CA1108791A - Cross-linkable polymeric flame-retarding compositions and cross-linked compositions obtained therefrom - Google Patents
Cross-linkable polymeric flame-retarding compositions and cross-linked compositions obtained therefromInfo
- Publication number
- CA1108791A CA1108791A CA305,429A CA305429A CA1108791A CA 1108791 A CA1108791 A CA 1108791A CA 305429 A CA305429 A CA 305429A CA 1108791 A CA1108791 A CA 1108791A
- Authority
- CA
- Canada
- Prior art keywords
- composition
- weight
- peroxide
- flame retardant
- cross
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 77
- 150000002978 peroxides Chemical class 0.000 claims abstract description 38
- 239000003063 flame retardant Substances 0.000 claims abstract description 29
- 238000004132 cross linking Methods 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000010521 absorption reaction Methods 0.000 claims abstract description 9
- 230000000694 effects Effects 0.000 claims abstract description 3
- 229920000642 polymer Polymers 0.000 claims description 31
- 150000001875 compounds Chemical class 0.000 claims description 27
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 23
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 20
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 20
- 229910052794 bromium Inorganic materials 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 20
- 239000011248 coating agent Substances 0.000 claims description 14
- 238000000576 coating method Methods 0.000 claims description 14
- 150000001451 organic peroxides Chemical class 0.000 claims description 12
- 150000001336 alkenes Chemical class 0.000 claims description 8
- 238000007493 shaping process Methods 0.000 claims description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 6
- 239000005977 Ethylene Substances 0.000 claims description 6
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 claims description 6
- 239000011203 carbon fibre reinforced carbon Substances 0.000 claims description 6
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Inorganic materials O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 5
- 229920001684 low density polyethylene Polymers 0.000 claims description 5
- 239000004702 low-density polyethylene Substances 0.000 claims description 5
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical group C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 2
- 229920006037 cross link polymer Polymers 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000012796 inorganic flame retardant Substances 0.000 claims 10
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 claims 2
- YEAUATLBSVJFOY-UHFFFAOYSA-N tetraantimony hexaoxide Chemical compound O1[Sb](O2)O[Sb]3O[Sb]1O[Sb]2O3 YEAUATLBSVJFOY-UHFFFAOYSA-N 0.000 claims 2
- 229920001567 vinyl ester resin Polymers 0.000 claims 2
- 150000001491 aromatic compounds Chemical class 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 9
- 241000218657 Picea Species 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 description 7
- 230000009102 absorption Effects 0.000 description 5
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical compound ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- -1 e.g. Chemical group 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000007765 extrusion coating Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- MYWOJODOMFBVCB-UHFFFAOYSA-N 1,2,6-trimethylphenanthrene Chemical compound CC1=CC=C2C3=CC(C)=CC=C3C=CC2=C1C MYWOJODOMFBVCB-UHFFFAOYSA-N 0.000 description 1
- 229940123457 Free radical scavenger Drugs 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 description 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 1
- 125000005196 alkyl carbonyloxy group Chemical group 0.000 description 1
- 150000001463 antimony compounds Chemical class 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-L fumarate(2-) Chemical compound [O-]C(=O)\C=C\C([O-])=O VZCYOOQTPOCHFL-OWOJBTEDSA-L 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Organic Insulating Materials (AREA)
- Graft Or Block Polymers (AREA)
- Insulated Conductors (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US80667677A | 1977-06-15 | 1977-06-15 | |
| US806,676 | 1977-06-15 | ||
| US828,731 | 1977-08-29 | ||
| US05/828,731 US4129616A (en) | 1977-06-15 | 1977-08-29 | Polymeric compositions containing brominated flame retardants |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1108791A true CA1108791A (en) | 1981-09-08 |
Family
ID=27122902
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA305,429A Expired CA1108791A (en) | 1977-06-15 | 1978-06-14 | Cross-linkable polymeric flame-retarding compositions and cross-linked compositions obtained therefrom |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS5416550A (ja) |
| BR (1) | BR7803815A (ja) |
| CA (1) | CA1108791A (ja) |
| DE (1) | DE2825995A1 (ja) |
| ES (1) | ES470731A1 (ja) |
| FR (1) | FR2394573A1 (ja) |
| GB (1) | GB1588485A (ja) |
| IT (1) | IT1096683B (ja) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1278128C (en) * | 1984-02-09 | 1990-12-18 | Nobuchika Tabata | Fire retardant polyolefin composition |
| JPH0376737A (ja) * | 1989-08-17 | 1991-04-02 | Mitsubishi Cable Ind Ltd | 走水防止用組成物及びそれを用いた走水防止ケーブル |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1383872A (ja) * | 1962-12-05 | 1964-11-23 | Kalk Chemische Fabrik Gmbh | |
| US3806555A (en) * | 1971-03-25 | 1974-04-23 | Wako Pure Chem Ind Ltd | Process for crosslinking olefin polymers |
| US3816564A (en) * | 1972-02-02 | 1974-06-11 | Itt | Insulation coating compositions |
| US3856890A (en) * | 1973-05-23 | 1974-12-24 | Nat Distillers Chem Corp | Flame retardant compositions |
| US3974132A (en) * | 1975-05-15 | 1976-08-10 | Borg-Warner Corporation | Process for curing olefin polymers |
-
1978
- 1978-05-31 GB GB24964/78A patent/GB1588485A/en not_active Expired
- 1978-06-13 FR FR7817629A patent/FR2394573A1/fr active Pending
- 1978-06-13 ES ES470731A patent/ES470731A1/es not_active Expired
- 1978-06-14 IT IT24561/78A patent/IT1096683B/it active
- 1978-06-14 CA CA305,429A patent/CA1108791A/en not_active Expired
- 1978-06-14 DE DE19782825995 patent/DE2825995A1/de not_active Withdrawn
- 1978-06-15 JP JP7269278A patent/JPS5416550A/ja active Pending
- 1978-06-15 BR BR787803815A patent/BR7803815A/pt unknown
Also Published As
| Publication number | Publication date |
|---|---|
| IT1096683B (it) | 1985-08-26 |
| JPS5416550A (en) | 1979-02-07 |
| GB1588485A (en) | 1981-04-23 |
| BR7803815A (pt) | 1979-01-16 |
| ES470731A1 (es) | 1979-01-16 |
| DE2825995A1 (de) | 1979-01-11 |
| FR2394573A1 (fr) | 1979-01-12 |
| IT7824561A0 (it) | 1978-06-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |