CA1068308A - High temperature resistant concrete and manufacturing process - Google Patents

High temperature resistant concrete and manufacturing process

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Publication number
CA1068308A
CA1068308A CA232,650A CA232650A CA1068308A CA 1068308 A CA1068308 A CA 1068308A CA 232650 A CA232650 A CA 232650A CA 1068308 A CA1068308 A CA 1068308A
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CA
Canada
Prior art keywords
silica
molded
varying
concrete
mass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA232,650A
Other languages
French (fr)
Inventor
Marcel A.L. Marre
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Individual
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Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CA232,650A priority Critical patent/CA1068308A/en
Application granted granted Critical
Publication of CA1068308A publication Critical patent/CA1068308A/en
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Aftertreatments Of Artificial And Natural Stones (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

Un béton résistant aux hautes températures pour permettre son émaillage. Le béton est obtenu en mélangeant froid du ciment Portland, de la silice, une autre substance à base de silice et un fondant, tel que du verre pulvérisé avec addition d'eau, moulage et prise normale. Le béton, une fois durci, est recouvert d'un émail ou autre revêtement fondant à haute température et chauffé à une haute température de 700.degree.C à 1500.degree.C, afin de causer la fonte et l'étalement de l'émail. Le béton est ensuite refroidi. La présence de la silice et de l'autre substance à base de silice provoque la formation de silicate de calcium insoluble et anhydre lors de la chauffe. La présence du fondant élimine les pores restant dans le ciment et aide à la fonte et à l'étalement de l'émail lors de la chauffe. Dans le produit obtenu, l'émail est uniformément réparti sur toute la surface du bloc ou du panneau de péteon.A concrete resistant to high temperatures to allow its enameling. Concrete is obtained by cold mixing Portland cement, silica, another silica-based substance and a flux, such as sprayed glass with the addition of water, molding and normal setting. The concrete, once hardened, is covered with an enamel or other coating melting at high temperature and heated to a high temperature from 700.degree.C to 1500.degree.C, in order to cause melting and spreading of the 'E-mail. The concrete is then cooled. The presence of silica and the other silica-based substance causes the formation of insoluble, anhydrous calcium silicate upon heating. The presence of the flux removes the pores remaining in the cement and helps the melting and spreading of the enamel during heating. In the product obtained, the enamel is uniformly distributed over the entire surface of the block or of the peton board.

