BR9812306A - Sistema catalisador, solução catalisadora, e, processo para preparar um aldeìdo - Google Patents

Sistema catalisador, solução catalisadora, e, processo para preparar um aldeìdo

Info

Publication number
BR9812306A
BR9812306A BR9812306-8A BR9812306A BR9812306A BR 9812306 A BR9812306 A BR 9812306A BR 9812306 A BR9812306 A BR 9812306A BR 9812306 A BR9812306 A BR 9812306A
Authority
BR
Brazil
Prior art keywords
catalyst
villager
preparing
catalyst solution
disclosed
Prior art date
Application number
BR9812306-8A
Other languages
English (en)
Other versions
BR9812306B1 (pt
Inventor
Thomas Puckette
Ginette Elizabeth Struck
Original Assignee
Eastman Chem Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Chem Co filed Critical Eastman Chem Co
Publication of BR9812306A publication Critical patent/BR9812306A/pt
Publication of BR9812306B1 publication Critical patent/BR9812306B1/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

"SISTEMA CATALISADOR, SOLUçãO CATALISADORA, E, PROCESSO PARA PREPARAR UM ALDEìDO" São divulgados sistemas catalisadores compreendendo um ou mais metais de transição selecionados dos metais do Grupo VIII e rênio e um ou mais compostos de fluorofosfito tendo fórmula geral (I) em que R^ 1^ e R^ 2^ são radicais hidrocarbila. Além disso, são divulgadas Soluções catalisadoras compreendendo um ou mais dos compostos fluorofosfito acima, ródio e um solvente de hidroformilação, e processos de hidroformilação em que olefinas são colocadas em contato com monóxido de carbono, hidrogênio e a solução catalisadora para produzir aldeídos.
BRPI9812306-8A 1997-09-15 1998-09-02 sistema catalisador, solução catalisadora, e, processo para preparar um aldeìdo. BR9812306B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/929,687 US5840647A (en) 1997-09-15 1997-09-15 Hydroformylation process using novel phosphite-metal catalyst system
PCT/US1998/018240 WO1999013984A1 (en) 1997-09-15 1998-09-02 Hydroformylation process using novel phosphite-metal catalyst system

Publications (2)

Publication Number Publication Date
BR9812306A true BR9812306A (pt) 2000-09-05
BR9812306B1 BR9812306B1 (pt) 2009-08-11

Family

ID=25458282

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI9812306-8A BR9812306B1 (pt) 1997-09-15 1998-09-02 sistema catalisador, solução catalisadora, e, processo para preparar um aldeìdo.

Country Status (8)

Country Link
US (1) US5840647A (pt)
EP (1) EP1017494B1 (pt)
KR (1) KR100568835B1 (pt)
CN (1) CN1293941C (pt)
BR (1) BR9812306B1 (pt)
DE (1) DE69821250T2 (pt)
MY (1) MY116276A (pt)
WO (1) WO1999013984A1 (pt)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6130358A (en) * 1998-10-16 2000-10-10 Eastman Chemical Company Hydroformylation process using novel phosphite-metal catalyst system
WO2001051441A1 (en) * 2000-01-12 2001-07-19 Eastman Chemical Company Hydroformylation method for making aldehydes from sterically hindered olefins
US6693219B2 (en) 2001-06-02 2004-02-17 Eastman Chemical Company Epoxide stabilization of fluorophosphite-metal catalyst system in a hydroformylation process
US6831035B2 (en) * 2002-01-22 2004-12-14 Eastman Kodak Company Stabilization of fluorophosphite-containing catalysts
US6846960B2 (en) * 2002-09-16 2005-01-25 Eastman Chemical Company Process for reducing fluoride impurities resulting from use of fluorophosphite catalysts
US6995292B2 (en) * 2002-09-16 2006-02-07 Eastman Chemical Company Process for reducing fluoride impurities resulting from use of fluorophosphite catalysts
US7420093B2 (en) * 2006-09-29 2008-09-02 Eastman Chemical Company Process for the preparation of glycolaldehyde
US7301054B1 (en) * 2006-09-29 2007-11-27 Eastman Chemical Company Process for the preparation of glycolaldehyde
US7586010B2 (en) * 2006-12-21 2009-09-08 Eastman Chemical Company Phosphonite-containing catalysts for hydroformylation processes
KR100964099B1 (ko) 2007-09-14 2010-06-16 주식회사 엘지화학 인을 포함하는 촉매 조성물 및 이를 이용한 히드로포밀화방법
US7872157B2 (en) * 2007-12-26 2011-01-18 Eastman Chemical Company Phosphonite containing catalysts for hydroformylation processes
US7872156B2 (en) * 2007-12-26 2011-01-18 Eastman Chemical Company Fluorophosphite containing catalysts for hydroformylation processes
US7674937B2 (en) * 2008-05-28 2010-03-09 Eastman Chemical Company Hydroformylation catalysts
US20100069679A1 (en) * 2008-09-12 2010-03-18 Eastman Chemical Company Acetylene tolerant hydroformylation catalysts
FR2946649B1 (fr) * 2009-06-16 2012-04-13 Rhodia Operations Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
US7928267B1 (en) 2009-06-22 2011-04-19 Eastman Chemical Company Phosphite containing catalysts for hydroformylation processes
US8513468B2 (en) 2010-12-30 2013-08-20 Eastman Chemical Company Process for removing degradation acids from hydroformylation reactions
US8492593B2 (en) 2011-08-16 2013-07-23 Eastman Chemical Company Amido-fluorophosphite compounds and catalysts
US9550179B1 (en) 2015-09-09 2017-01-24 Eastman Chemical Company Hydroformylation catalyst
US11306112B2 (en) * 2020-02-10 2022-04-19 Guangdong Oxo Chem Ltd. Biphenyl tetradentate phosphite compound: preparation method and application thereof

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3239566A (en) * 1960-07-22 1966-03-08 Shell Oil Co Hydroformylation of olefins
US3527809A (en) * 1967-08-03 1970-09-08 Union Carbide Corp Hydroformylation process
US4595753A (en) * 1982-05-03 1986-06-17 Exxon Research And Engineering Co. Heterocycle-substituted alkyl diaryl phosphine rhodium caronyl hydride complex hydroformylation catalyst compositions
US4605781A (en) * 1985-09-03 1986-08-12 Celanese Corporation Production of 2-methylbutanal
US4642395A (en) * 1985-11-18 1987-02-10 The Dow Chemical Company Poisoning of resin supported catalyst
US4608239A (en) * 1985-12-06 1986-08-26 Eastman Kodak Company Removal of iron pentacarbonyl from gaseous streams containing carbon monoxide
US4912155A (en) * 1987-02-27 1990-03-27 Ethyl Corporation Antioxidant aromatic fluorophosphites
US4871878A (en) * 1987-08-10 1989-10-03 Eastman Kodak Company Low pressure rhodium catalyzed hydroformylation of olefins
US5059710A (en) * 1988-08-05 1991-10-22 Union Carbide Chemicals And Plastics Technology Corporation Ionic phosphites and their use in homogeneous transition metal catalyzed processes
US5332846A (en) * 1993-06-01 1994-07-26 Eastman Kodak Company Hydroformylation process using novel phosphine-rhodium catalyst system

Also Published As

Publication number Publication date
DE69821250D1 (de) 2004-02-26
BR9812306B1 (pt) 2009-08-11
KR20010023978A (ko) 2001-03-26
WO1999013984A1 (en) 1999-03-25
MY116276A (en) 2003-12-31
EP1017494A1 (en) 2000-07-12
CN1270544A (zh) 2000-10-18
CN1293941C (zh) 2007-01-10
DE69821250T2 (de) 2004-11-18
US5840647A (en) 1998-11-24
EP1017494B1 (en) 2004-01-21
KR100568835B1 (ko) 2006-04-10

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Legal Events

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B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 22/09/2009, OBSERVADAS AS CONDICOES LEGAIS.

B21A Patent or certificate of addition expired [chapter 21.1 patent gazette]

Free format text: PATENTE EXTINTA EM 22.09.2019