solubillty in Polyol I and stabilizing effectiveness as ohserved in a general screening test conducted by preparing a polymer/polyol in the presence of the stabilizer. The macromonomer and stabilizer compositions as well as the properties of the stabilizers are set forth in Table II:

`

-~ ~3536 106~7 ~I ~ ~ ~' ~ V ,~

o U~
CO ~ ,~ o . o U~ ¦ -- -- Vl ~) O ~

c C: O ~ ~ L
O Ct~ V~ g O ~
o O O O
,1 ,~ o ~ v) ~ ~ ~ t~
S~ L C
O ~ N ~.) N . _ . . O Sa ._ C
.-,¦ ~ ~ '~' Z--~ E C
c ~ e e 0~ e ~

_~ r~
a~ ~ u E v ~
l o o u~~ ~ ~ 'E ~ C o " ' _ ~-- o a~
L~ L C V~
~_, o S. ~ ~, O 3 ~ O ~: L .

C V ~IJ O V ~.0 ' ~ ~D O ~ ~ C t~ ~0 .~ ~ ~1~ ~ S ~-~
C C ~ '. V 3 W

C ~
.`: E ~ C ~' = o ~ ~ c-_ O ~ . ~ V E ~ C~~ v~

v C~Ccovc~s~
. ~V a L ~ > a- ~ ~IJ
~ ~ c c o o ~ ~
E ~> d vl .d-- v O c c ~ c ~v V ~U ('t: V _ _ c ~ .~ V V ~ .o O ~~ V_~ Q U') ~ '-- V ~ ~ --n "
a) ~o c ~ C ~ V c ._ ., Vl C C 0 u~ ~ ~ 3 V
~ ~ v _~ ~ ~ u ~ al ~ c _ ~ ~v I I I n 3 --u ~ ~ ~ N ul ~ O O a~ V U~ V~ . C O
~ ~ V~ ~l ~ ~. ro ~ r- ~O ~ ~_ :.
. C~ V~ c~ V'l U~ ~

. :
'`~ , ' ' ,~

~..Z35~36 As can be seen, superior stabilization is provided with a stabilizer formed with a polypropylene oxide material of 2600 molecular weight, TBPO as the catalyst and toluene or benzene as the solvent. As shown in Examples 8, 13 and 23, a concentration of 30-50~ vinyl monomer is desirable.

; These Examples demonstrate the preparation of additional useful stabilizers with polypropylene oxide materials having molecular weights ranging from about 800 to about 5000 and with anchor portions wherein the acrylonitrile/styrene ratio varies from 25/75 to 50/50.
The terpolymerization was carried out using TBPO
catalyst; and the results are set forth in Table III, the stabilizers being evaluated in terms of solubility in Polyol I and stabilizing effectiveness observed in a general screening conducted by forming a polymer/polyol in the presence of the stabilizer:

~ ' .
` .
.
, ~;23~3~i :

a q~ ~ In o o ~ ~ Q~
~1 o ~O~eJ~D~ g Z XLn~
O
~) Ln ~ O ~O ~ ~
d ~ O ~ _ >~ ~ u7 1 ~ . o .
Q~ c u~ ~ o ~ _ ~ CL ~
O ~ ~ ~ 3 a) ~ E Q~ o ,: o ~ ~
C o o c ra O ~ ~ E O S
` ~ ~1 ~ -- ~ 3 ~ ~ ~ c c ~ E

L o o o o ~ s_ C
~ ~ ~!~ CO~ ~ C
. ~
` ~ ~ ~r c ~ o __ 2 ~ ~o ~ C, o ~o ~ ~

~ ., s ` ~ ~1 ~ r` 1 ~ ~ ~ s 3 Oc ~3 :, c a~ _ o . E ~ E

. E .. c- ~ ,a E ~, 3 ~o ~ C ~ s ~
o~_~ O ~ ~ 3 : `
E ~o :~ ~ 3 ~ I
o ~ ~ O Co O r~ ~ :- ~1~ .
a~ ~ c ,-~ o~ c t:

E ~ ,a 1~1 ~ C:5 ~~ ~, ~ ~ E~ ~
a~ E 3 -- ~ ~ ~ -- .-- o ~ x x ~_ O r ~ IJ) r3 ~1) O ~7 r~ r~- ~ . ~_ ~ --5 7 - ~
S ~ ~ V~ ~--~ ~ ~ ~ ~ "
- - - . . ~ ~-, As can be seen from Examples 34 and 35, stabilizers with good stabilizing ability were also provided when the polypropylene oxide material was not condensed with acrylic acid or the like to provide a macromonomer with terminal, monoethylenic unsaturation.

These Examples illustrate the preparation of polymer/
polyol using various stabilizers.
The polymer/polyols were prepared in Polyol I with a monomer content of 20% by weight of 40/60 acrylonitrile/
styrene using an azo catalyst. For comparison purposes, the acrylonitrile/styrene ratio was varied in selected Examples. The preparation of the polymer/polyols and the properties of the resulting products are summarized in Tables IV-VIII:

.

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10~87 J ¦ ~o 1~ 0 0 1 ~ g ~D O ' I ~ N ~D ~ Cl~ . N I ¦ O ~D O g N
I o o~ ~1 1 1 ~ N f~ ~1 _ O

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D O C~l ~ O U r~
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I C ~ r~ ~ O O O ~> O O~ o I I I I 1 > O O O C~
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~ o N ~ 0 r~ O 1~1 I CO 00 ~ ~ ~ I I O ¦
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N CO C~l _ ~ 0 3 O 1~) 0 O~ I C '--o ~ ~ .
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cn ¦ N N Gl ~ r-- o O O O N a~ ! _ 5 , ~ ~ A . N

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d~

~ 353~ 10687 While an anchor portion formed from an acrylonitrile/
styrene ratio of 30/70 provided effective stabilization for polymer/polyols made with a 40/60 acrylonitrile/styrene ratio (See, e.g. - Example 75), this composition stabilizer was considerably less effective when used with polymer/polyols made with styrene tSee Example 94). It can also be seen from a comparison of Example 75 with Examples 90 and 91 that precursors provided less effective stabilization than can be achieved with preformed stabilizers.

These Examples show the preparation of polymer/polyols in 400 molecular weight polyol (Polyol II), using stabilizers in accordance wi.th the present invention~
The resu1ts are set forth in Table IX:

, ~ ~ .

. . .

-64~
`: :
/~

3~i36 As can be seen from Examples, extremely stable polymer/polyols at about 20 percent polymer content can be formed in a low molecular weight polyol.

These Examples illustrate the preparation of polymex/
polyols in Polyol III, which has a molecular weight of about 1000, using preformed stabilizers.
The results are set forth in Table X:

~.23~36 10687 o ~ ~
_ ¦ 2 . o o o ~--8 m ~ ~ ~ ,~ ~D ) o j ~ I ~ I I O
l N Irl N ~JI ~I 1~ ~ O O O O O 01 Cll ~ ~ ~ I I I I I
o N N ~ C
--I ~OU 0'0~0~~O~ I I I I
~ ~ o O c~l o o~

O U CO ~
--~ ¦ O ~)_ , ~ O c~l O U'~ ~ O ~ L
O O ~ O ~ L _I I I I I I O

O ,~, t --I C~l ~ 00--0 0 ~C~ O O ~
tO
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_ et L~ ~ ul ~ ~1 r_ o I O I o a~ ~ c~ ~ ~ ~ I~ co I I a~ ~o~

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.

.. . .

, . ... _ .
. . .

~ i.23~ii36 As can be seen from Examples 107 and 108,polymer/polyols with satisfactory stability were achieved in the low molecular weight polyol with 40/60 and 50/50 acrylonitrile/styrene monomer systems.

These Examples illustrate the preparation of polymer/-polyols from Polyol I and high styrene monomer systems using a 50/50 acrylonitrile/styrene polymer as the anchor portion and a polypropylene oxide-butanol adduct of about 2600 mol. -wt. condensed with acrylic acid to provide terminal unsaturation as the solvatable portion.
The results are set forth in Table XI:

.
.
''. :
,.~, .

:

.

'~

. ~ .

. ` ' ' ' :

~.. 23~i 10687 .

:: ~1 ~ . o~ ~ ~ N D o~o 1~~ æ
_t ~I N O r-l 1~ 1 ID O O O I ~D ~D r-l ~ I I I I I ~
.~ . '.

D O O ~
~-1 O ~ ~ O~) O O lS) I ~ O
I 1~ 0 C~ O O I ~ I ~ A Ll~

.D a'~ 1~ I.D ~ d' e~N O O
~1 O ~ _ 00 0 Cl~ I O C~ O C~l O a~
-1 C~ ~ ~ C~ I ~ A r-l ~ 00 _1 ~1 C`J N ~ 1~ O _I O O O ~00 Cl~ O

o co a~ O O
~_ ~ O ~ -- ~ ~ r~ ~ I~ O - d- O ~ ~ C~J
' ~ X r~l C~l O O . ~ . . . . . el~ e~ o ~
.. , 1~1 ~ ~ C~l ~) ~11~ O 1 ~ 0 N O alCJ~ ~ ~C a~ r~ A Lt --1 '' ~
: ` .
....
~"; "

''':
: ' o ~ ` o o F E o C ~ ~ C_ ~ o ~ , ~ U~ ~ C ~ C Ul.
`.'~ ~ '~ ~ o ~ O ~ c u~
o t~ u'l C L ~ O ~ o ~
o c ~ o ~ 1~ ô ~) ~ . ~ I v~ S V'l ~ ~ .n .: ~ C O O ~ N ~ r~ C 5:: C ~ C C- O ~ a~ ~ a) O Q~-- O
~ 0 5:: C ~ ~ ~ (~ ~ ' ~ :~:o ~J~ So (~) <_ .~ 0 o~ ~Za~ ~ L57 0 ~
.. , _.a C ~ O L~ rd V~ C ~ C ~ ~ O O r--~1 1~ C
X S_ (I~ _~ ~ O a~ o o ~ C ~ o ~ 0 .. ' .
'' ' : , .

