BRPI0700207A - processo para a co-produção de olefinas e diésteres ou diácidos partindo de gorduras insaturadas - Google Patents

processo para a co-produção de olefinas e diésteres ou diácidos partindo de gorduras insaturadas

Info

Publication number
BRPI0700207A
BRPI0700207A BRPI0700207-6A BRPI0700207A BRPI0700207A BR PI0700207 A BRPI0700207 A BR PI0700207A BR PI0700207 A BRPI0700207 A BR PI0700207A BR PI0700207 A BRPI0700207 A BR PI0700207A
Authority
BR
Brazil
Prior art keywords
introduction
separation
zone
catalyst
ethylene
Prior art date
Application number
BRPI0700207-6A
Other languages
English (en)
Inventor
Helene Olivier-Bourbigou
Christophe Vallee
Gerard Hillion
Original Assignee
Inst Francais Du Petrole
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inst Francais Du Petrole filed Critical Inst Francais Du Petrole
Publication of BRPI0700207A publication Critical patent/BRPI0700207A/pt
Publication of BRPI0700207B1 publication Critical patent/BRPI0700207B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/207—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds
    • C07C1/213—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds by splitting of esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/475—Preparation of carboxylic acid esters by splitting of carbon-to-carbon bonds and redistribution, e.g. disproportionation or migration of groups between different molecules
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PROCESSO PARA A CO-PRODUçãO DE OLEFINAS E DIéSTERES OU DIáCIDOS PARTINDO DE GORDURAS INSATURADAS. A presente invenção refere-se a produzir tanto uma fração olefínica e uma composição de diácidos ou diésteres de gorduras, onde um processo é realizado incluindo, em sucessão: a) metátese de uma gordura insaturada com etileno na presença de pelo menos um líquido iónico não-aquoso; b) separação e reciclagem do líquido iónico usado na primeira etapa; c) separação por destilação, da fração olefínica (fração A) da fração de ácido monobásico ou monoáster da gordura insaturada (fração B) formado na etapa a); d) homometátese do éster de gordura monoinsaturada ou parte ácida (fração B) que permita a co-produção de diésteres ou diácidos de gordura insaturada (fração C) e etileno que é reciclado na primeira etapa de metátese do processo; e) opcionalmente, reciclagem do líquido iónico contendo o catalisador usado na etapa d). De aplicação particular a um óleo de semente de girassol oléico, um óleo de semente de colza olélco ou a uma mistura de ésteres de mono-álcool de tais óleos, onde o processo pode produzir tanto uma fração olefínica (composta principalmente de 1-deceno) e uma composição de diásteres ou diácidos onde, em geral, mais da metade das cadeias é constituída de cadeias C~ 18~ insaturadas (principalmente compostas de 9-octadeceno-1,18-diácido ou diáster) e a reciclagem do etileno empregado.
BRPI0700207A 2006-01-24 2007-01-24 processo para a produção de tanto uma fração olefínica como uma composição de diésteres ou diácidos de gorduras insaturadas e construção para executar o referido processo BRPI0700207B1 (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0600646A FR2896498B1 (fr) 2006-01-24 2006-01-24 Procede de co-production d'olefines et de diesters ou de diacides a partir de corps gras insatures.

Publications (2)

Publication Number Publication Date
BRPI0700207A true BRPI0700207A (pt) 2007-11-06
BRPI0700207B1 BRPI0700207B1 (pt) 2016-03-29

Family

ID=37057152

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0700207A BRPI0700207B1 (pt) 2006-01-24 2007-01-24 processo para a produção de tanto uma fração olefínica como uma composição de diésteres ou diácidos de gorduras insaturadas e construção para executar o referido processo

Country Status (11)

Country Link
US (1) US7906663B2 (pt)
EP (1) EP1810960B1 (pt)
JP (1) JP5171045B2 (pt)
AT (1) ATE449058T1 (pt)
AU (1) AU2007200278B2 (pt)
BR (1) BRPI0700207B1 (pt)
CA (1) CA2573638C (pt)
DE (1) DE602007003236D1 (pt)
ES (1) ES2335707T3 (pt)
FR (1) FR2896498B1 (pt)
NO (1) NO338394B1 (pt)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BRPI0606718A2 (pt) 2005-01-10 2009-07-14 Cargill Inc vela e cera para vela contendo produtos de metátese e semelhantes a metátese
FR2896500B1 (fr) * 2006-01-24 2010-08-13 Inst Francais Du Petrole Procede de co-production d'olefines et de diesters ou de diacides par homometathese de corps gras insatures dans des liquides ioniques non-aqueux.
CN102525829B (zh) * 2006-03-07 2014-08-06 埃莱文斯可更新科学公司 含有复分解不饱和多元醇酯的组合物
EP2046908B1 (en) 2006-07-12 2017-01-11 Elevance Renewable Sciences, Inc. Hot melt adhesive compositions comprising metathesized unsaturated polyol ester wax
WO2008010961A2 (en) 2006-07-13 2008-01-24 Elevance Renewable Sciences, Inc. Synthesis of terminal alkenes from internal alkenes and ethylene via olefin metathesis
EP2076484B1 (en) 2006-10-13 2020-01-08 Elevance Renewable Sciences, Inc. Synthesis of terminal alkenes from internal alkenes via olefin metathesis
EP2076483A4 (en) * 2006-10-13 2013-12-04 Elevance Renewable Sciences METHODS FOR PRODUCING ORGANIC COMPOUNDS BY METATHESIS AND HYDROCYANATION
WO2008063322A2 (en) 2006-10-13 2008-05-29 Elevance Renewable Sciences, Inc. Metathesis methods involving hydrogenation and compositions relating to same
EP3281931A1 (en) 2006-10-13 2018-02-14 Elevance Renewable Sciences, Inc. Methods of making organic compounds by metathesis
FR2921362B1 (fr) * 2007-09-20 2012-09-21 Arkema France Procede de synthese d'acides gras omega-insatures
EP2157076A1 (de) * 2008-08-21 2010-02-24 Cognis IP Management GmbH Verfahren zur Herstellung von ungesättigten alpha, omega Dicarbonsäurediestern
FR2939331B1 (fr) * 2008-12-10 2012-08-10 Inst Francais Du Petrole Composition catalytique et procede de metathese de corps gras insature
US8389625B2 (en) * 2008-12-23 2013-03-05 Exxonmobil Research And Engineering Company Production of synthetic hydrocarbon fluids, plasticizers and synthetic lubricant base stocks from renewable feedstocks
US9051519B2 (en) 2009-10-12 2015-06-09 Elevance Renewable Sciences, Inc. Diene-selective hydrogenation of metathesis derived olefins and unsaturated esters
EP2488474B1 (en) * 2009-10-12 2017-01-25 Elevance Renewable Sciences, Inc. Methods of refining and producing fuel from natural oil feedstocks
CN103080146B (zh) 2010-08-25 2015-07-01 埃克森美孚化学专利公司 可官能化的合成的烃流体和用于生产所述烃流体的集成的方法
CN103492357A (zh) * 2011-04-20 2014-01-01 考格尼斯知识产权管理有限责任公司 制备不饱和化合物的方法
WO2014168602A2 (en) 2011-12-28 2014-10-16 Elevance Renewable Sciences, Inc. Renewable fatty acid waxes and methods of making
AU2013277107B2 (en) 2012-06-20 2018-03-08 Wilmar Trading Pte Ltd Natural oil metathesis compositions
FR2992642B1 (fr) * 2012-06-29 2015-06-19 Novance Procede de synthese d’acides insatures biosources

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2715328B1 (fr) * 1994-01-26 1996-04-12 Inst Francais Du Petrole Composition catalytique et procédé pour la disproportion des oléfines.
JP2000256218A (ja) * 1999-03-05 2000-09-19 Bayer Ag イオン性液体存在下でのメタセシス
RU2289568C2 (ru) * 2001-03-26 2006-12-20 Дау Глобал Текнолоджиз Инк. Способ метатезиса сложных эфиров ненасыщенных жирных кислот или ненасыщенных жирных кислот с низшими олефинами и композиция гетерогенного катализатора, предназначенная для способа метатезиса
FR2878246B1 (fr) 2004-11-23 2007-03-30 Inst Francais Du Petrole Procede de co-production d'olefines et d'esters par ethenolyse de corps gras insatures dans des liquides ioniques non-aqueux
FR2896500B1 (fr) 2006-01-24 2010-08-13 Inst Francais Du Petrole Procede de co-production d'olefines et de diesters ou de diacides par homometathese de corps gras insatures dans des liquides ioniques non-aqueux.

Also Published As

Publication number Publication date
AU2007200278A1 (en) 2007-08-09
US7906663B2 (en) 2011-03-15
US20070179307A1 (en) 2007-08-02
FR2896498A1 (fr) 2007-07-27
ATE449058T1 (de) 2009-12-15
AU2007200278B2 (en) 2012-04-05
DE602007003236D1 (de) 2009-12-31
FR2896498B1 (fr) 2008-08-29
CA2573638C (fr) 2014-10-07
NO20070436L (no) 2007-07-25
CA2573638A1 (fr) 2007-07-24
NO338394B1 (no) 2016-08-15
JP2007197444A (ja) 2007-08-09
EP1810960B1 (fr) 2009-11-18
JP5171045B2 (ja) 2013-03-27
EP1810960A1 (fr) 2007-07-25
BRPI0700207B1 (pt) 2016-03-29
ES2335707T3 (es) 2010-03-31

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Legal Events

Date Code Title Description
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B09X Republication of the decision to grant [chapter 9.1.3 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 24/01/2007, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 16A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2706 DE 16-11-2022 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.