CA1109636A - Metal salt catalyzed polymerization of (npcl.sub.2) oligomers - Google Patents
Metal salt catalyzed polymerization of (npcl.sub.2) oligomersInfo
- Publication number
- CA1109636A CA1109636A CA300,792A CA300792A CA1109636A CA 1109636 A CA1109636 A CA 1109636A CA 300792 A CA300792 A CA 300792A CA 1109636 A CA1109636 A CA 1109636A
- Authority
- CA
- Canada
- Prior art keywords
- npcl2
- metal halide
- halide salt
- metal
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000003839 salts Chemical class 0.000 title claims abstract description 14
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 12
- 239000002184 metal Substances 0.000 title claims abstract description 12
- 238000006116 polymerization reaction Methods 0.000 title abstract description 12
- 238000000034 method Methods 0.000 claims abstract description 21
- 125000004122 cyclic group Chemical group 0.000 claims abstract description 13
- 229920000642 polymer Polymers 0.000 claims abstract description 13
- 229910052802 copper Inorganic materials 0.000 claims abstract description 4
- 150000004820 halides Chemical class 0.000 claims abstract description 4
- 229910052742 iron Inorganic materials 0.000 claims abstract description 4
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 4
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 4
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 3
- 229910052804 chromium Inorganic materials 0.000 claims abstract 3
- 229910001507 metal halide Inorganic materials 0.000 claims description 16
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 230000000379 polymerizing effect Effects 0.000 claims description 8
- QSWDMMVNRMROPK-UHFFFAOYSA-K chromium(3+) trichloride Chemical group [Cl-].[Cl-].[Cl-].[Cr+3] QSWDMMVNRMROPK-UHFFFAOYSA-K 0.000 claims description 4
- 229910021555 Chromium Chloride Inorganic materials 0.000 claims description 3
- 229910001510 metal chloride Inorganic materials 0.000 claims description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 4
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 2
- 239000011651 chromium Substances 0.000 claims 2
- 229910017052 cobalt Inorganic materials 0.000 claims 2
- 239000010941 cobalt Substances 0.000 claims 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 2
- 239000010949 copper Substances 0.000 claims 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims 2
- 239000011777 magnesium Substances 0.000 claims 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 1
- 239000011572 manganese Substances 0.000 claims 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 1
- 239000013638 trimer Substances 0.000 abstract description 7
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 229910017053 inorganic salt Inorganic materials 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 5
- 239000003607 modifier Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001212 derivatisation Methods 0.000 description 2
- 150000004677 hydrates Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 229910021556 Chromium(III) chloride Inorganic materials 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000011636 chromium(III) chloride Substances 0.000 description 1
- 235000007831 chromium(III) chloride Nutrition 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- UBIJTWDKTYCPMQ-UHFFFAOYSA-N hexachlorophosphazene Chemical compound ClP1(Cl)=NP(Cl)(Cl)=NP(Cl)(Cl)=N1 UBIJTWDKTYCPMQ-UHFFFAOYSA-N 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 229920002627 poly(phosphazenes) Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
- C01B21/097—Compounds containing nitrogen and non-metals and optionally metals containing phosphorus atoms
- C01B21/098—Phosphonitrilic dihalides; Polymers thereof
- C01B21/0986—Phosphonitrilic dichlorides; Polymers thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
- C01B21/097—Compounds containing nitrogen and non-metals and optionally metals containing phosphorus atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Polyethers (AREA)
- Catalysts (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US78848077A | 1977-04-18 | 1977-04-18 | |
| US788,480 | 1977-04-18 | ||
| US876,385 | 1978-02-09 | ||
| US05/876,385 US4137330A (en) | 1977-04-18 | 1978-02-09 | Metal salt catalyzed polymerization of (NPCl2) oligomers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1109636A true CA1109636A (en) | 1981-09-29 |
Family
ID=27120808
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA300,792A Expired CA1109636A (en) | 1977-04-18 | 1978-04-10 | Metal salt catalyzed polymerization of (npcl.sub.2) oligomers |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS5817124B2 (nl) |
| AU (1) | AU521138B2 (nl) |
| CA (1) | CA1109636A (nl) |
| DE (1) | DE2816227A1 (nl) |
| FR (1) | FR2388010B1 (nl) |
| GB (1) | GB1598974A (nl) |
| NL (1) | NL185201C (nl) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0004877B1 (en) * | 1978-04-20 | 1982-05-12 | The Firestone Tire & Rubber Company | A process for thermally polymerizing cyclic phosphazenes |
| GB9103666D0 (en) * | 1991-02-21 | 1991-04-10 | Dow Corning Sa | Method of making organopolysiloxanes |
| AT403285B (de) * | 1995-03-14 | 1997-12-29 | Stelzer Franz Dipl Ing Dr Tech | Verfahren zur polymerisation cyclischer olefine |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA614267A (en) * | 1961-02-07 | Albright And Wilson (Mfg.) Limited | Preparation of phosphonitrilic chloride polymers | |
| GB883587A (en) * | 1957-09-06 | 1961-11-29 | Albright & Wilson Mfg Ltd | Production of phosphonitrilic polymers |
| US3370020A (en) * | 1964-09-29 | 1968-02-20 | American Cyanamid Co | Process for the production of phosphonitrilic polymers and polymers produced thereby |
| US3515688A (en) * | 1967-08-30 | 1970-06-02 | Horizons Research Inc | Extreme service phosphonitrile elastomers |
| US4005171A (en) * | 1974-05-28 | 1977-01-25 | Horizons Incorporated, A Division Of Horizons Research Incorporated | Catalytic preparation of soluble poly(dichlorophosphazenes) |
| US3937790A (en) * | 1974-10-02 | 1976-02-10 | The Firestone Tire & Rubber Company | Use of water as a catalyst for the polymerization of chlorocyclophosphazenes |
| BE848157A (fr) * | 1975-08-22 | 1977-05-09 | Catalyse par les acides de lewis de la polymerisation des phosphazenes cycliques. | |
| US4080432A (en) * | 1975-08-22 | 1978-03-21 | The Firestone Tire & Rubber Company | Dissolution of polydihalophosphazenes |
| JPS5244900A (en) * | 1975-08-22 | 1977-04-08 | Firestone Tire & Rubber Co | Process for polymerizing cyclic chlorophosphasen |
| US4116891A (en) * | 1976-12-06 | 1978-09-26 | Armstrong Cork Company | Catalytic process for the preparation of phosphazene polymers |
-
1978
- 1978-04-10 CA CA300,792A patent/CA1109636A/en not_active Expired
- 1978-04-13 GB GB14587/78A patent/GB1598974A/en not_active Expired
- 1978-04-14 DE DE19782816227 patent/DE2816227A1/de active Granted
- 1978-04-17 FR FR7811204A patent/FR2388010B1/fr not_active Expired
- 1978-04-17 JP JP53045166A patent/JPS5817124B2/ja not_active Expired
- 1978-04-18 NL NLAANVRAGE7804109,A patent/NL185201C/nl not_active IP Right Cessation
- 1978-04-18 AU AU35201/78A patent/AU521138B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2388010A1 (fr) | 1978-11-17 |
| FR2388010B1 (fr) | 1987-07-24 |
| JPS5817124B2 (ja) | 1983-04-05 |
| DE2816227C2 (nl) | 1989-04-27 |
| NL7804109A (nl) | 1978-10-20 |
| AU3520178A (en) | 1979-10-25 |
| NL185201C (nl) | 1990-02-16 |
| NL185201B (nl) | 1989-09-18 |
| DE2816227A1 (de) | 1978-10-26 |
| GB1598974A (en) | 1981-09-30 |
| JPS53129300A (en) | 1978-11-11 |
| AU521138B2 (en) | 1982-03-18 |
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| JPS5850924B2 (ja) | 環状ホスホニトリルクロライドオリゴマ−の製造方法 | |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |