BRPI0912146A2 - fluid treatment apparatus, method for treating a fluid, and nozzle arrangement. - Google Patents

Abstract

FLUID TREATMENT DEVICE, METHOD FOR TREATING A FLUID, AND, NOZZLE ARRANGEMENT A fluid treatment apparatus (10) comprises a fluid vessel (12) having first and second fluid chambers (14, 16). A fluid inlet (26) is provided to dispense a fluid to be treated for the first fluid chamber (14). At least one nozzle assembly (34) is arranged between the first and second chambers (14, 16) to provide fluid communication from the first fluid chamber (14) to the second fluid chamber (16), where said set of nozzle (34) is adapted to facilitate mixing of a gas with said fluid.

Description

"FLUID TREATMENT DEVICE, METHOD FOR TREATING A FLUID, AND, MOUTH ARRANGEMENT"

FIELD OF THE INVENTION The present invention relates to a fluid treatment apparatus and, in particular, but not exclusively, an apparatus for treating water produced from an underground hydrocarbon-bearing formation. The present invention also relates to a method of treating a fluid.

BACKGROUND OF THE INVENTION 10 Fluids produced from underground reservoirs are generally a mixture of oil, water, gas, usually with an amount of sand. In the early stages of production, fluids can be "dry", that is, containing little or no water, but as production continues it is normal for a larger volume of water to be produced. 15 In mature fields, the proportion of water in the fluids produced can reach 90% and possibly around 95%. Reservoirs do not always produce large volumes of sand, but when they do, sand production generally increases with increasing water production. The water produced from the reservoir is called "produced water". 20 The produced water can be injected back into the formation or it can be discharged into the environment, for example, in offshore production areas, the water can be discharged into the sea. However, the water produced must be carefully treated, in order to remove substantially all traces of oil and gas, before being discharged into the environment, in order to meet extremely strict environmental standards. In conventional production operations, the fluid produced from the reservoir is initially treated to separate marketable oil and gas from non-marketable water and sand. However, the separated water usually still contains unacceptable amounts of oil and gas and, as such, is normally subjected to a secondary treatment to further reduce the concentration of hydrocarbons to acceptable levels for discharge into the environment or injection back into the formation. 5 A process known as "flotation" is commonly used to assist in the removal of oil and other contaminants from water.

The flotation principle is that gas bubbles are introduced (for example, induced gas flotation) or are established in (for example, dissolved gas flotation) a vessel containing contaminated water, in which the bubbles go, 10 in a larger or lesser degree, if it attaches to contaminants, such as oil droplets, and drag them to the water surface, leaving most of the water depleted of contaminants and the upper layers of water enriched with contaminants.

In the subsequent explanations, each volume of water to which gas bubbles are added or created to separate contaminants can be referred to as a "cell" or "flotation cell". Flotation is normally operated as a continuous process, where there is a continuous entry of contaminated water into the cell and a continuous exit of water enriched in contaminants entrained from the surface layers of the cell and a continuous exit of the exhausted water in 20 contaminants in the cell, at a rate, in order to maintain an essentially constant level in the reservoir.

It is common for contaminants floating on the water surface to be trapped in a naturally formed foam when the contaminants are present in the highest concentrations found on the water surface, or with the aid of chemicals that are added to the inlet liquid.

Floating contaminants, for example, oil droplets, may not need to be foamed to keep them on the surface.

Contaminants on the surface of the water can be removed by a variety of means, the two most common being drains placed slightly below the surface of the water so that the contaminated-enriched surface layer preferably flows over them, or shovels that sweep the layer surface enriched with contaminants 5 on a drain placed, normally, slightly above the water surface.

Numerous designs of floating skimmer devices are also known that have the advantage of being able to tolerate a wider variation in the level of operating liquid than any of the previously mentioned fixed drain methods can accommodate. 10 In the Induced Gas Flotation (IGF) methods, gas bubbles are typically added to the contaminated water by eductors or mechanical mixers.

An IGF cell must be mixed to bring the gas bubbles in close contact with the contaminants, such as oil droplets, so that they can be separated by them, but this mixture has the side effects of making it harder for the bubbles rise to the surface, and cause variation in the residence time of the water parcels inside the cell.

Although the average residence time in the cell can be determined by the volume of the cell and the flow of water, mixing can mean that some portions of water pass through the cell for a much shorter time than is necessary for good separation, and conversely, some plots of water may remain in the cell for much longer than the average residence time.

The need to mix in the cell to bring gas bubbles and contaminants into contact reduces the separation efficiency in the cell. For this reason, IGF vessels are usually horizontal vessels that contain a plurality of IGF cells in series, typically four, so that the overall efficiency of the separation is increased.

Examples of known IGF systems of this type are shown in USA 4,564,457, USA 2006 / 0,213,840, USA 3,972,815, USA 3,647,069 and USA 5,348,648.

However, in some applications, vertical single-stage flotation cell units are known, which have a single IGF cell that typically has a cell volume and therefore slightly longer residence time than that would be found in the four cells 5 of a typical horizontal IGF unit.

Examples of these IGF arrangements are shown in WO 2004 / 112.936 and USA 5,011. 597. It should be understood that an IGF unit requires the fluid to remain in the vessel for a sufficient period to allow oil flotation and gas separation. However, increasing the residence time 10 will directly reduce the maximum fluid treatment rate. that can be obtained.

It may be possible to solve this problem by increasing the size of the IGF unit, but this is not desired, due to the limited available space in conventional production environments.

It is desirable to reduce the space occupied and the weight of the equipment 15 installed on marine platforms and, for this reason, compact flotation units have been proposed in the art for the treatment of water produced with a minimum area occupied by the installation.

For example, with reference to the prior art, WO 02 / 41.965 discloses a vertically arranged vessel, which receives fluid being treated through a tangentially arranged fluid inlet 20.

The arrangement of the fluid inlet in this way establishes the rotation of the fluid in the vessel, which is supposed to aid the coalescence of oil and gas bubbles and flotation to the surface.

The vessel may incorporate a spiral guide vane to enhance the rotation of the fluid.

In WO 02 / 41.965 the vessel is operated at a low pressure to allow dissolved gas to evolve from the aqueous phase and create gas bubbles in the area adjacent to the fluid inlet to mimic the effect of IGF units.

However, if an insufficient volume of gas is present in the fluid, then additional gas can be added to the fluid.

EP 1,400,492 also features a compact flotation unit that comprises a vertically arranged vessel with one or more tangential fluid inlets to encourage fluid rotation. In EP

1,400,492, the vessel also includes tangentially arranged fluid / gas inlets. These inlets communicate carbonated water to the vessel. 5 Other techniques for the treatment of fluids by the use of gas bubbles include cascade flotation techniques, in which the fluid being treated is passed through eductors to containers, in the form of a cascade. Examples of these techniques are presented in US 1,311,919, US, 1,380,665 and US 4,406,782. 10 US 4,986,903 discloses a flotation apparatus for separating oil from water. The apparatus shown includes separate gasification and degassing chambers. Carbonated water is introduced into the gasification chamber via a gas eductor. Recirculation of the fluid to be aerated is possible between the degassing chamber and the aeration chamber via 15 of the recirculation line 70 and the gas eductor 40. Among the objectives of the present invention is to avoid or mitigate one or more problems of the prior art .

SUMMARY OF THE INVENTION In accordance with a first aspect of the present invention, a fluid treatment apparatus is provided comprising: a fluid vessel; first and second fluid chambers defined within the fluid vessel; a fluid inlet for dispensing a fluid to be treated 25 to the first fluid chamber; and at least one nozzle assembly to provide fluid communication from the first fluid chamber to the second fluid chamber, where said nozzle assembly is adapted to facilitate mixing of a gas with said fluid.

The at least one nozzle assembly can facilitate the carrying of a gas into said fluid.

Alternatively, or in addition, the at least one nozzle assembly can facilitate the injection, mixing or dispensing of a gas into said fluid.

However, for the sake of brevity of the present summary of the invention, the general concept of gas mixing, or dispensing a gas into the fluid being treated will generally be referred to as carrying.

The apparatus can be adapted to treat a fluid containing several components, the components of which may comprise any one or a combination of liquids, gases and solids.

For example, the fluid can comprise a water / oil mixture, water / oil / gas mixture, or the like.

The first fluid chamber can be adapted to receive the fluid to be treated and distribute this fluid to the second fluid chamber, with the gas carried to be treated therein.

The first fluid chamber 15 can therefore define a dispensing chamber and the second chamber can define a treatment chamber.

The second fluid chamber can be adapted to accommodate a fluid separation treatment therein.

The separation treatment can be adapted to separate the fluid components, such as 20 components of different densities, chemicals, phases, or the like.

Advantageously, the gas carried in the liquid entering the second chamber can enhance fluid separation.

The separation treatment can comprise a flotation separation treatment.

In one embodiment, the second fluid chamber can be adapted to accommodate a separation treatment to effect the separation of mineral oil and, optionally, water gas, such as water produced from an underground hydrocarbon reservoir.

In this arrangement, the carrying of gas to the fluid, communicated from the first fluid chamber, can help oil flotation.

The oil can be

. 7 skimmed or otherwise collected from the water surface inside the second fluid chamber.

Additionally, the gas released from the water can be collected.

Advantageously, the provision of at least one set of 5 nozzles to facilitate the carrying of gas for the fluid being treated can eliminate the need for the provision of external installation equipment, such as gasifiers, mixers, pumps, compressors and the like, associated with the prior art.

However, in embodiments of the present invention it may be desirable to use these external or additional equipment 10.

In addition, the at least one nozzle assembly can be adapted to communicate fluid that has already been mixed with a gas to the second fluid chamber.

In this way, the residence time of the fluid in the second chamber can be used substantially entirely for the treatment of the fluid, such as the separation of the fluid components. Therefore, this differs from prior art arrangements in which the residence time must also accommodate sufficient gas / fluid mix.

The fluid vessel can be arranged vertically.

This arrangement can help to minimize the area occupied by the fluid treatment apparatus, which is advantageous, especially in marine applications. Alternatively, the fluid vessel can be arranged horizontally.

Alternatively, the fluid vessel may be arranged to tilt.

The first and second fluid chambers can be arranged to be adjacent to each other, inside the vessel.

Alternatively, the first and second chambers can be arranged separately 25 in the vessel.

The first and second fluid chambers can be arranged vertically inside the vessel.

That is, one chamber can be, at least partially, arranged above the other chamber.

In one embodiment, the first chamber can be, at least partially, arranged above a portion of the second chamber.

This can make feeding easier

. 8 by gravity of the fluid between the chambers.

Alternatively, or in addition, the first and second chambers can be arranged horizontally inside the vessel.

That is, one chamber can be arranged, at least partially, next to the other chamber.

The apparatus may comprise a partition adapted to at least partially separate the first and second fluid chambers.

The partition can divide the vessel into at least the first and second fluid chambers.

The partition may comprise a plate or the like, and may be of any suitable shape, such as, generally, circular, annular, square, rectangular or similar.

The partition can be fixed to an internal surface of the vessel, for example, by welding, a flanged connection, screws, interference fit or the like, or any suitable combination thereof.

The partition can be formed as a single component, or it can be formed by several components.

The partition can define a wall or boundary portion of one or both of the first and second chambers.

The partition can define a base for one or both chambers.

The partition can define an upper region or ceiling for one or both chambers.

In an embodiment of the present invention the partition can define a base of the first chamber and a ceiling of the second chamber.

The at least one nozzle assembly can be adapted to extend through the partition.

The at least one nozzle assembly can be attached to the partition so that it provides support for the at least one nozzle assembly.

The at least one nozzle assembly may comprise a first fluid conduit defining a fluid port adapted to allow communication of fluid to be treated from the first fluid chamber to the first fluid conduit.

The fluid port can be provided in the base region of the first fluid chamber.

Alternatively, the fluid port can be provided at an elevated location relative to a base region of the first fluid chamber.

In this arrangement, the elevated location of the fluid port can allow the nozzle assembly to be operational only when a predefined gradient of fluid to be treated is present in the first fluid chamber.

This arrangement can help to achieve a preferred speed and flow range between the first and second chambers.

The first fluid conduit can be completely contained in the vessel.

Alternatively, at least a portion of the first fluid conduit may extend outside the vessel.

The at least one nozzle assembly may comprise a second fluid conduit adapted to allow fluid communication from a gas from a gas source to a portion of the nozzle assembly.

In this way, the gas from the gas source can be carried into the fluid being treated.

The gas source may comprise gas contained in the vessel, and may comprise gas contained in one or both of the first and second fluid chambers.

In this arrangement the second fluid conduit can define an open fluid port for a gas charged region of one or 20 both the first and second fluid chambers.

The gas may comprise gas released from the fluid being treated.

Alternatively, the gas may comprise gas provided by an external source.

The second fluid line can be coupled directly to an external gas source. The second fluid line can be completely contained in the vessel.

Alternatively, at least a portion of the second fluid conduit may extend outside the vessel.

The at least one nozzle assembly may comprise a discharge tube in fluid communication with one or both of the first and

, 10 second fluid conduits.

At least a portion of the discharge tube can facilitate mixing or mixing of dispensed fluid through the first fluid conduit with gas dispensed via the second fluid conduit.

In this arrangement, turbulence and mixing in the discharge tube can configure the gas in 5 small bubbles and cause these bubbles to mix intimately with the fluid coming from the first chamber.

Consequently, the nozzle assembly can dispense to the second chamber a fluid that contains a favorable distribution of gas bubbles for subsequent fluid treatment in the second chamber. The discharge tube can define a fluid outlet opening for the second fluid chamber to allow gas and the mixture of fluids to be discharged into said second chamber.

The fluid outlet of the discharge tube can be adapted to be, at least partially, submerged in the fluid being treated inside the second fluid chamber 15.

The discharge tube can be arranged to discharge fluid to any region of the second chamber.

In one embodiment, the discharge tube can be arranged to discharge fluid to an external region of the second chamber. The discharge tube can be oriented to allow fluid and gas mixture to be discharged to the second chamber in a predetermined direction.

This arrangement can help to establish a preferred fluid movement in the second fluid chamber.

In one embodiment, the discharge tube can be arranged to establish rotational flow in the second chamber.

The rotational flow can be established in relation to a central axis of the second chamber.

The rotational flow in the second fluid chamber can assist with fluid treatment therein.

For example, the rotary flow can assist the preferred movement of gas bubbles in the fluid being treated, the preferred movement of the fluid components to discharge regions of the second chamber, and the like.

The rotating flow can prevent mixing in front of the treated liquid towards an outlet (that is, premature discharge of the fluid being treated), and can modify the residence time distribution. The discharge tube can be arranged obliquely (i.e., not parallel) to a central axis of the second chamber.

The discharge tube can be arranged obliquely to discharge fluid to an external region of the second chamber to advantageously initiate the rotary flow in said second chamber.

The discharge tube can be adapted to discharge fluid with a first velocity component parallel to a central axis of the second fluid chamber, and a second velocity component perpendicular to the central axis (that is, tangential to a circle with an origin coinciding. with the central axis of the vessel). The apparatus may comprise a plurality of nozzle assemblies.

At least one of the plurality of nozzle assemblies can be similar to at least one nozzle assembly described above.

The nozzle assemblies can be arranged in an annular configuration with respect to the first fluid chamber.

However, 20 other configurations can be used.

For example, nozzle assemblies can be arranged to generally conform to the outer peripheral shape of the vessel, which may differ from the circular.

Each nozzle assembly can be adapted to be operational in substantially the same fluid gradient range in the first fluid chamber 25.

For example, each nozzle assembly may comprise a fluid port adapted to allow communication with the fluid contained in the first fluid chamber, where the fluid ports can be arranged at substantially the same height with respect to a base region of the first fluid chamber. fluid.

Consequently, when the gradient, i.e. the fluid level, inside the first fluid chamber falls below the level of the fluid ports, all nozzle assemblies will become ineffective, until a sufficient gradient is re-established.

Alternatively, at least one of the plurality of nozzle assemblies 5 can be adapted to be operative to a different fluid gradient within the first fluid chamber, different from at least another of the plurality of nozzle assemblies.

For example, at least two of the nozzle assemblies can comprise the respective fluid ports adapted to allow communication with fluid contained within the first fluid chamber, where the fluid ports can be arranged at the respective different heights in relation to a region. base of the first fluid chamber.

Consequently, in this arrangement, if the fluid gradient in the first fluid chamber starts to fall, for example, as a result of a reduced flow rate through the inlet, the nozzle assemblies will become sequentially ineffective according to the heights of the respective fluid ports.

Such an arrangement can therefore be used to maintain a preferred speed range of the fluid entering the second fluid chamber through the nozzle assemblies.

The preferred speed range can be selected according to the flow required in the second fluid chamber.

In this arrangement, the provision of a degree of control over the speed range can help maintain a preferred flow pattern (for example, rotary) in the second chamber, reducing the effect of variations in flow through the entrance of the first chamber.

The preferred speed range can also be selected 25 to maintain the proportion of gas carried with the fluid and the mixture between them, which occurs in the discharge tube within pre-defined values.

The apparatus may optionally comprise a baffle arrangement located within the second chamber.

The deflector arrangement can be configured to minimize mixing in front of fluids inside the second chamber.

The baffle arrangement can be positioned adjacent to a wall surface of the second chamber.

The baffle arrangement can be located in the region of at least one nozzle assembly.

The deflector arrangement can be configured to deflect fluid that falls on a wall surface of the nozzle assembly. • The baffle arrangement can define a continuous barrier for the fluid in the region of interest.

Alternatively, the deflector arrangement can define a discontinuous barrier.

This can allow the release of solid and similar particles that can be collected over the deflector arrangement.

The baffle arrangement may comprise holes or the like.

One or more holes can be defined on a surface of the baffle arrangement.

One or more holes can be defined between the edge surface of the deflector arrangement and the wall surface of the second chamber.

The baffle arrangement can be aligned substantially perpendicular to the wall surface of the second chamber.

The deflector arrangement can be aligned obliquely with respect to the wall surface of the second chamber.

A fluid passage can be provided between the first and second chambers to allow fluid communication between them, preferably 20 in both directions.

The fluid passage can be contained within the vessel.

Alternatively, or in addition, a portion of the fluid passage may extend outside the vessel.

The fluid passage can be adapted to allow fluid communication of a gas between the first and second chambers.

In one embodiment, the fluid passage can be adapted 25 to allow fluid communication of a gas from the second fluid chamber to the first fluid chamber.

The gas may comprise gas released from a fluid being treated within the second chamber.

Alternatively, or in addition, the gas may comprise a gas supplied by an external source.

The fluid passage can alternatively or additionally be adapted to communicate a liquid or solids, or the like, between the first and second fluid chambers.

The fluid passage can be provided centrally or eccentrically to the vessel.

A single fluid passage can be provided, or a plurality of fluid passages can be provided.

The fluid passage can extend through a partition that separates the first and second chambers.

The fluid passage can be defined by a wall that extends from a surface of the partition.

In this arrangement, the wall can define an annular region with the inner wall surface of the first fluid chamber, where said annular region is adapted to receive fluid to be treated from the vessel fluid inlet.

The at least one nozzle assembly can be positioned in the annular region.

The first fluid chamber may comprise a dispensing assembly adapted to receive fluid entering the first chamber via fluid inlet.

The distributor assembly can be adapted to dissipate the moment of the inlet fluid.

The dispensing assembly can be adapted to distribute the fluid towards at least one nozzle assembly minimizing turbulence.

The dispensing assembly may comprise a box-shaped structure adapted to receive fluid from the fluid inlet.

The box-like structure may comprise a perforated region, allowing fluid communication from said structure.

The apparatus may comprise one or more fluid outlets to allow the discharge of treated liquid, or its components, from the vessel.

The fluid outlets can be provided in one or both of the first and second fluid chambers.

In one embodiment, the apparatus may comprise a first fluid outlet adapted to predominantly allow the discharge of a first fluid component, such as a liquid, for example, water.

The first fluid outlet can be positioned inside the second chamber, and can be positioned inside

• 15 from a lower region of the second chamber.

The apparatus may additionally comprise a second fluid outlet adapted to predominantly allow the discharge of a second fluid component, such as a liquid, for example, oil.

The second fluid outlet can be positioned inside the second fluid chamber, and the second fluid outlet can be positioned within an upper region of the second chamber, or, alternatively, or additionally, within a lower region liquid chamber and / or in any location between them. The apparatus may additionally comprise a third fluid outlet adapted to predominantly allow the discharge of a third fluid component, such as a gas, for example, hydrocarbon gas.

The third fluid outlet can be positioned within the first fluid chamber, and can be positioned within an upper region of the first chamber.

At least one fluid outlet may comprise an arrangement adapted to substantially eliminate or at least minimize vortex flow through it.

The apparatus may additionally comprise a skimmer apparatus 20 adapted to skim a component of the fluid being treated from a surface thereof.

The skimmed component may comprise oil.

A conventional skimmer device can be used.

The second fluid chamber can be adapted to receive fluid from the first fluid chamber only.

Consequently, in this arrangement, the entire volume of fluid being treated flows through the first fluid chamber.

Alternatively, the second fluid chamber can be adapted to receive fluid from another source.

Fluid communication being handled between the first and second fluid chambers can be achieved exclusively through at least one nozzle assembly.

Alternatively, fluid communication can be obtained additionally by other means.

The at least one nozzle assembly may allow the addition of a fluid treatment agent to the fluid being treated.

For example, the fluid treatment agent can comprise a pH neutralizer, flocculant or the like.

The at least one nozzle assembly may comprise an eductor. This vessel may comprise a single vessel containing both the first and the second fluid chambers.

The vessel may comprise a closed vessel.

Alternatively, the vessel may comprise an open vessel, for example, opened at the top, so that at least part of the vessel can be exposed to the ambient atmosphere. The apparatus may comprise a third fluid chamber adapted to receive fluid from the second fluid chamber for further treatment.

Communicated fluid from the second fluid chamber to the third fluid chamber can be provided through at least one nozzle assembly. According to a second aspect of the present invention there is provided a method of treating a fluid, said method comprising the steps of: defining first and second fluid chambers; dispensing a fluid to be treated for the first fluid chamber; flow the fluid from the first fluid chamber through at least one nozzle assembly adapted to mix gas with said fluid; and discharge the fluid from at least one nozzle assembly into the

• 17 second fluid chamber to be treated additionally in it.

The fluid can be treated inside the second chamber and subsequently discharged, where mixing the gas with the fluid in at least one nozzle facilitates or assists subsequent treatment within the second fluid chamber.

A flotation treatment can be provided in the second fluid chamber.

The apparatus used to carry out the method can be provided in accordance with the apparatus of the first aspect, and it is to be understood that as the method of operation of said apparatus the method according to the present aspect of the invention must be applied.

According to a third aspect of the present invention, a fluid treatment apparatus is provided comprising: a first fluid chamber; a second fluid chamber; 15 a fluid inlet for dispensing a fluid to be treated for the first fluid chamber; and at least one nozzle assembly extending between the first and second fluid chambers to provide fluid communication between them, where said nozzle assembly is adapted to facilitate mixing a gas with said fluid.

The first and second fluid chambers can be provided in a single vessel.

The vessel can be closed or alternatively, it can be opened to the atmosphere.

Alternatively, the first and second fluid chambers can be defined in separate vessels.

At least one of the vessels 25 can be closed.

At least one of the vessels can be opened to the atmosphere.

According to a fourth aspect of the present invention, a fluid treatment apparatus is provided comprising: a fluid treatment vessel adapted to receive a fluid to be treated from a fluid source; and at least one nozzle assembly provided between the fluid treatment vessel and the fluid source, where the fluid from the fluid source is adapted to flow through at least one nozzle assembly before entering the fluid treatment vessel. , and where the at least one nozzle assembly is adapted to mix a gas with the fluid.

Consequently, the entire volume of fluid is mixed with gas before entering the fluid treatment vessel.

In this way, the residence time of the fluid inside the fluid treatment vessel can be fully used for the treatment of the fluid.

This differs from the prior art arrangements in which gas mixing is performed inside the fluid treatment vessel.

According to a fifth aspect of the present invention there is provided a nozzle arrangement for distributing a fluid to be treated between a first fluid chamber and a second fluid chamber, said nozzle arrangement comprising: a first nozzle assembly comprising a first fluid conduit extending between the first and second fluid chambers, where the first fluid conduit comprises a first fluid port providing communication with the first fluid chamber; and a second nozzle assembly comprising a second fluid conduit extending between the first and second fluid chambers, where the second fluid conduit comprises a second fluid port providing communication with the first fluid chamber; where the first and second fluid ports are provided at 25 different heights from the base of the first fluid chamber to facilitate the operation of the first and second nozzle assemblies with different ranges of liquid gradient within said first fluid chamber .

Such an arrangement can therefore allow for a preferred fluid velocity range distributed to the second fluid chamber,

regardless of the liquid flow to the first fluid chamber. The first and second nozzle assemblies can be adapted to facilitate mixing of a gas with said fluid. The first and second nozzle assemblies can facilitate the dispensing of a gas for said fluid. Each of the first and second nozzle assemblies may comprise an additional fluid conduit adapted to allow fluid communication of a gas from a gas source to a portion of the respective nozzle assembly. 10 Each of the first and second nozzle assemblies can comprise a discharge tube defining a fluid outlet opening for the second fluid chamber. The discharge pipe of the first and second nozzle assemblies can be arranged to establish rotational flow within the second chamber. It should be understood that, although different aspects of the invention have been presented, the characteristics presented in relation to one aspect can be applied to one or more of the other aspects.

BRIEF DESCRIPTION OF THE DRAWINGS These and other aspects of the present invention will now be described, by way of example only, with reference to the accompanying drawings, in which: Figure 1 is a longitudinal cross-sectional view of a fluid treatment apparatus, from according to an embodiment of the present invention; Figure 2 is a side view in cross section of the apparatus in the region of an upper chamber; Figure 3 is an enlarged view of an entrance region of the first apparatus shown in Figure 1; Figure 4 is a diagrammatic representation of anticipated flow patterns within the apparatus of Figure 1; Figure 5 is a cross-sectional view of a nozzle assembly according to an embodiment of the present invention, suitable for use in the apparatus of Figure 1; Figure 6 is a cross-sectional view of a nozzle assembly according to an alternative embodiment of the present invention, suitable for use in the apparatus of Figure 1, and Figure 7 is a diagrammatic representation of a treatment apparatus for fluids according to an alternative embodiment of the present invention.

DETAILED DESCRIPTION OF THE DRAWINGS Reference is first made to Figures 1 and 2 of the drawings, in which cross-sectional views of a fluid treatment apparatus are shown, generally identified by the numeral 15 reference 10, according to an embodiment of the present invention. The apparatus 10 is shown in Figure 1, in longitudinal cross section and in Figure 2 in lateral cross section. The fluid treatment apparatus 10 can be used in many applications. However, in the present embodiment, apparatus 10 is used to treat water produced from an underground reservoir comprising volumes of oil and gas. As will be described in more detail below, apparatus 10 is adapted to separate oil and gas from water produced by flotation separation. Apparatus 10 can therefore be described as a Compact Flotation Unit (CFU). The apparatus 10 comprises a generally cylindrical vessel arranged vertically 12 which defines a first fluid chamber or upper chamber 14 and a second fluid chamber or lower chamber 16. The upper and lower fluid chambers are separated by a partition 18 fixed to an inner wall surface of the vessel 12. The partition defines a base of the upper chamber 14 and a ceiling of the lower chamber 16. A fluid passage 20 extends between the upper and lower chambers 14, 16 and is defined by a portion of wall 22 extending vertically from partition 18. The wall portion 22, in combination with the inner wall surface of the vessel 12 defines a generally annular region or channel 24 within the upper chamber 14. As will be described below in greater detail, the fluid passage 20 allows gas communication between the upper and lower chambers 14, 16. A fluid inlet 26 is formed in a side wall of the vessel 12 and, in use, communicates the produced water to be treated for the upper fluid chamber 14 and, specifically, for the annular region 24. A dispensing assembly 28 is provided inside the upper chamber 14 and is initially arranged to receive the produced water that enters through inlet 26 The dispenser assembly 28, which is shown more clearly in Figure 2 and in the enlarged view in Figure 3, is shaped like a box defined by the partition 18, the wall portion 22, an inner wall portion of the vessel 12, plates perforated sides 30, and a solid lid 32 (shown in Figure 3 only). In this way, produced water that enters the upper chamber 14 via the inlet 26 will be received, first, in the distributor set 28 and then 20 distributed to the annular region 24 through the perforated side plates 30. The distributor set 28 works to dissipate the moment of the produced water that enters and to distribute it to the annular region 24 with the minimum of turbulence, preventing or minimizing the risk of accidental splashing or leakage of the water to the lower chamber 16 through the passage 20. 25 The apparatus 10 comprises, in addition, a plurality of nozzle assemblies or eductors 34 that provide fluid communication of the produced water from the annular region 24 of the upper chamber 14 to the lower chamber 16. In this way, the upper chamber 14 receives water produced through the fluid inlet 26 and subsequently distributes it to the lower chamber 16 through the nozzle assemblies 34. The water produced is then subjected to flotation treatment in the interior of the lower chamber 16. Consequently, the upper fluid chamber 14 can define a dispensing chamber and the lower fluid chamber 16 can define a treatment chamber.

Each nozzle assembly 34 facilitates the carrying of a gas to the produced water flowing through it.

The gas is carried from a collecting region 36 of the upper chamber 14 and the turbulence and the mixture inside each nozzle set 34 configure the gas carried in small 10 bubbles and cause them to mix intimately with the water produced before being discharged into the lower chamber 16. In this way, the nozzle assemblies 34 dispense water produced to the lower chamber 16 with a favorable distribution of gas bubbles for the subsequent treatment of fluid therein.

This is particularly advantageous due to the fact that the subsequent residence time of the water, inside the lower chamber 16, can be used exclusively for the flotation treatment and for the separation of the oil and gas from the water.

This differs significantly from prior art arrangements in which the gas mixture takes place inside a flotation chamber and, therefore, the residence time must accommodate both the gas mixture 20 and the flotation separation.

The shape of the nozzle assemblies 34 will be described in more detail below.

As the water produced enters the lower chamber 16, the water and the oil naturally begin to separate, with the oil tending to float on the surface of the water.

The presence of well-distributed gas bubbles inside the produced water increases the separation effect due to the fact that the bubbles adhere to the oil droplets inside the water, and helps the oil's coalescence and flotation.

Upon reaching the water surface, gas bubbles will be released to an upper region 90 of the lower chamber 16 and,

subsequently, they will flow to the collection region 36 of the upper chamber 14 through passage 20. Consequently, the gas released from the produced water can replenish the collection region 36 to maintain a sufficient volume of gas to carry the water inlet produced by the assemblies. Nozzle 5 5. The apparatus 10 further comprises a first outlet 38 formed in a lower region of the lower chamber 16 and adapted to facilitate the discharge of treated water.

A baffle 40 and vortex breaker 42 are also present within the lower region of the lower chamber 10 and are adapted to prevent gas bubbles from being discharged through the first outlet 38 with the treated water.

As shown in Figure 1, the baffle 40 is positioned concentrically to the vessel 12 and has a diameter that can be approximately 80 to 95% of the inner diameter of the vessel 12. 15 A skimmer apparatus 44 is provided in an upper region of the chamber bottom 16 and is adapted to skim oil from the water surface.

The skimmed oil is discharged through a tube 46 and finally through a second outlet 48 formed on one side of the vessel 12 above the location of the partition 18. The vessel 12 is advantageously maintained at a pressure slightly above atmospheric pressure to guide the scummed oil up through the tube 46 towards the second outlet 48. The oil can then be collected and processed as needed.

In an alternative arrangement, tube 46 can extend downwardly from skimmer apparatus 44 and discharge through an outlet in a lower region of vessel 12, for example, from a basal region, below baffle 40. The skimmer 44 is self-leveling, so that an upper skimmer region 50 is maintained in a predefined position with respect to the water / oil surface in the lower chamber 16, for

. 24 preserve the efficient skumage of the oil.

A third outlet 52 is provided in the upper region of the upper chamber 14 and this allows the gas in the collection region 36 to be discharged from vessel 12. The gas can be collected, burned, recycled or the like.

The outlet 52 can also function as an inlet to allow gas to be supplied to the vessel 12. In the present embodiment, the nozzle assemblies 34 comprise discharge pipes 54 which are partially immersed in the water produced in the lower chamber 16 and are arranged in a common direction for 10 to discharge the produced water downward and circumferentially in relation to vessel 12. This arrangement rotates the water inside the lower chamber 16, which advantageously helps the fluid treatment in the same chamber and provides preferential movement of bubbles of gas inside the fluid and oil floating towards skimmer assembly 44. In addition, the rotation of the produced water 15 helps to prevent water from passing through the lower chamber 16 without providing sufficient time for gas bubbles and oil droplets separate from the water.

A baffle arrangement in the form of an annular baffle 55 can optionally be fixed or integrally formed with the lower chamber wall 20 16 in a region below the discharge tubes 54 of the nozzle assemblies 34. In use, the baffle 55 minimizes a component downward fluid velocity to help minimize mixing ahead of liquid.

Although not illustrated, the deflector 55 includes numerous holes to allow the release of any solid matter that can be collected on an upper surface thereof.

Reference is now made to Figure 4 of the drawings, in which a diagrammatic representation of an anticipated flow pattern is shown inside vessel 12. The left side of vessel 12, shown in Figure 2, illustrates an anticipated secondary flow pattern of water, and the right side shows the anticipated trajectories of bubbles inside the lower chamber 16. It should be understood that the primary rotational movement of the fluid around the central longitudinal axis of the vessel 12 is not shown in Figure 4 for clarity.

In addition, the optional annular deflector 55, shown in Figure 5 1, is not shown in Figure 4. A lateral circulation loop 60 (closed loop 1) is driven by the gas rise of the large bubbles 62 discharged from the nozzle assemblies 34 rising rapidly to the surface.

Circulating loop 60 ensures that the flow over the liquid surface 10 is towards the skimmer assembly 44, so that the separated oil 64 can be carried in this direction.

A closed loop of longitudinal circulation 66 (closed loop 2) is driven by flow radially inward in the limit layer of liquid 68 over the deflector 40. The closed loop of circulation 66 captures the small gas bubbles 70, which have downward trajectories 15 out of the main water flow and transports them towards the center and then upwards towards the surface, to be captured by the closed circulation loop 60. The small bubbles of gas 70 must therefore cross into the circulation circuit 60 to finally reach the surface, and / or coalesce into larger bubbles. A detailed description of the shape of a nozzle assembly 34 will now be described with reference to Figure 5, in which the nozzle assembly 34 is shown in sectional view.

Assembly 34 comprises a first fluid conduit 72 which extends upwards and defines a fluid inlet port 74. A lower end of the first conduit is attached to the inclined discharge pipe 25. The first fluid port 74 allows water produced in the annular region 24 (see Figure 1) flows into the first conduit 72 and thus to the discharge pipe 54. A flange 78 is attached to the first fluid conduit 72 and allows the nozzle assembly 34 to be attached to the partition 18 (see Figure 1), separating the upper and lower chambers 14, 16.

Assembly 34 also comprises a second fluid conduit 80 that extends through the first fluid conduit 72. The second conduit 80 defines an upper fluid port 82 that opens into the collection region 36 (see Figure 1). A lower end of the second conduit 80 5 is opened in the region of the discharge pipe 54. Thus, in use, water flowing through the first fluid conduit 72 will cause gas to be carried from the second fluid conduit 80, coming from the region of collects 36 and subsequently mixed inside the discharge tube 54, thus establishing a good distribution of gas bubbles inside the water before being discharged through an outlet 84 to the lower chamber 16. The height of the door of fluid 74 from the first fluid conduit will dictate the fluid gradient within the annular region 24, necessary for the nozzle assembly 34 to operate.

This operating gradient can be varied and pre-selected by providing an extension tube 86 of the required length, fixed or integrally formed with the first fluid conduit 72. The operating gradient of the nozzle assemblies 34 can be in the region of 400 -500mm, for example.

In an embodiment of aspects of the present invention, the operational gradient may be equivalent for all nozzle assemblies 34 provided within the apparatus.

However, in alternative embodiments, two or more nozzle assemblies 34 can be provided with different operational gradients, by arranging the respective fluid ports 74 at different heights.

Consequently, in this arrangement, if the gradient or fluid level within the annular region 24 of the upper chamber 14 begins to fall, for example, as a result of a reduced flow rate through the inlet 26, the nozzle assemblies 34 will become sequentially ineffective, in accordance with the heights of the respective fluid ports 74, until the flow, passing through the reduced number of nozzle assemblies 34 in operation, to the second chamber 16, matches the flow entering the annular region 24 from inlet 26. This arrangement can therefore be used to maintain a preferred speed range of the fluid being discharged through outlets 84 of the discharge tubes 54 to the second fluid chamber 16. The preferred speed range can be selected according to the flow required inside the second fluid chamber 16. For example, a range of fluid discharge speeds may be required to establish and maintain the flow rotating flow inside the lower chamber.

The preferred speed range 10 can also be selected to maintain the proportion of gas carried within the fluid and the mixture between them, which occurs in the discharge tube within preferred values.

An alternative embodiment of a set of nozzles 34 that can be used in the apparatus 10 shown first in Figure 1, 15 is shown in Figure 6, to which reference will now be made.

The set 34a, in Figure 6, is similar to the set 34 in Figure 5 and, as such, equal components share equal reference numerals, followed by the letter "a". As noted, the nozzle assembly 34a is similar to the assembly 34 and, as such, comprises a first fluid conduit 72a defining a fluid port 20 74a, and a second fluid conduit 80a defining a fluid port 82a.

However, in this embodiment, the fluid port 82 of the second fluid conduit 80a opens to a collection region 90 (see Figure 1) of the lower chamber 16. In this way, gas from the collection region 90 can be carried and mixed with water produced inside a discharge tube 54 before 25 is discharged through an outlet 84 into the lower chamber 16. Although not illustrated, the nozzle assembly 34a may include an extension tube, similar to tube 86 in the example shown in Figure 5. A fluid treatment apparatus according to an alternative embodiment of the present invention will now be described with reference to Figure 7. The fluid treatment apparatus, generally identified by reference numeral 110, is similar to the apparatus 10 shown first in Figure 1 and, as such, equal characteristics share equal reference numerals, incremented by 100. 5 Therefore, the apparatus 110 comprises a vessel 112 which, in this case, is fixed horizontally.

First and second fluid chambers 114, 116, separated by a partition 118, are defined inside the vessel 12. A fluid passage 120 is provided between the first and second chambers 114, 116 to allow gas to pass between them.

A fluid inlet 126 10 communicates water produced to the first chamber 114, and a plurality of nozzle assemblies 134 are provided to allow communication of the water produced from the first chamber 114 and to the second chamber 116. The nozzle assemblies 134 facilitate carrying a gas within a collection region 136 of the first chamber 114, or a collection region 190 of the second chamber 116, for the water produced.

Therefore, this arrangement provides a good mixing and distribution of gas bubbles within the fluid produced before being discharged into the second chamber 116. The fluid produced can then remain for a period of time inside the second chamber 116, so that the gas and oil in the water 20 can float to the surface thereof, while the water moves in a direction generally from left to right.

Perforated deflectors 92, preferably at least two, are provided inside the second chamber 116 to prevent water from being mixed again.

Treated water with significantly reduced gas and oil content can be discharged through a first outlet 138. The floating oil can be skimmed from the water surface by a skimmer assembly 144 and subsequently discharged through a second outlet 148. The gas released from the water can be discharged via a third outlet 152.

It should be understood that the embodiments described herein are exemplary and that various modifications can be made to them, without departing from the scope of the present invention.

For example, features of the present invention described above, can be used in circumstances where the first and second chambers are provided in separate vessels.

In this arrangement, the benefits of the present invention can still be obtained by virtue of the passage of the produced water to be treated through the nozzle assemblies, so that a good mixture and distribution of bubbles inside the water is obtained before being discharged into the water. second fluid chamber 10 for treatment.

In other embodiments, the first chamber can be dispensed and fluid from a source can be supplied directly to at least one nozzle assembly to be discharged to a fluid treatment chamber.

In addition, in the described embodiments, several channels and passages are provided and located internally to the vessel.

However, these conduits and passages can extend totally, or at least partially, outside the vessel.

In addition, the apparatus may comprise a third fluid chamber adapted to receive fluid from the second fluid chamber for further treatment.

Communicated fluid from the second fluid chamber to the third fluid chamber can be provided through at least one nozzle assembly.

In addition, the gas to be carried into the fluid being treated can be provided from an external source. The vessel can be opened to the atmosphere.

Although the nozzle assemblies are arranged to carry gas to the fluid being treated, in alternative arrangements, at least one of the nozzle assemblies can be adapted to allow gas to be injected or otherwise dispensed into the fluid being treated.

