CA1118668A - Process and apparatus for analysis solid organic substances for sewage water - Google Patents
Process and apparatus for analysis solid organic substances for sewage waterInfo
- Publication number
- CA1118668A CA1118668A CA000320623A CA320623A CA1118668A CA 1118668 A CA1118668 A CA 1118668A CA 000320623 A CA000320623 A CA 000320623A CA 320623 A CA320623 A CA 320623A CA 1118668 A CA1118668 A CA 1118668A
- Authority
- CA
- Canada
- Prior art keywords
- ions
- amount
- solution
- sample
- sewage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 73
- 238000004458 analytical method Methods 0.000 title claims abstract description 62
- 239000010865 sewage Substances 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims abstract description 21
- 239000000126 substance Substances 0.000 title claims abstract description 16
- 230000008569 process Effects 0.000 title claims abstract description 13
- 239000007787 solid Substances 0.000 title claims abstract description 7
- 239000000243 solution Substances 0.000 claims abstract description 136
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract description 43
- 238000006243 chemical reaction Methods 0.000 claims abstract description 29
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims abstract description 11
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000003869 coulometry Methods 0.000 claims abstract description 7
- 238000011946 reduction process Methods 0.000 claims abstract 2
- 238000004448 titration Methods 0.000 claims description 34
- 230000009467 reduction Effects 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 18
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 16
- 239000011368 organic material Substances 0.000 claims description 14
- 238000000605 extraction Methods 0.000 claims description 10
- 238000003928 amperometric titration Methods 0.000 claims description 8
- 238000005259 measurement Methods 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 230000007935 neutral effect Effects 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 238000009835 boiling Methods 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- YPNVIBVEFVRZPJ-UHFFFAOYSA-L silver sulfate Chemical compound [Ag+].[Ag+].[O-]S([O-])(=O)=O YPNVIBVEFVRZPJ-UHFFFAOYSA-L 0.000 claims description 4
- 229910000367 silver sulfate Inorganic materials 0.000 claims description 4
- 230000006872 improvement Effects 0.000 claims description 2
- 239000011369 resultant mixture Substances 0.000 claims description 2
- 238000006479 redox reaction Methods 0.000 abstract description 3
- 230000002378 acidificating effect Effects 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 46
- 239000011651 chromium Substances 0.000 description 36
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 20
- 238000006722 reduction reaction Methods 0.000 description 18
- 239000012530 fluid Substances 0.000 description 16
- 238000004886 process control Methods 0.000 description 13
- 239000012153 distilled water Substances 0.000 description 9
- 239000007789 gas Substances 0.000 description 9
- 150000002500 ions Chemical class 0.000 description 8
- 239000011541 reaction mixture Substances 0.000 description 6
- -1 (K2Cr207) Substances 0.000 description 4
- 239000012528 membrane Substances 0.000 description 4
- 230000004913 activation Effects 0.000 description 3
- 238000001994 activation Methods 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 239000000306 component Substances 0.000 description 2
- 238000013213 extrapolation Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- DOBUSJIVSSJEDA-UHFFFAOYSA-L 1,3-dioxa-2$l^{6}-thia-4-mercuracyclobutane 2,2-dioxide Chemical compound [Hg+2].[O-]S([O-])(=O)=O DOBUSJIVSSJEDA-UHFFFAOYSA-L 0.000 description 1
- 101150014691 PPARA gene Proteins 0.000 description 1
- JKNZUZCGFROMAZ-UHFFFAOYSA-L [Ag+2].[O-]S([O-])(=O)=O Chemical group [Ag+2].[O-]S([O-])(=O)=O JKNZUZCGFROMAZ-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- XGGLLRJQCZROSE-UHFFFAOYSA-K ammonium iron(iii) sulfate Chemical compound [NH4+].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O XGGLLRJQCZROSE-UHFFFAOYSA-K 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 229910000370 mercury sulfate Inorganic materials 0.000 description 1
- KRELGAOTTAXPMR-UHFFFAOYSA-N mercury;sulfuric acid Chemical compound [Hg].[Hg].OS(O)(=O)=O KRELGAOTTAXPMR-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
- G01N31/005—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods investigating the presence of an element by oxidation
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
- G01N31/16—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using titration
- G01N31/162—Determining the equivalent point by means of a discontinuity
- G01N31/164—Determining the equivalent point by means of a discontinuity by electrical or electrochemical means
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/18—Water
- G01N33/1826—Organic contamination in water
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/18—Water
- G01N33/1826—Organic contamination in water
- G01N33/1833—Oil in water
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/11—Automated chemical analysis
- Y10T436/115831—Condition or time responsive
- Y10T436/116664—Condition or time responsive with automated titrator
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- General Physics & Mathematics (AREA)
- Pathology (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Immunology (AREA)
- Molecular Biology (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19782804267 DE2804267A1 (de) | 1978-02-01 | 1978-02-01 | Verfahren und analysegeraet zur bestimmung der menge von im wasser enthaltenen geloesten, festen und mit wasser nicht mischbaren, organischen stoffen |
| DEP2804267.3 | 1978-02-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1118668A true CA1118668A (en) | 1982-02-23 |
Family
ID=6030903
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000320623A Expired CA1118668A (en) | 1978-02-01 | 1979-01-31 | Process and apparatus for analysis solid organic substances for sewage water |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4238297A (enExample) |
| JP (1) | JPS54111890A (enExample) |
| BE (1) | BE873833A (enExample) |
| CA (1) | CA1118668A (enExample) |
| DE (1) | DE2804267A1 (enExample) |
| FR (1) | FR2416472A1 (enExample) |
| GB (1) | GB2013882B (enExample) |
| IT (1) | IT1110050B (enExample) |
| NL (1) | NL7900780A (enExample) |
| SE (1) | SE7900807L (enExample) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2517063A1 (fr) * | 1981-11-26 | 1983-05-27 | Elf France | Appareil d'analyses automatiques d'echantillons liquides par dosage electrochimique |
| CN109633081A (zh) * | 2019-01-31 | 2019-04-16 | 江苏中宜生物肥料工程中心有限公司 | 一种有机肥料有机质含量的测定方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3208827A (en) * | 1962-04-30 | 1965-09-28 | Robert F Borkenstein | Method for rapid quantitative analysis of ethyl alcohol |
| US3726778A (en) * | 1971-07-02 | 1973-04-10 | Photovolt Corp | Coulometric water titrator |
-
1978
- 1978-02-01 DE DE19782804267 patent/DE2804267A1/de not_active Withdrawn
-
1979
- 1979-01-11 US US06/002,536 patent/US4238297A/en not_active Expired - Lifetime
- 1979-01-23 FR FR7901618A patent/FR2416472A1/fr active Granted
- 1979-01-26 IT IT19626/79A patent/IT1110050B/it active
- 1979-01-30 SE SE7900807A patent/SE7900807L/ not_active Application Discontinuation
- 1979-01-31 GB GB7903429A patent/GB2013882B/en not_active Expired
- 1979-01-31 NL NL7900780A patent/NL7900780A/xx not_active Application Discontinuation
- 1979-01-31 BE BE193180A patent/BE873833A/xx unknown
- 1979-01-31 JP JP1027579A patent/JPS54111890A/ja active Pending
- 1979-01-31 CA CA000320623A patent/CA1118668A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| IT1110050B (it) | 1985-12-23 |
| GB2013882B (en) | 1982-07-14 |
| US4238297A (en) | 1980-12-09 |
| DE2804267A1 (de) | 1979-08-02 |
| SE7900807L (sv) | 1979-08-02 |
| FR2416472B1 (enExample) | 1980-10-03 |
| GB2013882A (en) | 1979-08-15 |
| IT7919626A0 (it) | 1979-01-26 |
| FR2416472A1 (fr) | 1979-08-31 |
| BE873833A (fr) | 1979-05-16 |
| JPS54111890A (en) | 1979-09-01 |
| NL7900780A (nl) | 1979-08-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |