CA1052763A - Tetra(neophyl) zirconium and its use in process for the polymerization of olefins - Google Patents
Tetra(neophyl) zirconium and its use in process for the polymerization of olefinsInfo
- Publication number
- CA1052763A CA1052763A CA227,242A CA227242A CA1052763A CA 1052763 A CA1052763 A CA 1052763A CA 227242 A CA227242 A CA 227242A CA 1052763 A CA1052763 A CA 1052763A
- Authority
- CA
- Canada
- Prior art keywords
- alumina
- zirconium
- neophyl
- ethylene
- tetra
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 65
- 238000000034 method Methods 0.000 title claims abstract description 54
- VSKUGEFWRDJTPS-UHFFFAOYSA-N C=1C=CC=CC=1C(C)(C)C[Zr](CC(C)(C)C=1C=CC=CC=1)(CC(C)(C)C=1C=CC=CC=1)CC(C)(C)C1=CC=CC=C1 Chemical compound C=1C=CC=CC=1C(C)(C)C[Zr](CC(C)(C)C=1C=CC=CC=1)(CC(C)(C)C=1C=CC=CC=1)CC(C)(C)C1=CC=CC=C1 VSKUGEFWRDJTPS-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 230000008569 process Effects 0.000 title claims abstract description 38
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 26
- -1 Neophyl zirconium aluminate Chemical class 0.000 claims abstract description 88
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 88
- 239000003054 catalyst Substances 0.000 claims abstract description 86
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 63
- 239000000178 monomer Substances 0.000 claims abstract description 19
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 11
- 229910052751 metal Inorganic materials 0.000 claims abstract description 10
- 239000002184 metal Substances 0.000 claims abstract description 10
- 239000002685 polymerization catalyst Substances 0.000 claims abstract description 7
- 230000000737 periodic effect Effects 0.000 claims abstract description 6
- 150000002739 metals Chemical class 0.000 claims abstract 3
- 239000005977 Ethylene Substances 0.000 claims description 56
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 55
- 229920000573 polyethylene Polymers 0.000 claims description 32
- 229920000642 polymer Polymers 0.000 claims description 32
- 239000004698 Polyethylene Substances 0.000 claims description 30
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 29
- 238000006243 chemical reaction Methods 0.000 claims description 25
- 229930195733 hydrocarbon Natural products 0.000 claims description 25
- 150000002430 hydrocarbons Chemical class 0.000 claims description 25
- 239000004215 Carbon black (E152) Substances 0.000 claims description 23
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 23
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 23
- 229920000098 polyolefin Polymers 0.000 claims description 20
- 239000007787 solid Substances 0.000 claims description 20
- 239000002904 solvent Substances 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 239000004743 Polypropylene Substances 0.000 claims description 18
- 229910044991 metal oxide Inorganic materials 0.000 claims description 16
- 229910001868 water Inorganic materials 0.000 claims description 16
- 150000004706 metal oxides Chemical class 0.000 claims description 15
- 229920001155 polypropylene Polymers 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 13
- 239000002002 slurry Substances 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 10
- 238000007334 copolymerization reaction Methods 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 8
- 239000012298 atmosphere Substances 0.000 claims description 6
- 238000009835 boiling Methods 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 150000004645 aluminates Chemical group 0.000 claims description 5
- 230000036571 hydration Effects 0.000 claims description 5
- 238000006703 hydration reaction Methods 0.000 claims description 5
- 230000009849 deactivation Effects 0.000 claims description 4
- 150000001993 dienes Chemical class 0.000 claims description 4
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 238000010924 continuous production Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000005062 Polybutadiene Substances 0.000 claims description 2
- 229920002857 polybutadiene Polymers 0.000 claims description 2
- XPYQFIISZQCINN-QVXDJYSKSA-N 4-amino-1-[(2r,3e,4s,5r)-3-(fluoromethylidene)-4-hydroxy-5-(hydroxymethyl)oxolan-2-yl]pyrimidin-2-one;hydrate Chemical compound O.O=C1N=C(N)C=CN1[C@H]1C(=C/F)/[C@H](O)[C@@H](CO)O1 XPYQFIISZQCINN-QVXDJYSKSA-N 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 claims 1
