CA1070878A - Dimethylol dihydroxyethylene urea phosphoric acid-sodium metaborate aqueous or alcoholic solutions, for permanent press textiles - Google Patents
Dimethylol dihydroxyethylene urea phosphoric acid-sodium metaborate aqueous or alcoholic solutions, for permanent press textilesInfo
- Publication number
- CA1070878A CA1070878A CA244,045A CA244045A CA1070878A CA 1070878 A CA1070878 A CA 1070878A CA 244045 A CA244045 A CA 244045A CA 1070878 A CA1070878 A CA 1070878A
- Authority
- CA
- Canada
- Prior art keywords
- phosphoric acid
- sodium metaborate
- sodium
- dihydroxyethylene urea
- dimethylol dihydroxyethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004753 textile Substances 0.000 title claims abstract description 18
- 230000001476 alcoholic effect Effects 0.000 title description 2
- YNMKQYYIBNJLOP-UHFFFAOYSA-N [Na].P(O)(O)(O)=O.NC(=O)N.C(O)C(=C(O)CO)O Chemical compound [Na].P(O)(O)(O)=O.NC(=O)N.C(O)C(=C(O)CO)O YNMKQYYIBNJLOP-UHFFFAOYSA-N 0.000 title 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 36
- ZEYUSQVGRCPBPG-UHFFFAOYSA-N 4,5-dihydroxy-1,3-bis(hydroxymethyl)imidazolidin-2-one Chemical compound OCN1C(O)C(O)N(CO)C1=O ZEYUSQVGRCPBPG-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 18
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000003054 catalyst Substances 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 239000006172 buffering agent Substances 0.000 claims abstract description 6
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims abstract description 5
- 238000013035 low temperature curing Methods 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 229910021538 borax Inorganic materials 0.000 claims description 3
- 239000004328 sodium tetraborate Substances 0.000 claims description 3
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 3
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 claims description 2
- 238000011065 in-situ storage Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims 1
- 238000004383 yellowing Methods 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- 230000002939 deleterious effect Effects 0.000 abstract description 3
- 239000004744 fabric Substances 0.000 description 40
- 239000011347 resin Substances 0.000 description 14
- 229920005989 resin Polymers 0.000 description 14
- 229920000742 Cotton Polymers 0.000 description 8
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 8
- 239000011734 sodium Substances 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 238000011282 treatment Methods 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 229940015043 glyoxal Drugs 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 239000000872 buffer Substances 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002964 rayon Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- TUHRVKQKRZLMHU-UHFFFAOYSA-N 2-(hydroxymethyl)prop-1-ene-1,1,3-triol Chemical group OCC(CO)=C(O)O TUHRVKQKRZLMHU-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000008366 buffered solution Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- -1 e.g. Chemical compound 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- RBWSWDPRDBEWCR-RKJRWTFHSA-N sodium;(2r)-2-[(2r)-3,4-dihydroxy-5-oxo-2h-furan-2-yl]-2-hydroxyethanolate Chemical compound [Na+].[O-]C[C@@H](O)[C@H]1OC(=O)C(O)=C1O RBWSWDPRDBEWCR-RKJRWTFHSA-N 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/565,071 US3954405A (en) | 1975-04-09 | 1975-04-09 | Permanent-press system |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1070878A true CA1070878A (en) | 1980-01-29 |
Family
ID=24257085
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA244,045A Expired CA1070878A (en) | 1975-04-09 | 1976-01-22 | Dimethylol dihydroxyethylene urea phosphoric acid-sodium metaborate aqueous or alcoholic solutions, for permanent press textiles |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US3954405A (en:Method) |
| JP (1) | JPS51119898A (en:Method) |
| BE (1) | BE839180A (en:Method) |
| CA (1) | CA1070878A (en:Method) |
| CH (2) | CH603888B5 (en:Method) |
| DE (1) | DE2533867A1 (en:Method) |
| FR (1) | FR2307079A1 (en:Method) |
| GB (1) | GB1495818A (en:Method) |
| IT (1) | IT1058393B (en:Method) |
| NL (1) | NL7509818A (en:Method) |
| SE (1) | SE7508209L (en:Method) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4088443A (en) * | 1976-02-06 | 1978-05-09 | The United States Of America As Represented By The Secretary Of Agriculture | Aluminum chlorhydroxide-phosphoric acid catalyst system for flash cure treatments to give improved durable-press properties in cellulose-containing textiles |
| US4269602A (en) * | 1979-05-07 | 1981-05-26 | Riegel Textile Corporation | Buffered non-formaldehyde durable press textile treatment |
| US4396391B2 (en) * | 1982-06-30 | 1993-03-16 | Treating cellulose textile fabrics with dimenthylol dihydroyethyleneuree-polyol | |
| US4539008A (en) * | 1984-03-06 | 1985-09-03 | The United States Of America As Represented By The Secretary Of Agriculture | Agents to produce durable press low formaldehyde release cellulosic textiles: etherified N,N-bis(hydroxymethyl)-carbamates |
| GB9304887D0 (en) * | 1993-03-10 | 1993-04-28 | Courtaulds Plc | Fibre treatment |
| CN104294678B (zh) * | 2014-09-25 | 2016-09-07 | 泰州市银杏织锦有限公司 | 一种助染组合物的制备方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB522341A (en) * | 1938-01-20 | 1940-06-14 | Permold Co | Improvements in or relating to water-cooled cylinder heads of internal combustion engines |
| US2482756A (en) * | 1944-06-10 | 1949-09-27 | Bancroft & Sons Co J | Flameproofing of fibrous materials |
| US2898238A (en) * | 1956-08-20 | 1959-08-04 | American Cyanamid Co | Process for treating textiles with ethylene urea-formaldehyde reaction products |
| US3165374A (en) * | 1958-09-24 | 1965-01-12 | Bancroft & Sons Co J | Process of partially methylenating cellulose textiles |
| GB1107796A (en) * | 1965-11-05 | 1968-03-27 | Sun Chemical Corp | Improvements in the treatment of cellulosic textile materials |
| US3526474A (en) * | 1966-09-30 | 1970-09-01 | Us Agriculture | Abrasion-resistant durably-pressed cellulosic textiles |
| US3576591A (en) * | 1968-04-23 | 1971-04-27 | Proctor Chemical Co Inc | Methylolated cyclic urea compositions containing sodium formate or sodium tetraborate |
| US3765836A (en) * | 1970-03-04 | 1973-10-16 | Union Carbide Corp | Process for creaseproofing cellulose-containing fabric with glyoxal-urea-formaldehyde reaction product and a boron compound |
| US3811210A (en) * | 1972-01-26 | 1974-05-21 | Us Agriculture | Mild cure finishing process incorporating improved catalyst systems to produce wrinkle resistant, durably pressed and creased cellulosic textile products |
-
1975
- 1975-04-09 US US05/565,071 patent/US3954405A/en not_active Expired - Lifetime
- 1975-05-14 GB GB20279/75A patent/GB1495818A/en not_active Expired
- 1975-07-17 SE SE7508209A patent/SE7508209L/xx unknown
- 1975-07-29 DE DE19752533867 patent/DE2533867A1/de not_active Withdrawn
- 1975-08-18 NL NL7509818A patent/NL7509818A/xx not_active Application Discontinuation
- 1975-08-22 CH CH1092575A patent/CH603888B5/xx not_active IP Right Cessation
- 1975-08-22 CH CH1092575D patent/CH1092575A4/xx unknown
-
1976
- 1976-01-22 CA CA244,045A patent/CA1070878A/en not_active Expired
- 1976-02-28 JP JP51021752A patent/JPS51119898A/ja active Pending
- 1976-03-04 BE BE164847A patent/BE839180A/xx unknown
- 1976-04-06 FR FR7609990A patent/FR2307079A1/fr active Granted
- 1976-04-07 IT IT22033/76A patent/IT1058393B/it active
Also Published As
| Publication number | Publication date |
|---|---|
| GB1495818A (en) | 1977-12-21 |
| IT1058393B (it) | 1982-04-10 |
| SE7508209L (sv) | 1976-10-10 |
| FR2307079A1 (fr) | 1976-11-05 |
| BE839180A (fr) | 1976-09-06 |
| DE2533867A1 (de) | 1977-03-31 |
| FR2307079B1 (en:Method) | 1979-06-22 |
| CH1092575A4 (en:Method) | 1977-08-31 |
| JPS51119898A (en) | 1976-10-20 |
| US3954405A (en) | 1976-05-04 |
| NL7509818A (nl) | 1976-10-12 |
| CH603888B5 (en:Method) | 1978-08-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |