BRPI0815732A2 - Aldiminas compreendendo grupos hidroxila, e composições contendo aldimina - Google Patents

Aldiminas compreendendo grupos hidroxila, e composições contendo aldimina

Info

Publication number
BRPI0815732A2
BRPI0815732A2 BRPI0815732A BRPI0815732A2 BR PI0815732 A2 BRPI0815732 A2 BR PI0815732A2 BR PI0815732 A BRPI0815732 A BR PI0815732A BR PI0815732 A2 BRPI0815732 A2 BR PI0815732A2
Authority
BR
Brazil
Prior art keywords
substrate
composition
acid ester
hydrocarbon
group
Prior art date
Application number
Other languages
English (en)
Inventor
Urs Burckhardt
Original Assignee
Sika Technology Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sika Technology Ag filed Critical Sika Technology Ag
Publication of BRPI0815732A2 publication Critical patent/BRPI0815732A2/pt
Publication of BRPI0815732B1 publication Critical patent/BRPI0815732B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/02—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups
    • C07C251/04—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C251/06—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of a saturated carbon skeleton
    • C07C251/08—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of a saturated carbon skeleton being acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3212—Polyhydroxy compounds containing cycloaliphatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225—Polyamines
    • C08G18/3253—Polyamines being in latent form
    • C08G18/3256—Reaction products of polyamines with aldehydes or ketones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C08G18/4808—Mixtures of two or more polyetherdiols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
    • C08G18/5024—Polyethers having heteroatoms other than oxygen having nitrogen containing primary and/or secondary amino groups
    • C08G18/503—Polyethers having heteroatoms other than oxygen having nitrogen containing primary and/or secondary amino groups being in latent form
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633—Compounds of group C08G18/42
    • C08G18/6637—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6648—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3225 or C08G18/3271 and/or polyamines of C08G18/38
    • C08G18/6651—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3225 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3225 or polyamines of C08G18/38
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/02—Polyureas
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31605—Next to free metal
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31609—Particulate metal or metal compound-containing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Paints Or Removers (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Sealing Material Composition (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)
  • Dental Preparations (AREA)
BRPI0815732-4A 2007-08-31 2008-08-29 Aldimina, processo para preparar uma aldimina, uso, composição curável ou curada, processo para ligar ou revestir um substrato, processo para vedação e artigo BRPI0815732B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP07115440.5 2007-08-31
EP20070115440 EP2030967A1 (de) 2007-08-31 2007-08-31 Hydroxylgruppen aufweisende Aldimine und Aldimin enthaltende Zusammensetzungen
PCT/EP2008/061400 WO2009027511A1 (de) 2007-08-31 2008-08-29 Hydroxylgruppen aufweisende aldimine und aldimin enthaltende zusammensetzungen

Publications (2)

Publication Number Publication Date
BRPI0815732A2 true BRPI0815732A2 (pt) 2015-02-10
BRPI0815732B1 BRPI0815732B1 (pt) 2019-05-07

Family

ID=39008127

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0815732-4A BRPI0815732B1 (pt) 2007-08-31 2008-08-29 Aldimina, processo para preparar uma aldimina, uso, composição curável ou curada, processo para ligar ou revestir um substrato, processo para vedação e artigo

Country Status (10)

Country Link
US (1) US8455100B2 (pt)
EP (2) EP2030967A1 (pt)
JP (1) JP5658032B2 (pt)
CN (1) CN101765583B (pt)
AT (1) ATE516265T1 (pt)
BR (1) BRPI0815732B1 (pt)
DK (1) DK2200973T3 (pt)
ES (1) ES2369224T3 (pt)
RU (1) RU2457199C2 (pt)
WO (1) WO2009027511A1 (pt)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2017260A1 (de) 2007-07-16 2009-01-21 Sika Technology AG Aldimine und Aldimin enthaltende Zusammensetzungen
EP2030967A1 (de) 2007-08-31 2009-03-04 Sika Technology AG Hydroxylgruppen aufweisende Aldimine und Aldimin enthaltende Zusammensetzungen
EP2236534A1 (de) * 2009-03-31 2010-10-06 Sika Technology AG Zweistufig aushärtende Zusammensetzung enthaltend ein oberflächendesaktiviertes Polyisocyanat
EP2465843A1 (de) * 2010-12-17 2012-06-20 Sika Technology AG Polyamine mit sekundären aliphatischen Aminogruppen
EP2465842A1 (de) * 2010-12-17 2012-06-20 Sika Technology AG Amine mit sekundären aliphatischen Aminogruppen
EP2468834A1 (de) * 2010-12-23 2012-06-27 Sika Technology AG Hitzehärtende Dichtstoffzusammensetzungen mit schneller Hautbildung und hoher Zugfestigkeit
EP2592100A1 (de) * 2011-11-10 2013-05-15 Sika Technology AG Härter für epoxidharz-beschichtungen
SG11201408103XA (en) * 2012-06-06 2015-01-29 Grace W R & Co Polyurethane-based waterproofing composition for the water-proofing of concrete structures
EP2706073A1 (de) * 2012-09-11 2014-03-12 Sika Technology AG Zweikomponentige Polyurethanzusammensetzung
PL2948492T3 (pl) * 2013-01-22 2020-09-21 Sika Technology Ag Nanoszona w postaci płynnej membrana hydroizolacyjna do dachów zawierająca trialdyminę
WO2014200100A1 (ja) * 2013-06-14 2014-12-18 積水フーラー株式会社 接着剤組成物
CN103666427A (zh) * 2013-11-15 2014-03-26 西安石油大学 油田用多功能羟基酰胺的制备方法及其应用
EP3394132B1 (de) 2015-12-21 2022-11-09 Sika Technology AG Zweikomponentige polyurethanzusammensetzung
CN111247187B (zh) * 2017-10-17 2023-02-17 赢创运营有限公司 作为用于生产聚氨酯的催化剂的酮亚胺锌络合物
CN107857704B (zh) * 2017-11-21 2020-04-10 万华化学集团股份有限公司 一种制备3-氨甲基-3,5,5-三甲基环己胺的方法及用于该方法的催化剂
KR101992921B1 (ko) * 2018-12-28 2019-06-25 지혜경 폴리우레탄용 사슬 연장제 조성물
EP3838957A1 (fr) * 2019-12-19 2021-06-23 Bostik Sa Polyimines et leurs utilisations
CN112029409A (zh) * 2020-08-21 2020-12-04 东南大学 聚多巴胺混凝土疏水涂层材料及制备方法
CN114605604B (zh) * 2022-01-27 2024-03-22 北京东方雨虹防水技术股份有限公司 一种带有离子液体结构的固化剂及制备方法和应用
TWI815490B (zh) * 2022-06-02 2023-09-11 湯姆隆實業股份有限公司 立體織物結構的製備方法

