CA1047778A - Underground storage for cold and hot products and methods for constructing same - Google Patents

Underground storage for cold and hot products and methods for constructing same

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Publication number
CA1047778A
CA1047778A CA248,925A CA248925A CA1047778A CA 1047778 A CA1047778 A CA 1047778A CA 248925 A CA248925 A CA 248925A CA 1047778 A CA1047778 A CA 1047778A
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CA
Canada
Prior art keywords
reservoir
storage
temperature
wall
insulation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA248,925A
Other languages
French (fr)
Inventor
Alf H. Grennard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
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Filing date
Publication date
Priority claimed from SE7504236A external-priority patent/SE409193B/en
Priority claimed from DE19752531366 external-priority patent/DE2531366A1/en
Priority claimed from SE7602003A external-priority patent/SE409194B/en
Application filed by Individual filed Critical Individual
Priority to CA304,489A priority Critical patent/CA1062026A/en
Application granted granted Critical
Publication of CA1047778A publication Critical patent/CA1047778A/en
Expired legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C3/00Vessels not under pressure
    • F17C3/005Underground or underwater containers or vessels
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C3/00Vessels not under pressure
    • F17C3/02Vessels not under pressure with provision for thermal insulation
    • F17C3/10Vessels not under pressure with provision for thermal insulation by liquid-circulating or vapour-circulating jackets
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00Vessel construction, in particular geometry, arrangement or size
    • F17C2201/05Size
    • F17C2201/052Size large (>1000 m3)
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00Handled fluid, in particular type of fluid
    • F17C2221/03Mixtures
    • F17C2221/032Hydrocarbons
    • F17C2221/033Methane, e.g. natural gas, CNG, LNG, GNL, GNC, PLNG
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/01Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
    • F17C2223/0146Two-phase
    • F17C2223/0153Liquefied gas, e.g. LPG, GPL
    • F17C2223/0161Liquefied gas, e.g. LPG, GPL cryogenic, e.g. LNG, GNL, PLNG
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00Applications
    • F17C2270/01Applications for fluid transport or storage
    • F17C2270/0142Applications for fluid transport or storage placed underground
    • F17C2270/0144Type of cavity
    • F17C2270/0147Type of cavity by burying vessels

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
  • Building Environments (AREA)

Abstract

1 of 12 Application Underground storage for cold and hot products and methods for con-structing same Inventor: Alf H Grennard, Bergstrasse 21, 6101 Nieder-Ramstadt, West Germany Abstract of disclosure In an underground storage, containing hot or cold storage mate-rials, a circulating gas or fluid is passed in a plurality of conducts in the walls, floor, and ceiling of the storage and near their surface towards the storage, and, if a container or containing vessel is con-structed inside the walls of said underground storage, the gas or the fluid is conducted either in the mentioned outer wall as previously mentioned or between the wall of the container and the outer rock walls, particularly in the last mentioned case also in ducts or in galleries with guiding devices for the medium to insure a corresponding contact with surfaces involved, or, in some cases, in the interior of said container wall. By controlling the temperature, humidity, and pressure of said circulating medium and creating a pressure differential towards adjacent areas, the stability and the sealing characteristics of the outer wall are greatly improved, the heat influx to the product storage further substantially reduced, the sublimation of ice brought under improved control with a view to prevent damage to the storage wall insulation.
The suggested method, using the envisaged multi-purpose circulating system, also offers further advantages such as a possibility of recove-ring losses of stored product from leaks and, in addition, increased control and safety, the latter in particular when storing volatile and combustible fluid materials. The design offers an improved method of applying sealants, adding auxilliary products, and removing others from suggested circulating system. New types of sealants are suggested.

Description

This invention relates in particular to the underground storage of products whose storage temperature as a rule differs from the natural temperature of the underground surroundings in which the storage is located. In one aspect it relates to a method of controlling the tempe-rature of the walls, floor, and ceiling of said underground storage, this storage often being located in rock, and keeping the temperature of these sections within a determined range or at a stipulated figure, using preferably a circulating stream of gas or in some cases a liquid as a medium, which functions as a vehicle for the transportation of heat to or the removal of heat from the mentioned storage ~alls, floor, and ceiling. As a consequence of said temperature control this invention provides the possibility of establishing a temperature barrier around the area of the circulation system envisaged in this paper, said barrier .