- 230000000887 hydrating effect Effects 0.000 claims 1
- 238000011027 product recovery Methods 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 7
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 61
- 229940093470 ethylene Drugs 0.000 description 44
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 30
- 239000000243 solution Substances 0.000 description 30
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 19
- 239000000047 product Substances 0.000 description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 16
- 238000002844 melting Methods 0.000 description 15
- 230000008018 melting Effects 0.000 description 15
- 239000000725 suspension Substances 0.000 description 14
- KSCFJBIXMNOVSH-UHFFFAOYSA-N dyphylline Chemical group O=C1N(C)C(=O)N(C)C2=C1N(CC(O)CO)C=N2 KSCFJBIXMNOVSH-UHFFFAOYSA-N 0.000 description 13
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 12
- 239000003708 ampul Substances 0.000 description 12
- 239000011521 glass Substances 0.000 description 11
- 229910001220 stainless steel Inorganic materials 0.000 description 11
- 239000010935 stainless steel Substances 0.000 description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 239000000377 silicon dioxide Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 238000004458 analytical method Methods 0.000 description 7
- 238000001914 filtration Methods 0.000 description 7
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 7
- NJXPYZHXZZCTNI-UHFFFAOYSA-N 3-aminobenzonitrile Chemical compound NC1=CC=CC(C#N)=C1 NJXPYZHXZZCTNI-UHFFFAOYSA-N 0.000 description 6
- 239000002480 mineral oil Substances 0.000 description 6
- 235000010446 mineral oil Nutrition 0.000 description 6
- 229920006395 saturated elastomer Polymers 0.000 description 6
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 5
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 5
- 239000012967 coordination catalyst Substances 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- 239000007818 Grignard reagent Substances 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
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- 239000003446 ligand Substances 0.000 description 4
- 229920002521 macromolecule Polymers 0.000 description 4
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- 239000005060 rubber Substances 0.000 description 4
- 229920001897 terpolymer Polymers 0.000 description 4
- YTZKOQUCBOVLHL-UHFFFAOYSA-N tert-butylbenzene Chemical compound CC(C)(C)C1=CC=CC=C1 YTZKOQUCBOVLHL-UHFFFAOYSA-N 0.000 description 4
- IJGRUMAEYZWBQI-UHFFFAOYSA-N C=1C=CC=CC=1C[Zr](CC=1C=CC=CC=1)(CC=1C=CC=CC=1)CC1=CC=CC=C1 Chemical compound C=1C=CC=CC=1C[Zr](CC=1C=CC=CC=1)(CC=1C=CC=CC=1)CC1=CC=CC=C1 IJGRUMAEYZWBQI-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000004913 activation Effects 0.000 description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
- 238000004455 differential thermal analysis Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 3
- 150000004795 grignard reagents Chemical class 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 230000003993 interaction Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 2
- HHKOVZSRQWOYKQ-UHFFFAOYSA-N C(C(C)(C)C1=CC=CC=C1)[Zr] Chemical compound C(C(C)(C)C1=CC=CC=C1)[Zr] HHKOVZSRQWOYKQ-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- VAUAMEDMLANPBY-UHFFFAOYSA-N [Zr]CC1=CC=CC=C1 Chemical class [Zr]CC1=CC=CC=C1 VAUAMEDMLANPBY-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 238000000149 argon plasma sintering Methods 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
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- 239000010936 titanium Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA306,718A CA1054154A (en) | 1974-05-20 | 1978-07-04 | Tetra(neophyl) zirconium and its use in process for the polymerization of olefins |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/471,813 US3932307A (en) | 1974-05-20 | 1974-05-20 | Tetra(neophyl) zirconium and its use in process for the polymerization of olefins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1052763A true CA1052763A (en) | 1979-04-17 |
Family
ID=23873093
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA227,242A Expired CA1052763A (en) | 1974-05-20 | 1975-05-16 | Tetra(neophyl) zirconium and its use in process for the polymerization of olefins |
Country Status (16)
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4018707A (en) * | 1969-08-13 | 1977-04-19 | Imperial Chemical Industries Limited | Transition metal compositions |
| US4011383A (en) * | 1974-05-20 | 1977-03-08 | E. I. Du Pont De Nemours And Company | Tetra(neophyl) zirconium and its use in process for the polymerization of olefins |
| DE2830160A1 (de) * | 1977-07-12 | 1979-01-25 | Du Pont | Fraktionierbares elastisches polypropylen und verfahren zu seiner herstellung |
| US4335225A (en) * | 1978-06-20 | 1982-06-15 | E. I. Du Pont De Nemours And Company | Elastomeric polypropylene |
| US4228263A (en) * | 1978-06-20 | 1980-10-14 | E. I. Du Pont De Nemours And Company | Polymerization of propylene with a catalyst prepared in situ |
| US4269733A (en) * | 1979-09-28 | 1981-05-26 | The Dow Chemical Company | Ultra high efficiency catalyst for polymerizing olefins |
| WO1982000826A1 (en) * | 1980-01-10 | 1982-03-18 | J Collette | Fractionable,elastomeric poly(1-butene) |
| US4298722A (en) * | 1980-03-11 | 1981-11-03 | E. I. Du Pont De Nemours And Company | Fractionable, elastomeric poly (1-butene) |
| US4304685A (en) * | 1980-07-31 | 1981-12-08 | E. I. Du Pont De Nemours And Company | Large pore alumina-supported transition metal alkyl |
| US4310648A (en) * | 1980-10-20 | 1982-01-12 | The Dow Chemical Company | Polymerization of olefins in the presence of a catalyst containing titanium and zirconium |
| US4356111A (en) * | 1980-10-20 | 1982-10-26 | The Dow Chemical Company | High efficiency catalyst containing titanium and zirconium for polymerizing olefins |
| US4399053A (en) * | 1980-12-24 | 1983-08-16 | The Dow Chemical Company | High efficiency catalyst containing titanium, zirconium and zinc for polymerizing olefins |
| US4411821A (en) * | 1981-02-23 | 1983-10-25 | E. I. Du Pont De Nemours And Company | 1-Olefin polymerization catalyst |
| US4361685A (en) * | 1981-06-01 | 1982-11-30 | The Dow Chemical Company | Polymerization of olefins in the presence of catalyst prepared from organo zirconium-chromium mixtures |
| US4376065A (en) * | 1981-06-01 | 1983-03-08 | The Dow Chemical Company | Organo zirconium-chromium compound, catalyst prepared therefrom and polymerization of olefins therewith |
| US4399056A (en) * | 1981-06-01 | 1983-08-16 | The Dow Chemical Company | Organo zirconium-chromium mixtures, catalyst prepared therefrom and polymerization of olefins therewith |
| US4381382A (en) * | 1981-06-01 | 1983-04-26 | The Dow Chemical Company | Polymerization of olefins from catalysts prepared from organo zirconium-chromium compounds |
| GB2139017A (en) * | 1983-04-30 | 1984-10-31 | Michael Anthony Thomas | A modular interconnector |
| US4665046A (en) * | 1985-10-21 | 1987-05-12 | The Dow Chemical Company | Organoactinide polymer catalysts |
| US5010129A (en) * | 1987-11-02 | 1991-04-23 | Koch Industries, Inc. | Petroleum resistant coating and method of preparing same |
| US5270276A (en) * | 1989-04-25 | 1993-12-14 | Shell Oil Company | Process for the production of elastomeric, primarily syndiotactic polypropylene and catalysts for use in said process |
| US5270410A (en) * | 1989-04-25 | 1993-12-14 | Shell Oil Company | Process for the production of elastomeric, primarily syndiotactic polypropylene and catalysts for use in said process |
| US4971936A (en) * | 1989-07-10 | 1990-11-20 | Shell Oil Company | Catalyst component for making primarily isotactic elastomeric polypropylene or polybutene |
| US5118649A (en) * | 1990-02-26 | 1992-06-02 | Shell Oil Company | Process for the production of elastomeric primarily isotactic polyolefins and catalysts for use in said process |
| US5089573A (en) * | 1990-02-26 | 1992-02-18 | Shell Oil Company | Process for the production of elastomeric, primarily isotactic polyolefins and catalysts for use in said process |
| US5118767A (en) * | 1990-02-26 | 1992-06-02 | Shell Oil Company | Process for producing mildly elastomeric primarily isotatic polypropylene and poly-1-butene |
| US5164352A (en) * | 1990-05-11 | 1992-11-17 | Shell Oil Company | Process for the production of elastomeric, primarily isotactic polyolefins and catalysts for use in said process |
| US5118768A (en) * | 1990-05-11 | 1992-06-02 | Shell Oil Company | Process for the production of elastomeric, primarily isotactic polyolefins and catalysts for use in said process |