~j -69- ~

, .
- . : , 35~

These Examples demonstrate that satisfactorily stable polymer/polyols can be made wi~h monomer systems having a relatively high styrene content (see Example 116) with stabilizers having anchor portions of appropriate composition.

These Examples show the preparation of polymer/polyols using Polyols I and III, contrasting the preparation using stabilizers in accordance with the present invention with polymer/polyol preparation without employing a preformed stabilizer.
A continuous polymerization system was used, employing a tank reactor fitted with baffles and an impeller. The feed components were pumped to the bottom of the reactor continuously after going through an inline mixer to assure complete mixing of the feed components before entering the reactor. The internal temperature of the reactor was controlled to within 1 Centigrade by controlled heating or cooling to the outside of the reactor. The product from the top of the reactor flowed out of the top of the reactor to a back pressure regulator adjusted to 10 pounds per square inch gauge back pressure and then through a watex cooled tubular heat exchanger to a product receiver. Portions of the crude product were vacuum stripped at 2 millimeters pressure and 120 to 130 deyrees C. for testing.
The experimental conditions and results are tabulated in Table XII:

.

~ 35~36 10687 ._ e iI . o 1~ . r~ 18 c~~1 a: O I 1~ CO Ln ~ 0 N ~ ~ I C~J
E c ._ " ~ ' -r~ ~n O LS') ~ ~ O ~ C~ O U~
C~J ~ O ~ O I -- O I O ~ O
_~ ~) ~ I CO CO ~ ~D ~ OOt~ C~J O ~ o F ~:1 ~ .
r +~ O
Lt~ ~ 0 000 C~ CO ~ U
C~U'~ O U~ O _ I~c~i O~g 0~ g O O c~J

O _C
o c~ ~OD ~. o ~ O
N ~ c~i o ~ O I g ~ 'J' la ~
I ~1 e~ O D ~ d' 0 ~3 0~
~,~ , ,a c . ~~ O :~ O N ~D 00 0 0~ rt O ~C~I E c ~ ~ I O 0 CO ~D O o ~ O O ,_~
E 3c o Lt~ 1~ o ~D 0 O O 00 o E
,~ O ,,~O ~n _ . s.~ o o o o . ~ ~ o o ~ 88 r~ ~~ o O ~) N ~3 r' ul ~ ~OD
Q
~ ~ ~ S
~ ~ ~0' C ~
~ ~ ~ , O ~ ~ L L E ~ 3 E ~ o, o O o C~l S Q Q~
~ Q~ o ~ O C ~ ~ 3 O
r~ ~o ~ 1~ 7 ~:1 X
S- la ~ F ~ ~ L ~ O ~
.~ 3 ,, . ,, ' .~ S_ V) ~ S ~ X ~ 13 O I 5_ Q~ 1~ C
o ~ s= a~ ~ c v~ ~ ~ a) o ~) s_ ~ . a) c u~ ~ c ~ o ~ ,o o ~ ~ ,--, E c ~ ~ ~ c ~ ~ ~ s U1. ~ ~ CL e s_ ~ o C~ O r ~ C 5: ~ s ~ ~ ~ ~ :~
. C ~ ~ ~ ~ 4- _ ~ .,_ ~ . ,- ~ o a~ _ o :~ ~ ~, ~
'11 r S_ O ~r~~_ _ Oo a~ ~ ~ ~ o ~ ~ v~ Xo V~ S O C
E~ " I~:s ~ ~ ~ E O ~ ~ E ~ `' S_ U~ O ~ ~) I~
x O . aJ ~a la ~ o (a o o ~ , ,, . _ L~J c~ ~ cy~ a~r51 -71- ~

, , ~ . .,,. ' :

~ 3536 10687 As can be seen from a comparison of Example 119 with Example 121 and Example 122 with Example 124, the use of stabilizers allows the formation of stable polymer/polyols which cannot be prepared by using azo catalysts alone.
A comparison of Example 119 with 120 and Example 122 with 123 shows the stabilizers decrease the viscosity and centrifugible solids level in comparison to preparation using only a peroxide catalyst.

These Examples illustrate the preparation of polymer/
polyols with a monomer system of acrylonitrile and styrene and/or methyl methacrylate as comonomers using the procedure set forth in Examples 119-124, except that Polyol IV was used.
The experimental conditions and results are tabulated in Table XIII:

- ~:

-7~-Z~;36 106~7 IO _ ~ ~ o I 1~ ~ o o ~ 1~ g ~ ~ o~ ~ N C~' ~OD t~ J I O O CO 00 I CO (D C~ I ~ æ ~ ~ ~ ~ . . ~
_ ~ O
~ _ o X ~ o C O J~ _ U~ .o 0,l ~ C ~ ~ ~
I N t` ~10 ~t ~ ~ ~ ~) a:l ID ~ U CO Cr~ e~ ~ O D CO U'l ~ 0~ ~.) ~ C~J ~J I C
U~) ~) . _~) d l:~J . O C~J ~D N .~ 0 1~ X _ ~IJ C) -o a~ o 3 ~ CL O
O C C '7 . V
O 'O ~ aJ ~ O
~ U- O r~ O~ CO 1~ ~ ~ ~ = V ~ ~ --I~ O ~ D ~ O ~ Otl ._ N ~ ~ O I O O Cr~ g ~ CI ~ 'O ~ C 1~) I ~C~J O 1$~ O ~ ~ ~ CO O ~ O ~1 (~1 ~t ~V ~ o C ~ ~:) O L
~_ o~ ~ c~ J ~ o o _~ o o c~ u E ~ O- " *, ~
~ ) o ::1 L ~ ~ V a~ E ~
~, Cl ~ O C ~IJ C
o ~ ~ ~ ~ O r C- L -- ~, O ~ ~) Cl~ Z . ~ 0~ ~L ~ ~
O Ln c~ r7 N I I ~ ~ C E V- c C n~ C E _ v~
N cr~ ~ ~ ~> O ~ ~ ~, c n E '~ o L
t~ ~ N ~ ~ r~ ~ U ~ C~ O a~ ~ LO . -¦ ~N . . ~D IS) O ~) ~ Cl . . . . . 11~1 N 1~ U~ o O _ N I~
_ ON C~l C~l N r~ N C~ O _ _I O O ~ CO 0tl Cl~ N ~ , L
v ~
O ,~ _ O L~ ~ o 1~ N NO CS~ O U7 U N O e~ O
_I ON N N N ~ N O~ O ~ ~ O O 0 a I CO ~ ~ er ~ ~ 1~ ~ N ~
~ ~0 S
c c O ~- CL a a> _ 0 3 ~.) .

~ 1 N ~ CO $ ~O CO t~:l N O 1~ (~ ~ a O _ U
U')c~ ~ L~> NO ~ I_ O~ O _1 ~ O O c~ l_ co ~ ~t ~ co ~ N C~ co ~ O O ~ --~ _ O J~ 3 ~Q V

~_ O C ~ ' :`: O O O _ . O '_ J-E -- U U . I E U E O U
v ~ L O ~ O ~ ~ ~ O ~~ ~
. oû~y E o o .o :-, N E ~ c ^ ~ o ~ :
~ >~ ~u v ~ v ~ ~ ~ ~ L
~ C ~ 0 ~ L~ 1~ L~ . _ V . ~ O ~ 1~ ~ 2 ~ N ~
L ~ ~ ~1) ~ _ L _o L ~ C L O 1~ 0 L ~-- ~ ~ C ~U C ~ V~
~ ~-~ '~ a~ ~ ~ cn ^ '-- ~ 'L S~ _O CL ~ c ~ O S. ~ ~ O
V L ~ ~ --~ 2) ~: V ~ ~ ~ -- O O ~ ~ V') I;~ o c~ ~ ~ v o c c ,~ s _ ~- v~ v GJ e ~ E _ V V~ ~ ~o E~ I 1~1 E

~ ~ e ~ o L O O L ~ O 'V~ ~V ~ O ~ ~ V ~ O O ~ C C
~t e~ ~ ~ ~o e ~, Eo o ~ aJ ~ ~ 10 L ~_ ,-1 1~ ~ 3: ~ I-- _I
, ~ ¦ V V ~ ~ C ,~ ~ o o OL a V ~ ~ ~ ~) ~ ~') OL ~ -- C e .

. .

-: ' `:

3~

As can be seen from Examples 126 and 131, stable polymer/polyols can be formed when methyl methacrylate is substituted for part or all of the styrene in the monomer system.

: EXAMPLES 132-147 These Examples show preparation of further polymer/polyols using the process set forth in connection with Examples 119-124.
The experimental conditions and results are set forth in Table XIV:
~ ~ .
~, ;
,~ ' `: :
' .

-74- ~
~;

1~ %35~3G 10687 n r~ r~ n 1~ o co o ~ ~ I~ I~ I o o 1 g o o ~
c~J ~ ~ ~ o o ~> ~ ~ ~ ~ ~ o _~ o ~ ~ ~ I ~ g ttl g N
a~ o r~
~1 ~n ~ ~ a~ 1~ ~ ~ O ~ ~ ~D In . ~ . . ~D I g o g ~D
~ _ c~J ~> ~ ~ N o~ O _ O ~ I _ _ N I
_ e~ n ~ ~ ~n e~ ~n ~ n o ~ . O O ~ co~ n ~ ~D ~ O I ~ g co g ~ a~
n ~ o~ o _~ o ~> co c~ ~n _ _ _ I ~ _ o o n ~ ~n 1~ 0 g ~ ~n ~ ~ I 1~ 0 I O O ~
_ o ~ r ~ r~ ~ o ~ o ~ c~ n o C~
n _ g ~ _ ~ ~ '7 N ~ ~ g N L~
_ O ~ ~ ~ D C~l ~ O C~J O ~ ~ CD ~D _ C~ n ~r ~ C~ ~ ~ _ O ~ ~D ~ oJ r~ 1~ O~ ~ _ ~ U- CO O ~ ~ 1~ _ ¦ ~n u~ O O NO ~ ~ a~ O ~ ~ ~ ~n D ¦ a~ O 1" O ~ ~ Q
X
I~J ,D ~ ~D ~ r~ ~ O r~l 1~ 0 ~D 1~ 0 g O ~
~! _ ¦ N ~n ~ ~ ~ ~ O~ N N ~ O _ ~
I-- _ N O N N N ~n N cn O N O C0 a:l 00 ~ I ~ ~ N ~ ~D N r~ ~ C
N 1~ et O 'D ~ ~ N C0 ~ el~ N ~ O~ ~ ~ ~ N C~
_¦ N o O N ~D r~ 3~ N r~ ,~ _ N ~D ~ _ N ~ L
~ O
--~ I _ N O ~ ~ _ cn N Csl O _ O CJ~ CJ~ cn _ _ ~ . ~> ~ D ~OD . cn . E~ ~
D N ~ r~ Cl~ D U7 0~ ~ d N N _ O ~ D ~ ~
_ ¦ N~D ~ _ _ O N n ~ a~ N O ~ N U~ ~ d d ! `n . C,~ N ~ ~ N

~ ~ ~ ) ~ O ~. N _ er r~) ~ 1~ a:~ N i 1~ N _~ ~" O N N ~ 5 o #I N n ~O ~r/ O N cn G 1~ CO O C0 C
_ I ~ N ' ~ N ~O rN` cn _ _ o co cn 0 co _ N _ ! ~ ,,1 _ "~ " I _ -o _¦ O N N O N q` N n _ _ O O O O ~0 o r~ N ! ~ ~ N ~
~1 n n ~ ~ ~ N ~r D ~o N IN` ~ o co ~ o co o er cn co o -o N _ O N 2 N ~n N 0~ _ _ O c0 C0 C0 1~ _ ~ cn I d cn r~ _ ~ _ ~ n ._ C
N :>~ n o N ~ n Ln ~r N n cc~ O, ~ ~n _ ~ C
¦ CO N `'`1_ CJ~ `D ~CO cn N ~ ' I ~ n o O ~ I` ~^ ~ O
~ L~

~; 3 ~ t~
_ _ + ~. I~ c ~ ~ ~ c O ~0 c C O

a ~ ~ ~ ~ v . c y a ~ c a ~ ~ ~ ~ a a e ~75--, . ' .. . .

. .
: :

~L~Z3~

While relatively stable polymer/polyols can be made rom monomer systems with relatively high styrene contents, Examples 144-147 demonstrate that, ignoring any possible ::
effect created by the change in polyol, stability is improved by significantly increasing the stabilizer concentration, allowing preparation of stable polymer/polyols with 70~ styrene in the monomer system at polymer contents up to 27.7 EXAMPT.~S 148-155 . . _ These Examples demonstrate the preparation of polymer/polyols having relatively high polymer contents (viz. - 24 to 36~) at acrylonitrile/styrene ratios of 30/70.
`~ The experimental conditions and results are tabulated in Table XV:
-:~ :

; , ' ' ' ' '':

^~.23~i~36 1û687 o~ ~ ~ ~ ~ ~ o U~l ~ o o'1o ! ~

N O O I O

o~ ~ o . . ¦ ~ O ~
1~ ~N ~0 O O O O 0~

8 ~1' o ~ ~ o~ O
- r-l--I H t~ ~0 ~ O O O I O ~ cr~ 0 o m o m ~ c~ I o ~ 0 ~ ~ ~ I I 1 0 .tl~`J ~ ~r oo I ~ ~ ~ N ` ~ ~ I
_I ~`1 0~1 ~ O O O I O a~ ~t~ . ~ I I N

~r~o~ oo~lr~ 8 ~
o o ~I m cn I ~ . . 1. . co I I 1 0 u~ ~ ~7 o o . . . I . co ~ I I I .
_I --I H ~ t") ~ ~0 0 0 0 1 0 a~ 0 N I I I _I
i~3 I` N N ~I CO~ l C~ I O C
l~i ~1 ~ (X~ ~ 8 ,~ r;
_i H _I N ~N ~ O O O O a~ N ~ I

O~ O ~ I ~ ~ o : ~ ~ ~~ O O ~ I ~ ~ ~ N ~
.~ . ~ o o o I o a~ i . ~:

:;'' ' .
.' .
~ .

u ~ _I
3 ~

a~a~2~55~ à~55 ~ aa- ~ 5 ~ .

~.2353~

While the filtration hindrance characteristics are substantially less than optimum, polymer/polyols with satisfactory viscosity and centrifugible solids characteristics were formed in all the Examples.

These Examples further illustrate the preparation of polymer/polyols using a monomer system in which methyl methacrylate is employed with various styrene and acrylonitrile monomer systems and also acrylonitrile and styrene alone.
The experimental conditions and the properties are set forth in Table XVI:

~.

' ' ~ .

!

.

.3~ 3536 u~ -~ ~ ~ ~ 2 ~ o o o " , Ln ~ o~ ~ ~ ~ ~ o ~ o .
I ~ ~ , ~ ~ m a' ~ ~ ~ ~ O ~ o ~
_1 ~1 ~1 i O o ,1 ~ ~ c~ I I r- 0 ~

1-~ ' ~ o O
r~ o ~ ~ ~ ~D ~ ~ ~ I ~r ~ . o o c~ o G~
- ~ _1 r~ . ~ O O O O ~ o Ln ~
. . .
' .: .
o o ~I ~ ~ I ~ I In a~ ~ o o o Q~
~1 ~ ~ ~ O Y~ O C~ D O tS~ o . ~ ~ ~ ~ O o o I o cr~

o~t- _.. .
.. ~ ~ ' `
0 ~

99 ~9 _79_ ,, 3~36 With the stabilizers used, as can be seen by comparing Example 158 with the other Examples, a less stable polymer/polyol is formed when no acrylonitrile is used in the monomer system.

These Examples show the preparation of polymer/polyols in Polyol I with a monomer system containing relatively high styrene content.
The experimental conditions and resulting properties are set forth in Table XVII:

.~
i :' ' . ' , ~.Z3536 : ~ ~ ~ ~ ~ ~ ~ U. c~ ~ o o ~ ~ 0 ~ ~ ~ ~ ~ ~ ~ ~ 3 .~

~ o ~ C~ ~ ~ CO ~ ~ o C~
H ~ i ~ U') o ~ Cl o 5~ C~ C~ ~ _I r ~ _i I I I I o .~ . .
:; ~ U~ ' ~
c o~ o~ C, a~

~ ~

~I ~ O o r~
Z~
~ ~ ~ r~ o o o ~ ~ c~r ~ ~

~
- ~ ~ a 3~DD~ a - O ~ o D ~ a .. . . . . . . .... .. . . . . . . . . . .. ...... . .. . ~ . . . .. .. .. . ... .... . . .

~ 3~3~ 10687 This further illustrates the formation of stable polymer/
polyols using high styrene in the monomer system.

These Examples illustrate the preparation of polymer/
polyols in Polyol V, employing the procedure described in connection with Examples 119-124, and compare the efficacy of - stabilizers made from a solvatable portion having terminal unsaturation (~.xamples 168-171) and those made without terminal unsaturation (Examples (165-167).

10The experimental conditions and results are tabulated in Table XVIII:

, ~
. ,' ~.235~6 ~ '7 0 o ~ ~ ~ Q C~ o ~ I O O r7 ~ ~

.

~1 ~ ~ ~ ~ ~ ~ ~ ~ c~ ~ o o ! ~ ~ ~ ~ N _1 1 ~ U:l ~ ~ ~

~ . o 1~ ~ ~ ~ o ~ o o I ~ ~ o ~ ~ ~ ¦ ~ O ~l o N ~

~ _i ~ ~ o ~ o o ~ ~ Q U~ ~1 1` ~ ~ l ~
, ~ r- 1~ ~ o Y~ ~ ~ o In O
,1 ~ o ~o I o~o~ r~ o~ o~ O

~D O ~ ~ N ~ , o o o ~.~
~ o_lo l oa~ ~~ ' ~ ~ ' ~ o ! o 5~ ~ ` ~
~ tl ~

Y ! 39.s e3 3 ~ ~
3`Y~ 3~ 3 ~ ~ ~ 9 ~e~9~ ' 3 Y9 3 ~ ~ 9 ~ ~ ~ 3 ~ 4 9 3 a ~ g ~ y ~e ~ e ~ S Y~ 9 -g ~ Y ~ 3 e s ~ 3 e 3 .

Z3~6 As can be seen , both types of stabilizers are effective although, at the concentrations utilized, a comparison of Example 170 with Example 167 shows that the stabilizers having unsaturation in the solvatable portion provide improved results when the polymer content is higher at similar stabili.zer levels.