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2 of 12 ~47778 reducing the ice sublimation process sufficiently for all practical purposes. In still another aspect this invention relates to a method of removing water or other substances from or adding the same to the walls, floor, and ceiling of the underground storage, again using the circu-lating medium in question as a vehicle, at wish applying pressure or vacuum, said medium also picking up water vapors from sublimed ice.
The invention furthur relates to a method of recovering products which possibly could leak out from the underground storage into the said circulating system and further provides a safety system of controlling if and to what extent products, in particular volatile combustible products, are escaping from the storage. In another aspect the object of this invention is to provide a method of utilizing the temperature difference between the suggested circulating medium and some other stream or body with a view to economically recover heat or 'cold' calo-ries. The invention also provides a new method of supplying sealants with the aid of said circulating system and also suggests new types of~ sealants which swell upon contact with the stored products. At the same time it relates to a safer method of regasification of condensed gaseous products. It is an object of this invention to provide for constructing a suitable underground storage for the purposes envisaged, and it therefore incorporates new types of insulation designs with-standing very low cryogenic temperatures and suitable for the invention presented here. Other objects and advantages will be apparant to those skilled in the art upon study of this disclosure including the detailed description of the invention and-the appended drawings wherein:
igure 1 is a schematic sectional view in elevation of an horizontal cylindric or rounded type of underground storage reservoir according to the invention with a plurality of boreholes for the circulation system, drilled near and along the rock sur-face of the cavity, or cast in a concrete wall inside a cavity in e. 9. silt, clay, or sand (the figure illustrates only the case of a rock cavity).
gure 2 illustrates a schematic sectional elevation of an horizontal cylindrical or rounded type of underground storage reservoir according to a modification of the same invention with a plurality of circulation channels between the actual rock storage wall or a cast concrete wall and the inner insulated storage wall (the figure illustrates only the case of 3 rock cavity).
igure 3 illustrates a schematic sectional elevation of a vertical underground storage reservoir with a round or rectangular bottom according to a modification of the same invention, showing the plurality of circulation channels, ducts, or galleries with guiding devices for the circulating medium, placed between the actual rock storage wall or a cast con-crete wall and the inner storage wall, all latter surfaces being equipped with some type of insulation withstanding large temperature differences (the figure illustrates only the case of a rock cavity), igure 4 illustrates a schematic sectional elevation of an vertical underground storage reservoir according to a modification of -~ 2 4 drawings 12 paqes 1~47778 the same inVention, the plurality circulation channels, ducts, or galleries with guidin~ devices ~or the circulating medium, being placed between the inner wall and the concrete wall con-structed inside of the actual ~uter rock wall or sourroundings of loosel~aterials such as clay, silt, and sand (the figures illustrates the case of a concrete outer cavity 29, surrounded by an insulating material), Figure 5 shows a schematic sectional plan view of one type of insulating design used according to the invention. Insulation is fastened to a system of rods.
`~ Figure 6 shows a schematic sectional plan view of another type - of insulating design used according to the invention. The in-sulation is supported by a system of wall laths, which have a ~-repeated regular wave-formed profile, the crest on each vertical ~; lath in the figure being at the same horizontal level on every second lath.
Figure 7 Is a sectional elevation along line 1-1 in Figure 6, and Figures 8a, 8b and 8C are examples showing temperature and water vapour pressures at two different operating pressures.
The principle of this invention offers advantages when storing cold as well as hot products underground. As the most prevalent need of underground storage refers to the storage of cold, combustible products such as Liquefied Petroleum Gases (LPG), Liquefied Natural Gas (LNG), Synthetic Natural Gas (SNG), petrochemical products, and industrial gases, I prefer for illustrative purposes to select the underground storage of LNG
as a typical example of the use of my invention though the same principle can for the most part be applied for all types of products which must be stored at temperatures differing from the - 30 natural temperatures of the underground environment. For the ~ sake of simplicity mainly the construction of reservoirs in rock is discussed, though the invention also refers to similar stor-, , .
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1(;~47778 ages built of concrete in silt, sand, or a mixture of different materials.
Pipes for the filling and the removal of liquid or gas may be conventional and may not be shown in the drawings. The same goes for some other equipment and instrumentation required.
Corresponding parts have been given the same numerals. The type of insulation or its design used in ~igures 1-4 has not been denoted, likewise the detailed attaching of it to the outer or inner storage wall.
The petroleum industry produces great quantities of volatile hydrocarbons as a result of processing crude oil and natural gas. Natural gas is being liquefied at ports of export-ation, stored there, then shipped overseas, and stored at terminals at the port of importation. Stand-by storage facili-ties are located outside consumption centers and along pipelines.
; Such liquids require enormous storage facilities, particularlyduring periods of slack use, for peak-shaving purposes, and on account of requirements stipulated by the authorities for emerg-ency cases such as war and embargos.
Other industrial gases require similar facilities.
Great quantities of volatile liquids including propane and butane have in the past been dissolved from impervious formations, - stored in earthern storage pits, or in mined underground caverns.
Loss of product, the difficulty of pro---' ' . ~ ' - : :

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4 of 12 1~47778 viding and maintaining an adequate vapor seal, and excessive heat losses are some of the problems encountered.
The general tendency is to locate storage facilities for combus-tible gases underground of the following reasons:
1. LNG fires and similar fires of highly volatile llquids cannot be extinguished and are therefore left to burn out. Such fires are also generally accompanied by repeated violent fatal exploslons with enormous devastations. When storing such products underground, explosions and other dangers can be prevented, and fires easily controlled and quickly extinguished. Authorities are therefore expected to stipulate underground storage location for such pro-ducts in the future, particularly with regard to public opinion and other environmental grounds generally presented.
2. Increased protection against wheather, sabotage, and hostile mili-~ tary operations. -
3. StorOge at constant and low temperature, generally in the range 8-10 centigrade; no exposure to sunl;ght.
4. No space required above ground.
5. Storage under pressure at low cost.
6. A better and improved understandTng lately of the real nature of forces in rock makes it possible to avail oneself of less fortunate locations where the underground rock is of inferior quality. Re-servoirs can also be built in sand, silt, or clay, which problem, though, will only be mentioned in this paper.
Though storage of LPG in underground rock reservoirs at tempera-tures in the range of -40C to -50C for a long time has been a success-ful application the same cannot be said about storage of LNG, SNG, other cryogenic liquefied products like ethane, ethylene, and other petrochemi-cals, in such underground caverns because the extremely low temperatures required to store these cryogenic products at substantially atmospheric pressure requires an excessive amount of refrigeration on account of the high heat losses tncurred. Another drawback has been the increased product losses at these lower temperature levels. The main reason for the mentioned heat losses is the increased amount of contraction with subsequent continued incessant cracking of the underground rock, deve-loping an ever larger seepage of product with time. Further, the inten-sified rate of sublimation of ice removes the sealing effect of the surroundings and spoils the insulation of the cavity if any.
The mentioned cracking of the rock can continue for years, steadily opening up new cracks and constantly furthur away out from the storage wall. The natural consequence of the cracking of the rock at these very low temperatures is a continous increase of observed heat influx from the cavity surroundings to the storaged product body, gas seeping out in the environment and causing general nuisance and an explosion danger. There are, of course~always a large number of original cracks in the rock, and these are opened wider up while new cracks are being created, sometimes causing large pieces of rock to fall out into the . . ., _ ,.

4 drawings 1~ pages - . . .
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` i 1~47778 storage cavity. Conventional reinforcements and precautions are therefore always required.
If the temperature of the rock is controlled within the ! predetermined limits by the aid of the multi-purpose system I have envisaged and which system is located about the surfaces of the ¦ walls, ceiling, and below the floor of the underground storage, such continued cracking can be totally avoided at the same time as the stability of the rock material is ensured. By supplying ~ heat the multi-purpose system thus prevents the temperature of ¦ 10 the rock from falling below a desired critical minimum. Difficul-ties on account of the ice sublimationprocess, such as damage to the insulation applied, are also halted, which all can be achieved ! with aid of the same multi-purpose circulation system, which ;j constitutes the core of this invention. Water vapors thus moving j in the direction of the storage may be carried away by the circulation system with its interconnecting cracks and inter-`~ spaces, said migration process substantially reduced by the tem-perature barrier established by temperature control around the area of the circulating system. By raising the temperature around the circulation system a change of the temperature gradient in relation to the temperature of the environs is attained, which in the presence of sufficient water in the rock pores towards the outer environs influences the rate of sublimation in the thus created bottle neck between the circulation system and the environs. Operatlon at a temperature below OC also implies generally reduced water vapor pressures and thus reduced sub-~ limation rates, water vapor pressures above ice being much lower ; than those over water except at OC. Frost heaving and front lenses often are consequences of not removing water by a device j 30 such as the one described. Said circulating system consists ofa multitude of comparatively closely spaced circulation channels along all surfaces of the storage, the channels carrying a liquid ~'"'-' _ g~

1~47778 but preferably a gas such as nitrogen, carbon dioxide, possibly hydrogen, hydro carbons or even the stored product itself, or one or several of its components. In some cases ducts, or galleries with devices to direct the circulating stream, may partly or completely substitute a plurality of channels or boreholes. These ~ circulation systems can also be used to heat or chill the rock.
¦ which latter operation also will be required when - as described below - sealing the rock at low temperatures in accordance with my proposed method. The typical operating range for the temper-ature barrier of the rock or concrete will depend on the quality of the rock or concrete but will in many cases vary in the range -10C to -50C, i.e. about the temperature range used in rock for many current installations. However, also higher temperatures, even above OC, may be used.
As rock is a good insulator a very long time, years, are required before the temperatures have asymptotically reached their final values. To the extent they can be controlled they are selected with regard to a number of factors such as rock 3 characteristics, rock material, drainage problems, distribution of stress in the rock, permeability and porosity of the rock, etc The operation of the rock storage may be controlled electronically and in accordance with a predetermined plan.
The controlled movement of water and water vapor in the rock is of great significance for the successful operation of the storage.
Water vapor will move in the direction of areas with ~ lower water vapor pressures in accordance with known physical - laws. If water is partly or totally removed from a particular area the saturated water vapor pressure at a certain temperature there cannot be fully developed, and the water vapor pressure in ¦ said area may therefore be lower than in a different area with a lower temperature, where there is sufficient water available to - 5a -, . .
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develop the full saturated water vapor pressure for the temper-ature at this last mentioned point. The porosity of the rock ¦ will, of course, also involve other physical processes of differ-j ent nature connected with the migration of water which all influences the general process as put forward. Figure 8a g illustrates the approximate distribution of temperatures, plotting ¦ only a few points, when keeping the temperature of the circulating system at a high level and at a lower level (dashed curve). The 3 corresponding water vapor pressures, unsaturated for the dashed curve except at the far right, are found in Figure 8b. The effect of using a drying gas is shown in Figure 8c. By lowering the water vapor pressure curve below OC the amount of water to ; be removed by the drying gas diminishes on account of the lower water vapor pressures and the reduced water migration rates encountered at these lower temperatures.
There exists a patented method which suggests a con-tinuous sealing of cracks opened up, applying a freezing liquid, which is continuously injected as the rock cracks. I prefer to start the sealing of natural and potential cracks by first opening ' 20 up these cracks comparatively wide by chilling the rock through my circulating system to a temperature far below the actual future operating temperature and then apply a sealing material, using pressure and partly distributing the sealing agent by said cir-culating system. At the same time conventional injection of the same or similar sealing agents may be carried out after a pluralit~ --! of auxiliary boreholes have been drilled into the surface from the cavity. I prefer to select sealants which swell upon getting in contact with the stored product, though such swelling sealants not always are imperative. If the product should leak out and ¦ 30 get in touch with a swelling sealing material in a crack the ! swelling sealing agent will automatically close the crack firmer.
In some instances the swelling action may be started by injection - 5b~
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- 1~47778 of water. ~y first injecting a sealing component and then adding ~ a second component and leave the two to react within a closure the ¦ swollen material will act as a very good and elastic seal. The `~ described method of first opening up the cracks by chilling the 1 wall material and then apply the sealant by injection after which the cracks are closed again by raising the temperature works as well with rock material as with concrete.
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6 of 12 ~47~8 There exists a great number of chemical compounds or mixtures hereof which have the propensity of swelling upon contact with fluids or gases, the fluids and gases being absorbed, adsorbed, dissolved by these materials, or forming new structures with them. Some of these materials are polymers, rubbers, or plastics. The sealant must be selected with regard to the product stored, and selection of proper material can be done by the average expert.
I prefer to remove the water in the rock by using a drying gas or fluid, the latter containing a water absorbing component. These media are circulated in the proposed system and then continously dried by some conventional drying agent. When using a circulating gas, water may also be separated out in condensation, adsorbation, or absorbtion processes, in some cases after compression. The water removal action may be facil-itated by first heating the medium. Applying a sealing medium and again taking advantage of the circulating system the sealant is then applied in all cracks and spaces in the environment of the circulating system pr~posed in this invention. A conventional water drainage system will always be required in all storage designs discussed.
A different mixture, also distributed under pressure through the proposed circulating system in a similar manner as in the previous case, contains principally two components, one of which absorbs water while the other works as a sealant simultaneously. Such products are commer-cially available. When using the last mentioned mixture the cracks may all be opened up by chilling and partly closed again by raising the temperature.
The sealing qualities of the storage cavity walls are at times dependant on the water content in the rock. Of this reason this inven-tion also involves the idea of adding water to the circulating stream when necessary. For the process of sublimation of ice in the rock the possibility of controlling the water content of the circulating stream is of utmost importance, because water from the rock tends to migrate and form ice on the inside wall of the actual storage, thereby having a tendency of pushing away applied insulation or damaging its valuable insulating characteristics.
it is also an object of this invention to provide a safety system which allows a good control of the proper functioning of the storage, which fact is of prime importance if the cavity contains a volatile combustible liquid or else a dangerous gas. This can be achieved by keeping the operating pressure of the circulati-ng system somewhat lower than the pressure in the actual storage. If product should leak out from the storage Tt will enter the circulating system where it immedi-ately can be sensed by a suitable instrument such as a gas chromato-graph or mass spectrometer. Such a product may then also be recovered, e.g. through absorbtion or condensation processes. In the case of com-bustible gases it would involve a direct danger not to use such a system or a similar device, should the sealing qualities of the cavity wall prove to be insufficient, needless to mention difficulties which arise at shut-down or maintanance of the storage.
The selection of a suitable medium to be employed for the circu-lation system depends very much upon product stored, its storage tem-perature, operating temperature range of the circulating medium, and '-4 drawings . . -12 pages ~ .

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7 oF 12 1~47778 what type of equipment the medium shall have to pass. A furthur point is the question if the circulating medium may affect materials contacted in the system. Among the gases, nitrogen, which is inert and often employed in start-up operations, is excellent. Another suitable gas may be carbon dioxide, hydrogen, refinery off-gases, and the product itself, if volatile. If natural gas is stored, nitrogen is a suitable medium, and in this case LNG and its components can be separated out completely, if product should leak into the circulating system, as long as the product does not contain hydrogen.
A furthur point which always arises is if the operating situation allows an economical heat exchange between the circulating medium and some other stream or body.
Underground storage offers the advantage of operating at a higher pressure at low cost as compared with storage above ground. This may be important when filling the storage with LNG liquid, when the specific gravity of the liquid to be filled differs somewhat from the specific gra'~ity of the storage content. Under such circumstances the pressure in the reservoir may rise suddenly on account of so called roll-over.
With regard to the same advantage to operate at higher pressures a further feature of this invention is the suggested use of the reser-voir as an evaporation chamber. The heat exchange equipment for the evaporation can be located inside as well as outside the reservoir.
The corresponding heat exchange equipment for this evaporation of liquid has not been denoted in the drawing and may be conventional.
When storing cryogenic products like LNG the contraction of the plastic insulations used amounts to about one per cent, while the cor-responding contraction of the rock for the same temperature interval will be in the order of one per mille. The contraction differences for these two different materials therefore call for special types of insulation designs to be employed along the cavity walls, on wooden or some other supports along the same walls, or on the walls of a built-in containing vessel. The basic design principle is to prevent the insulation from becoming subject to excessive tensile stress.
The insulation designs proposed here are all built up of several layers, e.g. of polyuretan insulation or similar plastics, along with sealing membranes, and a heat reflecting aluminium foil. Suitable sealing mem-branes and suitable insulating materials are known and commercially available. The designed final compound insulation layer is formed in such a way that the layer is divided up in equidistant cuplike elements, resulting in regular parallel rows of such elements, where each element is equidtstant to any next element. There is an ample amount of insu-lation material around each element to allow for temperature contrac-tions, which mainly result in flexural stresses instead of tensile stresses. The insulation is supported at the centre of each element. The first mentioned stresses again can be mitigated or relieved during the initial transition process at start-up by supplying heat to the outside of the insulation layers, using my proposed circulation system as a heat source.
The application of such insulation designs can easily be carried out on comparatively even wall surfaces but will otherwise require a system of support rods. When supporting the insulation with the ald of a system of laths with wave-formed profiles the cost will be lower when the cavtty surface is even and smooth.

