CA1020581A - Selective hydroformylation process using homogeneous catalysts - Google Patents

Selective hydroformylation process using homogeneous catalysts

Info

Publication number
CA1020581A
CA1020581A CA166,466A CA166466A CA1020581A CA 1020581 A CA1020581 A CA 1020581A CA 166466 A CA166466 A CA 166466A CA 1020581 A CA1020581 A CA 1020581A
Authority
CA
Canada
Prior art keywords
hydroformylation process
homogeneous catalysts
selective hydroformylation
selective
catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA166,466A
Other languages
English (en)
Other versions
CA166466S (en
Inventor
Irving Schwager
John F. Knifton
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Texaco Development Corp
Original Assignee
Texaco Development Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Texaco Development Corp filed Critical Texaco Development Corp
Application granted granted Critical
Publication of CA1020581A publication Critical patent/CA1020581A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
    • C07C27/20—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxo-reaction
    • C07C27/22—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxo-reaction with the use of catalysts which are specific for this process
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/828—Platinum

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA166,466A 1972-05-08 1973-03-20 Selective hydroformylation process using homogeneous catalysts Expired CA1020581A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/251,639 US3981925A (en) 1972-05-08 1972-05-08 Selective hydroformylation process using homogeneous catalysts

Publications (1)

Publication Number Publication Date
CA1020581A true CA1020581A (en) 1977-11-08

Family

ID=22952813

Family Applications (1)

Application Number Title Priority Date Filing Date
CA166,466A Expired CA1020581A (en) 1972-05-08 1973-03-20 Selective hydroformylation process using homogeneous catalysts

Country Status (9)

Country Link
US (1) US3981925A (xx)
JP (1) JPS5726248B2 (xx)
BE (1) BE798483A (xx)
CA (1) CA1020581A (xx)
DE (1) DE2322751A1 (xx)
FR (1) FR2183699B1 (xx)
GB (1) GB1391395A (xx)
IT (1) IT987197B (xx)
NL (1) NL7303413A (xx)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4193943A (en) * 1976-01-19 1980-03-18 Celanese Corporation Hydroformylation catalysts
US4299985A (en) * 1977-03-17 1981-11-10 Texaco Inc. Selective oxoamination process
US4101564A (en) * 1977-05-09 1978-07-18 Celanese Corporation Platinum-tin hydroformylation catalyst
US4101565A (en) * 1977-05-09 1978-07-18 Celanese Corporation Hydroformylation catalyst
US4147730A (en) * 1977-06-28 1979-04-03 Texaco Inc. Selective hydroformylation process
DE2809875C2 (de) * 1978-03-08 1983-05-05 Consortium für elektrochemische Industrie GmbH, 8000 München Verfahren zum Anlagern von Si-gebundenem Wasserstoff an aliphatische Mehrfachbindung
JPS54119407A (en) * 1978-03-09 1979-09-17 Agency Of Ind Science & Technol Preparation of aldehydes
US4198352A (en) * 1978-11-29 1980-04-15 Shell Oil Company Internal olefin hydroformylation process
DE2855506C3 (de) * 1978-12-22 1981-04-30 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur Herstellung von Methyl-nonyl-acetaldehyd
JPS55164640A (en) * 1979-06-12 1980-12-22 Agency Of Ind Science & Technol Preparation of aldehyde
JPS56166139A (en) * 1980-05-28 1981-12-21 Toa Nenryo Kogyo Kk Preparation of aldehyde
GB2085874B (en) * 1980-09-04 1984-08-08 Johnson Matthey Plc Hydroformylation of olefins
US4424380A (en) * 1981-12-07 1984-01-03 Sun Tech, Inc. Hydroformylation catalyst and process of using it
US4408078A (en) * 1981-12-23 1983-10-04 Shell Oil Company Process for the hydroformylation of olefins
US4487973A (en) * 1983-05-05 1984-12-11 Sun Tech, Inc. Hydroformylation process with platinum (O) catalyst
US4551559A (en) * 1984-04-11 1985-11-05 Sun Refining And Marketing Company Hydroformylation catalyst and process
US4542242A (en) * 1984-04-11 1985-09-17 Sun Refining And Marketing Company Platinum (O) complex-based hydroformylation catalyst
US4564711A (en) * 1984-04-11 1986-01-14 Sun Refining And Marketing Company Hydroformylation catalyst and process
US4542119A (en) * 1984-04-11 1985-09-17 Sun Tech, Inc. Hydroformylation catalyst and process
US4542120A (en) * 1984-04-11 1985-09-17 Sun Tech, Inc. Hydroformylation catalyst and process
US4524142A (en) * 1984-04-11 1985-06-18 Sun Tech, Inc. Platinum (O) complex-based hydroformylation catalyst
US4599456A (en) * 1984-12-20 1986-07-08 Phillips Petroleum Company Novel aldehyde-phosphine compositions and uses therefor
FR2578754B1 (fr) * 1985-03-13 1987-05-15 Charbonnages Ste Chimique Systeme catalytique electrochimique, son procede de preparation et son application a la fabrication d'aldehydes
EP4197995A1 (de) * 2021-12-17 2023-06-21 Evonik Operations GmbH Pt-xanthen-iod-komplex und pt-xanthen-brom-komplex

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1518236A1 (de) * 1964-12-15 1972-06-08 Johnson Matthey Co Ltd Katalytische Verfahren
GB1138601A (en) * 1964-12-15 1969-01-01 Geoffrey Wilkinson Improvements in catalytic reactions
US3657368A (en) * 1970-11-24 1972-04-18 Du Pont Catalysis by dispersions of metal halides in molten trihalostannate(ii) and trihalogermanate(ii) salts

Also Published As

Publication number Publication date
JPS5726248B2 (xx) 1982-06-03
IT987197B (it) 1975-02-20
FR2183699B1 (xx) 1977-02-04
NL7303413A (xx) 1973-11-12
DE2322751A1 (de) 1973-11-22
BE798483A (fr) 1973-10-19
FR2183699A1 (xx) 1973-12-21
GB1391395A (en) 1975-04-23
US3981925A (en) 1976-09-21
JPS4920112A (xx) 1974-02-22

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