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US1824676A (en) * 1928-06-25 1931-09-22 Mannich Charles Aldehyde base and process for the manufacture of same
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US3849156A (en) * 1969-01-31 1974-11-19 Union Carbide Corp Process for providing a backing on carpets
US3862879A (en) * 1973-03-12 1975-01-28 Dow Chemical Co Articles coated with air frothed polyurethane foams
DE2546536A1 (de) * 1975-10-17 1977-04-28 Bayer Ag Hochmolekulare polyamine und verfahren zu ihrer herstellung
DE3031248A1 (de) * 1980-08-19 1982-04-01 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von 3-dimethylamino-2,2-dimethylpropanal
CA1261538A (en) * 1984-07-19 1989-09-26 Ronald W. Novak Aldehyde or imine oxygen scavengers for vinyl polymerizations
DE3624924A1 (de) * 1986-07-23 1988-01-28 Basf Ag Feuchtigkeitshaertende, lagerstabile einkomponenten-polyurethansysteme und deren verwendung
EP0442583A1 (en) * 1990-02-16 1991-08-21 Dsm N.V. Powder coating based on a carboxyl-functional polyester and an epoxy-functional cross-linking agent
NL9000370A (nl) 1990-02-16 1991-09-16 Stamicarbon Hydroxyglycidylester.
US5214086A (en) * 1991-09-04 1993-05-25 Basf Corporation Coating compositions which may be ambient cured
DE4212795A1 (de) * 1992-04-16 1993-10-21 Agfa Gevaert Ag Fotografisches Aufzeichnungsmaterial
GB9602957D0 (en) * 1996-02-17 1996-04-10 Ici Plc Coating compositions
ES2227924T3 (es) * 1998-04-02 2005-04-01 Sika Schweiz Ag Prepolimeros de poliuretano conteniendo grupos amino latentes y grupos isocianato, procedimiento para su preparacion, asi como su utilizacion.
BR9917111A (pt) 1998-12-29 2001-10-23 Dow Chemical Co Processo para produzir uma espuma de poliuretano resiliente, espuma, espuma sobre um artigo de substrato e pisos ou têxteis acolchoados
CA2473437A1 (en) * 2002-01-18 2003-07-24 Sika Technology Ag Two-constituent polyurethane composition having high early strength
EP1384709A1 (de) * 2002-07-26 2004-01-28 Sika Technology AG Polyaldimine
EP1431325A1 (de) * 2002-12-17 2004-06-23 Sika Technology AG Hitze-härtbare Epoxidharzzusammensetzung mit verbesserter Tieftemperatur-Schlagzähigkeit
EP1498441A1 (de) * 2003-07-16 2005-01-19 Sika Technology AG Hitzehärtende Zusammensetzungen mit Tieftemperatur-Schlagzähigkeitsmodifikatoren
EP1524282A1 (de) * 2003-10-15 2005-04-20 Sika Technology AG Zweikomponentige Polyurethanzusammensetzung mit hoher Frühfestigkeit
US20050282989A1 (en) * 2004-06-17 2005-12-22 Rosthauser James W TDI prepolymers with improved processing characteristics
DE102005042380A1 (de) * 2005-09-06 2007-03-08 Nordson Corporation, Westlake Vorrichtung und Verfahren zum Erzeugen eines Schaummaterials
EP1772447A1 (de) 2005-09-30 2007-04-11 Sika Technology AG Aldimine mit aktivem Wasserstoff aufweisenden Reaktivgruppen sowie deren Verwendung
KR20080071132A (ko) * 2005-09-30 2008-08-01 시카 테크놀러지 아게 알디민 함유 화합물
EP2017260A1 (de) * 2007-07-16 2009-01-21 Sika Technology AG Aldimine und Aldimin enthaltende Zusammensetzungen
EP2030967A1 (de) 2007-08-31 2009-03-04 Sika Technology AG Hydroxylgruppen aufweisende Aldimine und Aldimin enthaltende Zusammensetzungen
EP2194082B1 (de) * 2008-12-02 2011-09-07 Sika Technology AG Aldimin und Aldimin enthaltende Zusammensetzung

Also Published As

Publication number Publication date
BRPI0815732B1 (pt) 2019-05-07
DK2200973T3 (da) 2011-10-03
US20100190014A1 (en) 2010-07-29
RU2010111891A (ru) 2011-10-10
EP2200973A1 (de) 2010-06-30
JP5658032B2 (ja) 2015-01-21
ES2369224T3 (es) 2011-11-28
EP2030967A1 (de) 2009-03-04
EP2200973B1 (de) 2011-07-13
WO2009027511A1 (de) 2009-03-05
ATE516265T1 (de) 2011-07-15
JP2010536937A (ja) 2010-12-02
CN101765583A (zh) 2010-06-30
CN101765583B (zh) 2014-06-04
US8455100B2 (en) 2013-06-04
RU2457199C2 (ru) 2012-07-27

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B06T Formal requirements before examination [chapter 6.20 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

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B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

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B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2595 DE 29-09-2020 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.