Claims (30)

1. Fluid treatment apparatus, characterized by the fact that it comprises: a fluid vessel; 5 first and second fluid chambers defined within the fluid vessel, wherein the second fluid chamber is adapted to accommodate a flotation separation treatment of a fluid therein; a liquid inlet for dispensing a fluid to be treated for the first fluid chamber; and at least one eductor nozzle assembly to provide fluid communication from the first fluid chamber to the second fluid chamber, where said eductor nozzle assembly is adapted to facilitate mixing of a gas with said fluid to communicate a mixing of said fluid and said gas in the second fluid chamber. 15 Fluid treatment apparatus according to claim 1, characterized in that it additionally comprises a partition adapted to at least partially separate the first and second fluid chambers. Fluid treatment apparatus according to claim 2, characterized in that the at least one eductor nozzle assembly is adapted to extend through the partition. Fluid treatment apparatus according to any one of the preceding claims, characterized in that the at least one eductor nozzle assembly comprises a first fluid conduit 25 defining a fluid port adapted to allow fluid communication to be treated from the first fluid chamber to the first fluid conduit. Fluid treatment apparatus according to claim 4, characterized in that the fluid port of the first fluid conduit is provided at an elevated location in relation to a base region of the first fluid chamber. Fluid treatment apparatus according to claim 4 or 5, characterized in that the at least one set of 5 eductor nozzles comprises a second fluid conduit adapted to allow fluid communication of a gas from a gas source for a portion of the nozzle assembly. Fluid treatment apparatus according to claim 6, characterized in that the gas source comprises gas 10 contained within the vessel. Fluid treatment apparatus according to claim 6 or 7, characterized in that the gas source comprises gas released from the fluid being treated. Fluid treatment apparatus according to claim 6, 7 or 8, characterized in that the gas source comprises gas provided externally to the vessel. Fluid treatment apparatus according to any one of the preceding claims, characterized in that the at least one eductor nozzle assembly comprises a discharge tube defining a fluid outlet opening for the second fluid chamber. Fluid treatment apparatus according to claim 10, when dependent on any one of claims 6 to 9, characterized in that at least a part of the discharge tube is configured to facilitate mixing of fluid dispensed through the first 25 fluid and gas conduit dispensed through the second fluid conduit. Fluid treatment apparatus according to claim 10 or 11, characterized in that the discharge tube is arranged to establish rotational flow within the second chamber. Fluid treatment apparatus according to any one of the preceding claims, characterized in that it comprises a plurality of eductor nozzle assemblies. Fluid treatment apparatus according to claim 13, characterized in that at least one of the plurality of 5 sets of the eductor nozzle is adapted to be operable in a different fluid gradient within the first, different fluid chamber at least one of the plurality of eductor nozzle assemblies. Fluid treatment apparatus according to any one of the preceding claims, characterized in that it additionally comprises a passage of fluid between the first and second chambers to allow fluid communication between them. Fluid treatment apparatus according to claim 15, characterized in that the fluid passage is adapted 15 to allow fluid communication of a gas from the second fluid chamber to the first fluid chamber. 17. Fluid treatment apparatus according to claim 15 or 16, characterized in that the fluid passage extends through a partition separating the first and second chambers. 20 18. Fluid treatment apparatus according to claim 17, characterized in that the fluid passage is defined by a wall extending from a surface of the partition. 19. Fluid treatment apparatus according to claim 18, characterized in that the wall defines a portion of the wall of the first chamber. 20. Fluid treatment apparatus according to any one of the preceding claims, characterized in that it additionally comprises a dispensing assembly adapted to receive liquid that enters the first chamber via the fluid inlet. 21. Fluid treatment apparatus according to any one of the preceding claims, characterized in that it additionally comprises one or more fluid outlets to allow discharge of treated fluid or its components from the vessel. 5 22. Fluid treatment apparatus according to any one of the preceding claims, characterized in that the second fluid chamber is adapted to receive only fluid from the first fluid chamber. 23. Fluid treatment apparatus according to any one of the preceding claims, characterized in that the fluid communication being handled between the first and second fluid chambers is obtained exclusively through at least one eductor nozzle assembly. 24. Fluid treatment apparatus according to any one of the preceding claims, further characterized by the fact that it comprises a deflector arrangement positioned inside the second chamber to help minimize mixing in front of a fluid being treated. 25. Method for treating a fluid, characterized by the fact that it comprises the steps of: defining first and second fluid chambers; 20 dispensing a fluid to be treated for the first fluid chamber; flow the fluid from the first fluid chamber through at least one eductor nozzle assembly, wherein the eductor nozzle assembly facilitates the mixing of a gas with said fluid; and discharging a mixture of said fluid and said gas from at least one eductor nozzle assembly to the second fluid chamber; and treating the fluid within the second chamber by flotation separation. 26. Nozzle arrangement for distributing a fluid to be treated between a first fluid chamber and a second fluid chamber, characterized by the fact that it comprises: a first set of the eductor nozzle comprising a first fluid conduit extending between the first and the second fluid chambers, where the first fluid conduit comprises a first fluid port providing communication with the first fluid chamber; and a second eductor nozzle assembly comprising a second fluid conduit extending between the first and second fluid chambers, where the second fluid conduit comprises a second fluid port providing communication with the first fluid chamber; where the first and second fluid ports are provided at different heights with respect to a base of the first fluid chamber to facilitate the operation of the first and second eductor nozzle assemblies with different gradient bands of fluid within said first fluid chamber, and in which the first and second nozzle assemblies of the eductor are adapted to facilitate the mixing of a gas with said fluid. 27. Nozzle arrangement according to claim 26, 20 characterized in that each of the first and second eductor nozzle assemblies comprises an additional fluid conduit adapted to allow fluid communication from a gas from a gas source to a portion of the respective nozzle assembly. 28. Nozzle arrangement according to claim 26 or 27, 25 characterized in that each of the first and second eductor nozzle assemblies comprises a discharge tube defining a fluid outlet opening for the second fluid chamber. 29. Nozzle arrangement according to claim 28, characterized in that the discharge of the first and second eductor nozzle assemblies are arranged to establish rotational flow within the second chamber. 30. Nozzle arrangement according to claim 28 or 29, characterized in that at least part of the discharge tubes 5 of the first and second nozzle assemblies of the eductor are configured to facilitate mixing of fluid dispensed through the first conduit of fluid and gas dispensed through the second fluid conduit.