CA1078164A - Conversion of radioactive ferrocyanide compounds to immobile glasses - Google Patents
Conversion of radioactive ferrocyanide compounds to immobile glassesInfo
- Publication number
- CA1078164A CA1078164A CA263,183A CA263183A CA1078164A CA 1078164 A CA1078164 A CA 1078164A CA 263183 A CA263183 A CA 263183A CA 1078164 A CA1078164 A CA 1078164A
- Authority
- CA
- Canada
- Prior art keywords
- percent
- ferrocyanide
- basalt
- charge
- radioactive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000002285 radioactive effect Effects 0.000 title claims abstract description 12
- 239000011521 glass Substances 0.000 title abstract description 16
- 150000001875 compounds Chemical class 0.000 title abstract description 5
- 238000006243 chemical reaction Methods 0.000 title abstract description 4
- 238000000034 method Methods 0.000 claims abstract description 26
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 24
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 15
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims abstract description 13
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 239000000292 calcium oxide Substances 0.000 claims description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 9
- 239000002244 precipitate Substances 0.000 claims description 8
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- 229910052681 coesite Inorganic materials 0.000 claims description 6
- 229910052906 cristobalite Inorganic materials 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims description 6
- 229910052682 stishovite Inorganic materials 0.000 claims description 6
- 229910052905 tridymite Inorganic materials 0.000 claims description 6
- 229910052793 cadmium Inorganic materials 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 239000005368 silicate glass Substances 0.000 claims description 2
- FCTBKIHDJGHPPO-UHFFFAOYSA-N uranium dioxide Inorganic materials O=[U]=O FCTBKIHDJGHPPO-UHFFFAOYSA-N 0.000 claims description 2
- 235000017550 sodium carbonate Nutrition 0.000 claims 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 229910052593 corundum Inorganic materials 0.000 claims 1
- 229910009112 xH2O Inorganic materials 0.000 claims 1
- 229910001845 yogo sapphire Inorganic materials 0.000 claims 1
- 229910052792 caesium Inorganic materials 0.000 abstract description 12
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 7
- 239000002699 waste material Substances 0.000 abstract description 6
- 238000002386 leaching Methods 0.000 abstract description 3
- UETZVSHORCDDTH-UHFFFAOYSA-N iron(2+);hexacyanide Chemical class [Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] UETZVSHORCDDTH-UHFFFAOYSA-N 0.000 abstract description 2
- 239000003758 nuclear fuel Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 230000004927 fusion Effects 0.000 abstract 1
- 238000012958 reprocessing Methods 0.000 abstract 1
- 230000002000 scavenging effect Effects 0.000 abstract 1
- 239000000047 product Substances 0.000 description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 239000000470 constituent Substances 0.000 description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- TVFDJXOCXUVLDH-RNFDNDRNSA-N cesium-137 Chemical compound [137Cs] TVFDJXOCXUVLDH-RNFDNDRNSA-N 0.000 description 2
- 230000004992 fission Effects 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 239000002901 radioactive waste Substances 0.000 description 2
- 239000005361 soda-lime glass Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- JISPBGBABLPNSV-UHFFFAOYSA-N [Ni].[Cs] Chemical compound [Ni].[Cs] JISPBGBABLPNSV-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- NNBFNNNWANBMTI-UHFFFAOYSA-M brilliant green Chemical compound OS([O-])(=O)=O.C1=CC(N(CC)CC)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](CC)CC)C=C1 NNBFNNNWANBMTI-UHFFFAOYSA-M 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- NLSCHDZTHVNDCP-UHFFFAOYSA-N caesium nitrate Inorganic materials [Cs+].[O-][N+]([O-])=O NLSCHDZTHVNDCP-UHFFFAOYSA-N 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- MPMSMUBQXQALQI-UHFFFAOYSA-N cobalt phthalocyanine Chemical compound [Co+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 MPMSMUBQXQALQI-UHFFFAOYSA-N 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 230000003100 immobilizing effect Effects 0.000 description 1
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 150000002696 manganese Chemical class 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(II) nitrate Inorganic materials [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
- 239000000276 potassium ferrocyanide Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Inorganic materials [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 1
- HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 description 1
- XOGGUFAVLNCTRS-UHFFFAOYSA-N tetrapotassium;iron(2+);hexacyanide Chemical compound [K+].[K+].[K+].[K+].[Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] XOGGUFAVLNCTRS-UHFFFAOYSA-N 0.000 description 1
- 125000005289 uranyl group Chemical group 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/28—Treating solids
- G21F9/34—Disposal of solid waste
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S210/00—Liquid purification or separation
- Y10S210/902—Materials removed
- Y10S210/903—Nitrogenous
- Y10S210/904—-CN containing
Landscapes
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Physics & Mathematics (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Glass Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/634,224 US4020004A (en) | 1975-11-21 | 1975-11-21 | Conversion of radioactive ferrocyanide compounds to immobile glasses |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1078164A true CA1078164A (en) | 1980-05-27 |
Family
ID=24542896
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA263,183A Expired CA1078164A (en) | 1975-11-21 | 1976-10-12 | Conversion of radioactive ferrocyanide compounds to immobile glasses |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4020004A (online.php) |
| JP (1) | JPS5278914A (online.php) |
| BE (1) | BE848369A (online.php) |
| CA (1) | CA1078164A (online.php) |
| DE (1) | DE2652858A1 (online.php) |
| FR (1) | FR2332596A1 (online.php) |
| GB (1) | GB1508966A (online.php) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110335695A (zh) * | 2019-05-27 | 2019-10-15 | 西南科技大学 | 一种放射性废物固化基础材料及玻璃固化体的制备方法 |
| CN110335693A (zh) * | 2019-05-27 | 2019-10-15 | 西南科技大学 | 一种用于放射性废物玻璃固化基础材料及玻璃固化体的制备方法 |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4320028A (en) * | 1979-05-17 | 1982-03-16 | Leuchtag H Richard | Nuclear waste disposal system |
| DE2923053C2 (de) * | 1979-06-07 | 1983-06-23 | 6000 Frankfurt Franz Josef Gattys Ingenieurbüro für Chem. Maschinen- und Apparatebau | Verfahren und Einrichtung zum Aufbereiten von Quecksilber aus radioaktiven Abfallösungen |
| US4395367A (en) * | 1981-11-17 | 1983-07-26 | Rohrmann Charles A | Process for treating fission waste |
| FR2526574A1 (fr) * | 1982-05-05 | 1983-11-10 | Commissariat Energie Atomique | Procede d'evacuation de dechets radioactifs et installation geologique pour l'evacuation de ces dechets |
| US4487711A (en) * | 1982-06-29 | 1984-12-11 | Westinghouse Electric Corp. | Cinder aggregate from PUREX waste |
| US4666490A (en) * | 1986-02-12 | 1987-05-19 | Drake Ronald N | Aqueous waste vitrification process and apparatus |
| US4735784A (en) * | 1986-07-11 | 1988-04-05 | Morrison-Knudsen Company, Inc. | Method of treating fluoride contaminated wastes |
| US4820325A (en) * | 1987-10-22 | 1989-04-11 | Stauffer Chemical Company | Treatment of toxicant-impregnated filter cake |
| USH1013H (en) | 1989-08-11 | 1992-01-07 | W. R. Grace & Co.-Conn. | Process for the immobilization and volume reduction of low level radioactive wastes from thorium and uranium processing |
| US5188649A (en) * | 1991-08-07 | 1993-02-23 | Pedro Buarque de Macedo | Process for vitrifying asbestos containing waste, infectious waste, toxic materials and radioactive waste |
| FR2683374B1 (fr) * | 1991-10-31 | 1994-05-06 | Pechiney Uranium | Agent piegeant la radioactivite de produits de fission generes dans un element combustible nucleaire. |
| FR2683373B1 (fr) * | 1991-10-31 | 1994-03-04 | Pechiney Uranium | Elements combustibles nucleaires comportant un piege a produits de fission a base d'oxyde. |
| US5288435A (en) * | 1992-05-01 | 1994-02-22 | Westinghouse Electric Corp. | Treatment of radioactive wastes |
| US5434333A (en) * | 1992-09-18 | 1995-07-18 | The United States Of America As Represented By The United States Department Of Energy | Method for treating materials for solidification |
| US5678236A (en) * | 1996-01-23 | 1997-10-14 | Pedro Buarque De Macedo | Method and apparatus for eliminating volatiles or airborne entrainments when vitrifying radioactive and/or hazardous waste |
| US6145343A (en) | 1998-05-02 | 2000-11-14 | Westinghouse Savannah River Company | Low melting high lithia glass compositions and methods |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2769780A (en) * | 1954-12-22 | 1956-11-06 | Warren E Clifford | Precipitation process |
-
1975
- 1975-11-21 US US05/634,224 patent/US4020004A/en not_active Expired - Lifetime
-
1976
- 1976-10-12 CA CA263,183A patent/CA1078164A/en not_active Expired
- 1976-11-16 BE BE172383A patent/BE848369A/xx unknown
- 1976-11-19 GB GB48375/76A patent/GB1508966A/en not_active Expired
- 1976-11-19 JP JP51139396A patent/JPS5278914A/ja active Pending
- 1976-11-19 FR FR7634972A patent/FR2332596A1/fr active Granted
- 1976-11-20 DE DE19762652858 patent/DE2652858A1/de active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110335695A (zh) * | 2019-05-27 | 2019-10-15 | 西南科技大学 | 一种放射性废物固化基础材料及玻璃固化体的制备方法 |
| CN110335693A (zh) * | 2019-05-27 | 2019-10-15 | 西南科技大学 | 一种用于放射性废物玻璃固化基础材料及玻璃固化体的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| GB1508966A (en) | 1978-04-26 |
| US4020004A (en) | 1977-04-26 |
| FR2332596B1 (online.php) | 1980-04-04 |
| DE2652858A1 (de) | 1977-06-02 |
| BE848369A (fr) | 1977-03-16 |
| JPS5278914A (en) | 1977-07-02 |
| FR2332596A1 (fr) | 1977-06-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |