BR9909182A - Processo para extrair ácidos orgânicos a partir de um óleo cru inicial - Google Patents

Processo para extrair ácidos orgânicos a partir de um óleo cru inicial

Info

Publication number
BR9909182A
BR9909182A BR9909182-8A BR9909182A BR9909182A BR 9909182 A BR9909182 A BR 9909182A BR 9909182 A BR9909182 A BR 9909182A BR 9909182 A BR9909182 A BR 9909182A
Authority
BR
Brazil
Prior art keywords
crude oil
oil
organic acids
mixtures
formula
Prior art date
Application number
BR9909182-8A
Other languages
English (en)
Inventor
Ramesh Varadaraj
Thomas Michael Pugel
David William Savage
Original Assignee
Exxon Research Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research Engineering Co filed Critical Exxon Research Engineering Co
Publication of BR9909182A publication Critical patent/BR9909182A/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G21/00Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
    • C10G21/06Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents characterised by the solvent used
    • C10G21/12Organic compounds only
    • C10G21/20Nitrogen-containing compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G19/00Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
    • C10G19/02Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment with aqueous alkaline solutions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20Organic compounds not containing metal atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/201Impurities
    • C10G2300/202Heteroatoms content, i.e. S, N, O, P
    • C10G2300/203Naphthenic acids, TAN

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Fats And Perfumes (AREA)

Abstract

"PROCESSO PARA EXTRAIR áCIDOS ORGâNICOS A PARTIR DE UM óLEO CRU INICIAL" A invenção presente é direcionada para um processo para a extração de ácidos orgânicos a partir de um óleo cru compreendendo as etapas de: (a) tratamento do óleo cru de partida contendo ácidos naftênicos com uma quantidade de aminas alcoxiladas em água sob condições e por um tempo e a uma temperatura suficiente para formar uma emulsão água em óleo de sal de amina, onde a referida amina alcoxilada é selecionada do grupo consistindo de aminas alcoxiladas tendo a fórmula (A), onde m+n = 5 a 50 e R = grupo alquil linear ou ramificado de C~ 8~ a C~ 20~, e (B) H-(OCH~ 2~CH~ 2~)~ y~-(CH~ 2~CHCH~ 3~O)~ p~-{NHCH~ 2~CH~ 2~NH}~ x~-(CH~ 2~CH~ 2~O)~ z~(CH~ 2~CHCH~ 3~O)~ q~-H, em que x=1 a 3 e y+z=2 a 6, e, onde p+q=0 a 15, misturas da fórmula (A) e misturas da fórmula (B); onde o referido óleo cru é selecionado do grupo consistindo de óleos crus, misturas de óleos crus, e destilados de óleos crus; e (b) separação da referida emulsão da etapa (a) em uma pluralidade de camadas, onde uma dessas camadas contém um óleo cruz tratado tendo quantidades reduzidas de ácidos orgânicos; (c) recuperação da referida camada da etapa (b) contendo o referido óleo cru tratado tendo uma quantidade reduzida de ácido orgânico e camadas contendo água e sal de amina alcoxilada.
BR9909182-8A 1998-03-27 1999-03-19 Processo para extrair ácidos orgânicos a partir de um óleo cru inicial BR9909182A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/049,465 US6096196A (en) 1998-03-27 1998-03-27 Removal of naphthenic acids in crude oils and distillates
PCT/US1999/006077 WO1999050375A1 (en) 1998-03-27 1999-03-19 Removal of naphthenic acids in crude oils and distillates

Publications (1)

Publication Number Publication Date
BR9909182A true BR9909182A (pt) 2000-12-05

Family

ID=21959965

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9909182-8A BR9909182A (pt) 1998-03-27 1999-03-19 Processo para extrair ácidos orgânicos a partir de um óleo cru inicial

Country Status (14)

Country Link
US (1) US6096196A (pt)
EP (1) EP1066360B1 (pt)
JP (1) JP2002509979A (pt)
CN (1) CN1295608A (pt)
AU (1) AU745351B2 (pt)
BR (1) BR9909182A (pt)
CA (1) CA2322223A1 (pt)
DE (1) DE69900888T2 (pt)
DK (1) DK1066360T3 (pt)
ES (1) ES2172983T3 (pt)
MX (1) MX211539B (pt)
NO (1) NO325474B1 (pt)
RU (1) RU2205857C2 (pt)
WO (1) WO1999050375A1 (pt)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6531055B1 (en) 2000-04-18 2003-03-11 Exxonmobil Research And Engineering Company Method for reducing the naphthenic acid content of crude oil and fractions
GB0031337D0 (en) * 2000-12-21 2001-02-07 Bp Exploration Operating Process for deacidfying crude oil
US6454936B1 (en) 2001-03-09 2002-09-24 Exxonmobil Research And Engineering Company Removal of acids from oils
FR2825369B1 (fr) * 2001-06-01 2005-04-15 Elf Antar France Procede de traitement de petrole bruts a acidite organique elevee
CA2455011C (en) 2004-01-09 2011-04-05 Suncor Energy Inc. Bituminous froth inline steam injection processing
CA2455149C (en) * 2004-01-22 2006-04-11 Suncor Energy Inc. In-line hydrotreatment process for low tan synthetic crude oil production from oil sand
US7976562B2 (en) 2004-01-22 2011-07-12 Rex Medical, L.P. Method of removing a vein filter
US20060016723A1 (en) * 2004-07-07 2006-01-26 California Institute Of Technology Process to upgrade oil using metal oxides
US20070287876A1 (en) * 2004-12-07 2007-12-13 Ghasem Pajoumand Method of removing organic acid from light fischer-tropsch liquid
US10076401B2 (en) 2006-08-29 2018-09-18 Argon Medical Devices, Inc. Vein filter
US8013195B2 (en) * 2007-06-15 2011-09-06 Uop Llc Enhancing conversion of lignocellulosic biomass
US8158842B2 (en) * 2007-06-15 2012-04-17 Uop Llc Production of chemicals from pyrolysis oil
US7960520B2 (en) 2007-06-15 2011-06-14 Uop Llc Conversion of lignocellulosic biomass to chemicals and fuels
MY153421A (en) * 2007-06-20 2015-02-13 Akzo Nobel Nv A method for preventing the formation of calcium carboxylate deposits in the dewatering process for crude oil/water streams
US7750302B2 (en) * 2008-09-09 2010-07-06 Schlumberger Technology Corporation Method and apparatus for detecting naphthenic acids
US8329941B2 (en) * 2008-12-23 2012-12-11 Exxonmobil Research And Engineering Company Process for the extraction of high molecular weight naphthenic acids from calcium naphthenate salts
CA2663661C (en) 2009-04-22 2014-03-18 Richard A. Mcfarlane Processing of dehydrated and salty hydrocarbon feeds
CA2677004C (en) 2009-08-28 2014-06-17 Richard A. Mcfarlane A process and system for reducing acidity of hydrocarbon feeds
US20130210155A1 (en) * 2009-09-17 2013-08-15 Chandrashekhar Khandekar Methods For Selection Of A Naphthenate Solids Inhibitor And Test Kit, And Method For Precipitating Naphthenate Solids
WO2011063459A1 (en) 2009-11-26 2011-06-03 M-I Australia Pty Ltd Compositions and methods for inhibiting naphthenate solids formation from liquid hydrocarbons
US8608949B2 (en) * 2009-12-30 2013-12-17 Uop Llc Process for removing metals from vacuum gas oil
US8608952B2 (en) * 2009-12-30 2013-12-17 Uop Llc Process for de-acidifying hydrocarbons
US8608950B2 (en) * 2009-12-30 2013-12-17 Uop Llc Process for removing metals from resid
US8608943B2 (en) * 2009-12-30 2013-12-17 Uop Llc Process for removing nitrogen from vacuum gas oil
US8580107B2 (en) * 2009-12-30 2013-11-12 Uop Llc Process for removing sulfur from vacuum gas oil
US8608951B2 (en) * 2009-12-30 2013-12-17 Uop Llc Process for removing metals from crude oil
KR101898289B1 (ko) 2011-01-10 2018-09-13 에스케이이노베이션 주식회사 탄화수소류 유분 내의 유기산을 저감하는 방법
JP6072790B2 (ja) 2011-07-29 2017-02-01 サウジ アラビアン オイル カンパニー 石油精製原料中の全酸価を減少させる方法
US8574427B2 (en) 2011-12-15 2013-11-05 Uop Llc Process for removing refractory nitrogen compounds from vacuum gas oil
MY164238A (en) 2012-07-27 2017-11-30 Petroliam Nasional Berhad (Petronas) A process of desalting crude oil
US9611422B2 (en) 2014-05-29 2017-04-04 Baker Hughes Incorporated Methods of obtaining hydrocarbons using suspensions including organic bases
CN114621783B (zh) * 2022-03-25 2023-07-28 佛山市创贸新能源科技有限公司 一种原油脱水装置