4 drawings 12 pages :-```" 8 of 12 lQ47778 The support rods are fixed in boreholes, drilled tnto the rock, orcast in the concrete wall. These boreholes form a regular symmetric equidistant pattern, evenly distributed along all walls. Each element of the insulation is thereafter fastened on these fixed rods, leaving a 'valley' around each rod to allow for temperature contraction. This design makes it possible to leave the actual rock wall in a rough un-finished condition.
The system of wooden laths is fixed to the rock walls in such a manner that the crest of a wave profile on one vertical lath is oppo-site to the 'valley' of a profile of the next adjacent vertical lath at the same horizontal level. When cooled the insulating layers will thus through contraction mainly rest on the crests of all laths, the surplus length of the insulation round each crest allowing for the temperature co~traction in conformity with what also happens when the insulation is fastened on the rods mentioned in the previous paragraph. In the last mentioned design the elements referred to correspond to the crests in th~ lath system.
The two insulation designs can be fitted with wooden supports, if so required; and the circulating medium can be directed between the insulated inner wall and the actual outer rock or concrete wall. The designs constitute a built-in container. In the figures is the plastic insulation cover over bolts and bolt heads omitted.
Referring now to FIGURE 1 of the drawing an horizontal rounded type of underground reservoir 10 is shown in cross section. A series of boreholes 11 have been drilled in the rock '6 along the periphery of the reservoir for the circulation system described, from both ends of the cavity, or, depending on length of storage, also from niches between the ends of the reservoir. If a concrete wall has been cast inside the rock wall or in surrounding loose material like clay or sand, the system of holes are cast. Small size boreholes 12 have also been drilled in from the storage (only one such borehole is shown in the figure) with a view to tighten cracks through the injection of swelling sealants or other materials after the rock has been cooled down below the future operating temperature. Other cracks have been mended with plastics, cement, or similar mixtures, and the outer cavity surface, depending on the type of insulation used, smoothed. After rock bolts and insulation supports have been positioned the insulation 13 is fastened.
14 is evaporation space, and 15 withdrawal pipe for gaseous products.
FIGURE 2 illustrates how a circulation system of channels 17, plàced on the inside of ~he outer cavity wall, may substitute the `-circulating system of drilled boreholes in the rock wall of the re-servoir 10 as described in figure 1. The insulation 13 is here fastened in conformity with what has been outlined in connection with figures 5 ~ -or 6. Sometimes it will be cheaper to construct galleries with directing devices for the circulating medium.
The reservoir 10 in FIGURE 3 is a modification of the previous two storage types described. This storage may be built according to choice with a rectangular or circular concrete bottom 19, this type of bottom being equipped with circulation channels 17, preferable in block elements of balsa wood 18. The circulation system along the walls consists of a plurality of vertical channels 17 or other gas stream guiding devices which insure a sufficient contact between .

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1~47778 the streaming medium and the outer and inner wall. While walls and bottom are equipped with the mentioned standard types of insulation 13, the ceiling of the reservoir, resting on a suspended structure 22, is insulated with some pervious loose insulation like rock wool, which permits the vapors to pass and the possibility to use the cavity as an evaporation chamber.
Valve 20 is used at start-up.
Figure 4 corresponds to figure 3 and illustrates how - a reservoir can be built in sand, silt, clay, or similar loose 10 materials, or elsewhere where only inferior rock is available.
The reservoir, including the walls with the built-in circulation svstem, is cast in concrete 29, using a travelling mould.
Another method is to construct the storage using prefabricated elements and pre-stressed concrete. Construction in earth is generally preceded by freezing the surrounding soil before excavation. When required insulating material, impervious insulating material, or foamed insulating material 27 may be filled in round the structure.
Figure 5 shows how the insulation 13 is fastened 20 after a regular pattern of equidistant support rods has been positoned in the rock wall. 23 are elastomeric membranes, 24 polyurethane foam, 25 aluminium foil, and 26 support rod, which has been fixed in a hole drilled in the rock or in the concrete. 28 is an optional support of wood, plywood, or plastic.
Figure 6 illustrates the utilization of a system of laths 30 with a configuration of regularly repeated wave-like profiles.
Figure 7 is a sectional elevation along line 1-1 in figure 6.