Description

`` ` iQ68308 La pr~snte invention a trait à de~ bloc8 ou panneau~ de b~ton recouverts d'un é~ail ou de tout au~re reve-~ement ~ondant ~ haut~
t~p~rature.
La pré~ente invention a égaloment trait à un proc~d~ pour l'obten~ion des blocs et panneaux pr~cit~s.
Da~ la de~nde AU Ca~ada d~po~e le 9 8vril 1974, sous le num~ro 197,364, intitul~es "PROCEDE DE F~R~ATION D'UN B~TON ~NHYDR$~, par le ~e i2venteur, l'on d~crlt un b~ton qui peut être chauff~ A
hAutes t~p~ratures sans désagr6gat~on. Ce b~ton pcut donc être recouvert d'un é~ail. Ce béton est compos~ plu8 particulièrement de ciment PortlaDd, de ~illce et de sillcate de sodlum ou de pota3sium. L'on a trouv6 que ce bSton contient encore dec porss et a une surface un peu rugueuse~ ce qui - e~êche l'~talement uniforme de 1'6mail lor~ de la cuisson.
Selon la pr~sonto invention, l'on a trouv~ qu'en a~outant un fondant à la co~position précit6e~ i'on aide grande~ent ~ la fonts et à
l'~tQlement unilorme de l'~mail super~icid.
Selon la pr~ente i~vention~ l'on procède de la raQon ~uivante;
; L~on m~lange du ciment Portland avec d0 la ailice et un sillcate dlun ~tal aloslln a~nsi qu'un fond~ avee une qusntité d'eau ~ppropriée.
La pâte ainsl obtonue est placée dans un moule. Une ~ois la pr13e de ; b6~on compl~tée, le bloo ou le panneau est recouvert d'un reretem~nt .: fondant à haute t~pératuro~ tel qu~un 6mailJ et le~ bloc~ ou panneQu~
aont eDeuite dhau~6s d~ns un rour ~ une temperature vsrlant entre 700 C ot 1500C et~ do preférenco à enriron 1120C~ de ta~on à liquérisr l'~nail qul s~étale alors sur la surface de blocs ou pannesu~ on laisse ~nsuite refroidir les blocs ou panneau~ sil duro~ recouvre les blocs ou panneau~ d~une ~açon absolument uniforme.
Les pourc~ntag~s en poids de~ diver~ i~gredients peu~ent varier coD~idérable~ents le ciment Portland entre 10~ et 6q~; la silice entre 10~ et 60~; le silicate de ~odiu~ ou de potassium entre 4~ et ~q~; et le ~ondant entre 7~ et 70~. ~e~ fondants utilis~ 80~ ~4~ parmi
`` `iQ68308 The pr ~ snte invention relates to ~ bloc8 or panel ~ of b ~ ton covered with é ~ garlic or all ~ reve- ~ ement ~ undulating ~ high ~
t ~ p ~ rature.
The pre ~ ente invention also relates to a proc ~ d ~ for obtaining the above-mentioned blocks and panels.
Da ~ la de ~ nde AU Ca ~ ada de ~ po ~ e 9 April 8, 1974, under the number 197,364, entitled "PROCEDE DE F ~ R ~ ATION DE A B ~ TON ~ NHYDR $ ~, by the ~ e i2venteur, we d ~ crlt a b ~ tone which can be heated ~ A
High tears without erosion. This b ~ your pcut therefore be covered of a garlic. This concrete is composed ~ plu8 particularly of PortlaDd cement, of ~ illce and sodlum or pota3sium sillcate. It was found that this bSton still contains dec porss and has a slightly rough surface ~ which - It prevents the uniform spreading of the enamel during cooking.
According to the pr ~ esto invention, it has been found that by having a melting at the co ~ aforementioned position ~ i'm helping great ~ ent ~ the font and the uniform element of the super ~ icid mail.
According to the pr ~ ente i ~ vention ~ we proceed from the following raQon ~;
; Portland cement is mixed with ailice and a sillcate dlun ~ tal aloslln a ~ nsi that a background ~ avee a qusntity of water ~ ppropriée.
The dough thus obtained is placed in a mold. Once the first ; b6 ~ on compl ~ tée, the bloo or the panel is covered with a reretem ~ nt .: fondant at high t ~ peraturo ~ such as ~ a 6mailJ and the ~ block ~ or breakdownQu ~
Have been around 6s in one round at a temperature between 700 C ot 1500C and ~ do preférenco to wrap around 1120C ~ of ta ~ on to liquefy the ~ nail qul then spreads over the surface of blocks or pannels leaves ~ nsuite to cool the blocks or panel ~ sil duro ~ covers the blocks or panel ~ of a ~ absolutely uniform lesson.
The percentages by weight of ~ diver ~ i ~ gredients can vary slightly coD ~ ideal ~ ents Portland cement between 10 ~ and 6q ~; silica enters 10 ~ and 60 ~; silicate of ~ odiu ~ or potassium between 4 ~ and ~ q ~; and the ~ undulating between 7 ~ and 70 ~. ~ e ~ fondants used ~ 80 ~ ~ 4 ~ from