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2168078A (en) * 1939-02-07 1939-08-01 Shell Dev Process for removing acid components from hydrocarbon distillates
US2424158A (en) * 1944-09-20 1947-07-15 Standard Oil Dev Co Process of refining a petroleum oil containing naphthenic acids
US3066094A (en) * 1957-02-27 1962-11-27 Exxon Research Engineering Co Recovery of hydrocarbons from spent caustic
US2878181A (en) * 1957-12-30 1959-03-17 Pure Oil Co Method of preparing neutral oils
US3176041A (en) * 1961-08-08 1965-03-30 Pure Oil Co Separation of naphthenic acids from a petroleum oil
US3186934A (en) * 1961-09-27 1965-06-01 Universal Oil Prod Co Recovery of acid oils
US4737265A (en) * 1983-12-06 1988-04-12 Exxon Research & Engineering Co. Water based demulsifier formulation and process for its use in dewatering and desalting crude hydrocarbon oils
GB8431013D0 (en) * 1984-12-07 1985-01-16 British Petroleum Co Plc Desalting crude oil
US4752381A (en) * 1987-05-18 1988-06-21 Nalco Chemical Company Upgrading petroleum and petroleum fractions
US4789460A (en) * 1987-08-10 1988-12-06 Phillips Petroleum Company Process for facilitating filtration of used lubricating oil
CA2133270C (en) * 1994-03-03 1999-07-20 Jerry J. Weers Quaternary ammonium hydroxides as mercaptan scavengers
US5961821A (en) * 1998-03-27 1999-10-05 Exxon Research And Engineering Co Removal of naphthenic acids in crude oils and distillates

Also Published As

Publication number Publication date
NO325474B1 (no) 2008-05-05
US6096196A (en) 2000-08-01
DK1066360T3 (da) 2002-04-02
EP1066360B1 (en) 2002-02-13
NO20004808D0 (no) 2000-09-26
JP2002509979A (ja) 2002-04-02
WO1999050375A1 (en) 1999-10-07
DE69900888T2 (de) 2002-06-27
AU3011899A (en) 1999-10-18
MXPA00008423A (es) 2001-03-01
AU745351B2 (en) 2002-03-21
RU2205857C2 (ru) 2003-06-10
MX211539B (en) 2001-12-21
EP1066360A1 (en) 2001-01-10
CN1295608A (zh) 2001-05-16
NO20004808L (no) 2000-11-27
ES2172983T3 (es) 2002-10-01
DE69900888D1 (de) 2002-03-21
CA2322223A1 (en) 1999-10-07

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Legal Events

Date Code Title Description
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B11B Dismissal acc. art. 36, par 1 of ipl - no reply within 90 days to fullfil the necessary requirements