CA1001992A - Process for producing n-phosphonomethyl glycine - Google Patents

Process for producing n-phosphonomethyl glycine

Info

Publication number
CA1001992A
CA1001992A CA188,637A CA188637A CA1001992A CA 1001992 A CA1001992 A CA 1001992A CA 188637 A CA188637 A CA 188637A CA 1001992 A CA1001992 A CA 1001992A
Authority
CA
Canada
Prior art keywords
producing
phosphonomethyl glycine
phosphonomethyl
glycine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA188,637A
Other languages
English (en)
Other versions
CA188637S (en
Inventor
Lowell R. Smith
Harry W. Frazier
John H. Wagenknecht
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Application granted granted Critical
Publication of CA1001992A publication Critical patent/CA1001992A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00Electrolytic production of organic compounds
    • C25B3/20Processes
    • C25B3/23Oxidation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/38Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813N-Phosphonomethylglycine; Salts or complexes thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Electric Double-Layer Capacitors Or The Like (AREA)
CA188,637A 1972-12-21 1973-12-20 Process for producing n-phosphonomethyl glycine Expired CA1001992A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US31749872A 1972-12-21 1972-12-21
US00385932A US3835000A (en) 1972-12-21 1973-08-06 Electrolytic process for producing n-phosphonomethyl glycine

Publications (1)

Publication Number Publication Date
CA1001992A true CA1001992A (en) 1976-12-21

Family

ID=26980991

Family Applications (1)

Application Number Title Priority Date Filing Date
CA188,637A Expired CA1001992A (en) 1972-12-21 1973-12-20 Process for producing n-phosphonomethyl glycine

Country Status (23)

Country Link
US (1) US3835000A (es)
JP (1) JPS5111094B2 (es)
AR (1) AR216882A1 (es)
BG (1) BG24411A3 (es)
BR (1) BR7309442D0 (es)
CA (1) CA1001992A (es)
CH (1) CH592105A5 (es)
DD (1) DD110503A5 (es)
DK (1) DK134559B (es)
EG (1) EG11507A (es)
ES (1) ES421614A1 (es)
FR (1) FR2211468B1 (es)
GB (1) GB1428499A (es)
HU (1) HU168961B (es)
IE (1) IE38667B1 (es)
IL (1) IL43880A (es)
IT (1) IT1001432B (es)
NL (1) NL163218C (es)
PH (1) PH10205A (es)
PL (1) PL94988B1 (es)
RO (1) RO64474A (es)
SE (1) SE403379B (es)
YU (1) YU37363B (es)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1494197A (en) * 1973-11-30 1977-12-07 Ici Ltd Electrochemical process for the preparation of n-phosphonomethyl glycine
US3991095A (en) * 1975-12-29 1976-11-09 Monsanto Company N-thiolcarbonyl derivatives of N-phosphonomethylglycine
US4047927A (en) * 1976-08-13 1977-09-13 Monsanto Company N-(2-hydroxyalkyl) derivatives of N-phosphonomethylglycine and the herbicidal use thereof
US4063922A (en) * 1976-08-13 1977-12-20 Monsanto Company N-(2-hydroxyalkyl) derivatives of N-phosphonomethylglycine for treatment of sugarcane
MX4703E (es) * 1976-12-20 1982-08-04 Monsanto Co Procedimiento mejorado para la preparacion de mono y disales de n-fosfonometilglicina
US4105432A (en) * 1977-07-18 1978-08-08 Monsanto Company Cyclized derivatives of N-(2-hydroxyalkyl)-N-phosphonomethylglycine compounds
US4180394A (en) * 1978-07-10 1979-12-25 Monsanto Company Derivatives of N-trifluoroacetyl-N-phosphonomethylglycinates and the herbicidal use thereof
US4218235A (en) * 1978-07-10 1980-08-19 Monsanto Company Ester derivatives of n-trifluoroacetyl-n-phosphonomethylglycine and the herbicidal use thereof
US4251258A (en) * 1978-09-29 1981-02-17 Monsanto Company N-(Substituted carbonyl) derivatives of N-phosphinylmethylglycinates and the herbicidal use thereof
US4300942A (en) * 1978-09-29 1981-11-17 Monsanto Company N-(Substituted carbonyl) derivatives of N-phos-phinylmethylglycinates and the herbicidal use thereof
US4251256A (en) * 1978-12-22 1981-02-17 Monsanto Company Herbicidal N-substituted ethylene derivatives of N-phosphonomethylglycine
US4261727A (en) * 1979-08-02 1981-04-14 Monsanto Company Herbicidal N-substituted triesters of N-phosphonomethylglycine
US4376644A (en) * 1980-12-04 1983-03-15 Stauffer Chemical Company Tri-mixed alkylsulfonium salts of N-phosphonomethylglycine and their use as plant growth regulators and herbicides
US4315765A (en) * 1980-12-04 1982-02-16 Stauffer Chemical Company Trialkylsulfonium salts of n-phosphonomethylglycine and their use as plant growth regulators and herbicides
US4384880A (en) * 1980-12-04 1983-05-24 Stauffer Chemical Company Trialkylsulfonium salts of N-phosphonomethyl-glycine and their use as plant growth regulators and herbicides
US4328027A (en) * 1981-04-16 1982-05-04 Stauffer Chemical Company Di-triethylamine salt of N,N'-bis-carboethoxymethyl-N,N'-bis-phosphonomethylurea and its use as a plant growth regulator
US4437874A (en) 1981-11-25 1984-03-20 Stauffer Chemical Company Tri-mixed alkylsulfonium salts of N-phosphonomethylgylcine and their use as plant growth regulators and herbicides
IL65187A (en) * 1982-03-08 1985-03-31 Geshuri Lab Ltd N-phosphonomethylglycine derivatives,processes for their preparation and herbicidal compositions containing them
US4472189A (en) * 1982-12-27 1984-09-18 Stauffer Chemical Co. Stannic N-phosphonomethyglycine and its use as a herbicide
FR2560198B1 (fr) * 1984-02-23 1987-05-07 Rhone Poulenc Agrochimie Esters de la famille de la n-phosphonomethylglycine et leur utilisation pour la preparation d'herbicides connus
ES534413A0 (es) * 1983-07-27 1986-01-01 Rhone Poulenc Agrochimie Procedimiento de preparacion de sulfonamidas con grupo ansinometilfosfonico
IL77364A (en) * 1984-12-28 1991-01-31 Monsanto Co Thermal dealkylation of n-alkyl n-phosphono-methylglycine
US4921991A (en) * 1985-02-22 1990-05-01 Guy Lacroix Preparation of esters of the N-phosphonomethylglycine and the N-phosphonomethyl glycines
US4804500A (en) * 1985-04-22 1989-02-14 Monsanto Company Amine dealkylation process
US4684483A (en) * 1985-09-23 1987-08-04 Monsanto Company Preparation of N-substituted amino acids
US5187292A (en) * 1988-08-18 1993-02-16 Rhone-Poulenc Agrochimie N-sulfomethylglycinate, use in the preparation of herbicides of the glyphosate type
FR2635522B1 (fr) * 1988-08-18 1990-11-16 Rhone Poulenc Agrochimie N-sulfonomethylglycinate procede de preparation, utilisation dans la preparation d'herbicides de type glyphosate
US6232494B1 (en) * 1998-02-12 2001-05-15 Monsanto Company Process for the preparation of N-(phosphonomethyl)glycine by oxidizing N-substituted N-(phosphonomethyl)glycine
ES2264196T3 (es) * 1998-02-12 2006-12-16 Monsanto Technology Llc Procedimiento para preparar glifosato oxidando glifosatos sustituidos en n.
US6417133B1 (en) * 1998-02-25 2002-07-09 Monsanto Technology Llc Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
DE60115019T2 (de) * 2000-05-22 2006-08-03 Monsanto Technology Llc. Reaktionssysteme zur herstellung von n-(phosphonomethyl)glyzin verbindungen
TW200624171A (en) * 2004-09-15 2006-07-16 Monsanto Technology Llc Oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
US7799571B2 (en) * 2005-04-01 2010-09-21 Monsanto Technology Llc Control of N-(phosphonomethyl)iminodiacetic acid conversion in manufacture of glyphosate
US8252953B2 (en) 2008-05-01 2012-08-28 Monsanto Technology Llc Metal utilization in supported, metal-containing catalysts

Also Published As

Publication number Publication date
EG11507A (en) 1977-08-15
YU37363B (en) 1984-08-31
RO64474A (fr) 1979-05-15
IT1001432B (it) 1976-04-20
US3835000A (en) 1974-09-10
BG24411A3 (en) 1978-02-10
IE38667L (en) 1974-06-21
DD110503A5 (es) 1974-12-20
YU330573A (en) 1983-04-27
DK134559B (da) 1976-11-29
JPS5111094B2 (es) 1976-04-08
GB1428499A (en) 1976-03-17
NL7317370A (es) 1974-06-25
SE403379B (sv) 1978-08-14
IE38667B1 (en) 1978-05-10
HU168961B (es) 1976-08-28
PL94988B1 (es) 1977-09-30
DE2363634A1 (de) 1974-06-27
AU6385173A (en) 1975-06-26
CH592105A5 (es) 1977-10-14
IL43880A (en) 1976-05-31
AR216882A1 (es) 1980-02-15
NL163218B (nl) 1980-03-17
ES421614A1 (es) 1976-10-16
DE2363634B2 (de) 1977-06-02
FR2211468A1 (es) 1974-07-19
IL43880A0 (en) 1974-03-14
NL163218C (nl) 1980-08-15
DK134559C (es) 1977-05-09
JPS4988827A (es) 1974-08-24
BR7309442D0 (pt) 1974-08-29
FR2211468B1 (es) 1976-05-07
PH10205A (en) 1976-09-27

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