CA1078137A - Procede d'oxydation du sulfate ferreux en solution aqueuse sulfurique - Google Patents
Procede d'oxydation du sulfate ferreux en solution aqueuse sulfuriqueInfo
- Publication number
- CA1078137A CA1078137A CA256,249A CA256249A CA1078137A CA 1078137 A CA1078137 A CA 1078137A CA 256249 A CA256249 A CA 256249A CA 1078137 A CA1078137 A CA 1078137A
- Authority
- CA
- Canada
- Prior art keywords
- solution
- ferrous
- oxydation
- ferrous sulphate
- sulfuric acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 235000003891 ferrous sulphate Nutrition 0.000 title claims abstract description 12
- 239000011790 ferrous sulphate Substances 0.000 title claims abstract description 12
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 10
- 238000000034 method Methods 0.000 title claims abstract description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 21
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims abstract description 11
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims abstract description 10
- 230000003647 oxidation Effects 0.000 claims abstract description 9
- 239000007789 gas Substances 0.000 claims abstract description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000001301 oxygen Substances 0.000 claims abstract description 5
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 5
- 239000000243 solution Substances 0.000 claims description 14
- 239000007864 aqueous solution Substances 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 17
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 9
- 229910052742 iron Inorganic materials 0.000 description 8
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical class [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 7
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 4
- 229940063656 aluminum chloride Drugs 0.000 description 3
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 229960002089 ferrous chloride Drugs 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- JGDITNMASUZKPW-UHFFFAOYSA-K aluminium trichloride hexahydrate Chemical compound O.O.O.O.O.O.Cl[Al](Cl)Cl JGDITNMASUZKPW-UHFFFAOYSA-K 0.000 description 1
- 229940009861 aluminum chloride hexahydrate Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 description 1
- 150000004687 hexahydrates Chemical class 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 1
- GDPKWKCLDUOTMP-UHFFFAOYSA-B iron(3+);dihydroxide;pentasulfate Chemical compound [OH-].[OH-].[Fe+3].[Fe+3].[Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GDPKWKCLDUOTMP-UHFFFAOYSA-B 0.000 description 1
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
- 235000020094 liqueur Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000010413 mother solution Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/14—Sulfates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Catalysts (AREA)
- Treating Waste Gases (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Compounds Of Iron (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7521556A FR2317231A1 (fr) | 1975-07-09 | 1975-07-09 | Procede d'oxydation du sulfate ferreux en solution aqueuse sulfurique |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1078137A true CA1078137A (fr) | 1980-05-27 |
Family
ID=9157717
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA256,249A Expired CA1078137A (fr) | 1975-07-09 | 1976-07-05 | Procede d'oxydation du sulfate ferreux en solution aqueuse sulfurique |
Country Status (17)
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE433843B (sv) * | 1982-11-01 | 1984-06-18 | Boliden Ab | Forfarande for framstellning av en vattenreningskemikalie med trevert jern |
| JPS648116A (en) * | 1987-06-26 | 1989-01-12 | Toa Gosei Chem Ind | Manufacture of locking screw |
| US5266297A (en) * | 1989-01-20 | 1993-11-30 | Sugita Wire Mfg. Co., Ltd. | Liquid oxidizing method and apparatus |
| JPH02191541A (ja) * | 1989-01-20 | 1990-07-27 | Sugita Seisen Kojo:Kk | 液体の酸化方法とその装置 |
| JPH0739961U (ja) * | 1993-12-28 | 1995-07-18 | タナカプリコート株式会社 | ボルト用ゆるみ止め剤の塗布装置 |
| CN112934919B (zh) * | 2021-02-05 | 2022-07-01 | 云南大地丰源环保有限公司 | 一种废弃无水氯化铝的处理方法 |
-
1975
- 1975-07-09 FR FR7521556A patent/FR2317231A1/fr active Granted
-
1976
- 1976-07-05 SE SE7607679A patent/SE412576B/xx not_active IP Right Cessation
- 1976-07-05 CA CA256,249A patent/CA1078137A/fr not_active Expired
- 1976-07-06 AU AU15624/76A patent/AU501423B2/en not_active Expired
- 1976-07-06 GB GB28087/76A patent/GB1486759A/en not_active Expired
- 1976-07-06 JP JP51079551A patent/JPS529697A/ja active Granted
- 1976-07-06 IL IL49977A patent/IL49977A/xx unknown
- 1976-07-07 DE DE2630628A patent/DE2630628C3/de not_active Expired
- 1976-07-07 ZA ZA764043A patent/ZA764043B/xx unknown
- 1976-07-07 NO NO762363A patent/NO140926C/no unknown
- 1976-07-07 CH CH869376A patent/CH615650A5/fr not_active IP Right Cessation
- 1976-07-07 NL NLAANVRAGE7607523,A patent/NL181986C/xx not_active IP Right Cessation
- 1976-07-07 BR BR4434/76A patent/BR7604434A/pt unknown
- 1976-07-08 BE BE168752A patent/BE843925A/xx not_active IP Right Cessation
- 1976-07-08 IT IT25131/76A patent/IT1064884B/it active
- 1976-07-08 LU LU75327A patent/LU75327A1/xx unknown
- 1976-07-08 ES ES449665A patent/ES449665A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| IL49977A (en) | 1979-01-31 |
| JPS529697A (en) | 1977-01-25 |
| ZA764043B (en) | 1977-08-31 |
| IT1064884B (it) | 1985-02-25 |
| AU501423B2 (en) | 1979-06-21 |
| GB1486759A (en) | 1977-09-21 |
| FR2317231B1 (enrdf_load_stackoverflow) | 1977-12-16 |
| NO762363L (enrdf_load_stackoverflow) | 1977-01-11 |
| DE2630628B2 (de) | 1978-03-02 |
| BE843925A (fr) | 1976-11-03 |
| SE412576B (sv) | 1980-03-10 |
| NL7607523A (nl) | 1977-01-11 |
| ES449665A1 (es) | 1977-07-01 |
| AU1562476A (en) | 1978-01-12 |
| FR2317231A1 (fr) | 1977-02-04 |
| CH615650A5 (en) | 1980-02-15 |
| DE2630628C3 (de) | 1978-10-26 |
| DE2630628A1 (de) | 1977-01-13 |
| NL181986B (nl) | 1987-07-16 |
| LU75327A1 (enrdf_load_stackoverflow) | 1977-04-01 |
| NO140926C (no) | 1979-12-12 |
| BR7604434A (pt) | 1978-01-31 |
| NO140926B (no) | 1979-09-03 |
| SE7607679L (sv) | 1977-01-10 |
| NL181986C (nl) | 1987-12-16 |
| JPS5329679B2 (enrdf_load_stackoverflow) | 1978-08-22 |
| IL49977A0 (en) | 1976-09-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |