CA1069264A - Manufacture of fibrids of polyolefins - Google Patents
Manufacture of fibrids of polyolefinsInfo
- Publication number
- CA1069264A CA1069264A CA215,799A CA215799A CA1069264A CA 1069264 A CA1069264 A CA 1069264A CA 215799 A CA215799 A CA 215799A CA 1069264 A CA1069264 A CA 1069264A
- Authority
- CA
- Canada
- Prior art keywords
- fibrids
- solvent
- polyethylene
- pressure
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 229920000098 polyolefin Polymers 0.000 title claims description 28
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical class CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims abstract description 72
- 239000002904 solvent Substances 0.000 claims abstract description 48
- 239000004698 Polyethylene Substances 0.000 claims abstract description 43
- -1 polyethylene Polymers 0.000 claims abstract description 42
- 229920000573 polyethylene Polymers 0.000 claims abstract description 39
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000000203 mixture Substances 0.000 claims abstract description 22
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000005977 Ethylene Substances 0.000 claims abstract description 16
- 238000009835 boiling Methods 0.000 claims abstract description 16
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims abstract description 12
- CRSOQBOWXPBRES-UHFFFAOYSA-N neopentane Chemical compound CC(C)(C)C CRSOQBOWXPBRES-UHFFFAOYSA-N 0.000 claims abstract description 10
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000001035 drying Methods 0.000 claims abstract description 6
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 5
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 22
- 239000000155 melt Substances 0.000 claims description 9
- 230000001680 brushing effect Effects 0.000 claims description 2
- 239000000243 solution Substances 0.000 description 41
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 20
- 229920001577 copolymer Polymers 0.000 description 15
- 229940093470 ethylene Drugs 0.000 description 14
- 239000007788 liquid Substances 0.000 description 13
- 229920000642 polymer Polymers 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 239000000835 fiber Substances 0.000 description 11
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- 239000011877 solvent mixture Substances 0.000 description 9
- 239000000499 gel Substances 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 5
- 239000012456 homogeneous solution Substances 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- 229940068921 polyethylenes Drugs 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 229920000877 Melamine resin Polymers 0.000 description 4
- 206010061592 cardiac fibrillation Diseases 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 230000002600 fibrillogenic effect Effects 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- 239000013557 residual solvent Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 239000007900 aqueous suspension Substances 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 230000001427 coherent effect Effects 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 229920001038 ethylene copolymer Polymers 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- WHOZNOZYMBRCBL-OUKQBFOZSA-N (2E)-2-Tetradecenal Chemical compound CCCCCCCCCCC\C=C\C=O WHOZNOZYMBRCBL-OUKQBFOZSA-N 0.000 description 1
- OZCMOJQQLBXBKI-UHFFFAOYSA-N 1-ethenoxy-2-methylpropane Chemical compound CC(C)COC=C OZCMOJQQLBXBKI-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical group CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 244000082988 Secale cereale Species 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 244000166490 Tetrameles nudiflora Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 238000009960 carding Methods 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- CRRYCJOJLZQAFR-UHFFFAOYSA-N cyclohexane;pentane Chemical compound CCCCC.C1CCCCC1 CRRYCJOJLZQAFR-UHFFFAOYSA-N 0.000 description 1
- UZUODNWWWUQRIR-UHFFFAOYSA-L disodium;3-aminonaphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].C1=CC=C(S([O-])(=O)=O)C2=CC(N)=CC(S([O-])(=O)=O)=C21 UZUODNWWWUQRIR-UHFFFAOYSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 235000011087 fumaric acid Nutrition 0.000 description 1
- 150000002238 fumaric acids Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- XONPDZSGENTBNJ-UHFFFAOYSA-N molecular hydrogen;sodium Chemical group [Na].[H][H] XONPDZSGENTBNJ-UHFFFAOYSA-N 0.000 description 1
- APVPOHHVBBYQAV-UHFFFAOYSA-N n-(4-aminophenyl)sulfonyloctadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NS(=O)(=O)C1=CC=C(N)C=C1 APVPOHHVBBYQAV-UHFFFAOYSA-N 0.000 description 1
- 229940044654 phenolsulfonic acid Drugs 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical group [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000006200 vaporizer Substances 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/11—Flash-spinning
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/10—Organic non-cellulose fibres
- D21H13/12—Organic non-cellulose fibres from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H13/14—Polyalkenes, e.g. polystyrene polyethylene
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H5/00—Special paper or cardboard not otherwise provided for
- D21H5/12—Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials
- D21H5/20—Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials of organic non-cellulosic fibres too short for spinning, with or without cellulose fibres
- D21H5/202—Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials of organic non-cellulosic fibres too short for spinning, with or without cellulose fibres polyolefins
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Nonwoven Fabrics (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Paper (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2363672A DE2363672C3 (de) | 1973-12-21 | 1973-12-21 | Verfahren zur Herstellung von Kurzfasern aus Niederdruckpolyäthylen und deren Verwendung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1069264A true CA1069264A (en) | 1980-01-08 |
Family
ID=5901457
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA215,799A Expired CA1069264A (en) | 1973-12-21 | 1974-12-11 | Manufacture of fibrids of polyolefins |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS5094234A (ja) |
| BE (1) | BE823440A (ja) |
| CA (1) | CA1069264A (ja) |
| DE (1) | DE2363672C3 (ja) |
| FR (1) | FR2255400B3 (ja) |
| GB (1) | GB1477378A (ja) |
| IT (1) | IT1025794B (ja) |
| SE (1) | SE406332B (ja) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4181794A (en) * | 1978-08-28 | 1980-01-01 | Gulf Oil Corporation | Method for manufacture of olefin polymer fibrils |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DK116229B (da) * | 1957-06-11 | 1969-12-22 | Du Pont | Kontinuerligt extruderet eller spundet filamentprodukt og fremgangsmåde til dets fremstilling. |
| US3227664A (en) * | 1961-12-07 | 1966-01-04 | Du Pont | Ultramicrocellular structures of crystalline organic polymer |
| US3081519A (en) * | 1962-01-31 | 1963-03-19 | Fibrillated strand | |
| NL300881A (ja) * | 1962-11-23 | |||
| US3904804A (en) * | 1968-10-14 | 1975-09-09 | Mitsubishi Rayon Co | Polyolefin micro-flake aggregation useful for manufacturing synthetic papers and polyolefin synthetic papers obtainable therewith |
| FR1596107A (ja) * | 1968-12-13 | 1970-06-15 | ||
| JPS4813722B1 (ja) * | 1970-07-14 | 1973-04-28 | ||
| JPS4813723B1 (ja) * | 1970-07-16 | 1973-04-28 | ||
| BE787032A (ja) * | 1971-08-06 | 1973-02-01 | Solvay | |
| BE787033A (ja) * | 1971-08-06 | 1973-02-01 | Solvay | |
| NL169760C (nl) * | 1972-04-22 | 1982-08-16 | Stamicarbon | Werkwijze voor het bereiden van polymeervezels. |
-
1973
- 1973-12-21 DE DE2363672A patent/DE2363672C3/de not_active Expired
-
1974
- 1974-11-18 IT IT29556/74A patent/IT1025794B/it active
- 1974-12-11 CA CA215,799A patent/CA1069264A/en not_active Expired
- 1974-12-17 BE BE151576A patent/BE823440A/xx not_active IP Right Cessation
- 1974-12-18 JP JP49144597A patent/JPS5094234A/ja active Pending
- 1974-12-18 FR FR7441758A patent/FR2255400B3/fr not_active Expired
- 1974-12-19 SE SE7416069A patent/SE406332B/xx unknown
- 1974-12-19 GB GB5485474A patent/GB1477378A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| IT1025794B (it) | 1978-08-30 |
| FR2255400B3 (ja) | 1977-09-16 |
| GB1477378A (en) | 1977-06-22 |
| BE823440A (fr) | 1975-06-17 |
| JPS5094234A (ja) | 1975-07-26 |
| SE406332B (sv) | 1979-02-05 |
| DE2363672A1 (de) | 1975-07-10 |
| DE2363672B2 (de) | 1975-10-30 |
| DE2363672C3 (de) | 1982-08-05 |
| FR2255400A1 (ja) | 1975-07-18 |
| SE7416069L (ja) | 1975-06-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3047456A (en) | Manufacture of paper products from fibers wet spun from polymer blends | |
| US3891499A (en) | Synthetic papermaking pulp and process of manufacture | |
| US3920508A (en) | Polyolefin pulp and process for producing same | |
| US3047455A (en) | Paper manufacture from synthetic non-cellulosic fibers | |
| JPH0157166B2 (ja) | ||
| US4297412A (en) | Two-component mixed acrylic fibres wherein acrylic components have different amounts of non-ionizable plasticizing comonomer | |
| CA1068861A (en) | Process for the production of fibrous structures | |
| Ota et al. | Chitin/cellulose blend fibers prepared by wet and dry‐wet spinning | |
| WO1997033018A1 (en) | Fibril based fibers, method of manufacturing same, spinning nozzle used in same, and moldings obtained therefrom | |
| US4457884A (en) | Continuous dry-spinning process for acrylonitrile filaments and fibres | |
| US4110385A (en) | Manufacture of fibrids of polyolefins | |
| US4377648A (en) | Cellulose-polyacrylonitrile-DMSO-formaldehyde solutions, articles, and methods of making same | |
| US2327460A (en) | Process for stapling and crimping synthetic textile fibers | |
| US3920509A (en) | Process of making polyolefin fibers | |
| RU2181798C2 (ru) | Способ получения формованного целлюлозного тела, целлюлозное формованное тело | |
| CA1069264A (en) | Manufacture of fibrids of polyolefins | |
| US4112029A (en) | Manufacture of fibrids of polyolefins | |
| US2585499A (en) | Production of shaped articles from acrylonitrile polymers | |
| US4224269A (en) | Process for spinning hygroscopic filaments and fibers | |
| CA1235267A (en) | Process for preparing polyacrylonitrile filaments having high tensile strength and modulus | |
| US4166091A (en) | Production of plexifilament strands | |
| US4997610A (en) | Process for producing filaments and fibers of acrylic polymers which contain carboxyl groups | |
| US5217701A (en) | Process for producing carbon materials | |
| CA1079465A (en) | Highly shrinkable acrylic fibres or filaments | |
| US4185059A (en) | Process for the preparation of hydrophilic fibres and filaments from synthetic polymers |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |