BR9007605A - Sistema de revestimento nao-pegajoso com duas sub-camadas finas,a primeira sendo polissiloxano - Google Patents

Sistema de revestimento nao-pegajoso com duas sub-camadas finas,a primeira sendo polissiloxano

Info

Publication number
BR9007605A
BR9007605A BR909007605A BR9007605A BR9007605A BR 9007605 A BR9007605 A BR 9007605A BR 909007605 A BR909007605 A BR 909007605A BR 9007605 A BR9007605 A BR 9007605A BR 9007605 A BR9007605 A BR 9007605A
Authority
BR
Brazil
Prior art keywords
polysiloxan
layers
coating system
sticky coating
thin sub
Prior art date
Application number
BR909007605A
Other languages
English (en)
Inventor
Harvey Paul Tannenbaum
Original Assignee
Du Pont
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Du Pont filed Critical Du Pont
Publication of BR9007605A publication Critical patent/BR9007605A/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/08Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
    • B05D5/083Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface involving the use of fluoropolymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/56Three layers or more
    • B05D7/57Three layers or more the last layer being a clear coat
    • B05D7/577Three layers or more the last layer being a clear coat some layers being coated "wet-on-wet", the others not
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/56Three layers or more
    • B05D7/58No clear coat specified
    • B05D7/587No clear coat specified some layers being coated "wet-on-wet", the others not
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/3405Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of organic materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2203/00Other substrates
    • B05D2203/30Other inorganic substrates, e.g. ceramics, silicon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2203/00Other substrates
    • B05D2203/30Other inorganic substrates, e.g. ceramics, silicon
    • B05D2203/35Glass
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/40Coatings comprising at least one inhomogeneous layer
    • C03C2217/43Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
    • C03C2217/44Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the composition of the continuous phase
    • C03C2217/445Organic continuous phases
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/40Coatings comprising at least one inhomogeneous layer
    • C03C2217/43Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
    • C03C2217/46Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
    • C03C2217/47Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase consisting of a specific material
    • C03C2217/475Inorganic materials
    • C03C2217/478Silica
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y10T428/2495Thickness [relative or absolute]
    • Y10T428/24967Absolute thicknesses specified
    • Y10T428/24975No layer or component greater than 5 mils thick
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/259Silicic material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31533Of polythioether
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/3154Of fluorinated addition polymer from unsaturated monomers
    • Y10T428/31544Addition polymer is perhalogenated
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31551Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31609Particulate metal or metal compound-containing
    • Y10T428/31612As silicone, silane or siloxane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31652Of asbestos
    • Y10T428/31663As siloxane, silicone or silane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31678Of metal
    • Y10T428/31692Next to addition polymer from unsaturated monomers
    • Y10T428/31699Ester, halide or nitrile of addition polymer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31721Of polyimide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Laminated Bodies (AREA)
  • Paints Or Removers (AREA)
  • Materials For Medical Uses (AREA)
BR909007605A 1989-08-21 1990-07-24 Sistema de revestimento nao-pegajoso com duas sub-camadas finas,a primeira sendo polissiloxano BR9007605A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/396,589 US5071695A (en) 1989-08-21 1989-08-21 Non-stick coating system with two thin undercoats, the first being polysiloxane
PCT/US1990/004035 WO1991002774A1 (en) 1989-08-21 1990-07-24 Non-stick coating system with two thin undercoats, the first being polysiloxane

Publications (1)

Publication Number Publication Date
BR9007605A true BR9007605A (pt) 1992-06-30

Family

ID=23567862

Family Applications (1)

Application Number Title Priority Date Filing Date
BR909007605A BR9007605A (pt) 1989-08-21 1990-07-24 Sistema de revestimento nao-pegajoso com duas sub-camadas finas,a primeira sendo polissiloxano

Country Status (11)

Country Link
US (1) US5071695A (pt)
EP (1) EP0489028B1 (pt)
JP (1) JPH05500327A (pt)
KR (1) KR927003739A (pt)
AU (1) AU6043890A (pt)
BR (1) BR9007605A (pt)
CA (1) CA2063835A1 (pt)
DE (1) DE69007622T2 (pt)
HK (1) HK81194A (pt)
WO (1) WO1991002774A1 (pt)
ZA (1) ZA906625B (pt)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5240775A (en) * 1991-09-23 1993-08-31 E. I. Du Pont De Nemours And Company Non-stick coating system with PTFE-PFA for concentration gradient
US5559398A (en) * 1991-11-28 1996-09-24 Hitachi, Ltd. Cathode ray tube and method of making the same
US5468798A (en) * 1994-02-18 1995-11-21 Whitford Corporation Basecoat for a coating system
FR2774554B1 (fr) * 1998-02-10 2000-04-28 Rhodia Chimie Sa Moules souples autoportants anti-adherents aptes au contact alimentaire et procede de fabrication
US6177655B1 (en) * 1999-12-08 2001-01-23 Premark Wb Holdings, Inc. Non-stick ceramic slow-cooker and method for making the same
US6638600B2 (en) 2001-09-14 2003-10-28 Ferro Corporation Ceramic substrate for nonstick coating
DE60232187D1 (de) 2001-12-06 2009-06-10 Jamak Fabrication Tex Llc Verbesserter scheibenwischer mit verbesserten reibungseigenschaften
US7997439B2 (en) 2003-06-06 2011-08-16 Jamak Fabrication-Tex, Llc Flexible bakeware having a multi-piece carrier system
US7282532B2 (en) 2003-06-06 2007-10-16 M Management-Tex, Ltd. Flexible bakeware
US20050193899A1 (en) * 2003-06-06 2005-09-08 Deblassie Russell T. Flexible bakeware having a clam shell carrier system
US20050247212A1 (en) * 2003-06-06 2005-11-10 Steve Meeks Flexible bakeware having an improved carrier system with tabs and attachment apertures
JP4542463B2 (ja) * 2005-04-25 2010-09-15 日立マグネットワイヤ株式会社 耐部分放電性絶縁塗料、絶縁電線、及びそれらの製造方法
US7147634B2 (en) 2005-05-12 2006-12-12 Orion Industries, Ltd. Electrosurgical electrode and method of manufacturing same
US8814861B2 (en) 2005-05-12 2014-08-26 Innovatech, Llc Electrosurgical electrode and method of manufacturing same
US7966970B2 (en) 2005-07-19 2011-06-28 M Management-Tex, Llc Dairy inflation
US8071198B2 (en) * 2006-11-17 2011-12-06 E.I. Du Pont De Nemours And Company Glass articles with adhesion and stain resistant non-stick coatings
KR101104680B1 (ko) * 2009-07-23 2012-01-13 (주) 더몰론코리아 난스틱 세라믹 코팅층을 구비한 법랑재 가열조리기구
WO2016161271A2 (en) * 2015-04-01 2016-10-06 3M Innovative Properties Company Multilayer articles comprising a release surface and methods thereof
CN107616670B (zh) * 2016-07-13 2022-09-27 佛山市顺德区美的电热电器制造有限公司 锅具及其制备方法和烹饪器具

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA887122A (en) * 1971-11-30 E.I. Du Pont De Nemours And Company Polytetrafluoroethylene organosols containing heat stable auxiliary materials
US2562118A (en) * 1950-02-09 1951-07-24 Du Pont Polytetrafluoroethylene coating compositions
DE1596801A1 (de) * 1967-01-31 1971-03-25 Bayer Ag Verfahren zur Herstellung festhaftender Schichten von Fluorkohlenstoffpolymeren auf Email- und Glasoberflaechen
US3801379A (en) * 1972-01-17 1974-04-02 Phillips Petroleum Co Hot water surface treatment of aluminum substrate
IT1009861B (it) * 1973-11-19 1976-12-20 Ici Ltd Composizioni per rivestimento
US4180609A (en) * 1975-07-11 1979-12-25 E. I. Du Pont De Nemours And Company Article coated with fluoropolymer finish with improved scratch resistance
FR2317342A1 (fr) * 1975-07-11 1977-02-04 Seb Sa Composition de revetement antiadhesif et autolubrifiant, son procede d'application, revetements et objets revetus s'y rapportant
US4123401A (en) * 1975-07-21 1978-10-31 E. I. Du Pont De Nemours And Company Finishes having improved scratch resistance prepared from compositions of fluoropolymer, mica particles or metal flake, a polymer of monoethylenically unsaturated monomers and a liquid carrier
GB1537851A (en) * 1975-07-29 1979-01-04 Ici Ltd Coating compositions
US4167605A (en) * 1975-07-29 1979-09-11 Imperial Chemical Industries Limited Article with antistick coating and composition
US4049863A (en) * 1975-07-31 1977-09-20 E. I. Du Pont De Nemours And Company Fluoropolymer primer having improved scratch resistance
US4118537A (en) * 1975-12-02 1978-10-03 E. I. Du Pont De Nemours And Company Fluorocarbon polymer coatings
JPS6021193B2 (ja) * 1976-12-14 1985-05-25 ダイキン工業株式会社 フツ素樹脂被覆用組成物
US4177320A (en) * 1976-12-10 1979-12-04 Daikin Kogyo Co., Ltd. Article coated with fluorocarbon polymer
AU507930B2 (en) * 1977-01-25 1980-03-06 Ici Ltd. Coating with polytetrafluoroethylene-polyethersulphone composition
US4183998A (en) * 1977-09-01 1980-01-15 E. I. Du Pont De Nemours And Company Craze-resistant polysiloxane resin coatings and coating compositions containing a discontinuous phase
US4252859A (en) * 1978-10-31 1981-02-24 E. I. Du Pont De Nemours And Company Fluoropolymer blend coating compositions containing copolymers of perfluorinated polyvinyl ether
US4252702A (en) * 1979-05-25 1981-02-24 E. I. Du Pont De Nemours And Company Coating composition comprising a polysiloxane resin forming precondensate, an epoxy resin, a silicone fluid, and a catalyst
US4259375A (en) * 1979-05-31 1981-03-31 E. I. Du Pont De Nemours And Company Decorative process
US4351882A (en) * 1981-01-13 1982-09-28 E. I. Du Pont De Nemours And Company Article coated with fluoropolymer finish with improved durability
US4369279A (en) * 1981-10-21 1983-01-18 E. I. Du Pont De Nemours And Company Low-temperature curing polysiloxane coating composition with fluorocarbon
US4425448A (en) * 1982-05-20 1984-01-10 E. I. Du Pont De Nemours & Co. Polytetrafluoroethylene resin with degradation retarder
DE3366454D1 (en) * 1982-07-20 1986-10-30 Hoechst Ag Primer for coatings containing fluorocarbon polymers with an amount of poly(arylene sulfide) resin, aromatic polyether sulfone resin or aromatic polyether ketone resin, and use thereof
FR2581649B1 (fr) * 1985-05-10 1987-08-28 Seb Sa Revetement antiadhesif pour support en matiere plastique, recipient culinaire comportant un tel revetement et procede d'application de ce revetement sur un support
FR2625450B1 (fr) * 1988-01-05 1992-05-07 Corning Glass Works Article muni d'un revetement anti-adherent presentant une adhesion audit substrat et une durabilite ameliorees, sa fabrication et composition mise en oeuvre

Also Published As

Publication number Publication date
EP0489028B1 (en) 1994-03-23
EP0489028A1 (en) 1992-06-10
HK81194A (en) 1994-08-19
DE69007622D1 (de) 1994-04-28
CA2063835A1 (en) 1991-02-22
WO1991002774A1 (en) 1991-03-07
DE69007622T2 (de) 1994-10-06
ZA906625B (en) 1992-04-29
AU6043890A (en) 1991-04-03
KR927003739A (ko) 1992-12-18
JPH05500327A (ja) 1993-01-28
US5071695A (en) 1991-12-10

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