CA1074341A - Alkali-resistant glass composition and glass fibers made therefrom - Google Patents
Alkali-resistant glass composition and glass fibers made therefromInfo
- Publication number
- CA1074341A CA1074341A CA256,890A CA256890A CA1074341A CA 1074341 A CA1074341 A CA 1074341A CA 256890 A CA256890 A CA 256890A CA 1074341 A CA1074341 A CA 1074341A
- Authority
- CA
- Canada
- Prior art keywords
- mole
- glass
- cao
- fibers
- zro2
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011521 glass Substances 0.000 title claims abstract description 121
- 239000000203 mixture Substances 0.000 title claims abstract description 110
- 239000003513 alkali Substances 0.000 title claims abstract description 50
- 239000003365 glass fiber Substances 0.000 title claims abstract description 46
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 56
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims abstract description 21
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 4
- 229910052785 arsenic Inorganic materials 0.000 claims abstract description 4
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 4
- 229910052802 copper Inorganic materials 0.000 claims abstract description 4
- 229910052735 hafnium Inorganic materials 0.000 claims abstract description 4
- 229910052742 iron Inorganic materials 0.000 claims abstract description 4
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 4
- 229910052751 metal Inorganic materials 0.000 claims abstract description 4
- 239000002184 metal Substances 0.000 claims abstract description 4
- 229910052718 tin Inorganic materials 0.000 claims abstract description 4
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 4
- 229910052727 yttrium Inorganic materials 0.000 claims abstract description 4
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 4
- 150000002222 fluorine compounds Chemical class 0.000 claims abstract 3
- 239000000835 fiber Substances 0.000 claims description 47
- 238000009987 spinning Methods 0.000 claims description 25
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 13
- 229910052681 coesite Inorganic materials 0.000 claims description 7
- 229910052906 cristobalite Inorganic materials 0.000 claims description 7
- 229910052682 stishovite Inorganic materials 0.000 claims description 7
- 229910052905 tridymite Inorganic materials 0.000 claims description 7
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims description 6
- 229910052787 antimony Inorganic materials 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 description 23
- 239000004568 cement Substances 0.000 description 22
- 208000012886 Vertigo Diseases 0.000 description 21
- 239000013078 crystal Substances 0.000 description 19
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- 239000000047 product Substances 0.000 description 17
- 239000000243 solution Substances 0.000 description 15
- 238000002844 melting Methods 0.000 description 13
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 13
- 238000011282 treatment Methods 0.000 description 13
- 230000001965 increasing effect Effects 0.000 description 12
- 230000008018 melting Effects 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 8
- 239000000306 component Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 230000004580 weight loss Effects 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 230000014759 maintenance of location Effects 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 5
- 239000004567 concrete Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 229910052697 platinum Inorganic materials 0.000 description 5
- 229910001260 Pt alloy Inorganic materials 0.000 description 4
- 238000011835 investigation Methods 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 230000010494 opalescence Effects 0.000 description 4
- 230000003014 reinforcing effect Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 101100536354 Drosophila melanogaster tant gene Proteins 0.000 description 3
- 239000010425 asbestos Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 3
- 239000000920 calcium hydroxide Substances 0.000 description 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 3
- 235000011116 calcium hydroxide Nutrition 0.000 description 3
- 238000001723 curing Methods 0.000 description 3
- 239000006066 glass batch Substances 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 239000006060 molten glass Substances 0.000 description 3
- 238000005191 phase separation Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 239000011819 refractory material Substances 0.000 description 3
- 229910052895 riebeckite Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 2
- 239000011398 Portland cement Substances 0.000 description 2
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000000378 calcium silicate Substances 0.000 description 2
- 229910052918 calcium silicate Inorganic materials 0.000 description 2
- 239000011083 cement mortar Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000011151 fibre-reinforced plastic Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 230000002787 reinforcement Effects 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- MQWCQFCZUNBTCM-UHFFFAOYSA-N 2-tert-butyl-6-(3-tert-butyl-2-hydroxy-5-methylphenyl)sulfanyl-4-methylphenol Chemical compound CC(C)(C)C1=CC(C)=CC(SC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O MQWCQFCZUNBTCM-UHFFFAOYSA-N 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229910016287 MxOy Inorganic materials 0.000 description 1
- 229910018967 Pt—Rh Inorganic materials 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000006063 cullet Substances 0.000 description 1
- 238000004031 devitrification Methods 0.000 description 1
- 238000004512 die casting Methods 0.000 description 1
- BXKDSDJJOVIHMX-UHFFFAOYSA-N edrophonium chloride Chemical compound [Cl-].CC[N+](C)(C)C1=CC=CC(O)=C1 BXKDSDJJOVIHMX-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000003733 fiber-reinforced composite Substances 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000007496 glass forming Methods 0.000 description 1
- 239000011396 hydraulic cement Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 238000009740 moulding (composite fabrication) Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 235000009991 pite Nutrition 0.000 description 1
- 244000293655 pite Species 0.000 description 1
- PXXKQOPKNFECSZ-UHFFFAOYSA-N platinum rhodium Chemical compound [Rh].[Pt] PXXKQOPKNFECSZ-UHFFFAOYSA-N 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C13/00—Fibre or filament compositions
- C03C13/001—Alkali-resistant fibres
- C03C13/002—Alkali-resistant fibres containing zirconium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/20—Compositions for glass with special properties for chemical resistant glass
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15877475A JPS5282915A (en) | 1975-12-30 | 1975-12-30 | Composite of alkaliiproof glass and alkaliiproof glass fibers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1074341A true CA1074341A (en) | 1980-03-25 |
Family
ID=15679036
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA256,890A Expired CA1074341A (en) | 1975-12-30 | 1976-07-13 | Alkali-resistant glass composition and glass fibers made therefrom |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4067744A (enExample) |
| JP (1) | JPS5282915A (enExample) |
| CA (1) | CA1074341A (enExample) |
| DE (1) | DE2631653C3 (enExample) |
| GB (1) | GB1540770A (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0631995A1 (en) | 1993-06-24 | 1995-01-04 | Dentsply GmbH | Dental prosthesis |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6054248B2 (ja) * | 1978-07-08 | 1985-11-29 | 日本板硝子株式会社 | 耐アルカリ性ガラス組成物 |
| IE50727B1 (en) * | 1980-02-27 | 1986-06-25 | Pilkington Brothers Ltd | Alkali resistant glass fibres and cementitious products reinforced with such glass fibres |
| AT385027B (de) * | 1985-09-27 | 1988-02-10 | Porr Allg Bauges | Feststoffmasse fuer spritzbeton |
| DE4419388C2 (de) * | 1994-05-30 | 1996-10-02 | Witega Angewandte Werkstoff Forschung Gemeinnuetzige Gmbh Adlershof | Recycling von Abfallmaterialien in Form des Bildschirmglases von Bildröhren aus Fernsehgeräten und von Computer-Monitoren |
| FR2823510B1 (fr) * | 2001-04-11 | 2003-06-06 | Saint Gobain Vetrotex | Procede, installation de fabrication de mats et utilisation associee |
| ITMI20091046A1 (it) * | 2009-06-12 | 2010-12-13 | Ruredil Spa | Malta cementizia, rinforzo e metodo di rinforzo di strutture edili |
| CN109896740B (zh) * | 2019-04-24 | 2022-04-22 | 成都光明光电股份有限公司 | 光学玻璃及光学元件 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU464066B2 (en) * | 1972-05-12 | 1975-08-14 | Kanebo, Ltd | Alkali resistant glass fibers |
| GB1459385A (en) * | 1973-02-14 | 1976-12-22 | Turner Newall Ltd | Glass fibres |
| GB1497223A (en) * | 1974-03-20 | 1978-01-05 | Kanebo Ltd | Alkali-resistant glass composition |
-
1975
- 1975-12-30 JP JP15877475A patent/JPS5282915A/ja active Granted
-
1976
- 1976-07-13 CA CA256,890A patent/CA1074341A/en not_active Expired
- 1976-07-14 DE DE2631653A patent/DE2631653C3/de not_active Expired
- 1976-07-16 US US05/706,009 patent/US4067744A/en not_active Expired - Lifetime
- 1976-07-23 GB GB30862/76A patent/GB1540770A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0631995A1 (en) | 1993-06-24 | 1995-01-04 | Dentsply GmbH | Dental prosthesis |
| US5849068A (en) * | 1993-06-24 | 1998-12-15 | Dentsply G.M.B.H. | Dental prosthesis |
| US6126732A (en) * | 1993-06-24 | 2000-10-03 | Dentsply Detrey Gmbh | Dental prosthesis |
Also Published As
| Publication number | Publication date |
|---|---|
| GB1540770A (en) | 1979-02-14 |
| JPS5345323B2 (enExample) | 1978-12-06 |
| US4067744A (en) | 1978-01-10 |
| DE2631653B2 (de) | 1979-01-04 |
| AU1574976A (en) | 1978-01-12 |
| DE2631653C3 (de) | 1979-08-23 |
| JPS5282915A (en) | 1977-07-11 |
| DE2631653A1 (de) | 1977-07-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |