BR9712859A - Propelente aerossol, composição azeotrópica ou do tipo azeótropo, composições binárias, processos para produção de um aerossol, de refrigeração e para preparação de uma espuma termoplástica ou termorrìgida - Google Patents
Propelente aerossol, composição azeotrópica ou do tipo azeótropo, composições binárias, processos para produção de um aerossol, de refrigeração e para preparação de uma espuma termoplástica ou termorrìgidaInfo
- Publication number
- BR9712859A BR9712859A BR9712859-7A BR9712859A BR9712859A BR 9712859 A BR9712859 A BR 9712859A BR 9712859 A BR9712859 A BR 9712859A BR 9712859 A BR9712859 A BR 9712859A
- Authority
- BR
- Brazil
- Prior art keywords
- aerosol
- azeotropic
- compositions
- agents
- thermoplastic
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 7
- 239000000443 aerosol Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 239000003380 propellant Substances 0.000 title abstract 2
- 229920001169 thermoplastic Polymers 0.000 title abstract 2
- 239000004416 thermosoftening plastic Substances 0.000 title abstract 2
- 238000001816 cooling Methods 0.000 title 1
- 239000006269 thermoset foam Substances 0.000 title 1
- 239000012530 fluid Substances 0.000 abstract 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 239000003507 refrigerant Substances 0.000 abstract 2
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 abstract 1
- NSGXIBWMJZWTPY-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropane Chemical compound FC(F)(F)CC(F)(F)F NSGXIBWMJZWTPY-UHFFFAOYSA-N 0.000 abstract 1
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 abstract 1
- GSMZLBOYBDRGBN-UHFFFAOYSA-N 2-fluoro-2-methylpropane Chemical compound CC(C)(C)F GSMZLBOYBDRGBN-UHFFFAOYSA-N 0.000 abstract 1
- PRNZBCYBKGCOFI-UHFFFAOYSA-N 2-fluoropropane Chemical compound CC(C)F PRNZBCYBKGCOFI-UHFFFAOYSA-N 0.000 abstract 1
- 239000004604 Blowing Agent Substances 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 239000012459 cleaning agent Substances 0.000 abstract 1
- 239000002274 desiccant Substances 0.000 abstract 1
- 239000003989 dielectric material Substances 0.000 abstract 1
- UHCBBWUQDAVSMS-UHFFFAOYSA-N fluoroethane Chemical compound CCF UHCBBWUQDAVSMS-UHFFFAOYSA-N 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000005498 polishing Methods 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 229920000098 polyolefin Polymers 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C19/00—Acyclic saturated compounds containing halogen atoms
- C07C19/08—Acyclic saturated compounds containing halogen atoms containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
- C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/149—Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/30—Materials not provided for elsewhere for aerosols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
- C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
- C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2207/00—Foams characterised by their intended use
- C08J2207/04—Aerosol, e.g. polyurethane foam spray
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/11—Ethers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/22—All components of a mixture being fluoro compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/32—The mixture being azeotropic
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- Physics & Mathematics (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
<B>"PROPELENTE AEROSSOL, COMPOSIçãO AZEOTRóPICA OU DO TIPO AZEóTROPO, COMPOSIçõES BINáRIAS, PROCESSOS PARA PRODUçãO DE UM AEROSSOL, DE REFRIGERAçãO E PARA PREPARAçãO DE UMA ESPUMA TERMOPLáSTICA OU TERMORRìGIDA"<D>. A presente invenção diz respeito à descorberta de composições que incluem fluoroetano, 2-fluoropropano ou terc-butilfluoreto. Estas composições são úteis como componentes puros ou com pelo menos um dentre tetrafluoroetano, difluoroetano, hexafluoropropano, um hidrocarboneto ou dimetiléter. Estas composições são úteis como propelentes de aerossol, refrigerantes, agente de limpeza, agentes de expansão para poliolefinas e poliuretanos, refrigerantes, meios de transferência de calor; dielétricos gasosos, agentes extintores de incêndio, fluidos de trabalho de ciclo de potência, meio de polimerização, fluidos de remoção de particulados, fluidos veículos, agentes abrasivos de polimento, e agentes secantes de substituição.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US2997196P | 1996-11-04 | 1996-11-04 | |
US08/943,420 US6261472B1 (en) | 1996-11-04 | 1997-10-03 | Azeotrope-like compositions containing fluoroethane |
PCT/US1997/019887 WO1998020089A2 (en) | 1996-11-04 | 1997-11-03 | Hydrofluorocarbon compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9712859A true BR9712859A (pt) | 1999-12-07 |
Family
ID=26705527
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR9712859-7A BR9712859A (pt) | 1996-11-04 | 1997-11-03 | Propelente aerossol, composição azeotrópica ou do tipo azeótropo, composições binárias, processos para produção de um aerossol, de refrigeração e para preparação de uma espuma termoplástica ou termorrìgida |
Country Status (10)
Country | Link |
---|---|
US (5) | US6261472B1 (pt) |
EP (1) | EP0938527B1 (pt) |
JP (1) | JP4130477B2 (pt) |
CN (1) | CN1181155C (pt) |
AU (1) | AU5160898A (pt) |
BR (1) | BR9712859A (pt) |
CA (2) | CA2509506C (pt) |
DE (1) | DE69714067T2 (pt) |
MY (1) | MY139234A (pt) |
WO (1) | WO1998020089A2 (pt) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6261472B1 (en) * | 1996-11-04 | 2001-07-17 | E. I. Du Pont De Nemours And Company | Azeotrope-like compositions containing fluoroethane |
KR100398093B1 (ko) * | 2000-12-20 | 2003-09-19 | 주식회사 제이오 | 냉장고/에어컨용 혼합냉매 |
HU229798B1 (en) * | 2001-03-30 | 2014-07-28 | Jagotec Ag | Medical aerosol compositions and process for their preparation |
EP1577619B1 (en) * | 2002-12-03 | 2017-04-19 | Nihon Freezer Co., Ltd. | Refrigerator system using non-azeotropic refrigerant, and non-azeotropic refrigerant for very low temperature used for the system |
CN1233780C (zh) * | 2003-01-20 | 2005-12-28 | 天津大学 | 一种中高温热泵混合工质 |
JP2008510870A (ja) * | 2004-08-25 | 2008-04-10 | ハム,ヨーンシク | R502、r12またはr22代替用の混合冷媒及びそれを用いた冷凍システム |
US7379446B2 (en) * | 2004-10-14 | 2008-05-27 | Qualcomm Incorporated | Enhanced beacon signaling method and apparatus |
US8192723B2 (en) * | 2006-03-31 | 2012-06-05 | Reckitt Benckiser (Uk) Limited | Aerosol composition |
GB0610124D0 (en) * | 2006-05-20 | 2006-06-28 | Earthcare Products Ltd | Natural alternatives to r410a refrigerant |
CN100457850C (zh) * | 2006-06-26 | 2009-02-04 | 浙江蓝天环保高科技股份有限公司 | 一种替代cfc-12的环保型制冷剂 |
JP2011513538A (ja) | 2008-02-29 | 2011-04-28 | アーケマ・インコーポレイテッド | ブロックコポリマー油リターン剤 |
US8436218B2 (en) | 2010-05-27 | 2013-05-07 | Honeywell International Inc. | Azeotrope-like composition of hexafluoropropane, hexafluoropropene and hydrogen fluoride |
KR20180089556A (ko) | 2011-10-26 | 2018-08-08 | 제이엑스티지 에네루기 가부시키가이샤 | 냉동기용 작동 유체 조성물 및 냉동기유 |
KR101909545B1 (ko) | 2012-03-27 | 2018-10-19 | 제이엑스티지 에네루기 가부시키가이샤 | 냉동기용 작동 유체 조성물 |
JP5871688B2 (ja) * | 2012-03-29 | 2016-03-01 | Jx日鉱日石エネルギー株式会社 | 冷凍機用作動流体組成物 |
CN104540888A (zh) * | 2012-08-15 | 2015-04-22 | 纳幕尔杜邦公司 | 2,3,3,4,4,4-六氟-1-丁烯和1,1,1,2,3,3-六氟丙烷的共沸和类共沸组合物及其用途 |
CN103965836B (zh) * | 2014-04-02 | 2017-04-19 | 浙江大学 | 一种用于汽车空调的环保型制冷剂及其制备方法 |
DE102014112294A1 (de) * | 2014-08-27 | 2016-03-03 | Technische Universität Dresden | Arbeitsstoffgemisch für Vorrichtungen zum Wärmetransport |
CN104974718B (zh) * | 2015-06-30 | 2018-10-23 | 太原理工大学 | 一种制冷剂及其应用 |
KR101866686B1 (ko) * | 2017-03-02 | 2018-06-11 | 박정배 | 마이크로 캡슐 기반의 자동 소화 기능을 구비한 배전반 시스템, 그리고 이를 위한 자동 소화 기능을 구비한 마이크로 캡슐 모듈 |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2411442A1 (de) * | 1974-03-11 | 1975-10-02 | Basf Ag | Verfahren zur herstellung von aliphatischen isocyanaten |
US4226976A (en) * | 1976-09-20 | 1980-10-07 | Tenneco Chemicals, Inc. | Process for the removal of vinyl chloride from polyvinyl chloride latexes and slurries with hydrocarbon compounds |
JPS5362789A (en) | 1976-11-17 | 1978-06-05 | Daikin Ind Ltd | Aerosol propellant |
JPH0730311B2 (ja) * | 1987-09-21 | 1995-04-05 | ダイキン工業株式会社 | 冷 媒 |
JPH075880B2 (ja) * | 1987-09-21 | 1995-01-25 | ダイキン工業株式会社 | 冷 媒 |
US4937398A (en) * | 1988-12-27 | 1990-06-26 | Allied-Signal Inc. | Process for the preparation of fluorinated alkanes from alkenes |
US5370811A (en) * | 1989-11-30 | 1994-12-06 | Matsushita Electric Industrial Co., Ltd. | Working fluid containing tetrafluoroethane |
US5304319A (en) * | 1989-11-30 | 1994-04-19 | Matsushita Electric Industrial Co., Ltd. | Working fluid |
ATE115994T1 (de) | 1990-07-26 | 1995-01-15 | Du Pont | Quasi-azeotrope mischungen zur verwendung als kältemittel. |
CN1029625C (zh) | 1990-12-17 | 1995-08-30 | 纳幕尔杜邦公司 | 氟化烃的恒沸组合物 |
DE4113397A1 (de) * | 1991-04-24 | 1992-10-29 | Rathor Ag | Verfahren zur wiederaufbereitung und rueckgewinnung von polyurethanpraepolymer aus rueckstaenden |
US5814674A (en) * | 1992-04-23 | 1998-09-29 | Rathor Ag | Method for processing residue-containing packages |
US5248433A (en) | 1992-04-30 | 1993-09-28 | E. I. Du Pont De Nemours And Company | Binary azeotropic mixtures of octafluoropropane and fluoroethane |
US5605882A (en) * | 1992-05-28 | 1997-02-25 | E. I. Du Pont De Nemours And Company | Azeotrope(like) compositions of pentafluorodimethyl ether and difluoromethane |