- 2 - ~

6l~308 les ingrédionts suivant~s lo le ~taphosphate d~ c~lcium Ca (P3) 2 dqs rrittos ou verre ~ondu brusqu~m~n~ rsfroidi puls ~ine~olt pulv~ri~6 3O d~ verre en poudre ~eo ac~mplc3 suivants aont de8 OE~aples pr~réa. Il ~t entendu qu~un grand no~bre d~autros co~po itions peu~ent êtro utili~ées dans le8 li~ites Dlentiol~nées ci-do~sus.
- 1~ ~E
- 10 ~e ~éla~gc ~ulvant a ete pr~par6s H61ango ~ grsnulo~trie (msill~ de ta~is poid~ en pourcsntage par pouce ¢arrfi) li~roY en poids ailico 16 7 9.5 ailice 24 7 9.5 ~ilice 4~ 20 27-3 sllic~ 200 10 13.6 ~ 59.9 ¢i~ent Portland 15 20.4 silloato de ~odium on poudro 7 9-5 . 20 ~erre en poudre 7.5 10.2 Total lb~73.5 lOO.
Ie ~filange obtonu a ~té additlonn6 d~aau en quantlt~ au~
~anto pour for~er uno pât- qul, une rois moul~e dans de~ noule3 pour for~r d-s blocs ~t de~ psnnesus, a ~t~ lsiJ~é~ ~u repos ~u3qu~ conplè-t~nont de la pris- du béton IB ~urr~co dos bloos ou pannesu~ a étb ensuito reoouverte d'un ~nail do la coulour d~sir~- ~es blocs ainsi recouverts d'un ~2ail ont été places dans un four et chauff~s à uno te~p~rsture do 1120C pour liqu~fior ll~msil Apr~s rofroidisssnent~ les blocs et pan-neaus ~e uontraient aucune d~3sgrégation et l'~msil recouvrait la aurface d'une fs~on conpl~tement unlfor~e.
Les D~lange3 sdditioDnols suivant3 ont ~t3 pr6par5s et chauf-106~08 f~s ~ de~ t~mp~rature3 varisn~ eD~re 700 et 1500C en utili~ant la ~thode décrite dans lle~s~ple I~
N~lan~e B
8ilics, granulom~trie ~ariant entre 6 et 2G0 2~ en poids ciment Portland 2q~
silicate dc potassium 2 métaphosphate de ¢alclu~ ~0 lange C
;~ 10 sillce 15% en poids ` : ci~ent Portland 25%
dlicate de potasoiu~ 10 v~rro on poudre 5 lOC~

8111¢~ ~o%
oi~nG Portla~d 6q~
~ilicate do oodiu~ 4%
~ fritte colorée æ%
,; ~o 100 N~lang~
8ilico 40% on poid~
oi~ent Portland l sili¢ate de sodiu~ 20 ~orre en poudre 3 lOC~
Dans tous le~ CB8~ lo p~oduit obte~u 6v~it ~ubstsntielle~ent les ~es caraot~rlstiques que 19 produit de llex~ple I.

' :
- 2 - ~

6l ~ 308 the following ingredients lo le ~ taphosphate d ~ c ~ lcium Ca (P3) 2 dqs rrittos or glass ~ abrupt wavy ~ m ~ n ~ pulsed chilled ~ ine ~ olt pulv ~ ri ~ 6 3O glass powder ~ eo ac ~ mplc3 following have de8 OE ~ aples pr ~ sheave. It ~ t heard that a great number of other co ~ po itions little ~ ent be very useful in le8 li ~ ites Dlentiol ~ born above do ~.
- 1 ~ ~ E
- 10 ~ e ~ éla ~ gc ~ ulvant has been prepared ~ par6s H61ango ~ grsnulo ~ trie (msill ~ de ta ~ is poid ~ en pourcsntage per inch arrfi) li ~ roY by weight ailico 16 7 9.5 ailice 24 7 9.5 ~ ilice 4 ~ 20 27-3 sllic ~ 200 10 13.6 ~ 59.9 ¢ i ~ ent Portland 15 20.4 silloato de ~ odium on poudro 7 9-5 . 20 ~ wanders in powder 7.5 10.2 Total lb ~ 73.5 lOO.
Ie ~ filange obtonu a ~ té additlonn6 d ~ aau en quantlt ~ au ~
~ anto for for ~ er uno pât- qul, a kings mold ~ e in de ~ noule3 for for ~ r ds blocks ~ t of ~ psnnesus, a ~ t ~ lsiJ ~ é ~ ~ u repos ~ u3qu ~ conplè-t ~ do not take concrete IB ~ urr ~ co dos bloos or pannesu ~ a étb ensuito reopening of a ~ nail do the corridor of ~ sir ~ - ~ es blocks thus covered of a ~ 2ail were placed in an oven and heated ~ s to uno te ~ p ~ rsture do 1120C for liqu ~ fior ll ~ msil After cool down the blocks and pan neaus ~ e had no disaggregation and the msil covered the aurface fs ~ on conpl ~ tement unlfor ~ e.
The following mixtures3 have been prepared and heated.

106 ~ 08 f ~ s ~ de ~ t ~ mp ~ rature3 varisn ~ eD ~ re 700 and 1500C using the ~ method described in lle ~ s ~ ple I ~
N ~ lan ~ e B
8ilics, granulom ~ sorting ~ ranging between 6 and 2G0 2 ~ by weight Portland cement 2q ~
potassium silicate 2 ¢ alclu metaphosphate ~ ~ 0 swaddle C
; ~ 10 sillce 15% by weight `: ci ~ ent Portland 25%
delicate potasoiu ~ 10 v ~ rro on powder 5 lOC ~

8111 ¢ ~ ~ o%
oi ~ nG Portla ~ d 6q ~
~ ilicate do oodiu ~ 4%
~ colored frit æ%
,; ~ o 100 N ~ lang ~
8ilico 40% on weight ~
oi ~ ent Portland l sodiu sili ~ 20 ~ powdered orre 3 lOC ~
In all ~ CB8 ~ lo p ~ oduit obte ~ u 6v ~ it ~ ubstsntielle ~ ent the ~ es caraot ~ rlstiques that 19 produces llex ~ ple I.

'' :

Claims (7)

LES REALISATIONS DE L'INVENTION AU SUJET DESQUELLES UN DROIT
EXCLUSIF DE PROPRIETE OU DE PRIVILEGE EST REVENDIQUE, SONT
DEFINIES COMME SUIT:
THE ACHIEVEMENTS OF THE INVENTION ABOUT WHICH A RIGHT
EXCLUSIVE OF OWNERSHIP OR PRIVILEGE IS CLAIMED, ARE
DEFINED AS FOLLOWS:
1. Comme matériau de construction, une mas moulée obtenue par la chauffe à une température entre 700°C et 1500°C, d'un mélange moulé et durci contenant en pourcentage par poids 10% à 60%
de ciment Portland, 10% à 60% de silice, ?% à 20% de silicate d'un métal alcalin et de 7% à 70% d'un fondant.
1. As a building material, a molded mas obtained by heating to a temperature between 700 ° C and 1500 ° C, a molded and hardened mixture containing in percentage by weight 10% to 60%
Portland cement, 10% to 60% silica,?% to 20% silicate of a alkali metal and from 7% to 70% of a flux.
2. Le produit comme défini dans la revendication 1, dans lequel le fondant est choisi parmi:
a) le verre pulverisé
b) le métaphosphate de calcium.
2. The product as defined in claim 1, in which the fondant is chosen from:
a) sprayed glass b) calcium metaphosphate.
3. Le produit comme défini dans la revendication 1, dans lequel l'une au moins des faces de la masse moulée est recouverte d'un revêtement fondant à ladite température de chaffe. 3. The product as defined in claim 1, in which at least one of the faces of the molded mass is covered a coating melting at said chaffe temperature. 4. Le produit tel que défini dans la revendication 1, dans lequel la silice est un mélange de poudre de silice de diffé-rentes granulométries variant entre 6 et 200 mailles de tamis par pouce carré. 4. The product as defined in the claim 1, in which the silica is a mixture of silica powder of different grain sizes varying between 6 and 200 mesh screens square inch. 5. Un procédé pour la fabrication d'un bloc ou panneau utilisé comme matériau de construction, comportant le mélange de de ciment Portland en quantité variant entre 10% et 60%, de la silice en une quantité variant entre 10% et 60%, du silicate de sodium ou de potassium en quantité variant entre 4% et 20% et un fondant en quantité variant entre 7% et 70%, tous ces ingrédients étant pulvérisés et les pourcentages étant par poids, et de l'eau pour former une pâte, le moulage de cette pâte dans un moule pour former une masse moulée, le repos dudit mélange jusqu'à ce qu'il y ait prise en béton, l'appli-cation d'un revêtement fondant à haute température sur au moins l'une des faces de la masse moulée et la chauffe de ladite masse moulée à une température variant entre 700°C et 1500°C pour la fonte et l'étalement de revêtement et le refroidissement de la masse pour obtenir le produit final. 5. A process for manufacturing a block or panel used as a building material, comprising the mixture of Portland cement in quantities varying between 10% and 60%, silica in an amount varying between 10% and 60%, sodium silicate or potassium in an amount varying between 4% and 20% and a flux in quantity varying between 7% and 70%, all of these ingredients being sprayed and the percentages being by weight, and water to form a paste, molding this dough in a mold to form a molded mass, the rest of said mixture until there is concrete setting, the appli-cation of a coating melting at high temperature on at least one of the faces of the molded mass and the heating of said mass molded at a temperature varying between 700 ° C and 1500 ° C for cast iron and coating spreading and mass cooling for get the final product. 6. Le procédé défini dans la revendication 5, dans lequel le fondant est choisi parmi a) le métaphosphate de calcium b) les frittes c) le verre en poudre 6. The method defined in claim 5, in which the fondant is chosen from a) calcium metaphosphate b) frits c) powdered glass 7. Un procédé tel que défini dans la revendication 6, dans lequel la silice est constituée d'un mélange de silice de diffé-rentes granulométries passant à travers un tamis dont le nombre de mailles au pouce carré varie de 6 à 200. 7. A method as defined in claim 6, in which the silica consists of a mixture of silica of different grain size rents passing through a sieve whose number of mesh per square inch ranges from 6 to 200.
CA232,650A 1975-07-31 1975-07-31 High temperature resistant concrete and manufacturing process Expired CA1068308A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA232,650A CA1068308A (en) 1975-07-31 1975-07-31 High temperature resistant concrete and manufacturing process

