BR9803490A - Catalisador ·til para a hidrogenação simultânea e seletiva de diolefinas e nitrilas presentes em um estoque de alimentação de hidrocarbonetos e processos para a preparação do catalisador e para a hidrogenação simultânea e seletiva de diolefinas e nitrilas a partir de um estoque de alimentação de hidrocarbonetos. - Google Patents

Catalisador ·til para a hidrogenação simultânea e seletiva de diolefinas e nitrilas presentes em um estoque de alimentação de hidrocarbonetos e processos para a preparação do catalisador e para a hidrogenação simultânea e seletiva de diolefinas e nitrilas a partir de um estoque de alimentação de hidrocarbonetos.

Info

Publication number
BR9803490A
BR9803490A BR9803490-1A BR9803490A BR9803490A BR 9803490 A BR9803490 A BR 9803490A BR 9803490 A BR9803490 A BR 9803490A BR 9803490 A BR9803490 A BR 9803490A
Authority
BR
Brazil
Prior art keywords
diolefins
simultaneous
selective hydrogenation
catalyst
hydrocarbon feed
Prior art date
Application number
BR9803490-1A
Other languages
English (en)
Other versions
BR9803490B1 (pt
Inventor
Magdalena Ramirez De Agudelo
Djamal Djaouadi
Julia Guerra
Original Assignee
Intevep Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Intevep Sa filed Critical Intevep Sa
Publication of BR9803490A publication Critical patent/BR9803490A/pt
Publication of BR9803490B1 publication Critical patent/BR9803490B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/072—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/10—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using elemental hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
    • C07C209/48—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of nitriles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
    • C07C7/163—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/18—Carbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • C07C2529/068—Noble metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

"CATALISADOR úTIL PARA A HIDROGENAçãO SIMULTANEA E SELETIVA DE DIOLEFINAS E NITRILAS PRESENTES EM UM ESTOQUE DE ALIMENTAçãO DE HIDROCARBONETOS E PROCESSOS PARA A PREPARAçãO DO CATALISADOR E PARA A HIDROGENAçãO SIMULTANEA E SELETIVA DE DIOLEFINAS E NITRILAS A PARTIR DE UM ESTOQUE DE ALIMENTAçãO DE HIDROCARBONETOS". Um catalisador útil para a hidrogenação simultânea e seletiva de diolefinas e nitrilas presentes em um estoque de alimentação de hidrocarbonetos inclui (a) um material de suporte selecionado do grupo consistindo de óxido inorgânico, carbono, zeólito e suas misturas; e (b) uma base metálica cataliticamente ativa, incluindo pelo menos dois metais selecionados do grupo consistindo de metais do Grupo IB pelo menos parcialmente reduzidos e metais do Grupo VIII completamente reduzidos, a fase de metal ativo estando presente em uma quantidade de cerca de <242>0,03 % em peso.
BRPI9803490-1A 1997-09-19 1998-09-18 processo para a preparaÇço de um catalisador, catalisador étil para a hidrogenaÇço simultÂnea e seletiva de diolefinas e nitrilas presentes em um estoque de alimentaÇço de hidrocarbonetos, e, processo para a hidrogenaÇço simultÂnea e seletiva de diolefinas e nitrilas a partir de um estoque de alimentaÇço de hidrocarbonetos. BR9803490B1 (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/934,243 US5948942A (en) 1994-12-13 1997-09-19 Bimetallic catalyst for the simultaneous selective hydrogenation of diolefins and nitriles and method of making same

Publications (2)

Publication Number Publication Date
BR9803490A true BR9803490A (pt) 1999-12-07
BR9803490B1 BR9803490B1 (pt) 2008-11-18

Family

ID=25465225

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI9803490-1A BR9803490B1 (pt) 1997-09-19 1998-09-18 processo para a preparaÇço de um catalisador, catalisador étil para a hidrogenaÇço simultÂnea e seletiva de diolefinas e nitrilas presentes em um estoque de alimentaÇço de hidrocarbonetos, e, processo para a hidrogenaÇço simultÂnea e seletiva de diolefinas e nitrilas a partir de um estoque de alimentaÇço de hidrocarbonetos.

Country Status (3)

Country Link
US (1) US5948942A (pt)
EP (2) EP2196259A1 (pt)
BR (1) BR9803490B1 (pt)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MXPA02006446A (es) * 1999-12-28 2002-11-29 Corning Inc Composiciones de soporte de catalizador de zeolita/alumina y metodos para elaborarlas.
US6576588B2 (en) * 2000-04-07 2003-06-10 Catalytic Distillation Technologies Process for selective hydrogenation of alkynes and catalyst therefor
US6872678B2 (en) * 2000-04-11 2005-03-29 Akzo Nobel N.V. Process for activating a catalyst containing an S-containing additive
FR2850113B1 (fr) * 2003-01-22 2007-03-02 Inst Francais Du Petrole Procede d'obtention d'une charge utilisable dans une unite d'etherification
CN1261216C (zh) 2003-05-30 2006-06-28 中国石油化工股份有限公司 一种含分子筛的烃类裂化催化剂及其制备方法
US7208646B2 (en) * 2004-05-14 2007-04-24 Catalytic Distillation Technologies Selective hydrogenation of butadiene
US20060173224A1 (en) * 2005-02-01 2006-08-03 Catalytic Distillation Technologies Process and catalyst for selective hydrogenation of dienes and acetylenes
FR2949077B1 (fr) * 2009-08-17 2011-07-22 Inst Francais Du Petrole Procede de preparation d'un catalyseur supporte a base de ni et d'un metal du groupe ib pour l'hydrogenation selective d'hydrocarbures polyinsatures
FR2970881B1 (fr) * 2011-01-31 2015-03-20 IFP Energies Nouvelles Catalyseur thioresistant, procede de fabrication et utilisation en hydrogenation selective
FR3080299B1 (fr) 2018-04-18 2020-07-10 IFP Energies Nouvelles Procede de preparation d'un catalyseur bimetallique d'hydrogenation selective a base de nickel et de cuivre
FR3080298B1 (fr) * 2018-04-18 2020-07-10 IFP Energies Nouvelles Procede de preparation d’un catalyseur bimetallique a base de nickel et de cuivre pour l’hydrogenation de composes aromatiques
WO2019233961A1 (en) * 2018-06-07 2019-12-12 Bp P.L.C. Selective hydrogenation of polyunsaturates
FR3091658A1 (fr) * 2019-01-15 2020-07-17 IFP Energies Nouvelles Procédé de préparation d’un catalyseur d’hydrogénation des aromatiques comprenant une étape de formation d’un alliage de NiCu en post-imprégnation
FR3091659B1 (fr) * 2019-01-15 2023-04-14 Ifp Energies Now Procédé de préparation d’un catalyseur d’hydrogénation des aromatiques comprenant une étape de formation d’un alliage de NiCu en pré-imprégnation
FR3091660A1 (fr) * 2019-01-15 2020-07-17 IFP Energies Nouvelles Procédé de préparation d’un catalyseur d’hydrogénation sélective comprenant une étape de formation d’un alliage de NiCu en post-imprégnation
FR3091657B1 (fr) * 2019-01-15 2023-04-14 Ifp Energies Now Procédé de préparation d’un catalyseur d’hydrogénation sélective comprenant une étape de formation d’un alliage de NiCu en pré-imprégnation
FR3099388B1 (fr) 2019-07-31 2021-07-16 Ifp Energies Now Catalyseur comprenant une phase active de nickel sous forme de petites particules repartie en croute et un alliage nickel cuivre
FR3099390B1 (fr) * 2019-07-31 2021-10-29 Ifp Energies Now Catalyseur comprenant une phase active de nickel sous forme de petites particules et un alliage nickel cuivre
FR3099386B1 (fr) * 2019-07-31 2021-07-16 Ifp Energies Now Catalyseur comprenant une phase active de nickel repartie en croute et un alliage nickel cuivre

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1253947A (fr) * 1960-01-07 1961-02-17 Dow Chemical Co Catalyseurs d'hydrogénation sélective et procédé d'hydrogénation
DE1542187A1 (de) * 1965-10-20 1970-03-26 Grace W R & Co Katalysator zum Hydrokracken von Kohlenwasserstoffen
JPS4931433B1 (pt) * 1970-02-25 1974-08-21
JPS5740811B2 (pt) * 1973-05-08 1982-08-30
US3912789A (en) * 1973-12-17 1975-10-14 Dow Chemical Co Dealkynation of olefin and diolefin streams
US4152351A (en) * 1977-08-22 1979-05-01 Phillips Petroleum Company Process for the hydrogenation of olefinic unsaturation in an aliphatic dinitrile
FR2411030A1 (fr) * 1977-12-12 1979-07-06 Azote & Prod Chim Catalyseur et procede de fabrication d'amines a partir d'alcools
DE3524330A1 (de) * 1985-07-08 1987-01-08 Basf Ag Verfahren zur herstellung von katalysatoren und ihre verwendung bei hydrier- und aminierreaktionen
US4734540A (en) * 1986-12-22 1988-03-29 Uop Inc. Catalyst for the selective hydrogenation of polyunsaturated organics
NL9200281A (nl) * 1992-02-14 1993-09-01 Veg Gasinstituut Nv Werkwijze voor de reductie van stikstof-oxiden tot stikstof.
IT1254909B (it) * 1992-04-23 1995-10-11 Procedimento per la preparazione di un catalizzatore metallico supportato per l'idrogenazione selettiva di idrocarburi, catalizzatoreottenuto mediante tale procedimento e procedimento di idrogenazione selettiva di idrocarburi che utilizza tale catalizzatore.
US5523271A (en) * 1994-12-13 1996-06-04 Intevep, S.A. Catalyst for the simultaneous selective hydrogenation of diolefins and nitriles and method of making same

Also Published As

Publication number Publication date
EP0908235A3 (en) 2000-03-01
EP2196259A1 (en) 2010-06-16
EP0908235A2 (en) 1999-04-14
US5948942A (en) 1999-09-07
BR9803490B1 (pt) 2008-11-18

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Legal Events

Date Code Title Description
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]
B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time
B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)