| US5192730A (en) * | 1991-11-13 | 1993-03-09 | E. I. Du Pont De Nemours And Company | Stable solutions of tetra(hydrocarbyl)metal compounds and use thereof for catalyst preparation |
| US5179178A (en) * | 1992-05-15 | 1993-01-12 | Phillips Petroleum Company | Olefin polymerization |
| DE59404305D1 (de) * | 1993-05-21 | 1997-11-20 | Danubia Petrochem Polymere | Hochaktive Katalysatoren für die Olefinpolymerisation und Polymerisationsverfahren unter Verwendung dieser Katalysatoren |
| AT403582B (de) * | 1993-05-21 | 1998-03-25 | Danubia Petrochem Polymere | Verfahren zur herstellung von elastomeren polypropylenen |
| US5629255A (en) * | 1993-05-21 | 1997-05-13 | Pcd Polymere Gesellschaft M.B.H. | Highly active catalysts for olefin polymerization and a polymerization process using these catalysts |
| DE4321498A1 (de) * | 1993-06-29 | 1995-01-12 | Danubia Petrochem Deutschland | Hochaktive Katalysatoren für die Olefinpolymerisation und Polymerisationsverfahren unter Verwendung dieser Katalysatoren |
| ES2266265T3 (es) * | 2000-09-25 | 2007-03-01 | Iogen Energy Corporation | Metodo para la produccion de glucosa con una mezcla de celulosa que comprende una celulosa modificada. |
| DK1485495T3 (da) * | 2002-03-15 | 2010-11-22 | Iogen Energy Corp | Fremgangsmåde til glucosefremstilling under anvendelse af endoglucanasekerneprotein til forbedret indvinding og genbrug af enzym |
| WO2019207991A1 (ja) * | 2018-04-24 | 2019-10-31 | 旭化成株式会社 | ポリエチレンパウダー、成形体、及び微多孔膜 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1314828A (en) * | 1969-08-13 | 1973-04-26 | Ici Ltd | Transition metal compositions and polymerisation process catalysed thereby |
| BE763475A (fr) * | 1970-03-03 | 1971-08-25 | Ici Ltd | Compositions pour amorcer la polymerisation des olefines et leur utilisation |
| GB1313183A (en) * | 1970-09-03 | 1973-04-11 | Ici Ltd | Polymerisation process and catalysts |
| US3694422A (en) * | 1971-02-02 | 1972-09-26 | Hercules Inc | Light activation of tetraalkylchromium compounds in polymerization of olefins |
| US3817931A (en) * | 1972-01-06 | 1974-06-18 | Ici Ltd | Process for the production of polyesters |
-
1974
- 1974-05-20 US US05/471,813 patent/US3932307A/en not_active Expired - Lifetime
-
1975
- 1975-04-30 IT IT22936/75A patent/IT1037796B/it active
- 1975-05-13 IE IE1067/75A patent/IE41239B1/xx unknown
- 1975-05-15 NL NLAANVRAGE7505755,A patent/NL179651C/xx not_active IP Right Cessation
- 1975-05-16 NO NO751764A patent/NO145012C/no unknown
- 1975-05-16 DK DK218675A patent/DK147797C/da active
- 1975-05-16 FR FR7515364A patent/FR2272099B1/fr not_active Expired
- 1975-05-16 CA CA227,242A patent/CA1052763A/en not_active Expired
- 1975-05-16 AR AR258818A patent/AR222136A1/es active
- 1975-05-16 JP JP5756575A patent/JPS558004B2/ja not_active Expired
- 1975-05-16 GB GB20937/75A patent/GB1513673A/en not_active Expired
- 1975-05-19 BR BR3944/75A patent/BR7503095A/pt unknown
- 1975-05-20 LU LU72520A patent/LU72520A1/xx unknown
- 1975-05-20 FI FI751471A patent/FI62105C/fi not_active IP Right Cessation
- 1975-05-20 BE BE156527A patent/BE829279A/xx not_active IP Right Cessation
- 1975-05-20 DE DE19752522331 patent/DE2522331A1/de not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| IE41239B1 (en) | 1979-11-21 |
| BE829279A (fr) | 1975-09-15 |
| DK147797B (da) | 1984-12-10 |
| NL179651C (nl) | 1986-10-16 |
| FI62105C (fi) | 1982-11-10 |
| JPS558004B2 (US20030220297A1-20031127-C00033.png) | 1980-03-01 |
| JPS50161584A (US20030220297A1-20031127-C00033.png) | 1975-12-27 |
| DK218675A (da) | 1975-11-21 |
| NL179651B (nl) | 1986-05-16 |
| GB1513673A (en) | 1978-06-07 |
| DK147797C (da) | 1985-08-26 |
| FR2272099A1 (US20030220297A1-20031127-C00033.png) | 1975-12-19 |
| FI751471A (US20030220297A1-20031127-C00033.png) | 1975-11-21 |
| DE2522331A1 (de) | 1975-12-04 |
| LU72520A1 (US20030220297A1-20031127-C00033.png) | 1975-10-08 |
| NL7505755A (nl) | 1975-11-24 |
| NO145012B (no) | 1981-09-14 |
| FR2272099B1 (US20030220297A1-20031127-C00033.png) | 1979-05-11 |
| BR7503095A (pt) | 1976-04-27 |
| IT1037796B (it) | 1979-11-20 |
| FI62105B (fi) | 1982-07-30 |
| AR222136A1 (es) | 1981-04-30 |
| IE41239L (en) | 1975-11-20 |
| NO145012C (no) | 1981-12-28 |
| US3932307A (en) | 1976-01-13 |
| NO751764L (US20030220297A1-20031127-C00033.png) | 1975-11-21 |
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