US5733472A (en) * | 1992-07-15 | 1998-03-31 | E. I. Du Pont De Nemours And Company | Compositions which include 1,1,2,2-tetrafluoroethane and fluoropropane |
US5441659A (en) | 1993-11-12 | 1995-08-15 | E. I. Du Pont De Nemours And Company | Compositions including a fluoroamine and a second component |
US5417871A (en) | 1994-03-11 | 1995-05-23 | E. I. Du Pont De Nemours And Company | Hydrofluorocarbon compositions |
GB9504955D0 (en) | 1995-03-11 | 1995-04-26 | Star Refrigeration | High efficiency refrigerant |
FR2733241B1 (fr) * | 1995-04-20 | 1997-05-30 | Atochem Elf Sa | Melanges pseudo-azeotropiques a base de difluoromethane et de pentafluorodimethylether , et leurs applications comme fluides frigorigenes |
AU7276996A (en) * | 1995-10-20 | 1997-05-15 | Beijing Inoue Qinghua Freeze Technology Co. Ltd | Refrigerant |
US6261472B1 (en) * | 1996-11-04 | 2001-07-17 | E. I. Du Pont De Nemours And Company | Azeotrope-like compositions containing fluoroethane |
-
1997
- 1997-10-03 US US08/943,420 patent/US6261472B1/en not_active Expired - Lifetime
- 1997-11-03 CN CNB971995761A patent/CN1181155C/zh not_active Expired - Fee Related
- 1997-11-03 BR BR9712859-7A patent/BR9712859A/pt not_active IP Right Cessation
- 1997-11-03 WO PCT/US1997/019887 patent/WO1998020089A2/en active IP Right Grant
- 1997-11-03 DE DE69714067T patent/DE69714067T2/de not_active Expired - Lifetime
- 1997-11-03 EP EP97946444A patent/EP0938527B1/en not_active Expired - Lifetime
- 1997-11-03 CA CA002509506A patent/CA2509506C/en not_active Expired - Fee Related
- 1997-11-03 CA CA002271666A patent/CA2271666C/en not_active Expired - Fee Related
- 1997-11-03 AU AU51608/98A patent/AU5160898A/en not_active Abandoned
- 1997-11-03 JP JP52162498A patent/JP4130477B2/ja not_active Expired - Fee Related
- 1997-11-04 MY MYPI20040269A patent/MY139234A/en unknown
-
2001
- 2001-07-09 US US09/901,239 patent/US6641752B2/en not_active Expired - Fee Related
-
2003
- 2003-04-22 US US10/420,368 patent/US6932918B2/en not_active Expired - Fee Related
-
2005
- 2005-04-12 US US11/104,082 patent/US7195718B2/en not_active Expired - Fee Related
-
2006
- 2006-10-24 US US11/585,536 patent/US7384572B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
WO1998020089A2 (en) | 1998-05-14 |
CA2509506C (en) | 2009-09-15 |
DE69714067D1 (de) | 2002-08-22 |
MY139234A (en) | 2009-09-30 |
EP0938527B1 (en) | 2002-07-17 |
JP4130477B2 (ja) | 2008-08-06 |
US20030199408A1 (en) | 2003-10-23 |
JP2002500684A (ja) | 2002-01-08 |
US7384572B2 (en) | 2008-06-10 |
CN1237197A (zh) | 1999-12-01 |
DE69714067T2 (de) | 2003-02-27 |
EP0938527A2 (en) | 1999-09-01 |
US20050178998A1 (en) | 2005-08-18 |
WO1998020089A3 (en) | 1998-09-17 |
CA2271666C (en) | 2007-02-13 |
US6641752B2 (en) | 2003-11-04 |
US20070034824A1 (en) | 2007-02-15 |
US6932918B2 (en) | 2005-08-23 |
US20010054705A1 (en) | 2001-12-27 |
AU5160898A (en) | 1998-05-29 |
CA2509506A1 (en) | 1998-05-14 |
CN1181155C (zh) | 2004-12-22 |
US7195718B2 (en) | 2007-03-27 |
CA2271666A1 (en) | 1998-05-14 |
US6261472B1 (en) | 2001-07-17 |
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