BRPI0410471A - processo para a carbonilação de um dieno conjugado, ligante de difosfina bidentada, composição catalìtica, e, composição de produto de carbonilação - Google Patents
processo para a carbonilação de um dieno conjugado, ligante de difosfina bidentada, composição catalìtica, e, composição de produto de carbonilaçãoInfo
- Publication number
- BRPI0410471A BRPI0410471A BRPI0410471-4A BRPI0410471A BRPI0410471A BR PI0410471 A BRPI0410471 A BR PI0410471A BR PI0410471 A BRPI0410471 A BR PI0410471A BR PI0410471 A BRPI0410471 A BR PI0410471A
- Authority
- BR
- Brazil
- Prior art keywords
- atom
- binder
- conjugated diene
- carbonylation
- range
- Prior art date
Links
- VURFVHCLMJOLKN-UHFFFAOYSA-N diphosphane Chemical compound PP VURFVHCLMJOLKN-UHFFFAOYSA-N 0.000 title abstract 6
- 150000001993 dienes Chemical class 0.000 title abstract 4
- 239000011230 binding agent Substances 0.000 title abstract 3
- 230000003197 catalytic effect Effects 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 230000006315 carbonylation Effects 0.000 title 2
- 238000005810 carbonylation reaction Methods 0.000 title 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 2
- 125000004429 atom Chemical group 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 125000004437 phosphorous atom Chemical group 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 abstract 1
- 125000000962 organic group Chemical group 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C231/00—Preparation of carboxylic acid amides
- C07C231/12—Preparation of carboxylic acid amides by reactions not involving the formation of carboxamide groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5027—Polyphosphines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/657163—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms the ring phosphorus atom being bound to at least one carbon atom
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
"PROCESSO PARA A CARBONILAçãO DE UM DIENO CONJUGADO, LIGANTE DE DIFOSFINA BIDENTADA, COMPOSIçãO CATALìTICA, E, COMPOSIçãO DE PRODUTO DE CARBONILAçãO". Um processo para a carbonilação de um dieno conjugado, compreendendo reagir o dieno conjugado com monóxido de carbono e um co-reagente possuindo um átomo de hidrogênio móvel na presença de um sistema catalítico incluindo: (a) uma fonte de paládio; e (b) um ligante de difosfina bidentada de fórmula (II): R¬ 1¬R¬ 2¬>P¬ 1¬-R¬ 3¬ ~ m~-R-R¬ 4¬~ n~-P~ 2¬<R~ 5¬R¬ 6¬ na qual P¬ 1¬ e P¬ 2~ representam átomos de fósforo; R¬ 1~, R¬ 2¬, R¬ 5¬, e R¬ 6¬ independentemente representam radicais orgânicos iguais ou diferentes opcionalmente substituídos contendo um átomo de carbono terciário por intermédio do qual cada radical está ligado no átomo de fósforo; R¬ 3¬ e R¬ 4~ independentemente representam grupos metileno iguais ou diferentes opcionalmente substituídos; R representa um grupo orgânico compreendendo o grupo ponte bivalente C¬ 1¬-C¬ 2¬ por meio do qual R está conectado em R¬ 3¬ e R¬ 4¬, m e n independentemente representam um número natural dentro da faixa de 0 a 4, no qual a rotação ao redor da ligação entre os átomos de carbono C¬ 1¬ e C¬ 2¬ do grupo ponte é restringida por uma temperatura dentro da faixa de 0<198>C a 250<198>C, e no qual o ângulo diédrico entre o plano ocupado pela seqüência de três átomos composta de C¬ 1¬, C¬ 2¬ e o átomo diretamente ligado em C¬ 1¬ na direção de P¬ 1¬, e o plano ocupado pela seqüência de três átomos C¬ 1¬, C¬ 2¬ e o átomo diretamente ligado em C¬ 2~ na direção de P¬ 2¬ , está dentro da faixa de 0<198> a 120<198>; e (c) uma fonte de um ânion.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP03076567 | 2003-05-22 | ||
EP04251065 | 2004-02-26 | ||
PCT/EP2004/050794 WO2004103948A1 (en) | 2003-05-22 | 2004-05-13 | Process for the carbonylation of a conjugated diene |
Publications (1)
Publication Number | Publication Date |
---|---|
BRPI0410471A true BRPI0410471A (pt) | 2006-05-30 |
Family
ID=33477630
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0410471-4A BRPI0410471A (pt) | 2003-05-22 | 2004-05-13 | processo para a carbonilação de um dieno conjugado, ligante de difosfina bidentada, composição catalìtica, e, composição de produto de carbonilação |
Country Status (7)
Country | Link |
---|---|
US (1) | US20060235241A1 (pt) |
EP (1) | EP1625109A1 (pt) |
JP (1) | JP2007502315A (pt) |
KR (1) | KR20060015274A (pt) |
BR (1) | BRPI0410471A (pt) |
CA (1) | CA2526348A1 (pt) |
WO (1) | WO2004103948A1 (pt) |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1651587A1 (en) | 2003-07-03 | 2006-05-03 | Lucite International UK Limited | Process for the hydroformylation of ethylenically unsaturated compounds |
GB0403592D0 (en) * | 2004-02-18 | 2004-03-24 | Lucite Int Uk Ltd | A catalyst system |
US7265242B2 (en) * | 2004-02-26 | 2007-09-04 | Shell Oil Company | Process for the carbonylation of ethylenically or acetylenically unsaturated compounds |
GB0411951D0 (en) | 2004-05-28 | 2004-06-30 | Lucite Int Uk Ltd | Carbonylation of ester |
TW200639149A (en) * | 2005-02-11 | 2006-11-16 | Shell Int Research | Process for the preparation of a dicarboxylic acid |
CN101137611A (zh) * | 2005-02-11 | 2008-03-05 | 国际壳牌研究有限公司 | 羰基化共轭二烯为二羧酸的方法 |
WO2006084891A1 (en) * | 2005-02-11 | 2006-08-17 | Shell Internationale Research Maatschappij B.V. | Process for the carbonylation of a conjugated diene |
US20090131630A1 (en) * | 2005-02-11 | 2009-05-21 | Van Broekhoven Johannes Adrian | Process For the Preparation of a Dicarboxylic Acid |
US20080269459A1 (en) * | 2005-02-11 | 2008-10-30 | Eit Drent | Process for the Preparation of a Dicarboxylic Acid |
WO2006125801A1 (en) * | 2005-05-27 | 2006-11-30 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of adipic acid from n-pentenoic acid |
GB0516556D0 (en) | 2005-08-12 | 2005-09-21 | Lucite Int Uk Ltd | Improved catalyst system |
CA2626107C (en) * | 2005-11-17 | 2016-06-21 | Lucite International Uk Limited | Carbonylation of ethylenically unsaturated compounds |
GB0607494D0 (en) | 2006-04-13 | 2006-05-24 | Lucite Int Uk Ltd | Metal complexes |
KR101464702B1 (ko) | 2006-12-02 | 2014-11-26 | 루사이트 인터내셔널 유케이 리미티드 | 신규한 카르보닐화 리간드 및 에틸렌성 불포화 화합물의 카르보닐화에서 이들의 용도 |
GB0625518D0 (en) * | 2006-12-21 | 2007-01-31 | Lucite Int Uk Ltd | Carbonylation of conjugated dienes |
GB0713624D0 (en) * | 2007-07-13 | 2007-08-22 | Lucite Int Uk Ltd | Improved solvent for catalyst system |
GB0812297D0 (en) | 2008-07-04 | 2008-08-13 | Lucite Int Uk Ltd | Novel carbonylation ligand sand thier use of in the carbonylation of ethylenically unsaturated compounds |
FR2950349B1 (fr) * | 2009-09-18 | 2011-08-26 | Rhodia Operations | Composes organophosphores, systemes catalytiques comprenant ces composes et procede d'hydrocyanation utilisant ces systemes catalytiques |
US20120309613A1 (en) | 2009-12-15 | 2012-12-06 | Lucite International Uk Limited | Carbonylation process |
GB0921875D0 (en) | 2009-12-15 | 2010-01-27 | Lucite Int Uk Ltd | A continuous process for the carbonylation of ethylene |
GB201000078D0 (en) | 2010-01-05 | 2010-02-17 | Lucite Int Uk Ltd | Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands |
DE102010002809A1 (de) | 2010-03-12 | 2011-11-17 | Evonik Degussa Gmbh | Verfahren zur Herstellung von linearen alpha,omega-Dicarbonsäurediestern |
GB201122054D0 (en) | 2011-12-21 | 2012-02-01 | Lucite Int Uk Ltd | A continuous process for the carbonylation of ethylene |
EP3272731B1 (de) * | 2016-07-19 | 2019-05-01 | Evonik Degussa GmbH | Verfahren zur herstellung von di- oder tricarbonsäureestern durch alkoxycarbonylierung von dienen mit konjugierten doppelbindungen |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1140319B (it) * | 1981-12-04 | 1986-09-24 | Consiglio Nazionale Ricerche | Catalizzatori contenenti fosfine steroidali chirale precessi catalitici asimmetrici che li impiegano |
KR880007418A (ko) * | 1986-12-10 | 1988-08-27 | 오노 알버어스 | 공역 디엔의 선택적 카르보닐화 방법 및 이를 위한 유기 질소-함유 열기를 갖지 않는 촉매 시스템 |
US5495041A (en) * | 1995-02-22 | 1996-02-27 | Dsm N.W. | Process for the preparation of a pentenoate ester |
US6137012A (en) * | 1998-10-13 | 2000-10-24 | E. I. Du Pont De Nemours And Company | Phosphole and diphosphole ligands for catalysis |
MY127358A (en) * | 2000-03-14 | 2006-11-30 | Shell Int Research | Process for the carbonylation of ethylenically unsaturated compounds |
DE10106348A1 (de) * | 2001-02-09 | 2002-08-14 | Basf Ag | Als Katalysator oder zur Herstellung eines Katalysatorsystems geeignete Verbindung |
DE10148712A1 (de) * | 2001-10-02 | 2003-04-17 | Basf Ag | Diphosphin |
CA2476736C (en) * | 2002-02-19 | 2012-06-05 | Shell Internationale Research Maatschappij B.V. | Process for the carbonylation of an ethylenically unsaturated compound and catalyst therefore |
GB0218613D0 (en) * | 2002-08-10 | 2002-09-18 | Lucite Int Uk Ltd | Process for the carbonylation of ethylenically unsaturated compounds |
-
2004
- 2004-05-13 KR KR1020057022099A patent/KR20060015274A/ko not_active Application Discontinuation
- 2004-05-13 JP JP2006530189A patent/JP2007502315A/ja active Pending
- 2004-05-13 BR BRPI0410471-4A patent/BRPI0410471A/pt not_active IP Right Cessation
- 2004-05-13 US US10/557,309 patent/US20060235241A1/en not_active Abandoned
- 2004-05-13 EP EP04766012A patent/EP1625109A1/en not_active Withdrawn
- 2004-05-13 WO PCT/EP2004/050794 patent/WO2004103948A1/en active Search and Examination
- 2004-05-13 CA CA002526348A patent/CA2526348A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
KR20060015274A (ko) | 2006-02-16 |
US20060235241A1 (en) | 2006-10-19 |
CA2526348A1 (en) | 2004-12-02 |
WO2004103948A1 (en) | 2004-12-02 |
JP2007502315A (ja) | 2007-02-08 |
EP1625109A1 (en) | 2006-02-15 |
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Legal Events
Date | Code | Title | Description |
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B08F | Application fees: application dismissed [chapter 8.6 patent gazette] |
Free format text: REFERENTE AS 5A, 6A, 7A E 8A ANUIDADES. |
|
B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 2159 DE 22/05/2012. |