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Application Number Priority Date Filing Date Title
CA232,650A CA1068308A (en) 1975-07-31 1975-07-31 High temperature resistant concrete and manufacturing process

Publications (1)

Publication Number Publication Date
CA1068308A true CA1068308A (en) 1979-12-18

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2478072A2 (en) * 1980-03-14 1981-09-18 Daussan & Co Fire resistant coating for protecting buildings - comprising flux, perlite or vermiculite, inorganic binder, and synthetic fibres
EP0050171A1 (en) * 1980-10-20 1982-04-28 Ina Seito Co., Ltd A method of making cement products having high mechanical strength
WO2001012571A1 (en) * 1999-08-17 2001-02-22 Philippe Dubois Moulding composition
FR2797869A1 (en) * 1999-08-17 2001-03-02 Philippe Dubois Ceramic molding composition comprises refractory aggregate selected from calcined clay, pure alumina and silica in the form of quartz and cristobalite, hydraulic binder, fluxing medium, and water

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2478072A2 (en) * 1980-03-14 1981-09-18 Daussan & Co Fire resistant coating for protecting buildings - comprising flux, perlite or vermiculite, inorganic binder, and synthetic fibres
EP0050171A1 (en) * 1980-10-20 1982-04-28 Ina Seito Co., Ltd A method of making cement products having high mechanical strength
EP0050171B1 (en) * 1980-10-20 1984-06-06 Ina Seito Co., Ltd A method of making cement products having high mechanical strength
WO2001012571A1 (en) * 1999-08-17 2001-02-22 Philippe Dubois Moulding composition
FR2797869A1 (en) * 1999-08-17 2001-03-02 Philippe Dubois Ceramic molding composition comprises refractory aggregate selected from calcined clay, pure alumina and silica in the form of quartz and cristobalite, hydraulic binder, fluxing medium, and water
FR2798378A1 (en) * 1999-08-17 2001-03-16 Philippe Dubois COMPOSITION FOR MOLDING

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