These Examples show the use of polymer/polyols to prepare flexible foams.
Examples 172-173 and 176 177, wherein the polymer/

polyols were prepared using stabilizers in accordance with the present invention, can be contrasted with the remaining Examples wherein the polymer/polyols were prepared either with a peroxide or an azo catalyst and no stabilizer. The ;~ experimental conditions are tabulated in Table XIX:

: :

-8~4-~o~O oO.~ ~ 106~7 -0 ~ r) N 0~ O O n ~
0 l_ 0 N C~ g I '1 (~1 O ~t I~ t'') ~ O ~ I ~ O O ~ ~ ~ O

O O U- CO
~I C~l O~ I g I ~ ~ CO V
d 11~ _I C~ O ~ I ~ O O ~ o ~0 ~ U~
CO_~00 01~ CO
- ~U~ o ao ~ o I --'--' 0 et G` ~ ~ O _~ I ~ O O
: ' CO O O~ + ~
--~ I o O r~ . g I O--~ N O O
J C v~ I ~ O O ~ ~ ~ V~

Q~ , I~ co + 'O q~ o ~ ~ 3 N O ~ ~ ~ _ ~ g I O ~ N O ~ ~ o ~ ~0 `.
Ln I ~ r~ ~ o ~ u c ~ I et O o C'- 0 j . ~ ~ ~ a~ c X ~ O ~ ~00 X
L~JeJ ~ ~ ~ o ~ E ~
r o o ~ g I ~ ~ a? L e~ 3 e~l-- O ~ I ~00 , ~~ ~ l Cl V~ ~ I ~ 0 ~ V
--' ~

c~~ I~ ~ ~ a~ o r~ ~ X
_~ou~o~ ~-~ g 1 ~ ~_ v~, ~ _~ I ~ o O ~ O e ` ._ ~ .
~ .
.~. q~ .

~ ,, e ~
', .
. I~
V~
~ n ~e , ,o ~; 3 ~
.. ~
T ~ ~1 1~
O` ,~ O r~~
E ~` -- O ~ ~J ~ ,I~
O V O ,_ >~ O ~ ~ ~ . E ~
: ~ o O z VC ~ ~ O OV~ ~llJI.- O
q) _ >, ~ v~ o _ ::, ~ v c E v aJ ~
a~ ~ x ~ ~ :>, ~ ~ ~ . ~ O o ~ ~ c s c E ~ LO c~ ~ E ~ ~, ~ ~ c ~ = ~ ,_ ~ ~ , o vl . ~ o ~ , ~, ~ ,o . o v- ~ _ _ X ~ ~ CC O ~ ~ V~ ~ o ~ ~
.

~ -85-~`.Z3~36 10687 As can be seen by comparing Example 172 and 173 with Examples 174 and 175 (where no stabilizer was used), satisfactory foams were prepared with the 30/70 acrylonitrile/
styrene polymer/polyols made with the stabilizer while top splits and powdery foams resulted from use of the polymer/
polyols prepared with a peroxide catalyst and no stabilizer.
The physical properties of the foams which were tested are tabulated in Table XX:

3~36 o o~ C~
o~ O ~ o r~ O ~ ~ ~
_, 0 ~ ~ U~ o o o ~D ~ O ~ ~ O
C~ o U . o .o~ . o a~

U~ C~ ~ o . ~ ~ ~ o o I~ ~ O

,~,,, 0~ CO ~ d' Ct C~ O 0 r~. ~D ~ ~ O U~ r~ ~ . u~

t~ d` L~ J ~ N ~) C

N ~ ~)_~ O 0~
oo ~) u~ ~ oo oO r~ E
~1 ~ N N ~D O ~D I~ O N w C
X ~ C~ l N t`') 0~ 1~ ~
00 N ~ ~ CJ N a) ~' Q
~ . .
-- ~ S
O ~

:~ ~D X
o r~
:
~--I X

o ~ O N
, ~ ~n ~ O ¦ C ~ o ¦ ~ C C
O ro ~- ~ c o c v) o o ~
.. ~ ~ O O ~ ~ ~ E~-~ ^ O -- u7 o o o c~ r~ u7 o a~ s ~ u ~ ___ ~ ~ aJ c~ C~
1~ ~> O ~ _ O O O ~ ~ O O O ~Q
Q ~ ~n - L~ 5) O O C: ' _ X O ~ ~ -- ~) O ~ N ' 1~ 1~ O 5 1:~ ~ 1_ ~

:
-87- ~ ~

3S3~

The ILD values in all instances were satisfactory.

These Examples illustrate the improvement in discoloration resistance with foams prepared from polymer/polyols in which the acrylonitrile/styrene ratio has been reduced from 50/50 to 4Q/60 and 30/70.
; The foams evaluated were made using the polymer/polyols described in Table XXI:
~.' .

:

: : .

~a~.z3536 ~ j~; o o _ i ~o o~

d :
....

d ~ d --89-- t ~ 3~6 10687 Foams were prepared using polymer/polyols A-D, and the foam formulations and the resuLting discoloration characteristics are set forth in Table XXII:

~ 2353~

~ABLE XXII
.
`:
Ex~l~le No. 1 189 190 191 Polymer/Polyol A B C D
phr 100~ 0 100. 0 100. 0 100. 0 Water 6.0 6.0 6.0 6.0 Urethane Ca~alyst 0.07 0.07 0.07 0.07 Silicone Surfactant II 1.2 1.2 1.2 1.2 Stannous Octoate 0.20 0.20 0.20 0.20 ~ : :
TDI Index 105 105 105 105 Height of Rise, inches 26.0 25.3 24.0 24.0 Nopco Breathability, SCFM 3.25 1.30 1.95 2.25 :.
Density, pcf 1.02 1.04 1.11 1.09 Reflectometer Readings:
Top 59.3 71.5 78.3 74.6 Middle 56.8 71.5 77.4 72.7 : Bott3m 61.8 74.6 78.g 76.2 Bottom-Center 5.0 3.1 1.5 3.5 . .
; As:can be seen, the data shows a general trend of decreased scorch : with decreased acrylonitrile ccn ent in:the mo~omer system us~d to form : the polymex/polyols.
.: :
: ~ - EX~MPT,T'S 192-195 These Example illustrate the use of various anchor portion ccmpositlons . ~ ~
`~ in preparing polymer/polyols using the procedure described in EXamples , 119-124 and Wlth a 40/60 acrylonitrile/styrene nencm:r system. m e `~ solvatable portion in ~ les 193-195 consisted of polypropylene oxide material III condensed to form an acrylate. Polypropylene oxide ~aterial :
: 10 III was used in Example 192~without mcdification.
Ihe experimental conditions and results are tabulated m Table XXIII~

$Z3536 ' 10~87 1 o ~ I ~ '9 ' t~ ~ ~ co ~i ~0 ~ W ~1 H ~ o "~ o O

g 3 to '~ ~
a 8 3 3 8 ~ a ~

y ~ ~ Y ~ a u~ ~ ~ 3 = ~ 3 3 a ~ a 3 ~ D

--92-- .

~.23S~

While the viscosity and centrifugible solids level of all of the polymer/polyols were satisfactory, only the Example 195 polymer/polyol exhibited the preferred filtration hindrance characteristics.

These Examples show the effect of increasing the amount of monomer used in preparing a 40/60 acrylonitrile/styrene polymer/polyol. ;
The experimental conditions and results are tabulated in Table XXIV:

~ .

!

~, ~ 5~

o ~ C~o ~ o ~ U~
~1 ~1 ~) el ~ el~ -1 0 0 1 01 Cl~ I N d~ N ~ O ~ C~l o o O ~ O C~ ~ O ~ ~1 0 0 C~.l I C~J ~O N O I ~ 1-'> ~t ~ ei O ~--I ~ O ~> -1 0 ~ ~
~0 -OO O r~ l ~ O ~ O
1~ 1~ ~ ~D ~ U d l_O C~l 1~ ~ ~ t~ O cn ~3 o .
cr u~ ~ _ ~ _ r~ oo ~ 1 0O o u ~ 1' ~ '' _I~ L~ t~ ~t O O O I a~ I N 1~ 00 ~ _t c~
O 1~ 0 cnl ~ _ O C~J ~ I . . . . ~-1 . O N O ~ r--l O C~.l O r--l ~) N r--l 1~ a~ ~) ~ O CO r--l O 1~) O
1 0 a~ ~.c o ~
X

Xl 103.
o ~ o O
O ~ ~ ~ ~ ," o Q
~ 3 ~ ~ ~) E
o a~ ~ o ~
~ ~ 3 2 ~
c~ . a. a~ _ o ~ t~ ~ ~ ~n L ^ o V a~
.-- ~ o~ ~ ~ ~ 3 ~ ~ , ~ ~. ~
~8 ~^~ s~ ~_ ~ ~ ~ E s- E ~E --~ O r~ ~ ~o r~ ~ _ O ~
o~ ~ ~ ~ L ~ ~ ~ ~ 3 L C c aJ ~ ~ . Q. ~ ~ O o ^ E ^ ~
~ ~ o ~ O a) .--~ ~, ., ~ ~ z _ c ~ O aJ
S_ ~; c t L o ~ C aJ O a~ ~ s~
L ~ O ~ ~ ~ -- Q ~7 :~, c ~ ~ Q~
~_o~ ~-,-_ ~, e ~ ~ ~ x ~ ~ u ~ ~ o~

~ a~ 3 ~ c O ~ O ,o ~ ~ ~ O ,0 ~ a~ o o a~ -- O o CC o ~ S. L O-CJ r L c a~ O
~ ~ _o S,. ~> ~ ~ ~ O ~) ~ O ~ r E 3 L - ~ - o o ~o o ~ a~ Q ~ ~ L .
o o ~ O v~ ~ 8 E O ~ ~ s ~ ~ r Z .~ N C ~ r8 a)o ~) O Q~ ~ r r~- r-- ~ >~ al O ~ n ~
~ C ~ ~ o . ~ C C - ~ ~ o o o ~ ~ ~ ~ ~ 2~ 0 .-- ~ ~
r_ ~ o C . r ~ 3 ~J z a~ L '- ~ ~ r- O ~ s o sO~ o 1~-- O O
~:L ~ ~> 1~ . L ~ E~ O ~ ~ O ~ s_ O O s_ t~ e E CL 1~ ~ o ~-~ ~ s o ~ ~ o a 1~ ~ ~ ~ ) O ~
~ ~a o /a eS ~) C ~ V~ c~ ~ ~ ~ o v~ _~.
~1~ ~ ~ U~ ~ r8 O O O O ._ _ ~ r-l :

~4 ~3~

106~7 As can be seen from Example 196-198, while the vis-cosity increased with increasing monomer content, acceptable filtration hindrance was provided, up to a polymer content of about 40 percent.

These Examples illustrate the preparation of polymer/
polyols from a monomar system with high styrene content and with various stabilizers and with varying monomer system contents.
Experimental conditions and results axe tabulated in Table XXV:

':

_95_ ~:

o ~oo Ln~ ,~ ,_, 10687 ~ l Ln ~r~ n O 1~ 1~ o~ ~ n N ¦ NO e~ O ~1 O I ~ a~ L~l ~ ~ ~ N _ et ~ 1 NO ¦ L ~--N . 1~ tl:l n I D~ 0~ 1~ ~ NN C~l O 1~ ~ O rD

o~ ¦ Ln rD_ O . _ ~ O ~D ~ ~D ~ 0~ ~D O~D Ln _ CO ~n ~Ln ~ ~ ~ ~ Ln ~n a ~ ~ N ~ o N ~ n ~ N ~ o - I c; I Ln Ln ~ ~ ~ ~

o l n ~--o -- ~ ct~ o L - ~ Ln ~ ~ a:l ~ ~ N d' I I I N "~ --N ¦ n ~_ N _ CO ~D o I o 1~ ~ O Ln N N o _ D N ~ ->

Ln Lt~--CO O--D~ ~ o ~n 0~ ~ ~D O O O _~ E
N ¦ _~ _Ln ~t N (~ O N O I CO CO ~D ~r N_ et O ~n c~ O O
O o l~ l~ d ~n ~n N ¦n ~ --d O r~ C~7 N N ~I d` .--1 N ~n ~ ~o O N O O ~ ~ ~ ._ o ~ o ~n ~n ~o cn N
~ l~n ~ r~ n t~ ~ Gl 1~ r~ ~ n oo æ . O D O ~ O
--I N ~ ~ N 1~ 0 _ O I 00 CO O ~ N N ~ O 1~ 0 , 11~ Nn ~ 7~ o I ~ r~ ~ ~ N . O O O n ;~ N ¦ _ ,_~ d- N ~ O _~ O 10 co r1 N~ ~ ~ ~O O ~ O~ O ~
~nt ~ n ~ ~n~ N ~ N '~ :
o l N .n ~ N O ~ O O ~ ~ O _ N N ~ 1~ N ~ O ~ C
d ~ O 1~ N 1~ ~ CO ~ ~n ~ o~ r~) O O ~D N ~ e Vl O j N . ~ O-- O ~ ~ n ~ _ , ~o ~o oo --'~
~ o - -- . o L L L L
O ~ 10 .0 ~o o ~o ~ ~
_ . u 30 .. 3 ~ ~ u I E u a~ Q) u u o a~ ~ ~ . ~ 3 ~ . T _ O O O O
'_ ~ Q _ O U (~ ~ ~ L L L L
_ L ~ c U 3 N E~L E vl t: ._ . u o o O O
O~1 0 ILI~ _ ^ L ~ L U . ~ U~ U C~ D_ n.
L L ~ _ -- C L O _ ~O ~IJ ~ a) V~
o >~ O ~ L _ ~V~~ c ~ 1) ,_ o I I I C~l _ V)- O '-- '-- ~ ~ X ~ C U C U _ CL O N ~ CO
rao ~ _ c c ~ O _ >, L t ~ ~J U C U ~
~ ~ u ~ ~ ~ l~ u~ u o o o-- u~ o u ~ E ~D I T V l V') L '1~ n ~ v, zo O L C aJ 1~ Uo ~ O QJ ~L) ~ ~ '- CJ O ~ V ~ _ "~ ~ o y U ,0 ~ ~ ~0 '~ --~ .~ ~ ~ S 'O ~ 'O ~ O X X X X
U . ~'-- ~ O ~ >~Vl 3;, ~ _ ~') o~ oO U) _ v~
~ u ~ ,~ o o -- , . 5- ~ ~ ~ o ,a ~ n~ X u ~ n ~ ,.X L 'I ~ ~ 2 aJ ~ ~ DL -- ~ '-- aJ

~1 -96-.

~23S3~ 106~7 Stabilizers are effective, as can be seen, for example, from Examples 204 and 211, regardless of whether or not the solvatable portion was made from a macromonomer condensed with acrylic acid. Somewhat more stable polymer/polyols at higher polymer contents can, however, be achieved at approximately equivalent stabilizer contents with the acrylate mode as can be seen by comparing Examples 206 and 207 with Examples 210 and 211.
~A~ r9 ':~ ~
These Examples illustrate the preparation of polymer/
polyols with stabilizers prepared with 30/70 and 50/50 acrylonitrile/styrene anchor portions and with varying solvatable portions.
The polypropylene oxide material used for Examples 212-215 was material III and was a monohydroxyl propylene oxide produced from propylene oxide and butanol; the average molecular weight for the polypropylene oxide material of Examples 216 and 217 was about 2555. In Examples 212-213, the macromonomer was prepared by condensing 1 mole of maleic 23 anhydride per 1 mole of the polypropylene oxide material; in Examples 214-215, 1 mole of ~DI was reacted with 1 mole of the polypropylene oxide material, followed by reaction of 1 mole of hydroxyethylacrylate per mole of the TDI-polypropylene oxide material reaction product; and, in Examples 216-217, 1 mole of TDI per 2 moles of the polypropylene oxide material were reacted to form the solvatable portion.
Experimental conditions and results are set forth in Table XXVI:

o o ~ o 1~ u~ 1~ ~ o co r~ o e~ O
C~J N o t~ o o d~ 1~ ~ ~ O g ~ ~1 ~1 ~ ~--- ~ N O O O O0~ ~1 ~ ~ ~ A

O O U:~ O
~ 1 o o r~ t~ ~ ~ C~ r` o o~ N O IS~ N
C~l ¦ N ~ O ~ O O o ~ O Ln .--1 . ~ -_~ ~ N O O O C~ ~ ~ ~ ~ ~

Ln ~~ O C~ ~ O ~ ~ 00 _I O O _ 00 ~ ~ o o o a~
N N O N O O ~ 0 00 N 01~
.~ ~ c`J o o o o a) o~ ~ N O

~O ~ ~ O ~t) O ~O g t~
O O ~ N ~ L~7 ~1 . ~ O C~l O a~
~ O O O N a~ ~ O N ~I N ~D

:~. ~ 1n ~ o ~ $ g ~
X ~--1 O ~ CO ~ _ O 1~ O O N ~ 1~ >, X N ~ ~ ~-- ~ N o o o o 1 0~ ~ A

I_ N 1 1`. ~ ~ N _I d- O N O O 0~ 01:) ~ -~ ~r c~l o O O ~ t A ~ O O -U
:~ (O
:~ ~ . S ~
3`~
:: aJ ~_) ~
:~ ~ a~
~, .~ ~,1 3 . ~ O C
, a~ ' ~, o O C _ o ~-.,._ ~ o ~ C C
C~ G~ V) r~~7~ i L ~ G 3 '' ~ a1 o ^ E ^ . ~ c ~ ^ ~ O O
al o s_ O ~ _ o,- ~o~ ~ a~ E~
s_ ~ ~_~ S_ E S~ ~ 0 _ L v't _~ ~ O .~ Q n , c~ S ~ ~ ~ a) a) o 1:50 o c v~ ~ , ~ 5~ o ~ ~ ~
c ~ ~ ~n o >~o O 5_o ~ ~ O ~ ~ ~ ~ O O O
0 ~ 3 ~ ~ ~ o aJO C 5_ C L C c c c E 3 ~ L ~ U 5 S_ ~ 5_o o o o ~ C~ ~ I V~ Vl L ~ ~ -:. . C ~ ~ ~ o aJ 3 ~ o ~ ^ E O ~ S ~n 2 t~ C ~ O . ~)o â) a) o a~ ~ ~ ~ o 5cn ~ us7 ~ ~ '~
~ c ~ ~ o ~-- ~ c ~7 . c ~ c ~-- c ~- o ~ ~ O ~ r~
a) a o c ~ . a) o o L ~ a~ n a~ ~~ Q ~ ~ ~ ~: O ~ _ O
E Q ~ O ~ ~ ) , c oO a~ ~ ~ 5 0 0 5_ a) ~ o ~ c ~ ~c ~n ~ l~ C ~ ~ ~ o ~n ~ ~ ~ c _ ~ s_ a~ r~ ~ ~ ~ O a) O o 5_ .~ ._ a~ ,a 1~ ~ c~ E Q t~ ~~ CL ~u_ <~
.~ .

'''' -'''' ' ' , .

:~.Z35~3~

o o I_ ~ In N ~ Cl:l cr O . ~ O O . . . . ~ ~ 8 ~ ~ o ~
rs ~ ~ ~ c~ o o o c~ O

o o o l O ~ ~ O O ~ CO cr~ o O ~ ) o cn ~9 O ~ --~ ^ ~ - - O O O O
c~ ~ u~ J O O ~ ~ o ~ o . .
~ O ~ O 00 ~ 0 ~_1 o o ~ o N Ll?
N N O ~ C~J O O I ~ ~ '~ 0 C~l ~ ~ ~ ~ 0 0 0 1O~
O
C~ o co ~ ~
c~ I ~o o O ~ ~ o O ~ 0 a~ I I g a-O ~ J C~
a~ o o ~ o c~
x _, ~ .~ ~ ,i~ ~~ ~ o o o C~ cn ~ a~ 'J` ~, ~ cr) ~ I~X
. ~ ~ ~ ~0 C~O
. ~ ool C~ oo - - - ~ c~ g c~
C C~l O O O C~ i :~ "
: a~ ~
c L~ ::
.` " ,~ .

. 3 E ~I -- = s E~ In E e =
E ^ ~ ~ c ~ S = ~ ~ O ~0 C r c ~ _ c E E ~
Q ~ u ~_ 3 ~ ~ O o _ E ~
z . a~ o ~0 â a) o ~ ~ o ~ ~,_~
. . o c ~ ) ~ jZ a) >, F-- ~5 O ~O O S
o ~ ~ ~ o al ~ ~ o ~a ~ ~ O ~
~ a~ ~a o ~ ~ c ~ .. - c u~ v~ ~ ~ m ~ ~ ~ ~ o .J7 .--~ ~ ~ ~
I~J cr~ ~ 'J ~ ~ ' ~ ~ .
. `
_99_ , ~L~.235~

As sho~, the stabilizers using the various techniques to form the macromonomer provide satisfactory stabilization.
The technique of Examples 216-217 provides a further processing advantage in that stabilizers of the frea radical mode can be formed at relatively lower temperatures, e.g., 100C.

These Examples show the use of stabilizers wherein terminal ethylenic unsaturation in the macromonomer was accomplished by conventional ester interchange or transesterification and illustrate the effectiveness of these stabilizers in relation to stabilizers produced using acrylic acid condensed with polypropylene oxide material III
and also as comapared to stabilizers formed by the free radical grafting mode.
Experimental conditions and results are displayed in Table XXVII: .

,~.
.
, '~

-100~

106~7 3~;3~

o o N O ~ _ ~) ^ -- 1~ C~ ~t IS~ . ~ O O O 1 c~ ~ ~ O ~ o o ~ ^ o ~ ~ o e~
d- N O O O C~ '1 ~ ~ ~ ~ ~ O

CS~ .D O
C~l o ~ _ ~ ~_ ~ 1--~ ~ . ~ O ~n c~J ~
C~ O ~O O - - .~ ~ ~00 ~ O ~ L~l~ .
l O o o c~l o~ ~1 ~ A IS) U') O Cl~
C~l C~ ~ O O O O-C~J C~ lO O o _~ o I co 00 a ~ I ~) ~ cr~ ~r) ,;

O 00 0 C~ O
N I C` l O C~l O O C~ D ^ _~ N

CO O~ O 00 0~
N O O `~ ~--` _ O 0 d' I ~ ~ ^ 00 Cl~ I I O al :
~J c~J . o . .-1 o o . . . I a- 1~ Ln co 1~ ^ ) I o _I ~ Ln ~1-- 5`~ C~l O O O I O~ I I o ~ ,~

~ 1 d' 1,9 ~ N O
:` ~ O O ~ 1 0 C~
~_ C~J c~l o ~ o o ~ o a~ ~ r~
~ ~ ~ l O O O c~ ~ ~ I~ A
X . ,~
:, X
~ ' ~ ~.n o~ ~ Og ~ ~ ' .. C~ ~_ O C~ -- ~ ~ ~ U ' ~ O
C~J C~ JOOOC~ n~ ~ '1:3 , ~
C~
., ., ~ ~ .
.
. O n~

~' . 16~'3 O C _ o . ~ ~ O
o ~_ ^ F Vl E ~ ~7 o ~_ ,, '~ ~ ~ ~ o c F ~ ~) ~ ~ :~
q_ ~ 5'` ~ v~
~ O o _. ~c ~n _ c... ~, ~ ., v ~ J v7 0 ~' ~ ~:` ' c ~ 3 ~1 o :~ o ' o ~,~ ~ o ~ ~ al ~ o :7 o o o ~~ ~ 5., o c s ~: 5 c ~- c- c F 3 5~ o o o c ~3 0 S_ I ~ ~1 ~ C a~ o Q~ 3 t.) o ~ ^ E O ~ Vl S v o o i-- ^ ~ ~ QCC E c~ c ~ ~: ~ ~ s ~ ~ , .~ z .,. ~ ~ c , v) o ~ ~0 a) a~ o ~ Q~ L ~ O ~ .~ V) ._ cn Q~rts C N O .', ~ ~o o r 1~ ~V ~` a) ~1> a~ ~ ~ X O ~: _ O ' ~I ~1 ~) r~5_ -- O r ~ ~ ~ ~ 5_ Z ~ ~ 5~ u~ o V~ ~
Q ~ ~ t~ -- 5_ ~ ~ O E 0 >~ V~ C ~ >~ o 5_ r~ O
e Q. ~ ~ v-,- C O ~ ~ O (:L) > ~ O n3 ~ ~ ~ U'~ O ~
~:1 a~~:5 o ~ cl u~ ~ ~ , c ~ tO 1~ ) ~ O ~, ~ 1~ c X ~ 0~ ~ O

, ~3S~6 10687 Example 218 demonstrates that utilizing transesterification provides a further useful alternative technique for preparing satisfactory stabilizers.

_ ; These Examples show the effect on stability of polymer/
polyols prepared from a 40/60 acrylonitrile/styrene monomer system caused by varying the composition of the anchor portion of the stabilizer. The solvatable portion was formed by condensing polypropylene oxide material III with acrylic acid.
The experimental conditions and results are tabulated in Table XXVIII:

-10~-.

353~i 10~87 ~ D CO O ~ ~D ~ ~ O C~ O CO
~1 ~ o ~ o o . ~ co ~_ ~ ~ ~~ ~ O O O ~ O~

o o ~ o U~
¦ 9 r-- _ ~1_ ~ N ~ O ~ ~ ~ O C~ C~J
o o ~ cr ~ A N N .--1 Ln ~D 1~ Lt O ~ 0:) ~ 1.~> 0 N I C~J O O O ~ CO U~ O
_ O 'S3 --1~ N O O O N ~ ~ CJ ~ ~

O O ' O O
a- u~ ~D ~ O ~ D O
N ~ O
C~l C~l O O O ~ D cn ^ o ~ ~ o ~
u~ ~ ~ c~l o o o c~ o ~ O t~ O ~ .D 1~ N I I I
C~l --I ~ ~~ C~l o O O ~ d a~ ~ a~ ~ cn Ln I I I

O ~~ ,~ ,; O ~
N O ~) ~ ) N et LO ~ D O ~ O O L~
~ ~ ~ ~ 2 c~ O O O N ~ c~ ~ ~ ~ ~ ~
o CO v~ ~ ~D CO ~ O ~D t~ ~ N 1~ g ~) O O
N O O O ~ ~ C~ ~ ~ ~ ~ N ~ O ~) ~) X
tJJ D ~ r C~ C~ ~ CO ~ N
~ ~I c~ ~ o o ~ ~ ~ oo ~ a~ C ^ I I
o o o ~ ~ a~

o o o C~J
0 ~ ~'J N O O O ~i C7 ~ Ct~ ~ ~ 'S ~1 1 1 (~ .

~-- E ~ e 3 L o .-- . ~ ~J ~ _ c~, S ~ 3 o ~-- o ~ c ~ ~ ~ C ~ U ~

u s u ~ ~ C ~W ~ a ~_ C ~ " E ol u ~ _~ c cl X c~ ~

~L~.Z;:~36 As seen, Example 228 demonstrates that a 30/70 acrylonitrile/styrene anchor portion is to be preferred for a 40/60 acrylonitrile/styrene polymer/polyol. However, as seen from Examples 229 and 233, anchor portion compositions with increasing acrylonitrile content up to 80/20 provide polymer/polyols with satisfactory viscosity and centrifugible solids contents at the stabilizer levels used.

These Examples show the effect on the stability of a polymer/polyol prepared ~rom a 20/80 acryloni-trile/styrene monomer system of varying the composition (i.e.-acrylonitrile/
styrene ratio) of the anchor portion. The solvatable portion was made by condensing polypropylene oxide material III with acrylic acid.
The experimental conditions and results are contained in Table XXIX:

31 ~!.;~3~36 10~87 ~J CO Ul ~ ~ N u~ 1~ ~ O
~-- o . O O ' 'D ~ ~ I I I
~ O Cl~ l ~ O C~l O I 01 ~0 CO ~ _I O CO I I ~ U

d l NO ~ o~C~o ~Od O) I ~

l o ~ooo~O ~ Oo D ^ Uo~

I O O Ln 00 oo ~, a' ~ I ~ . . . . O^ I ~ I I ~ ` .
c~ o ~ O I O~ 0 a~ I ~ O ~ ~ o ~O O N O ! ~ ~ ,~, ~ ~ o ~ ~ ~ ~ ~

D ' ' ' , o~ ~ ~ o~ ~ ~ 0 U~ o ~ o ~1 ~ ~ ~ N 2 o ~ o ! a~ oo ~ ~ ~ ~ .~ ~ o ~ ~

~ ~ GOO ~ ~ ~O ID ~
x ~1 ~~ O~O~oOa`~o !a~~
, 1_ ~ ~ $' O N ~ 0Lr) ~ O ~ ~
~1 ~ o~~0~o !~~ ~ ~~

C~ $ ~ ~ ~ ~ ~ a~ 8 ~1 ~ ~o~~~o~O !a~ o~A~

a) D

5~ e b ~

^105-~ .

~L~Z3S36 The centrifugible solids characteristics of the polymer/polyols prepared in Examples 238 and 239 in comparison to the other Examples indicate that, for optimum stabilization,.an anchor portion of 40/60 to 50/50 acrylonitrile/styrene is to be preferred.
EXAMPLE5 243~245 These Examples demonstrate the stabilization in a 40/60 A/S ratio polymer/polyol by a stabilizer wherein the anchor portion comprised acrylonitrile and a comonomer other than styrene. The solvatable portion was formed by condensing polypropylene oxide material III with acrylic acid.
Experimental conditions and results are contained in Table XXX:

., i .

' , .

~A. __ _ __., _ .. __ . . _ .. _ .. , . . . . . . . _ . .

;3 U~ I o o CO o CO
O ~ ~ N d' N ~ ~ ~ ~ ~ NO o o O ~) .

, ~ .

N _ .
d- ~ ~D ~ ~ ~ d tr~ O cn Cl~ 8 D co ._ ~ O _ ~ _ ~t ~ ~ ~) _I N II ~ 1-N N O O O ~ ) ~ ~ ~ I
I O O O ~ ~ ~ O~ N I I ~
' 'O
. I ~

D 00 d- 1~ CO ~ O ~ _Io o ~ O --~ _ N t~ d' ~1 N 0 0 li ~t ~ 1 X N ~ ~ ~ ~ ~ N O O O ~ a ~ ~ N el~
X
: :
. . E
,: ~ ~__ : ~
:~ .~ : :
`: ... ~ u U : ~
O ~ ~:
a) ~ C-~> O c ~ ~ Ln c E 1~ E ~
c~ O Q~ c~ ~ _~
O , E a~ . O c- E C _~
c O ~
c c~ E ~'~ E c '-- 'a~ ..
o ~ ~ ~ ~ ~ c .~ c,~ ,, c~_ ~n o S_ C~ ~ ~ O ~_ ~ Qlq_ ~ C U~ o " ~0 S ~: O ?~0 ,0 o o ~ o _ ~ o c c_ o ~ ~ o O ~ aJ C ._ ~ C~ ~ Cl~ Q~
E ~ cS ~ s_ ~ ~ ~ LJ O O a~ Q a~ ) S ~ C
o ~ ie ~ ~ ~ ~ E 3 c~ o c~ ^ E ,o ~ c ~ ,~ , E
Z .~ ~ q~ ~ , o ~ CiJo a o c~ a~ ~ ~ ~ O ~ ~ O
~ c: O $~ o, - ~_ c ~ ~ cc ~ c e o ~ , a~ o a) _ o ::1 c ~_ ~ -- O -- ~ D ~E. ~ 3 Z 3 C ' 0~ 0 r^ ~ ~, V1 ~ o V) ~ O
5:~ ~1 ~ O O E 3 O ~ Q O
E ~ ~ n ~ o_ ~ s o ~ ~ o ~ ~ ~ ~ o . ~ ~ ~ O ~ ~ v~ ~ , s:: U ~ ~ ~ ~ v- c~ ~ o u ~ ~ r~
c~ c~ cC X ~ c~ ~ ~ ,,, ~ :

,~ .

: ' ~ 10687 The data indicates that optimum stabilization is achieved using ethyl acrylate as the comonomer for the anchor in preference to the other comonomers used.

These Examples show the preparation of stabilizers of the present invention in the equipment described in connection with Examples 119-124, followed by the use of the thus-prepared stabilizers to form polymer/polyols in the same equipment.
The experimental conditions and results are set forth in Table XXXI, the solvent, solvatable portion and catalyst being added as one stream and the monomers used being added as the other stream:

~. ~

1~6~7 `.23~;3~

a , o X o c Q E
o ~ ~ C C
L _ _ ~ O L~ O _o ,~
C~l I C~ E " c o ,_ ~ c~l u~ ~ ~ r~ I I I I I ¦ . ¦ I I ~ I v~ cn r~
L~ ~D O
~ E
~o ~ O
æ ~ O ~ ~n ~r Ln ~ tD ~ o~ N
n m o o ~ N ~ O O
.0 O
.
.~ ~ ~
_~ X 'O
XX
x a~
_ ~ ~ Ln a- v ~.0 ~ ~ O Ln _ ~ ~ I r~ t~ Ln ~ ~J N 1-- Ln Cl~ 1 m _0 X
., N C~ E ~ o C~ ~t~ ~) ~ Ln ~ o N r~ ~ ' >~ :

O ~ ~ ~ 'o Q~ 'o ^ o 0 3_ 1' o ~ . .
~o ~ <1~ ~ o ~, ~ ~ t o~ ~ 0~ r- ~ V~ ~ .
._ a E C ~ ~ ~ ~ ~ V 3 QJ ~ ~ ,~, ~U O O , ~ C . ~`~ ~ ~ ~ al , C D r~ . ~ ~ S_ ~ C ~ ~ .0 aJ ^ ~ O ~ _ ~ _ ~ 0 ~ ro L ~
0 3~ 0 ^ O (~ ~> ~ O ~ n~ 0 _ :.,__ C . C . ._ . ~ 'n:~ 'O ~ _ ~ ~ I
> ~ ::~ ~ . . C aJ I ~ Q~ :- Z~ . o ~ o o ~ ~ ~ ~ ~ ~ C
~ ~. O ) ~ E ~ 3, LO ~ ~ o C~ 3 ,~ 3 ~ 3 ~ C ~> C

u ~ ~ ~ , S ~ o ~ 0 ~ ~ ~ E ~ ~ ~

: ' :'`
:` .
, ~`.23~i3~

The thus formed stabilizers were then used to form acrylonitrile/styrene polymer/polyols in the same equipment.
A blend of the stabilizer and the polyol was added as one stream and the monomer system and catalyst were added as the other stream~
The experimental conditions and results are set forth in Table XXXII:

, --11 o--lOh87 353~i O o oo ~ o~
N ~ Nr~ N ~ ~) N ~ N n 1~ N N . O O O d- ~
--~1 0 N ~ ~ S ~ 00 N ~ _ _ O CO 0 ~ I` ~ Ci~ ~ G~ ~ O N N D ,3 ' ~Ll C V_C
~ o i~
>, U~ O _ ~ O ~ 0 N ¦ ~ N ~ . N o ~ ~ r N ~ d o ~7 8 8N ' a~ _ ~ o ~
--_~ O N ~ N ~ _~ _I O ~ O~ ~ ~ ~ r~> ' ~J ~ .-4 N _ ~D 1~ N I~J ~c ~
~ 0 ~ C O o C o .a o ~
:: ~ _ ~ ~ V
1~ O~ ~ ~D ~ V~ N 0 0 3 C:7~ 0 N I-- CO CO Ir~ N 1~ 1~ O O el O 0~ 1~ Ja O N
d' ~ ~ N ~ N ~7 N ~n N O~ O N O 0~ 0 ~ D N --N _ > O Cl. ~
. o a E ' . .- V~.c X
X ~ ~ 3 ~ D
LLJ ~ .~ ~ ~
I_ --^ ------ E E x o x ~ , N ~ u ~ c ~, ~ V~ Q N

v~ . " '~) '~' ''''~ o q, O S ~J
.C u~ S ~1 ~ E
V) o o ~ O o. O O s .
O ~ v~ c~ v~ _ w 3 >~ D N _C Vl S U~ ~ ~ e ~ O 'O
L ~ V V ~ o o _ E -- ~ ~ D E~ ~_ ~_ v ~ ~ ~ ~
CaD ~ ~ ~ aJ Gl ~'~ ~, ~ ~ ~ ~ X~ 0 C C _ ~ ^ ~ ~ ~
c ;a . w o al ~ w c ~ ~- O _ ~= c ~ ~ v C~ o -- qJ -- X ~ ~-- _ ~ C--~ ~ o ._ ._ Vl ~ C L C ~ U~
.: O Q l J 3 C ~,5~, O S el ~ D ~ 5_ '~ ~'~ V W

~ O C C ~ >, -O -o O ~ ~o v O ~ ~ ~ c -- ~O 3 "-- '~ W _ oLJ ~ n~ ~ 8 ~ ~ ~ J~ _ " ~ " w ~ ~ x 4-- # ~ o -- o ~ QJ ~ n 8 ~, ~., 8 ~ ~ ~ v) ~ o ~ $ ~ ) o o o o ~ 3 Vl ~ ~ O ~ C ~ C O ~ ~ ~ C ~~ ~ ~ ~ O O ~ ~ W

: ,. ' ~.::

., ~ .

~.235~ 10687 In each Example, as can be seen, the polymer/polyol produced was stableO
EXAMæLES 252-260 These Examples illustrate the physical appearance of the stabilizers of the present invention and their viscosity characteristics.
Table XXXIII sets forth the experimental conditions and results for a series of stabilizers made in toluene from various solvatable and anchor portions: .

3~;3~i o o I

~1 ~ ~ C~JO o j O
~D
~, ~ C~l O O O q) i O

~
o o U~ V C
:: ~ ~ ,~ U~ U~ , I o C~ _ o o ~

, ~ ._ s. V

~¦ ~, _ ~r ~ E ¦ c _ ~ ~ I U~ V' j Y.

;~ C
O C~

~ ~¦ ~ ~ ~ ; N O ~
111 ~
9 ~ ~ I = ._ ~ r~
~ . o~
~ ~~ o o ~t a~ è^e' ~"

3S3~i As shown, the physical appearance of the stabilizers, all made by the free radical grafting mode, varied from solids or semi-solids (Examples 255-259) when using an anchor portion made with a 30/70 acrylonitrile/styrene monomer ratio to pastes when monomer ratios of increasing acrylonitrile content were employed (Examples 252-254).
Also, the viscosities of these stabilizers were well in excess of the viscosities of polymer/polyols prepared from comparable monomer contents.
A further stabilizer was prepared for evaluation, using i 10 : the technique described in Examples 246-251. The experimental conditions and results are set forth in Table XXXIV:

:, ;, ' .' `'.

:: :
:, ,.. ` "-;` ~.

~.

~ 23~!;36 TA~LE XXXIV
Example No. 260 Solvatable Portion of Stabilizer (1) Amount of 5Olvatable Portion, wt. % in total feed 24.31 Amount of Solvent (Toluene), wt. ~ in total feed 48.62 Catalyst Type TBPO
Cataly t, wt~ % in total feed 1.46 Ratio of Acxlylonitrile to Styrene, wt. ~ S0/50 Total Monomer Content, wt. ~ in total feed 25.61 Ratio of Vinyl Monomers to Solvatable Portion in Feed 51 3/48.7 Reaction Temperature, C~ 130 Toluene ~ Solvatable Portion +
Catalyst Feed Rate, gm/hr 1255 Monomer Feed Rate, gm/hr 432 Product Rate, gm/hr 1672 Material Balance, % 99.10 Residual Acrylonitrile, % 4.39 Styrene, ~ 3-04 Conversions, Acrylonitrile, ~ 66.20 , Styrene, % 76.47 , Combined, % 71.24 Total Poly A in Unstripped Product by Calc., wt. ~ 9.12 Total Poly S in Unstripped Product by Calc., ~t. ~ 10.57 Total Polymer in Unstripped Product by Calc., wt~ % 19.69 Ratio o Vinyl Polymer to Soluble Portion by Calc., wt. ~ 42.87/57.13 Calculated Hydroxyl No. of Unstripped Product, mg. KOH/gm 7.47 Total Poly A on (Toluene-Free) Product by Calc~, wt. % 19.86 Total Poly S in Stripped (Toluene-free) Product by Calc., wt. ~ 23.01 Total Polymer on S ripped (~oluene~free) Product by Calc., wt. ~ 42.87 Ratio o Poly A to Poly S in Product, by Calc., wt % 46.3/53.7 Solids (nonvolatiles), wt. ~ by analysis 43.82 Solids (nonvolatiles), wt~ % by calculation 45.94 Properties Appearance Sta~le Dispersion ~iscosity 260,000 cps.

. _ . , _ ~
(1) Same as used in Example 2S3.

~.2~

In evaluating the stabilizer of Example 260, it was determined by an electron micrograph that the stripped stabilizer was in fact a dispersion. A portion of the stabilizer in the toluene solvent was used to prepare two polymer/polyols, one employing a 30/70 acrylonitrile/
styrene monomer system with a monomer content of about 18%
in Polyol V and the other using a 40/60 acrylonitrile/styrene system at a monomer content of about 28% in the polyol blend described in Examples 250 and 251. The process used was that described in Examples 119-124; and both polymer/polyols were stable as determined by their viscosity, centrifugible solids level and filtration hindrance characteristics.
The stabilizer of Example 260 was also evaluated to determine whether it behaved similar to a polymer/polyol.
A 20/80 blend of the stabilizer with a conventional polyol was compared to a similar blend of a commercially available polymer/polyol by prepaxing foams from the two blends.
While some properties of the resulting foams were somewhat ;~ different, the data indicated that the stabilizer behaved like a ~ 20 polymer/polyol in providing a foam with load reinforcement.

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Claims (39)

WE CLAIM:

1. A process for producing a fluid, stable polymer/
polyol composition which comprises polymerizing, in the presence of a free radical catalyst, a reaction mixture comprising:
(1) from about 10 to about 40 weight percent of an ethylenically unsaturated monomer or a mixture of such monomers, (2) from 60 to about 90 weight percent of a normally liquid polypropylene oxide polyol having a number average molecular weight of at least about 400 and a hydroxyl number of from about 20 to about 280, said weight percents of the monomer or monomer mixture and polyol being based on the total weight thereof, and (3) a preformed stabilizer compatible with said polyol and present in an amount sufficient to stabilize the resulting polymer/polyol, said stabilizer being a copolymer comprising:
(a) an anchor portion consisting of a polymer of the monomer or mixture of monomers as defined in (1) chemically bonded to (b) a solvatable portion consisting of a propylene oxide polymer having a number average molecular weight at least about 800.

2. The process of claim 1 wherein said anchor portion consists of a copolymer of a first monomer that forms a polymer insoluble in the first monomer and a second monomer that forms a polymer soluble in the second monomer.

3. The process of claim 2 wherein said first monomer is acrylonitrile.

4 The process of claim 2 wherein the weight ratio of the first monomer to the second monomer is in the range of from about 30/70 to 80/20.

5. The process of claim 4 wherein the first monomer is acrylonitrile and the second monomer is a member selected from the group consisting of styrene, ethyl acrylate, vinyl acetate, and methyl methacrylate.

6. The process of claim 5 wherein the second monomer is styrene.

7. The process of claim 1 wherein (1) is a mixture of monomers comprising a first monomer that forms a polymer soluble in the first monomer and a second monomer that forms a polymer insoluble in the second monomer and wherein (a) is a polymer of a mixture of the first monomer and second, the ratio of the first monomer to the second monomer in (1) being different than the ratio of the first monomer to the second monomer in (a).

8. The process of claim 1 wherein the solvatable portion has a number average molecular weight of at least about 1800.

9. The process of claim 1 wherein the solvatable portion has a number average molecular weight of at least about 2600.

10. The process of claim 1 wherein the ethylenically unsaturated monomer is a member selected from the group consisting of acrylonitrile, styrene, ethyl acrylate, vinyl acetate, and methyl methacrylate.

11. The process of claim 1 wherein the polypropylene oxide polymer has ethylenic terminal unsaturation, on the average, at no more than one end of the polymer.

12. The process of claim 1 wherein the solvatable portion is a reaction product of the polypropylene oxide polymer and toluene diisocyanate.

13. The polymer/polyol composition produced by the process of claim 12.

14. The process of claim 1 wherein the stabilizer is present in an amount of at least about 1 percent, based on the total weight of the polymer/polyol composition.

15. The process of claim 1 wherein the stabilizer is present in an amount of from about 1 to 6 percent, based upon the total weight of the polymer/polyol composition.

16. The process of claim 1 wherein the mixture of monomers in the reaction mixture consists of acrylonitrile and styrene in the ratio of from about 30/70 to 60/40 and the anchor portion is formed from a mixture of acrylonitrile and styrene in the ratio of from about 30/70 to 50/50, the ratios being by weight.

17. The process of claim 16 wherein the anchor portion ratio is from about 30/70 to 40/60.

18. The process of claim 1 wherein the mixture of monomers in the reaction mixture consists of acrylonitrile and styrene in the ratio of from about 0/100 to 30/70 and the anchor portion is formed from a mixture of acrylonitrile and styrene in the ratio of from about 40/60 to 50/50, the ratios being by weight.

19. The process of claim 1 wherein the mixture of monomers in the reaction mixture consists of acrylonitrile and styrene in the ratio of from about 60/40 to 100/0 and the anchor portion is formed from a mixture of acrylonitrile and styrene in the ratio of from about 50/50 to about 80/20, the ratios being by weight.

20. The process of claim 19 wherein the mixture of monomers in the reaction mixture consists of acrylonitrile and styrene in the ratio of from 60/40 to 80/20.

21. The process of claim 1 wherein the mixture of monomers in the reaction mixture consists of acrylonitrile and styrene in the ratio of about 20/80 and the anchor portion is formed from a mixture of acrylonitrile and styrene in the ratio of about 50/50, the ratios being by weight.

22. The process of claim 1 wherein the mixture of monomers in the reaction mixture consists of acrylonitrile and styrene in the ratio of about 30/70 and the anchor portion is formed from a mixture of acrylonitrile and styrene in the ratio of about 50/50, the ratios being by weight.

23. The process of claim 1 wherein the mixture of monomers in the reaction mixture consists of acrylonitrile and styrene in the ratio of about 40/60 and the anchor portion is formed from a mixture of acrylonitrile and styrene in the ratio of about 30/70, the ratios being by weight.

24. The process of claim 1 wherein the mixture of monomers in the reaction mixture consists of acrylonitrile and styrene in the ratio of about 50/50 and the anchor portion is formed from a mixture of acrylonitrile and styrene in the ratio of about 30/70, the ratios being by weight.

25. The process of claim 1 wherein (1) comprises a mixture of acrylonitrile and a comonomer in which the comonomer is present in an amount of at least about 70 percent by weight of the mixture.

26. The process of claim 1 wherein the ethylenically unsaturated monomer or a mixture of such monomers in (1) is present in an amount of at least about 30 weight percent.

27. The process of claim 1 wherein said normally liquid polypropylene oxide polyol has a number average molecular weight of less than about 2000.

28. The process of claim 1 wherein said polypropylene oxide polymer is a polyol.

29. The polymer/polyol composition produced by the process of claim 1.

30. The polymer/polyol composition produced by the process of claim 2.

31. The polymer/polyol composition produced by the process of claim 5.

32. The polymer/polyol composition produced by the process of claim 10.

33. The polymer/polyol composition produced by the process of claim 16.

34. The polymer/polyol composition produced by the process of claim 18.

35. The polymer/polyol composition produced by the process of claim 19.

36. The polymer/polyol composition produced by the the process of claim 25.

37. The polymer/polyol composition produced by the process of claim 26.

38. The polymer/polyol composition produced by the process of claim 27.

39. The polymer/polyol composition produced by the process of claim 28.