~' :- ~ . - . - .,: :

Claims (24)

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. A method of storing a product below 0°C in a reservoir at a temperature which differs from the natural ambient temperature of the surrounding walls, floor, and ceiling of said reservoir and its surroundings, which comprises circulating a medium gaseous heat exchange under a slight vacuum with a capacity for absorbing moisture, in a circulating system comprising of a plurality of uniformly distributed and substantially parallel passages, which are disposed about and adjacent the surfaces of said reservoir, supplying of heat through continuous heat exchange between the medium and areas surrounding the system, said heat exchange being sufficient to keep the areas surrounding the system and thus also the walls, floor, and ceiling of the reservoir within a predetermined temperature range, the temperature of which differing from the temperature of the stored product, and, in addition, constituting a temperature barrier between the wall surfaces of the reservoir and the external environment, which reduces the sublimation rate and at the same time keeping the temperature barrier around the reservoir at a higher level, the circulation of the gaseous medium in the system continuously removing vapors emanating from any sublimed ice and water.
2. A method as claimed in claim 1 in which the passages are boreholes disposed along and below the surface of the reservoir, which reservoir is insulated.
3. A method as claimed in claim 1 in which the system comprises substantially parallel and uniformly distributed channels along the walls, floor, and ceiling of said reservoir and located between said reservoir and an inner storage container one of said reservoir and said container being insulated.
4. A method as claimed in claim 3 in which the reservoir is uninsulated and the storage container insulated.
5. The method of claim 3 wherein the insulation is disposed on the inside of the outer wall, the inner container being uninsulated.
6. The method of claim 3, 4 or 5 wherein the system is located in the wall of the inner container.
7. The method of claim 1, 2 or 3 applied to an under-ground reservoir.
8. The method of claim 1, 2 or 3 wherein the reservoir is located in rock.
9. The method of claim 1, 2 or 3 wherein the said gaseous medium is the stored product itself or one of its components.
10. The method of claim 1, 2 or 3 wherein the said gaseous medium also removes water from the surroundings of the system.
11. The method of claim 1, 2 or 3 wherein the said fluid medium is used as a vehicle to distribute a substance throughout the system and its surrounding areas.
12. The method of claim 1, 2 or 3 wherein the said system is used for monitoring purposes to detect which gaseous and other products leak out from the storage into the system.
13. The method of claim 1, 2 or 3 wherein the fluid stream is used to recover product, which has leaked into the system by an absorbtion, adsorbtion, or condensation process.
14. The method of claim 1, 2 or 3 wherein the temperature difference between said fluid stream and another outside stream or body is utilized for heat exchange.
15. The method of claim 1 wherein the fluid stream is used to chill the surroundings of the system below the normal operating temperature to open up cracks wide and sealing materials are injected in the walls, ceiling and floor of the reservoir to seal said cracks.
16. The method of claim 15 wherein the sealing material swells upon contact with the product stored.
17. The method of claim 15 wherein the sealing material swells upon contact with water.
18. The method of claim 1, 2 or 3 wherein the reservoir is used as an evaporation chamber for the product stored.
19. The method of claim 1, 2 or 3 wherein the stored liquid product is used as a heat exchange medium for the evaporation of the liquid stored.
20. The method of claim 1, 2 or 3 wherein the product is stored at subatmospheric temperature and is at least partly liquefied.
21. The method of claim 1 wherein the channels comprise a plurality of ducts or galleries with guiding devices.
22. The method of claim 1, 2 or 3 wherein the insulation is supported by a plurality of rods which are fixed in concrete and rock surfaces of the reservoir.
23. The method of claim 1 wherein the insulation is a compound insulation and supported by a plurality of rods which are fixed in the uninsulated concrete and rock surfaces of the reservoir, the compound insulation comprising layers of plastic foam, sealing membranes, and heat reflecting aluminium foil, the compound insulation layer further being supported by each rod such that an excess of compound insulation exists round each rod the excess insulation being mainly subject to flexural stresses upon large temperature contractions, the compound insulation also being supported by a wall, wood or plastics.
24. The method of claim 23 wherein the compound insulation of the reservoir is supported on a regularly and parallelly arranged lath system, fixed to uninsulated reservoir surfaces, each lath having a regularly repeated wave-profile and positioned in such a way that a crest of one particular lath profile is adjacent to a 'valley' of the next lath on both sides, the compound insulation being fixed at the crests of the laths, the compound insulation further being supported by a wall, consisting of wood or plastics, and, the compound insulation layer mainly being supported at the crests at low temperatures.
CA248,925A 1975-04-14 1976-03-26 Underground storage for cold and hot products and methods for constructing same Expired CA1047778A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA304,489A CA1062026A (en) 1975-04-14 1978-05-31 Underground storage for cold and hot products and methods for constructing same

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
SE7504236A SE409193B (en) 1975-04-14 1975-04-14 PROCEDURE FOR UNDERGROUND STORAGE OF COLD AND HOT PRODUCTS
DE19752531366 DE2531366A1 (en) 1975-07-11 1975-07-11 RELIABLE AND ECONOMICAL STORAGE OF SOLID MATERIALS, LIQUIDS AND GASES, IN PARTICULAR NATURAL GAS AND INDUSTRIAL GASES AT TEMPERATURES THAT ARE NOTICABLE FROM THE TEMPERATURES OF THE STORAGE CONTENTS
SE7602003A SE409194B (en) 1976-02-20 1976-02-20 PROCEDURE FOR STABILIZATION AND SEALING OF MOUNTAINS AND SUCCESS IN CONNECTION WITH UNDERGROUND STORAGE OF COLD AND HOT PRODUCTS

Publications (1)

Publication Number Publication Date
CA1047778A true CA1047778A (en) 1979-02-06

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CA248,925A Expired CA1047778A (en) 1975-04-14 1976-03-26 Underground storage for cold and hot products and methods for constructing same

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JP (1) JPS5230912A (en)
CA (1) CA1047778A (en)
DD (1) DD125728A5 (en)
DK (1) DK141376A (en)
FI (1) FI760839A (en)
FR (1) FR2308045A1 (en)
NL (1) NL7603897A (en)
NO (1) NO145875C (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7810471A (en) * 1977-10-24 1979-04-26 Grennard Alf H PROCEDURE FOR THE SAFE UNDERGROUND STORAGE OF CRYOGENIC PRODUCTS AND THE RELATED STORAGE INSTALLATION.
JPS54128820A (en) * 1978-03-29 1979-10-05 Hitachi Zosen Cbi Kk Low temperature underground tank
AT357929B (en) * 1978-09-12 1980-08-11 Teich Ag Folienwalzwerk CONTAINER FOR LIQUID OR GIANT MATERIALS
JPS55129699A (en) * 1979-03-28 1980-10-07 Shoichi Suzuki Inside earth floor of liquid embankment for low- temperature liquid storage tank
JPS55129698A (en) * 1979-03-28 1980-10-07 Daiki Netsukougiyou Kk Heat-insulating process of liquid embankment or earth floor for low-temperature liquid storage tank
JPS56138594A (en) * 1980-04-01 1981-10-29 Ohbayashigumi Ltd Volatile fuel storage facility
FR2528811A1 (en) * 1982-06-17 1983-12-23 Geostock METHOD AND DEVICE FOR STORING GAS LIQUEFIED AT LOW TEMPERATURE IN A GROUND CAVITY
JPS643706U (en) * 1987-06-29 1989-01-11
JPH01168335U (en) * 1988-05-20 1989-11-28
JPH0541070Y2 (en) * 1989-05-25 1993-10-18
JPH0467538U (en) * 1990-10-18 1992-06-16
JPH055568U (en) * 1991-07-06 1993-01-26 小野谷機工株式会社 Service car for tire repair
JPH0692370A (en) * 1992-07-22 1994-04-05 Daiwa Gravure Kk Liquid let-out container
JPH0648466A (en) * 1992-07-22 1994-02-22 Daiwa Gravure Kk Liquid feed container
JPH0648465A (en) * 1992-07-22 1994-02-22 Daiwa Gravure Kk Liquid taking out device

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Publication number Priority date Publication date Assignee Title
FR1252820A (en) * 1959-12-24 1961-02-03 Lebon & Cie Underground liquefied gas storage tank
FR1448246A (en) * 1965-06-23 1966-08-05 Improvements in the storage of liquefied hydrocarbons
US3489311A (en) * 1967-05-25 1970-01-13 Aerojet General Co Tanks for storage of liquefied gas
GB1248419A (en) * 1968-12-09 1971-10-06 Motherwell Bridge Eng Improvements in or relating to storage of liquefied gases
JPS48102309A (en) * 1972-04-12 1973-12-22

Also Published As

Publication number Publication date
JPS5230912A (en) 1977-03-09
NO145875B (en) 1982-03-08
NL7603897A (en) 1976-10-18
NO761092L (en) 1976-10-15
DD125728A5 (en) 1977-05-11
FR2308045B1 (en) 1981-08-07
NO145875C (en) 1982-06-16
FI760839A (en) 1976-10-15
DK141376A (en) 1976-10-15
JPS5728039B2 (en) 1982-06-14
FR2308045A1 (en) 1976-11-12

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